Journal of Power Sources Advances最新文献

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The effect of sidewall rupture on the propensity for thermal runaway propagation in a small lithium-ion battery module 侧壁破裂对小型锂离子电池模块热失控传播倾向的影响
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-11-24 DOI: 10.1016/j.powera.2024.100162
Elliott Read , Simon Jones , James Marco
{"title":"The effect of sidewall rupture on the propensity for thermal runaway propagation in a small lithium-ion battery module","authors":"Elliott Read ,&nbsp;Simon Jones ,&nbsp;James Marco","doi":"10.1016/j.powera.2024.100162","DOIUrl":"10.1016/j.powera.2024.100162","url":null,"abstract":"<div><div>Six thermal runaway propagation tests were performed on small modules consisting of seven 21700 lithium-ion cells in a hexagonal configuration with 3 mm spacing between adjacent cells. One cell in the centre of the module was triggered into thermal runaway using an 8 mm diameter nail penetrated through the positive terminal of the cell. For half of the tests, sidewall rupture was initiated in the trigger cell using a 35 mm penetration depth. For the other half of the tests, sidewall rupture was not initiated in the trigger cell using a 10 mm penetration depth. In all tests where the trigger cell experienced sidewall rupture, there was thermal runaway propagation to the remaining six cells in the module; in all tests where the trigger cell did not experience sidewall rupture, there was no thermal runaway propagation to any other cells in the module. These results are explained by the directionality and magnitude of heat transfer for sidewall rupture failures relative to nominal failure. These results highlight the increased propensity for thermal runaway propagation when a sidewall rupture failure occurs in a battery module and emphasise the importance of methods to mitigate this failure in battery systems.</div></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"30 ","pages":"Article 100162"},"PeriodicalIF":5.4,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142704141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergetic effect of double-layer coating on silicon nanoparticles for high-performance lithium-ion battery anodes 用于高性能锂离子电池阳极的硅纳米颗粒双层涂层的协同效应
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-11-21 DOI: 10.1016/j.powera.2024.100163
Chaerin Gim , Hyokyeong Kang , Seungwon Lee , Gwangeon Oh , Shivam Kansara , Jang-Yeon Hwang
{"title":"Synergetic effect of double-layer coating on silicon nanoparticles for high-performance lithium-ion battery anodes","authors":"Chaerin Gim ,&nbsp;Hyokyeong Kang ,&nbsp;Seungwon Lee ,&nbsp;Gwangeon Oh ,&nbsp;Shivam Kansara ,&nbsp;Jang-Yeon Hwang","doi":"10.1016/j.powera.2024.100163","DOIUrl":"10.1016/j.powera.2024.100163","url":null,"abstract":"<div><div>Silicon has emerged as a potential candidate for next-generation lithium-ion battery (LIB) anodes owing to its exceptionally high theoretical capacity (3580 mAh g<sup>−1</sup>) and environmental abundance. However, the practical application of Si anodes is severely hindered by low electrical conductivity and a substantial volume expansion rate of over 300 % during the lithiation–delithiation process, leading to rapid capacity degradation. To address these challenges, a double-layer coating strategy was developed and successfully applied to simultaneously enhance the electrical conductivity and mechanical integrity of Si nanoparticles (Si). The double coating layer was designed with an inside conductive pathway and outside robust coverage, which was achieved by encapsulating silicon with a conductive amorphous carbon layer on the silicon surface and coating it with a TiO<sub>2</sub> layer (Si@C@TiO₂). These features improved the interfacial and structural stability of the electrodes during repeated cycling. Compared with its respective uncoated and single-coated analogous anodes, the Si, carbon-coated Si (Si@C), and TiO<sub>2</sub>-coated Si (Si@TiO<sub>2</sub>) anodes, the Si@C@TiO₂ anode demonstrates exceptional cycling stability and power capability. We believe that this study offers a breakthrough in the design of high-performance Si-based anodes for LIBs.</div></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"30 ","pages":"Article 100163"},"PeriodicalIF":5.4,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142704910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formulating PEO-polycarbonate blends as solid polymer electrolytes by solvent-free extrusion 通过无溶剂挤压法将聚醚砜-聚碳酸酯混合物配制成固体聚合物电解质
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-10-19 DOI: 10.1016/j.powera.2024.100160
Francesco Gambino , Matteo Gastaldi , Alia Jouhara , Samuel Malburet , Simone Galliano , Nicola Cavallini , Giovanna Colucci , Marco Zanetti , Alberto Fina , Giuseppe Antonio Elia , Claudio Gerbaldi
{"title":"Formulating PEO-polycarbonate blends as solid polymer electrolytes by solvent-free extrusion","authors":"Francesco Gambino ,&nbsp;Matteo Gastaldi ,&nbsp;Alia Jouhara ,&nbsp;Samuel Malburet ,&nbsp;Simone Galliano ,&nbsp;Nicola Cavallini ,&nbsp;Giovanna Colucci ,&nbsp;Marco Zanetti ,&nbsp;Alberto Fina ,&nbsp;Giuseppe Antonio Elia ,&nbsp;Claudio Gerbaldi","doi":"10.1016/j.powera.2024.100160","DOIUrl":"10.1016/j.powera.2024.100160","url":null,"abstract":"<div><div>Liquid electrolytes are currently state-of-the-art for commercial Li-ion batteries. However, their use implicates inherent challenges, including safety concerns associated with flammability, limited thermal stability, and susceptibility to dendrite formation on the lithium metal anode, that can compromise the battery lifespan. Solid-state polymer electrolytes offer an alternative to conventional liquid electrolytes, aiming to mitigate safety, stability, and performance drawbacks. This study investigates the preparation and the comprehensive characterization of polyethylene oxide (PEO) and polycarbonate (PC) blends obtained through extrusion process. The process is solvent-free and easily scalable at the industrial level; it grants the efficient dispersion and mixing of <span>PEO</span> and <span>PC</span>. Blends at different ratios of PEO (M<sub>w</sub> of 4 × 10<sup>5</sup> and 4 × 10<sup>6</sup> g mol<sup>˗1</sup>) and two types of PCs (namely, polyethylene and polypropylene carbonate) including lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) are prepared. Optimization and investigation of the relative effects between the application of different PCs and the variable ratios of PEO/PCs on the mechanical, morphologic and electrochemical properties of the final polymeric membranes is carried out for future applications of these systems, as efficient electrolytes in all-solid-state lithium batteries.</div></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"30 ","pages":"Article 100160"},"PeriodicalIF":5.4,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing performance and sustainability of lithium manganese oxide cathodes with a poly(ionic liquid) binder and ionic liquid electrolyte 利用聚(离子液体)粘合剂和离子液体电解质提高锂锰氧化物正极的性能和可持续性
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-10-15 DOI: 10.1016/j.powera.2024.100161
Ana Clara Rolandi , Nerea Casado , Anthony Somers , Iratxe de Meatza , David Mecerreyes , Cristina Pozo-Gonzalo , Patrick C. Howlett , Robert Kerr , Maria Forsyth
{"title":"Enhancing performance and sustainability of lithium manganese oxide cathodes with a poly(ionic liquid) binder and ionic liquid electrolyte","authors":"Ana Clara Rolandi ,&nbsp;Nerea Casado ,&nbsp;Anthony Somers ,&nbsp;Iratxe de Meatza ,&nbsp;David Mecerreyes ,&nbsp;Cristina Pozo-Gonzalo ,&nbsp;Patrick C. Howlett ,&nbsp;Robert Kerr ,&nbsp;Maria Forsyth","doi":"10.1016/j.powera.2024.100161","DOIUrl":"10.1016/j.powera.2024.100161","url":null,"abstract":"<div><div>Current battery production involves various energy intensive processes and the use of volatile, flammable and/or toxic chemicals. This study explores the potential for using a water-soluble and functional binder, poly(diallyldimethylammonium) (PDADMA) with diethyl phosphate (DEP) as a counter anion, for lithium manganese oxide (LMO) cathodes. By replacing the traditional polyvinylidene fluoride (PVDF) binder and its associated toxic N-methyl-2-pyrrolidone (NMP) solvent, PDADMA-DEP offers a more sustainable and cost-effective solution. Notably, PDADMA-DEP electrodes do not require high-temperature calendaring to achieve high performance unlike PVDF electrodes. X-ray Photoelectron Spectroscopy (XPS) indicated significant interactions between the binder and LMO that enhance stability and ion conduction. The PDADMA-DEP binder demonstrated excellent electrochemical rate capability up to 10C with the conventional organic liquid electrolyte (LP30), outperforming PVDF electrodes. The performance of both binders using a safer and non-volatile ionic liquid electrolyte, specifically 50 mol% LiFSI in N-trimethyl-N-propylammonium bis(fluorosulfonyl)imide, was also investigated to enhance the overall safety and environmental impact of the battery system. IL-based cells utilizing a PDADMA-DEP cathode binder demonstrated a 58 % capacity retention over 500 cycles at 0.5C when cycled at room temperature.</div></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"30 ","pages":"Article 100161"},"PeriodicalIF":5.4,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the stability of sodium-ion capacitors by introducing glyoxylic-acetal based electrolyte 通过引入乙醛基电解质提高钠离子电容器的稳定性
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-09-21 DOI: 10.1016/j.powera.2024.100158
Andrea Hainthaler, Akshaya S. Sidharthan, Desirée Leistenschneider, Andrea Balducci
{"title":"Enhancing the stability of sodium-ion capacitors by introducing glyoxylic-acetal based electrolyte","authors":"Andrea Hainthaler,&nbsp;Akshaya S. Sidharthan,&nbsp;Desirée Leistenschneider,&nbsp;Andrea Balducci","doi":"10.1016/j.powera.2024.100158","DOIUrl":"10.1016/j.powera.2024.100158","url":null,"abstract":"<div><div>Sodium-ion Capacitors (SICs) are becoming increasingly important energy storage devices. This study presents an in-depth comparison of a largely used electrolyte for said application, sodium hexafluorophosphate in ethylene carbonate:propylene carbonate (NaPF<sub>6</sub> in EC:PC), with the novel electrolyte sodium bis(trifluoromethanesulfonyl)imide in 1,1,2,2-tetraethoxyethane:propylene carbonate (NaTFSI in TEG:PC). Firstly, half-cells of the SIC standard electrode materials, hard carbon (HC) and activated carbon (AC), are shown to perform comparably well with the two electrolytes. However, the use of the novel electrolyte in SICs allows for an improved stability during float tests. All in all, the novel electrolyte NaTFSI in TEG:PC appears to be a very promising alternative electrolyte for SIC application.</div></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"30 ","pages":"Article 100158"},"PeriodicalIF":5.4,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000246/pdfft?md5=c8e082d94221c43a647862db7da48bcc&pid=1-s2.0-S2666248524000246-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142311215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The implementation of a voltage-based tunneling mechanism in aging models for lithium-ion batteries 在锂离子电池老化模型中实施基于电压的隧道机制
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-09-04 DOI: 10.1016/j.powera.2024.100157
Zhenya Wang , Dmitri L. Danilov , Rüdiger‐A. Eichel , Peter H.L. Notten
{"title":"The implementation of a voltage-based tunneling mechanism in aging models for lithium-ion batteries","authors":"Zhenya Wang ,&nbsp;Dmitri L. Danilov ,&nbsp;Rüdiger‐A. Eichel ,&nbsp;Peter H.L. Notten","doi":"10.1016/j.powera.2024.100157","DOIUrl":"10.1016/j.powera.2024.100157","url":null,"abstract":"<div><p>Precise explanation and prediction of the aging behavior of lithium-ion batteries (LIBs) is essential for improving battery management systems. It is quickly becoming a hotspot in battery research. Solid electrolyte interphase (SEI) growth is regarded as the dominant factor of capacity losses in LIBs. However, the growth of SEI is yet to be understood in more detail due to its complexity. In the present paper, an advanced voltage-based aging model using an electron tunneling mechanism is proposed and validated by experiments. This model employs the electrode voltage as an input parameter for the first time with a tunneling mechanism, which is more flexible than existing energy-based approaches and can be used to predict the electron tunneling (dis)charge cycles. The proposed model is used to simulate tunneling current profiles during (dis)charging of graphite, LTO, and blend Si/C negative electrodes. The simulation results prove and explain that lower states-of-charge of LIBs mitigate electron tunneling and SEI growth, further reducing calendar aging. That work can be used to describe battery capacity losses better and it is crucial for predicting the state-of-health of LIBs.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"29 ","pages":"Article 100157"},"PeriodicalIF":5.4,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000234/pdfft?md5=9f4d36d84489a8287ddbd6e0fad46b5e&pid=1-s2.0-S2666248524000234-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142137399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electronic structure evolution upon lithiation: A Li K-edge study of silicon oxide anode through X-ray Raman spectroscopy 锂化过程中的电子结构演变:通过 X 射线拉曼光谱研究氧化硅阳极的锂 K 边
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-07-30 DOI: 10.1016/j.powera.2024.100155
Hong-Jyun Huang , Chia-Shuo Hsu , Jin-Ya Huang , Shu-Chih Haw , Han-Yi Chen , Nozomu Hiraoka , Yen-Fa Liao , Chih-Wei Hu
{"title":"Electronic structure evolution upon lithiation: A Li K-edge study of silicon oxide anode through X-ray Raman spectroscopy","authors":"Hong-Jyun Huang ,&nbsp;Chia-Shuo Hsu ,&nbsp;Jin-Ya Huang ,&nbsp;Shu-Chih Haw ,&nbsp;Han-Yi Chen ,&nbsp;Nozomu Hiraoka ,&nbsp;Yen-Fa Liao ,&nbsp;Chih-Wei Hu","doi":"10.1016/j.powera.2024.100155","DOIUrl":"10.1016/j.powera.2024.100155","url":null,"abstract":"<div><p>The comprehensive understanding of the local structural changes surrounding lithium in lithium silicate (Li<sub>x</sub>SiO<sub>y</sub>) and silicide (Li<sub>x</sub>Si) within Li/SiO<sub>x</sub> batteries during the reversible structural transformations has been hindered by the limitations of current methodologies. In this work, the evolution of electronic structure at various lithiation stages has been addressed well by examining the Li K-edge spectra through X-ray Raman spectroscopy (XRS). The features observed in the Li K-edge XRS spectra provide insights into the development and alteration of Li<sub>x</sub>SiO<sub>y</sub>, which emerges in the initial phases and may be accompanied by a reduction in the ionicity of Li–O bonding during lithiation. These features also agree well with the accompanying FDMNES code simulation. The correlation between electrochemical mechanisms and spectral characteristics is further explored by applying pseudo-Voigt peaks and cumulative pseudo-Voigt functions for fitting purposes. The absence of a significant edge shift indicates a similarity in the electronic structure of Li<sub>x</sub>Si throughout lithiation, and no evidence of Li<sub>2</sub>O formation has also been observed. The Li K-edge XRS spectra exhibit strong agreement with the electrochemical behavior, establishing it as a valuable tool for investigating the evolution of electronic structure in Li/SiO<sub>x</sub> batteries.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"29 ","pages":"Article 100155"},"PeriodicalIF":5.4,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000210/pdfft?md5=76b32eabf2e3c2de1d453a662d44a423&pid=1-s2.0-S2666248524000210-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141962309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ionic liquids with sulfinyl-functionalized imide anion and their lithium electrolytes: (I) Physical and electrochemical properties 具有亚磺酰官能化亚胺阴离子的离子液体及其锂电解质:(I)物理和电化学特性
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-07-18 DOI: 10.1016/j.powera.2024.100154
Hao Wu , Kai Han , Weican Hu , Wenfang Feng , Michel Armand , Zhibin Zhou , Heng Zhang
{"title":"Ionic liquids with sulfinyl-functionalized imide anion and their lithium electrolytes: (I) Physical and electrochemical properties","authors":"Hao Wu ,&nbsp;Kai Han ,&nbsp;Weican Hu ,&nbsp;Wenfang Feng ,&nbsp;Michel Armand ,&nbsp;Zhibin Zhou ,&nbsp;Heng Zhang","doi":"10.1016/j.powera.2024.100154","DOIUrl":"10.1016/j.powera.2024.100154","url":null,"abstract":"<div><p>Imide-based ionic liquids (ILs) are intriguing candidates for constructing safer electrolytes and better rechargeable batteries. In this work, a sulfinyl-functionalized imide anion, (trifluoromethanesulfinyl) (trifluoromethanesulfonyl)imide anion ([(CF<sub>3</sub>SO) (CF<sub>3</sub>SO<sub>2</sub>)N]<sup>−</sup>, [qTFSI]<sup>−</sup>), is proposed as negative charge for building low-melting ILs and high-performing electrolytes. The physicochemical properties of [qTFSI]-based ILs and their electrolytes are extensively characterized, and the reference systems with the classic sulfonimide anion, bis(trifluoromethanesulfonyl)imide anion ([(CF<sub>3</sub>SO<sub>2</sub>)<sub>2</sub>N]<sup>−</sup>, [TFSI]<sup>−</sup>) are also comparatively investigated. It has been revealed that the [qTFSI]<sup>−</sup> anion shows lesser extent of negative charge delocalization as compared to the reference [TFSI]<sup>−</sup> anion, which is responsible for slightly stronger interactions between IL cations and the sulfinyl-functionalized anion. The asymmetric feature of the [qTFSI]<sup>−</sup> anion contributes to lower glass and melting transitions of the corresponding ILs vs. [TFSI]-based ones, which effectively expands the operational temperature of the rechargeable batteries. Furthermore, the co-utilization of [qTFSI]<sup>−</sup> with [TFSI]<sup>−</sup> is found to improve the electrochemical compatibility of Li metal anode with the IL-based electrolytes, sustaining better cycling stability of the Li symmetric cells. The current work offers an elegant approach for the design of new anions for interface-favorable ILs and their electrolytes.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"28 ","pages":"Article 100154"},"PeriodicalIF":5.4,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000209/pdfft?md5=7c9b6e2215ce8193cb108128d1d0697a&pid=1-s2.0-S2666248524000209-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141637166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tri-sulfur radical trapping in lithium–sulfur batteries 锂硫电池中的三硫自由基陷阱
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-06-26 DOI: 10.1016/j.powera.2024.100153
Roza Bouchal , Clément Pechberty , Athmane Boulaoued , Niklas Lindahl , Patrik Johansson
{"title":"Tri-sulfur radical trapping in lithium–sulfur batteries","authors":"Roza Bouchal ,&nbsp;Clément Pechberty ,&nbsp;Athmane Boulaoued ,&nbsp;Niklas Lindahl ,&nbsp;Patrik Johansson","doi":"10.1016/j.powera.2024.100153","DOIUrl":"https://doi.org/10.1016/j.powera.2024.100153","url":null,"abstract":"<div><p>Lithium-sulfur (Li–S) batteries have emerged as a next-generation battery technology owing to their prospects of high capacity and energy density. They, however, suffer from rapid capacity decay due to the shuttling of reaction intermediate species: Li polysulfides (LiPSs). One of the more important and intriguing PSs is the tri-sulfur radical (<span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span>), observed mainly in high-donor number (DN) solvent-based electrolytes. Although this radical has been proposed to be crucial to full active material (AM) utilization, there is currently no direct evidence of the impact of <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span> on cycling stability. To gain more insight into the role of the <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span>, we studied the use of radical traps in low and high DN solvent-based electrolytes by <em>operando</em> Raman spectroscopy. The traps were based on nitrone and iminium cation, and <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span> was indeed successfully trapped in <em>ex situ</em> analysis. However, it was the ionic liquid-based trap, specifically pyridinium, that effectively suppressed <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span> during battery operation. Overall, the PS formation was altered in the presence of the traps and we confirmed the impact of <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span> formation on the Li–S battery redox reactions and show how the trapping correlates with Li–S battery performance. Therefore, stabilization of the <span><math><mrow><msubsup><mi>S</mi><mn>3</mn><mrow><mo>•</mo><mo>−</mo></mrow></msubsup></mrow></math></span> might be a path to improved Li–S batteries.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":"28 ","pages":"Article 100153"},"PeriodicalIF":5.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666248524000192/pdfft?md5=d3bf5ed5febce78519798da3441e763a&pid=1-s2.0-S2666248524000192-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141484911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Establishing Li-acetylide (Li2C2) as functional element in solid-electrolyte interphases in lithium-ion batteries 将乙酰化锂(Li2C2)确立为锂离子电池中固体电解质相间层的功能元素
IF 5.4
Journal of Power Sources Advances Pub Date : 2024-06-25 DOI: 10.1016/j.powera.2024.100152
Viviane Maccio-Figgemeier , Gebrekidan Gebresilassie Eshetu , Damian Mroz , Hyunsang Joo , Egbert Figgemeier
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