Journal of Power Sources Advances最新文献

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In situ polymerized poly(1,3-dioxolane) in polyacrylonitrile porous scaffolds: A novel composite polymer electrolyte for room temperature battery application 聚丙烯腈多孔支架中的原位聚合聚(1,3-二氧戊环):用于室温电池的新型复合聚合物电解质
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-02-09 DOI: 10.1016/j.powera.2024.100140
Nicolò Albanelli , Francesco Capodarca , Michele Zanoni , Giampaolo Lacarbonara , Maria Letizia Focarete , Chiara Gualandi , Catia Arbizzani
{"title":"In situ polymerized poly(1,3-dioxolane) in polyacrylonitrile porous scaffolds: A novel composite polymer electrolyte for room temperature battery application","authors":"Nicolò Albanelli ,&nbsp;Francesco Capodarca ,&nbsp;Michele Zanoni ,&nbsp;Giampaolo Lacarbonara ,&nbsp;Maria Letizia Focarete ,&nbsp;Chiara Gualandi ,&nbsp;Catia Arbizzani","doi":"10.1016/j.powera.2024.100140","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100140","url":null,"abstract":"<div><p>The need for high-energy and safe batteries is more and more urgent, and a possible approach is to use solid polymer electrolyte with high conductivity combined with lithium metal anode. Poly (1,3-dioxolane)-based electrolytes are promising, and the feasibility to polymerize 1,3-dioxolane (DOL) in situ makes this approach very attractive. In this paper, we present the in situ electro-initiated polymerization of DOL in polyacrylonitrile nanofibrous mats, without using initiator or crosslinking agents. The amount of monomer loaded in the porous scaffold, the electrochemical technique used to initiate the polymerization and the salt amount were investigated as important parameters that affect the ion conductivity and the performance of the obtained polymer electrolyte. Particular attention was directed towards minimizing the presence of residual monomer in the resulting polymer, with the aim of progressing towards the development of a real solid-state polymer electrolyte. The results of the thermal, morphological, and electrochemical characterization are reported and discussed.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100140"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000064/pdfft?md5=92e513ea4e52103b208c94749199c4dd&pid=1-s2.0-S2666248524000064-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139719457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Vapor-transport-deposited Sb2S3 thin-film solar cells: Tailoring photovoltaic properties through deposition temperature 气相传输沉积 Sb2S3 薄膜太阳能电池:通过沉积温度调整光伏特性
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-03-11 DOI: 10.1016/j.powera.2024.100143
Indu Sharma, Pravin S. Pawar, Rahul K. Yadav, Yong Tae Kim, Neha Bisht, Parag R. Patil, Jaeyeong Heo
{"title":"Vapor-transport-deposited Sb2S3 thin-film solar cells: Tailoring photovoltaic properties through deposition temperature","authors":"Indu Sharma,&nbsp;Pravin S. Pawar,&nbsp;Rahul K. Yadav,&nbsp;Yong Tae Kim,&nbsp;Neha Bisht,&nbsp;Parag R. Patil,&nbsp;Jaeyeong Heo","doi":"10.1016/j.powera.2024.100143","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100143","url":null,"abstract":"<div><p>Crystal orientation plays a crucial role in the performance of Sb<sub>2</sub>S<sub>3</sub> thin-film solar cells (TFSCs). Among various deposition techniques, vapor transport deposition (VTD) stands out as a viable technique for producing scalable and uniformly deposited thin films, particularly in the solar industry. This study explores temperature-modulated VTD-Sb<sub>2</sub>S<sub>3</sub> deposition to enable efficient carrier transport in photovoltaic cells. In the VTD process, the deposition temperature is altered between 480 °C and 540 °C. XRD, SEM, EDS, and AFM techniques are employed to obtain the characteristics of the Sb<sub>2</sub>S<sub>3</sub> thin films at varying temperatures and evaluate critical features like crystal structure and orientation, surface morphology, composition, and roughness. The prominent crystal orientation changes from the (hk0) to the (hk1) plane after increasing the deposition temperature from 500 to 520 °C. The (211)- and (221)-planes become more prominent when the deposition temperature exceeds 520 °C. The device with the architecture SLG/Mo/Sb<sub>2</sub>S<sub>3</sub>/CdS/i-ZnO/AZO/Al, a substrate-configured TFSC, yields a maximum power conversion efficiency of 0.22% when the VTD-Sb<sub>2</sub>S<sub>3</sub> absorber film is deposited at 520 °C. This study presents a promising approach to producing thin films with a preference for specific crystal orientations. The primary aim is to enhance the efficiency of solar cells that utilize VTD-Sb<sub>2</sub>S<sub>3</sub> absorbers.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100143"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266624852400009X/pdfft?md5=e911d88fb29d749a4a2d6c0d9abdd3d9&pid=1-s2.0-S266624852400009X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140104026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of carbon content on the ionic and electronic conductivities of dense Na3V2(PO4)3/C composites 碳含量对致密 Na3V2(PO4)3/C 复合材料离子导电率和电子导电率的影响
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-03-07 DOI: 10.1016/j.powera.2024.100144
Pradhyun Veerapanaicker Soundaraj , Enkhtsetseg Dashjav , Daniel Grüner , Stephan Prünte , Christian Dellen , Frank Tietz
{"title":"Influence of carbon content on the ionic and electronic conductivities of dense Na3V2(PO4)3/C composites","authors":"Pradhyun Veerapanaicker Soundaraj ,&nbsp;Enkhtsetseg Dashjav ,&nbsp;Daniel Grüner ,&nbsp;Stephan Prünte ,&nbsp;Christian Dellen ,&nbsp;Frank Tietz","doi":"10.1016/j.powera.2024.100144","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100144","url":null,"abstract":"<div><p>Sodium vanadium triphosphate (Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>, NVP) is a promising cathode material for Na-ion batteries. Due to its intrinsically low electronic conductivity, it is usually mixed or coated with carbon. However, so far there have been no systematic studies on the ionic and electronic conductivity of carbon-coated NVP particles. In this work, NVP with varying carbon contents are prepared. The powders are sintered as single pellets or sandwiched between a solid electrolyte for measurements in an ion blocking and non-ion blocking configuration. In these two different configurations, two different electrodes are attached and several electrochemical characterization techniques are applied such as impedance spectroscopy, chronoamperometry, and four-point measurements. The NVP/C composites with carbon content &gt;0.1 wt% show a high degree of densification and an amorphous carbon network. The conductivity of NVP in composites with carbon content &lt;0.1 wt% shows dominating ionic conduction with an average value of ∼2 × 10<sup>−6</sup> S cm<sup>−1</sup>. NVP/C samples with carbon contents &gt;0.1 wt% show a dominance of electronic conduction in the range of 0.01–0.2 mS cm<sup>−1</sup> because of the percolated carbon network at the grain boundaries. The ionic conductivity, however, remains almost constant in the same order of magnitude (∼6 × 10<sup>−6</sup> S cm<sup>−1</sup>).</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100144"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000106/pdfft?md5=e304c80bc594d37d5b3ef9ddad21d7ac&pid=1-s2.0-S2666248524000106-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140063221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Field performance analysis of solar cell designs 太阳能电池设计的现场性能分析
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-03-13 DOI: 10.1016/j.powera.2024.100145
Sungho Hwang , Dongchul Suh , Yoonmook Kang
{"title":"Field performance analysis of solar cell designs","authors":"Sungho Hwang ,&nbsp;Dongchul Suh ,&nbsp;Yoonmook Kang","doi":"10.1016/j.powera.2024.100145","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100145","url":null,"abstract":"<div><p>This study analyzes the field performance of various solar cell designs. Most research and development efforts concerning solar cells aim to increase their efficiency or power under standard test conditions (STC). However, conducting an actual field performance analysis is crucial because of the various ambient conditions present in the field, including temperature, irradiance, PV system installation, and albedo. These conditions can result in different performance results compared to STC. This study compares and analyzes case studies to assess field performance. One particular case study compares the field performance of monofacial modules with a monofacial passivated emitter and rear cell (PERC) and bifacial PERC at a carport system in the ambient conditions of the Korean Peninsula during summer and winter. The module material properties (white EVA and white backsheet) can impact module performance owing to the transmittance spectra at longer wavelengths. Certain transmittance values also contribute to the bifaciality number. Although the monofacial cell demonstrates better STC results, the field performance of the bifacial cell is superior in terms of energy yield and cost-effectiveness. Therefore, this study highlights the importance of considering the field performance (energy yield), in addition to STC, when designing solar cells and modules.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100145"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000118/pdfft?md5=786090fbb89d83e7b34e3dfaee453a7f&pid=1-s2.0-S2666248524000118-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140113423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the joint dynamics of potentials and currents in porous electrodes: Model reduction 多孔电极中电位和电流的联合动力学:模型还原
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-02-29 DOI: 10.1016/j.powera.2024.100138
Keivan Haghverdi , Dmitri L. Danilov , Grietus Mulder , Luis D. Couto , Rüdiger-A. Eichel
{"title":"On the joint dynamics of potentials and currents in porous electrodes: Model reduction","authors":"Keivan Haghverdi ,&nbsp;Dmitri L. Danilov ,&nbsp;Grietus Mulder ,&nbsp;Luis D. Couto ,&nbsp;Rüdiger-A. Eichel","doi":"10.1016/j.powera.2024.100138","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100138","url":null,"abstract":"<div><p>The dynamic behavior of potentials and currents in porous electrodes is crucial for optimizing the computational speed of lithium-ion battery models. Pseudo-two-dimensional (P2D) models, based on partial differential equations, offer insight but pose computational challenges. P2D equations are tackled with iterative algorithms, like the Newton or the shooting method. Yet, initiating the algorithm with random guesses for solid and electrolyte potentials can cause diverging ionic current values inside the electrolyte phase, increasing the computation time required to converge to the final solution. This study proposes a novel model order reduction using a galvanic pseudo-potential to prevent the occurrence of diverging currents. By sidestepping infinite values for ionic current inside the electrolyte phase, the method streamlines math and speeds up the shooting method used for solving battery model equations.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100138"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000040/pdfft?md5=e0650646599be2165804b4eae6208c8c&pid=1-s2.0-S2666248524000040-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139993480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel approach for modelling voltage hysteresis in lithium-ion batteries demonstrated for silicon graphite anodes: Comparative evaluation against established Preisach and Plett model 硅石墨负极锂离子电池电压滞后建模新方法:与已建立的 Preisach 和 Plett 模型的比较评估
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-04-01 Epub Date: 2024-02-08 DOI: 10.1016/j.powera.2024.100139
Jakob Schmitt, Ivo Horstkötter, Bernard Bäker
{"title":"A novel approach for modelling voltage hysteresis in lithium-ion batteries demonstrated for silicon graphite anodes: Comparative evaluation against established Preisach and Plett model","authors":"Jakob Schmitt,&nbsp;Ivo Horstkötter,&nbsp;Bernard Bäker","doi":"10.1016/j.powera.2024.100139","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100139","url":null,"abstract":"<div><p>Lithium-ion batteries with silicon-graphite composite anodes feature an asymmetric and direction-dependent voltage hysteresis. Upon comparing established hysteresis models from literature, it was found that a separate modelling of charge and discharge direction is required for both the operator-based Preisach model and the differential equation-based one-state model, often referred to as Plett model. This paper presents the first bidirectional implementation of the one-state hysteresis model based on extensive measurements of first-order reversal branches of a <em>Si</em>/<em>C</em> NMC cell. The approach accounts for directionality but cannot deal with the complexity of the hysteresis traverses, so an extension of the Preisach model is discussed and found to be infeasible. This justifies the development of a novel hysteresis model, the trajectory correction hysteresis (TCH) model, that fulfils the identified requirements for bidirectionality, closed-loop property and direct data fit and can be generally applied to any cell chemistry. The TCH model considers the traverse starting point, which allows for the unambiguous definition of hysteresis states and enables the simulation of complex trajectories due to two correction mechanisms. The static and dynamic current profiles in complex hysteresis scenarios demonstrate superior performance with 4.5 mV mae compared to Preisach (19.6 mV mae) and Plett (11.7 mV mae) models.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"26 ","pages":"Article 100139"},"PeriodicalIF":4.5,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000052/pdfft?md5=a12cad96f18322b34cb9fd4305271905&pid=1-s2.0-S2666248524000052-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139710197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MgO coated P2-Na0.67Mn0.75Ni0.25O2 layered oxide cathode for Na-Ion batteries 用于钠离子电池的氧化镁涂层 P2-Na0.67Mn0.75Ni0.25O2 层状氧化物阴极
IF 4.5
Journal of Power Sources Advances Pub Date : 2024-01-01 Epub Date: 2024-01-14 DOI: 10.1016/j.powera.2024.100135
Cornelius Gauckler , Gints Kucinskis , Lukas Fridolin Pfeiffer , Abdelaziz A. Abdellatif , Yushu Tang , Christian Kübel , Fabio Maroni , Ruihao Gong , Margret Wohlfahrt-Mehrens , Peter Axmann , Mario Marinaro
{"title":"MgO coated P2-Na0.67Mn0.75Ni0.25O2 layered oxide cathode for Na-Ion batteries","authors":"Cornelius Gauckler ,&nbsp;Gints Kucinskis ,&nbsp;Lukas Fridolin Pfeiffer ,&nbsp;Abdelaziz A. Abdellatif ,&nbsp;Yushu Tang ,&nbsp;Christian Kübel ,&nbsp;Fabio Maroni ,&nbsp;Ruihao Gong ,&nbsp;Margret Wohlfahrt-Mehrens ,&nbsp;Peter Axmann ,&nbsp;Mario Marinaro","doi":"10.1016/j.powera.2024.100135","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100135","url":null,"abstract":"<div><p>In this study, we propose an effective strategy to improve the electrochemical performance of a P2-Na<sub>0.67</sub>Mn<sub>0.75</sub>Ni<sub>0.25</sub>O<sub>2</sub> (P2-MNO) cathode material for Na-ion batteries based on MgO surface coating. The MgO coating, with a thickness of ∼20–50 nm, is obtained by means of a facile wet-chemistry approach followed by heat treatment carried out at comparatively low temperatures (400–500 °C) in order to avoid possible Mg doping in the bulk of the P2-MNO. Detailed electrochemical investigations demonstrate improved electrochemical performance of the MgO-coated material (M-P2-MNO) in comparison to pristine bare one at both room and elevated (40 °C) temperatures. <em>Operando</em> differential electrochemical mass spectroscopy (DEMS) demonstrate that the MgO coating is effective in suppressing unwanted gas evolution due to side reactions thus stabilizing the cathode/electrolyte interface.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"25 ","pages":"Article 100135"},"PeriodicalIF":4.5,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000015/pdfft?md5=cc187801898b4e554c910f6ef3bafceb&pid=1-s2.0-S2666248524000015-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139467759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries 用于低温锂离子电池的独立SnSe@C纳米纤维负极材料
IF 4.5
Journal of Power Sources Advances Pub Date : 2023-10-01 Epub Date: 2023-09-27 DOI: 10.1016/j.powera.2023.100128
Aiym Rakhmetova , Ayaulym Belgibayeva , Gulnur Kalimuldina , Arailym Nurpeissova , Zhumabay Bakenov
{"title":"Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries","authors":"Aiym Rakhmetova ,&nbsp;Ayaulym Belgibayeva ,&nbsp;Gulnur Kalimuldina ,&nbsp;Arailym Nurpeissova ,&nbsp;Zhumabay Bakenov","doi":"10.1016/j.powera.2023.100128","DOIUrl":"https://doi.org/10.1016/j.powera.2023.100128","url":null,"abstract":"<div><p>A novel approach to develop a low-temperature lithium-ion battery (LIB) based on tin selenide (SnSe) and carbon (C) nanofibers as the active electrode material has been successfully achieved. The SnSe@C nanofiber anode exhibited excellent electrochemical properties, such as high capacity and good rate capability. The anode maintained a consistent charge capacity of ∼923 mAh g<sup>−1</sup> at a current rate of 0.1 A g<sup>−1</sup> over 100 cycles at room temperature. Furthermore, investigated for the first time at low temperatures, the SnSe@C nanofiber anode exhibited superior capacity (∼430 mAh g<sup>−1</sup> at −20 °C) compared to conventional graphite electrode (∼25 mAh g<sup>−1</sup> at −20 °C). The proposed SnSe@C nanofiber anode demonstrated a great potential to be applied for developing next-generation LIBs with improved low-temperature performance.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"24 ","pages":"Article 100128"},"PeriodicalIF":4.5,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49759296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unraveling the importance of water ratio in direct lithium-ion battery cathode recycling 揭示水比在锂离子电池正极直接回收中的重要性
IF 4.5
Journal of Power Sources Advances Pub Date : 2023-10-01 Epub Date: 2023-10-31 DOI: 10.1016/j.powera.2023.100131
Felix Nagler , Nino Christian , Philip Daubinger , Andreas Flegler , Michael Hofmann , Guinevere A. Giffin
{"title":"Unraveling the importance of water ratio in direct lithium-ion battery cathode recycling","authors":"Felix Nagler ,&nbsp;Nino Christian ,&nbsp;Philip Daubinger ,&nbsp;Andreas Flegler ,&nbsp;Michael Hofmann ,&nbsp;Guinevere A. Giffin","doi":"10.1016/j.powera.2023.100131","DOIUrl":"https://doi.org/10.1016/j.powera.2023.100131","url":null,"abstract":"<div><p>This study investigates the impact of water ratio on the direct aqueous recycling of NMC811. Three different ratios of NMC811 to water were examined. The results demonstrate that the water ratio significantly affects the electrochemical performance of NMC811. Capacity fading is observed in all water-exposed samples, with the sample having the lowest water ratio showing less fading compared to the samples processed with higher water ratios. Both samples with higher water ratios exhibit similar performance, suggesting an equilibrium at the NMC811-water interface is established. Characterization of the cathode materials reveals variations in the amount and type of surface species. The pristine sample, not exposed to water, only shows Li<sub>2</sub>CO<sub>3</sub> and NiO as surface species, while the water-exposed NMC811 samples exhibit nickel carbonates and hydroxides along with associated water. The poorer performance of samples exposed to higher water ratios is likely due to higher amounts of these species forming on the particle surface. Additionally, lithium, cobalt, and manganese carbonates, as well as lithium hydroxide with associated water, are detected and could further contribute to the poorer performance.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"24 ","pages":"Article 100131"},"PeriodicalIF":4.5,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248523000239/pdfft?md5=a837c9a86a7c9b02fddad3dd7a48ff45&pid=1-s2.0-S2666248523000239-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92100703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MnO2 nanotube/GO composite anode for high performance lithium-ion capacitor 高性能锂离子电容器用二氧化锰纳米管/氧化石墨烯复合阳极
IF 4.5
Journal of Power Sources Advances Pub Date : 2023-10-01 Epub Date: 2023-10-12 DOI: 10.1016/j.powera.2023.100130
M. Binari , A.C. Lokhande , F. AlMarzooqi , Daniel S. Choi
{"title":"MnO2 nanotube/GO composite anode for high performance lithium-ion capacitor","authors":"M. Binari ,&nbsp;A.C. Lokhande ,&nbsp;F. AlMarzooqi ,&nbsp;Daniel S. Choi","doi":"10.1016/j.powera.2023.100130","DOIUrl":"https://doi.org/10.1016/j.powera.2023.100130","url":null,"abstract":"<div><p>Li-ion capacitors (LICs) have emerged as promising energy storage devices within the electronic industry. The performance of LICs is predominantly influenced by the electrode material utilized, making the proper selection and development of said material of utmost importance. This study focuses on fabricating a composite electrode material using a simple, cost-effective, and environmentally friendly technique, combining Manganese dioxide (MnO<sub>2</sub>) nanotube and graphene oxide (GO). The low cost, high natural abundance, and high theoretical specific capacity (1230 mAh/g) of MnO2 enables it to be effectively used in energy storage systems. The resulting material showcases a distinctive architecture where MnO<sub>2</sub> nanotube nanorods are enveloped by GO nanosheets. By employing a binder-free buckypaper approach, the MnO<sub>2</sub> nanotube/GO composite anode exhibits exceptional electrochemical performance, including high energy (213.29 Wh/kg) and power density (28.5 kW/kg), improved rate capability, and excellent cyclic stability. These findings undoubtedly indicate a promising future for the MnO<sub>2</sub> nanotube/GO composite anode in lithium-ion-based energy storage systems.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"24 ","pages":"Article 100130"},"PeriodicalIF":4.5,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49759297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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