Russian Journal of General Chemistry最新文献_第7页

Design, Efficient One-Step Synthesis of Bromo-p-hydroxybenzamides and Herbicidal Activity Evaluation 溴对羟基苯酰胺的设计、高效一步合成及除草活性评价

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224612869

J. Wang, Y. Zhou, X. Wu, X. Zhou, Y. Sun, W. Wu, X. Wang

{"title":"Design, Efficient One-Step Synthesis of Bromo-p-hydroxybenzamides and Herbicidal Activity Evaluation","authors":"J. Wang, Y. Zhou, X. Wu, X. Zhou, Y. Sun, W. Wu, X. Wang","doi":"10.1134/S1070363224612869","DOIUrl":"10.1134/S1070363224612869","url":null,"abstract":"Discovering super-efficient herbicides with novel structures is one of the effective ways to solve the increasingly severe weed resistance problem and meet ecological requirements. In this work, a series of novel bromo-p-hydroxybenzamides were designed based on the molecular hybridization strategy, and rapidly synthesized by one-step amidation reaction, and then characterized by 1H NMR, 13C NMR and HRMS. The herbicidal activity assay indicated that most of the target compounds exhibited good-to-excellent inhibition effects on seed germination of two model plants. At a concentration of 100 mg/L, the inhibition rate of 3,5-dibromo-N-(4-bromo-3-chlorophenyl)-p-hydroxybenzamide reached up to 98 and 96% on the roots and stalks of the monocotyledonous barnyard grass (E. crus-galli), respectively. 3,5-Dibromo-N-(2-bromophenyl)-p-hydroxybenzamide showed excellent inhibitory activity on the roots and stalks of dicotyledonous rape (B. napus) at 100 mg/L, with an inhibitory rate of more than 90%. Furthermore, the concentration was reduced to 1 mg/L, the inhibitory rate of 3,5-dibromo-N-(2-bromophenyl)-p-hydroxybenzamide on the roots of B. napus was still as high as 90%. This work provides a novel molecular scaffold for the development and research of new super-efficient herbicides.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 3","pages":"644 - 653"},"PeriodicalIF":0.9,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation of Chestnut Shell Biochar Loaded with Zinc/Manganese for Effective Removal of Oxytetracycline from Aqueous Solution 载锌锰板栗壳生物炭的制备及其对土霉素的有效去除

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224612092

H. Li, Q. Liu, Z. Yang, G. Ji, X. Lu, Z. Zhang, S. Lan

{"title":"Preparation of Chestnut Shell Biochar Loaded with Zinc/Manganese for Effective Removal of Oxytetracycline from Aqueous Solution","authors":"H. Li, Q. Liu, Z. Yang, G. Ji, X. Lu, Z. Zhang, S. Lan","doi":"10.1134/S1070363224612092","DOIUrl":"10.1134/S1070363224612092","url":null,"abstract":"Abandoned biomass derived from agricultural production has been widely applied to deal with environmental challenges. This work prepared biochar modified by zinc and manganese (Zn/Mn–BC) through straightforward impregnation pyrolysis for the removal of oxytetracycline from wastewater. Characterizations, adsorption performance, reusability, and mechanisms were studied. Results showed that the Zn/Mn–BC had the highest OTC adsorption capacity (60.81 mg/g) and exhibited finer separation performance at low OTC concentrations. Notably, Zn/Mn–BC can keep a high removal rate (75.86%) of OTC after 5 cycles. The kinetic and isotherm models reveal that the adsorption process is multi-layer chemisorption. Thermodynamic data indicates that OTC adsorption by Zn/Mn–BC is an exothermic, spontaneous process with decreasing entropy. In addition, the possible mechanisms of adsorption are mainly electrostatic, hydrogen bonds, π–π stacking interactions, and especially metal oxide bonds (M–O) for OTC removal. This study not only realizes the strategy of turning waste into a treasure of chestnut shell but also provides an alternative and sustainable adsorbent for antibiotics from wastewater.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 3","pages":"580 - 592"},"PeriodicalIF":0.9,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, Characterization, and Molecular Docking Studies of Chalcone-Based Imidazole Derivatives as Potential Antioxidant Agents 查尔酮基咪唑类潜在抗氧化剂的合成、表征及分子对接研究

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363225600043

R. J. Kamel, N. A. Abdul-Rida

引用次数: 0

Microwave-Assisted Green Synthesis, In Silico Study, and Plant Growth Stimulant Activity of Novel 3-(2-Arylidenehydrazinyl)-6-chloropyridazines 新型3-（2-芳基肼基）-6-氯吡嗪的微波辅助绿色合成、硅研究及植物生长活性研究

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224613395

E. A. Ghazaryan, T. A. Gomktsyan, A. V. Karapetyan, Y. A. Gharibyan, T. K. Gharibyan, S. V. Harutyunyan, M. V. Dovlatyan, S. A. Hunanyan, A. O. Markosian, A. P. Yengoyan, A. S. Vorskanyan

引用次数: 0

Solvate Complexes of Lithium Salts with Sulfolane as Electrolytes for Advanced Energy Storage Devices 锂盐与亚砜溶剂配合物在先进储能装置中的应用

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224612432

A. A. Savvina, S. E. Mochalov, E. V. Karaseva, V. S. Kolosnitsyn

引用次数: 0

Interaction of Baclofen with Vanillin in Aqueous Acidic Medium: Kinetics, Mechanism and Computational Studies 巴氯芬与香兰素在酸性水溶液中的相互作用：动力学、机理和计算研究

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224612699

T. A. Ibrahim, E. S. H. Khaled, R. A. Mohamed, M. M. Abdel-Hafeez, S. A. Mahmoud, A. A. Abdel-Khalek

{"title":"Interaction of Baclofen with Vanillin in Aqueous Acidic Medium: Kinetics, Mechanism and Computational Studies","authors":"T. A. Ibrahim, E. S. H. Khaled, R. A. Mohamed, M. M. Abdel-Hafeez, S. A. Mahmoud, A. A. Abdel-Khalek","doi":"10.1134/S1070363224612699","DOIUrl":"10.1134/S1070363224612699","url":null,"abstract":"The reaction of vanillin (Van) with baclofen (Bac) was studied kinetically in an aqueous acidic medium. The reaction product was examined using 1H, 13C NMR and IR spectroscopy methods, in addition to ultra-performance liquid chromatography (UPLC). Moreover, the reaction was monitored spectrophotometrically, with (0.1–0.4) × 10–4 mol/dm3 of Bac, (0.5–5.0) × 10–2 mol/dm3 Van and 0.2–1.0 mol/dm3 ionic strength (I) over the temperature range of 40–60°C. The reaction is first order with respect to [Van] and [Bac], and the rate of the reaction decreases as pH increases in the range of 3.60–4.66. In addition, the effect of catalyst on the rate of the reaction was studied, and the thermodynamics activation parameters involving ∆H* and ∆S* were calculated. The rate of the reaction obeys the rate law d[Bac–Van]/dt = {k2 + (k4 + k3[H+])[Van]} × [Bac]. This experimental rate law is consistent with a mechanism in which both the protonated and unprotonated forms of Van are involved in the rate-determining step, with the protonated species being the more reactive form. Furthermore, density functional theory (DFT) was performed to search the geometries of the final product resulting from the reaction between Bac and Van. Finally, interaction region indicator (IRI) calculations were used to reveal chemical bonding and weak interaction in the coupled compound Bac–Van.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 3","pages":"620 - 629"},"PeriodicalIF":0.9,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Complexes of Nickel(II) with [(Prop-2-en(yn)-1-yl)oxy]ethanimidothioate and Their Applications 镍（II）与[（Prop-2-en(yn)-1-yl）氧]乙胺硫代酸盐配合物及其应用

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363225600833

A. Z. Zalov, K. A. Kuliev, G. M. Talybov, U. B. Abasguliyeva, N. A. Novruzova

引用次数: 0

Features of Cycloaddition Reaction Between Me2Ge=Ge: and Formaldehyde Me2Ge=Ge：与甲醛的环加成反应特征

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224611116

Jingsong Gu, Huilian Xu, Xiuhui Lu

引用次数: 0

Molecular Docking and Spectroscopic Exploring of the Binding Intermolecular between BSA with Complex of Zirconium 牛血清白蛋白与锆配合物分子间结合的分子对接与光谱探索

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363224612894

H. Dezhampanah, A. M. Moghaddam Pour

{"title":"Molecular Docking and Spectroscopic Exploring of the Binding Intermolecular between BSA with Complex of Zirconium","authors":"H. Dezhampanah, A. M. Moghaddam Pour","doi":"10.1134/S1070363224612894","DOIUrl":"10.1134/S1070363224612894","url":null,"abstract":"In this study, the mechanism of the binding interaction of Zr(CUR), a novel six-coordinate complex of zirconium with a curcumin ligand and bovine serum albumin (BSA), was elucidated via fluorescence spectroscopy, Fourier transform infrared spectroscopy and molecular modeling methods. The analysis indicated that Zr(CUR) could effectively quench the endogenous fluorescence of BSA, forming a 1 : 1 complex with a static quenching mechanism. The distance between the donor (BSA) and acceptor [Zr(CUR)] was determined to be 1.19 nm on the basis of Forester’s theory of nonradiative energy transfer. The results of the infrared absorption spectrum revealed that the secondary structure of BSA changed. The molecular docking results demonstrated that the Zr(CUR) with the minimum binding energy is at position IIIA. Furthermore, as shown by the docking study, Zr(CUR) has several hydrogen bonds and van der Waals contacts with BSA. The synchronous fluorescence and Fourier transform infrared spectroscopy data revealed that Zr(CUR) could lead to conformational changes in BSA, which could affect its biological functions.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 3","pages":"654 - 662"},"PeriodicalIF":0.9,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Exploring Antiproliferative Activity of Some Pyrazole-Bearing Heterocycles: DFT, Molecular Docking, and ADME Study 含吡唑类杂环化合物的合成及抗增殖活性研究：DFT、分子对接和ADME研究

IF 0.9 4区化学

Russian Journal of General Chemistry Pub Date : 2025-03-27 DOI: 10.1134/S1070363225600134

S. K. Ramadan, S. M. Gomha, E. A. E. El-Helw

{"title":"Synthesis and Exploring Antiproliferative Activity of Some Pyrazole-Bearing Heterocycles: DFT, Molecular Docking, and ADME Study","authors":"S. K. Ramadan, S. M. Gomha, E. A. E. El-Helw","doi":"10.1134/S1070363225600134","DOIUrl":"10.1134/S1070363225600134","url":null,"abstract":"Worldwide, millions of people are impacted by cancer. In vitro antiproliferative activity of some pyrazole-bearing N-heterocycles was tested against HCT116 and MCF7 cancer cell lines, which showed the most efficacy of pyranoquinoline and chromene. Among molecular docking simulation towards cyclin-dependent kinase-2 (CDK2) protein, pyranoquinoline had the best docking, compared to doxorubicin and roscovitine (RRC), hinting at a possible mechanism of action (interactions with common amino acids). DFT simulation displayed unprecedented insights into these compounds' electronic properties and structure-activity relationships. Pyranoquinoline had the greatest softness and the lowest energy gap, increasing its reactivity to radical surface interactions. Compounds with notable antiproliferative activity were those with high electrophilicity values. Modeling pharmacokinetics simulation also revealed the ideal drug-likeness and oral bioavailability features of compounds. This research may aid in the creation of innovative, highly effective agents used in the battle against cancer and other infections in the future.","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 3","pages":"732 - 741"},"PeriodicalIF":0.9,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0