E. S. Kelbysheva, T. V. Strelkova, A. V. Babaytsev, A. V. Naumkin, L. N. Telegina
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引用次数: 0
Abstract
The photochemical behavior of substituted phthalimides with carboxylate groups associated with the cymantrenyl fragment is studied by infrared spectroscopy (IR), nuclear magnetic resonance (NMR) spectroscopy, UV-visible spectroscopy, and cyclic voltammetry (CV). During the formation of hemilabile dicarbonyl chelate complexes, a sharp change in the electronic, electrochemical, and optical properties of compounds is observed. According to the dynamic light scattering (DLS) method, further irradiation of solutions of these complexes leads to the formation of previously undescribed stable nanoparticles in liquid media containing manganese in two degrees of oxidation Mn2+/Mn+ and a phthalimide fragment associated with a Cp-ring coordinated or uncoordinated with manganese(I).
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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