Journal of Rubber Research最新文献

{"title":"Beyond fungicides: embracing bioformulation innovation in mitigating white root rot disease impact on rubber plantations","authors":"Imran Shabbir,&nbsp;Mui-Yun Wong,&nbsp;Zulkefly Sulaiman,&nbsp;Muhammad Shahbaz,&nbsp;Iqra Khan,&nbsp;Humaira Rizwana,&nbsp;Mohamed Soliman Elshikh,&nbsp;Muhammad Faheem Adil","doi":"10.1007/s42464-024-00289-9","DOIUrl":"10.1007/s42464-024-00289-9","url":null,"abstract":"<div><p>The white root rot (WRR) disease poses a formidable economic challenge to rubber plantations globally, with Malaysia particularly hard-hit. This disease is attributed to <i>Rigidoporus microporus</i>. This glasshouse experiment investigated the effects of a stored, peat moss-based formulation containing silicon (Si), <i>Glomus mosseae</i>, and <i>Enterobacter</i> sp. UPMSSB7 on combatting WRR and promoting the growth of rubber plants. Compared to the positive control, the experimental bioformulation significantly reduced disease incidence (<i>P</i> &lt; 0.0001), with efficacy comparable to the propiconazole fungicide. Furthermore, the bioformulation and fungicide treatments demonstrated superior disease mitigation compared to the positive control 24 weeks after <i>R. microporus</i>-inoculation. The bioformulation treatment not only reduced disease incidence and mitigated foliar and root rot symptoms, but it also resulted in a lower disease progressive curve and reduced <i>R. microporus</i> colonisation. Additionally, bioformulation significantly increased (<i>P</i> &lt; 0.001) plant growth parameters 24 weeks after <i>R. microporus</i> inoculation. These parameters included stem height, girth size, chlorophyll content, leaf area, root and shoot dry weight, root volume, total root length, and root surface area. These effects surpassed those observed in fungicide and control treatments. The Si content in shoot and root and leaf N, P, and K nutrient contents were also significantly (<i>P &lt;</i> 0.001) increased in the <i>R. microporus</i>-inoculated plants with the tested bioformulation than the fungicide and control. In the case of <i>R. microporus</i>-inoculated plants of bioformulation treatment, there was a significant (<i>P &lt;</i> 0.001) increase in the population density of <i>Enterobacter</i> sp. (1.5 × 10⁸ cfu g^− 1 soil), surpassing the levels observed in non-inoculated plants of bioformulation and inoculants with Si, with or without <i>R. microporus</i>-inoculation. Moreover, bioformulation treatments improved (<i>P &lt;</i> 0.001) root colonisation as well as spore density of <i>G. mosseae</i> after <i>R. microporus</i>-inoculation than control and fungicide. This study suggests that a peat-based bioformulation containing <i>G. mosseae</i>, <i>Enterobacter</i> sp., and Si could be an effective strategy for both enhancing plant growth and mitigating WRR in rubber plants.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 5","pages":"691 - 702"},"PeriodicalIF":1.2,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Improving the curing performance of styrene-butadiene rubber/butadiene rubber composites through the addition of silicon nitride","authors":"Amirreza Zabihi,&nbsp;Gholamreza Bozorg Panah Kharat,&nbsp;Mohammad Fasihi,&nbsp;Sajad Rasouli","doi":"10.1007/s42464-024-00288-w","DOIUrl":"10.1007/s42464-024-00288-w","url":null,"abstract":"<div><p>The objective of this research was to investigate the impact of silicon nitride (Si₃N₄) on the compression moulding process of potential passenger tyre tread compounds, which include both butadiene rubber (BR) and styrene-butadiene rubber (SBR). Understanding how Si₃N₄ influences the curing process, particularly through temperature monitoring in the mould, is crucial for optimising the vulcanisation and performance characteristics of tyre tread compounds. By examining the kinetic reaction characteristics and thermal properties, this study aims to elucidate the role of Si₃N₄ in enhancing the efficiency and effectiveness of the curing process. The obtained kinetic reaction characteristics demonstrated a decrease in the duration of optimum curing and scorch by ~ 25 and ~ 40%, respectively, by adding silicon nitride. Moreover, the rheometry analysis illustrated an increase of ~ 12% in maximum torque when 6 phr of Si₃N₄ was loaded. The Kamal–Sourour model, employed for the determination of kinetic parameters, revealed that the thermal conductivity of Si₃N₄ played a catalytic role in enhancing the curing reaction by approximately 40%, notably at 6 phr of filler. Temperature monitoring results revealed that the Si₃N₄ particles increase the heat transfer rate and thermal diffusivity by approximately 17 and 98%, respectively, during curing. This increase is also observed in the cured compound, with a notable improvement of around 17%, particularly at 6 phr of Si₃N₄. This phenomenon facilitated a uniform heat distribution within the sample during the moulding process, resulting in an accelerated vulcanisation reaction.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 5","pages":"677 - 689"},"PeriodicalIF":1.2,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142994465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Publisher Correction: Properties of vulcanised concentrated skim natural rubber latex dipped film","authors":"Nurul Hayati Yusof,&nbsp;Manroshan Singh,&nbsp;Tan Kim Song,&nbsp;Nurulhuda Abdullah,&nbsp;Fatimah Rubaizah Mohd Rasdi","doi":"10.1007/s42464-024-00287-x","DOIUrl":"10.1007/s42464-024-00287-x","url":null,"abstract":"","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 5","pages":"719 - 719"},"PeriodicalIF":1.2,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142994602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of strains and temperatures on the stress relaxation of unfilled natural rubber","authors":"Muhammad Umar Zulkefli,&nbsp;Julia Gough","doi":"10.1007/s42464-024-00284-0","DOIUrl":"10.1007/s42464-024-00284-0","url":null,"abstract":"<div><p>Many rubber-based components are required to withstand long-term stress or strain without developing excessive stress relaxation or creep. A model was implemented for simple shear which used the Boltzmann superposition principle (BSP) to predict the stress relaxation following changes in strain and the William–Landel–Ferry transformation to allow for changes in temperature. Stress relaxation was modelled as linear with the logarithmic of time with a Prony series deduced from two independent parameters. By means of small-time increments, the model can be used to model the stress relaxation under arbitrary strain and temperature histories. Stress relaxation measurements were carried out for two types of deformations: simple shear and compression. The samples were made of an unfilled natural rubber and tested under varying strains and temperatures and the results compared to the predictions of the model. The agreement was generally good, and the discrepancies are discussed. The model parameters were also used within the linear viscoelastic model in the commercial finite element analysis package ABAQUS, which enables modelling in deformation modes other than simple shear.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"28 1","pages":"87 - 103"},"PeriodicalIF":1.2,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Studying the effect of untreated and treated rice straw on different properties of carbon black filled styrene-butadiene rubber composites","authors":"Eyad Sayed Abdallah Khalaf","doi":"10.1007/s42464-024-00269-z","DOIUrl":"10.1007/s42464-024-00269-z","url":null,"abstract":"<div><p>Extensive investigations have been performed on Egyptian rice straw (RS) fibre residues to be employed as a supplementary reinforcement material in polymer composites. In this study, two identical groups based on carbon black (CB) filled styrene butadiene rubber (SBR) vulcanisates were prepared by incorporating different proportions (10–50 phr) of treated and untreated rice straw (TRS/ URS) in the SBR composites to examine their effects on some of the demanded properties in rubber applications. Maleic anhydride (MA), as a coupling agent, was added to improve the interfacial bonding between the hydrophilic RS natural fibre and the hydrophobic SBR matrix. The TRS and URS were selectively grinded through a grinding machine to obtain RS fine powder with a selective grain size distribution ranging from about 20–180 μm. Some important physico-mechanical properties of the rubber vulcanisates were studied. The prepared samples were analysed by using X- ray diffractometer (XRD) and scanning electron microscopy (SEM). The tensile strength (TS), modulus (M100) and hardness values of TRS filled composites were almost superior compared to the URS ones, and 20 phr of TRS was found to be the optimum filling in SBR vulcanisates and this was obviously revealed through all the mechanical properties results as well as in the percentage swelling findings. The SEM analysis indicates that the presence of MA increases the interfacial interaction between SBR, and the alkali treated rice straw fibres, as well it was found to be in complete agreement with the TS findings. The XRD analysis reveals that the alkaline pretreatment of RS fibres was found to yield a higher crystallinity index for the SBR vulcanisates. The results indicate the potential of using TRS as filler in the rubber industry for cost reduction and raising the environmental credentials of the product.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 4","pages":"639 - 652"},"PeriodicalIF":1.2,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effects of oil palm trunk biochar as filler on physical and mechanical properties of deproteinised and epoxidised natural rubber latex foam","authors":"Roslim Ramli,&nbsp;Ai Bao Chai,&nbsp;Shamsul Kamaruddin,&nbsp;Jee Hou Ho,&nbsp;Fatimah Rubaizah Mohd. Rasdi,&nbsp;Davide S. A. De Focatiis,&nbsp;Siew Kooi Ong,&nbsp;Robert Thomas Bachmann","doi":"10.1007/s42464-024-00283-1","DOIUrl":"10.1007/s42464-024-00283-1","url":null,"abstract":"<div><p>Oil palm trunk biochar (OPTB) serves as a flame-retardant additive aimed at enhancing the thermal stability of natural rubber (NR) latex foam. This study explores whether OPTB affects the physical and mechanical properties of specialty NR (SpNR) latex foam, specifically deproteinised NR (DPNR) latex foam and epoxidised NR (ENR) latex foam. The results indicate that the addition of OPTB up to 8 phr insignificantly increases the density of DPNR and ENR latex foams, but significantly at 16 phr and 24 phr (p &lt; 0.05). Shore F hardness also shows a significant increase with OPTB loading (p &lt; 0.05), while volume shrinkage decreases with higher OPTB loading (p &lt; 0.05), thereby enhancing foam dimensional stability. The study also found that the addition of OPTB reduced the elasticity of both DPNR and ENR latex foams, resulting in higher hysteresis loss ratios as OPTB loading increased from 8 to 16 phr and 24 phr. The highest observed hysteresis loss ratio was 0.32 in DPNR latex foam loaded with 24 phr of OPTB. Additionally, OPTB loading up to 24 phr in DPNR latex foam decreased its rebound resilience from 66 to 55% and increased its vibration-damping ratio from 0.14 to 0.24. This implies that the addition of OPTB to SpNR latex foam alters its physical and mechanical properties, making it ideal for applications requiring good vibration damping and impact absorption, such as seat cushions and headliners for vehicles.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 4","pages":"623 - 637"},"PeriodicalIF":1.2,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of talc modified by poly (glycidyl methacrylate)- block -polybutadiene- block -poly (glycidyl methacrylate) on the properties of nitrile butadiene rubber","authors":"Guangyang He,&nbsp;Qilai Wang,&nbsp;Jianjian Tian,&nbsp;Bikuan Wang,&nbsp;Xianrong Shen,&nbsp;Yixin Xiang","doi":"10.1007/s42464-024-00286-y","DOIUrl":"10.1007/s42464-024-00286-y","url":null,"abstract":"<div><p>In this study, we investigated the reinforcement of nitrile butadiene rubber (NBR) using talcum powder modified with polybutadiene (M-Talc). To achieve this, a block copolymer of poly (glycidyl methacrylate)- <i>block</i> -polybutadiene- <i>block</i> -poly (glycidyl methacrylate) (PGMA-<i>b</i>-PB-<i>b</i>-PGMA) was synthesised via reversible addition-fragmentation chain transfer (RAFT) polymerisation. The PGMA-<i>b</i>-PB-<i>b</i>-PGMA solution was then sprayed onto talc powder (Talc) and dried, yielding the modified talc (M-Talc). Both M-Talc and Talc were subsequently incorporated into NBR. The results showed that NBR composites with M-Talc exhibited a notably slower vulcanisation rate compared to those with unmodified Talc. Additionally, M-Talc demonstrated improved dispersion within the NBR matrix. The mechanical properties of NBR/M-Talc composites were significantly enhanced, with a 30% increase in tensile strength, a 17% improvement in tear strength, and an impressive 757% boost in elongation at break. Furthermore, there was a substantial 37% reduction in the compression set.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 5","pages":"663 - 675"},"PeriodicalIF":1.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142995672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rheological simulation of bituminous mixes with crumb rubber by the dry process","authors":"Fayssal Cheriet,&nbsp;Alan Carter,&nbsp;Smail Haddadi","doi":"10.1007/s42464-024-00285-z","DOIUrl":"10.1007/s42464-024-00285-z","url":null,"abstract":"<div><p>There is compelling evidence supporting the benefits of incorporating crumb rubber to enhance the properties of bituminous mixes. The main aim of this paper is to investigate the effect of crumb rubber on the rheological properties of bituminous mixes using the dry method. A comparison was made in terms of linear viscoelastic behaviour, between five mixtures including the control mixture and four mixtures modified with 1% or 2% crumb rubber added and the various bitumen content. This modification was conducted to replace a portion (volume) of the aggregate with an equivalent volume of crumb rubber. Complex modulus tests on cylindrical specimens were carried out for each mixture by the tension–compression method. The complex modulus tests were carried out over a wide range of frequencies (from 0.01 to 10 Hz) and temperatures (− 25 to 45 °C). The specimens are obtained by sawing laboratory specimens in accordance with a gyratory compactor with an air voids content of not more than 1%. The results are modelled and calibrated with the 2S2P1D rheological model. All mixtures have similar rheological behaviour and respect the specification of a BB 0/15, with a modulus values (15 °C, 10 Hz) is greater at 7000 MPa.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"28 1","pages":"119 - 127"},"PeriodicalIF":1.2,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and optimisation of ENR-CR-HNBR ternary elastomeric blend and composites with hybrid CB-silica fillers for hard rubber mountings","authors":"S Vishnu,&nbsp;B Prabu,&nbsp;M Pugazhvadivu","doi":"10.1007/s42464-024-00280-4","DOIUrl":"10.1007/s42464-024-00280-4","url":null,"abstract":"<div><p>The present work focuses on developing a novel composite using a ternary elastomeric blend of epoxidised natural rubber/chloroprene rubber/hydrogenated nitrile-butadiene rubber(ENR/CR/HNBR- ECH) with hybrid fillers in different proportions, aiming to partially replace conventional filler of carbon black with silica as a cheaper alternative to suitable for hard rubber mountings. The work has two parts, the first part deals with determination of optimum blends of ternary elastomers namely ENR, CR and HNBR using a simplex centroid mixture design model. Seven samples are prepared and tested for their mechanical properties using which the optimum combination is determined by adopting Grey Relation Analysis (GRA)-based Response Surface Methodology (RSM) approach and benchmarked using GRA based Kriging-GA surrogate optimisation. The confirmed optimum combination of ECH blend is 33.34/53.33/13.33 phr. Hence in the second part, this optimum blend is taken as the base matrix for developing novel hybrid filled ECH composites by varying the filler contents of CB and silica. Thirteen composites are fabricated following a Face Centered Central Composite (CCF) design and tested for mechanical properties. The optimisation of hybrid filler content is carried out following the same numerical techniques used for optimum blend determination. The optimum filler combination obtained is verified experimentally. Furthermore, these experimental studies are supported with morphological and ATR spectroscopic studies.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"28 1","pages":"51 - 69"},"PeriodicalIF":1.2,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Application of bio-based vegetable oils as processing aids in industrial natural rubber composites","authors":"Hu Li,&nbsp;Xiaoqing Wang,&nbsp;Zhen Guo,&nbsp;Zhenfeng Li,&nbsp;Wenmin Wang,&nbsp;Peng Fu,&nbsp;Xiucheng Fu","doi":"10.1007/s42464-024-00282-2","DOIUrl":"10.1007/s42464-024-00282-2","url":null,"abstract":"<div><p>Rubber composites based on vegetable oils are being increasingly developed as these materials significantly reduce the use of petroleum-based carcinogenic oils as plasticisers in rubber products. Apart from renewability, vegetable oils have some functional groups such as polar group, double bond and long alkyl chain, which could make rubber performance more comprehensive, making processing oil from petroleum-based “one agent for one function” to bio-based “one agent for multiple functions”. In this work, we selected one bio-based vegetable oil (FN-B17) as green processing aid for nature rubber (NR) composites and petroleum-based oils (PB-1,2,3,4,5) were also chosen to be investigated for comparison. The plasticisation effects of FN-B17 and other plasticisers on composites were systematically studied. In specific, Mooney viscosity, processing properties and cross-linking characteristics of composites with various kinds of oils were characterised while the mechanical properties and RPA dynamic behaviors were also evaluated. The results indicated that the performance of bio-based oil on processing and mechanical properties of NR composites are similar or even better than that of petroleum-based oils, whereas bio-based oil is renewable with lower cost, which would be cost-effective green processing oil that could replace petroleum-based oil for NR composites. Soon, the trend of utilising bio-based oil may bring considerable advancements in the performance of filled rubber composites in an environmentally acceptable and sustainable manner.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 4","pages":"615 - 622"},"PeriodicalIF":1.2,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}