Advanced Energy and Sustainability Research最新文献_第4页

Comparative Life Cycle Assessment of Perovskite Solar Cell Production: Mesoporous n-i-p Versus Inverted p-i-n Architectures 钙钛矿太阳能电池生产的生命周期比较评估：介孔n-i-p与倒p-i-n结构

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-19 DOI: 10.1002/aesr.202400368

Joana Príncipe, Luísa Andrade, Teresa M. Mata, António A. Martins

{"title":"Comparative Life Cycle Assessment of Perovskite Solar Cell Production: Mesoporous n-i-p Versus Inverted p-i-n Architectures","authors":"Joana Príncipe, Luísa Andrade, Teresa M. Mata, António A. Martins","doi":"10.1002/aesr.202400368","DOIUrl":"10.1002/aesr.202400368","url":null,"abstract":"Perovskite solar cells (PSCs) offer a viable alternative to silicon-based technologies. Assessing their environmental performance is essential for a responsible development. This study compares the life cycle impacts of two PSC architectures, mesoporous n-i-p and inverted p-i-n, using the life cycle assessment methodology. The functional unit (FU) is a PSC with an active area of 2.88 cm2. The life cycle inventory uses primary production data complemented with literature, the EcoInvent v3.9.1 database, and process modeling. Environmental impacts are evaluated using the ReCiPe 2016 method in SimaPro v9.5.0.1. Results indicate that producing mesoporous PSCs has a higher environmental impact than producing inverted PSCs, due to differences in material and energy consumption. Specifically, mesoporous PSCs require about 132 MJ/FU compared to 25 MJ/FU for inverted PSCs, leading to carbon footprints of 14.1 kg CO2 eq./FU and 2.31 kg CO2 eq./FU, respectively. For inverted PSCs, energy consumption dominates the environmental impacts, accounting for around 80% of the total impact, while for mesoporous PSCs, depending on the environmental category, both materials and energy can dominate. Results highlight that energy consumption is critical and could be significantly reduced by using fully renewable electricity and/or minimizing the presence of metal in the back-contact.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400368","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanoarchitectonics of N- and S-Doped Nanoporous Biocarbons with High Specific Surface Area from Casein and Dithiooxamide for Supercapacitor Applications 基于酪蛋白和二硫脲的高比表面积掺杂纳米多孔生物碳的纳米结构及其在超级电容器中的应用

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-18 DOI: 10.1002/aesr.202500037

Vibin Perumalsamy, Rohan Bahadur, Arun Vijay Baskar, CI Sathish, Ajanya Maria Ruban, Zhenxiang Cheng, Xiaoning Li, Gurwinder Singh, Jiabao Yi, Ajayan Vinu

{"title":"Nanoarchitectonics of N- and S-Doped Nanoporous Biocarbons with High Specific Surface Area from Casein and Dithiooxamide for Supercapacitor Applications","authors":"Vibin Perumalsamy, Rohan Bahadur, Arun Vijay Baskar, CI Sathish, Ajanya Maria Ruban, Zhenxiang Cheng, Xiaoning Li, Gurwinder Singh, Jiabao Yi, Ajayan Vinu","doi":"10.1002/aesr.202500037","DOIUrl":"10.1002/aesr.202500037","url":null,"abstract":"Porous carbons are ideal contenders for supercapacitor electrodes; however, challenges in creating a high surface area in conjunction with controlled surface functionalization still exist. Herein, a low cost and green route for the synthesis of nitrogen and sulfur codoped nanoporous biocarbons using casein and dithiooxamide with high specific surface areas is reported. The textural properties are tuned by varying the synthesis temperature, wherein the nitrogen-doped porous carbon (N-PC) shows a high surface area (2132 m2 g−1) and ample microporosity (>90%). The N and S codoped porous carbons shows considerable surface areas (2068–1944 m2 g−1). N-PC displays a specific capacitance of 149 F g−1 at a current density of 0.5 A g−1 in a three-electrode system. Interestingly, N and S codoped material N,S-PC500 shows an uplift of ≈20% (178 F g−1) in the specific capacitance. The synergetic effect of S and N heteroatoms enhances the specific capacitance due to the provision of additional electrochemical active sites and enhances conductivity. N,S-PC500 also reveals a capacity retention of 93.2% after 3000 cycles at a current density of 5 A g−1. Overall, N and S codoping in porous carbon prove to be a facile ploy to enhance the specific capacitance of materials.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 7","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202500037","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144589631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced and Durable Light-Driven Hydrogen Evolution by Cobalt-Based Prussian Blue Analogs in Phospholipid Bilayers 磷脂双层中钴基普鲁士蓝类似物增强和持久的光驱动析氢

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-17 DOI: 10.1002/aesr.202400372

Subrata Mandal, Akash Deshpande, Robert Leiter, Johannes Biskupek, Ute Kaiser, Andrea Pannwitz

{"title":"Enhanced and Durable Light-Driven Hydrogen Evolution by Cobalt-Based Prussian Blue Analogs in Phospholipid Bilayers","authors":"Subrata Mandal, Akash Deshpande, Robert Leiter, Johannes Biskupek, Ute Kaiser, Andrea Pannwitz","doi":"10.1002/aesr.202400372","DOIUrl":"10.1002/aesr.202400372","url":null,"abstract":"Light-driven hydrogen (H2) evolution in water is performed using a series of cobalt-based Prussian blue analogs (MCo PBAs) with MII3[CoIII(CN)6]2, M = Co, Ni, Cu, Zn embedded in phospholipid bilayers with the amphiphilic ruthenium-based photosensitizer RuC9. Hydrophobic surface functionalization of MCo PBA nanoparticles with oleylamine facilitates close proximity of the PBA to the photosensitizer within lipid bilayers of vesicles, enhancing photocatalytic performance. The type of metal and rigidity of the lipid environment significantly influences hydrogen evolution reaction efficiency, with the trend: Ni > Co > Zn > Cu and DMPC > DOPC > DPPC. Among these, NiCo PBA in DMPC: (14:0 PEG2000 PE) vesicles shows the highest efficiency, with a ninefold increase in H2 production compared to the conventional aqueous system. This sustained activity is attributed to the efficient electron transfer and the scaffold's stability. This study provides valuable insights for the development of scalable and cost-effective photocatalytic technologies.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 8","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400372","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144782898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pretreatment and Valorization of Critical Materials from Lithium-Ion Batteries Using Electrostatic and Magnetic Separation 锂离子电池中关键材料的静电和磁分离预处理及增值研究

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-16 DOI: 10.1002/aesr.202400366

Hyeyeon Lee, Elizabeth H. Driscoll, Kristian Waters, Emma Kendrick, Roberto Sommerville

{"title":"Pretreatment and Valorization of Critical Materials from Lithium-Ion Batteries Using Electrostatic and Magnetic Separation","authors":"Hyeyeon Lee, Elizabeth H. Driscoll, Kristian Waters, Emma Kendrick, Roberto Sommerville","doi":"10.1002/aesr.202400366","DOIUrl":"10.1002/aesr.202400366","url":null,"abstract":"\u0000The electric revolution has driven a significant increase in the use of rechargeable batteries, particularly lithium-ion batteries, which contain several strategic elements and critical materials: Li, Co, Ni, P, and graphite. Efficient recovery of these materials is crucial to enhancing the resilience of the materials supply chain. Traditional recycling methods such as pyrometallurgy and hydrometallurgy have limitations, including high carbon intensity, cost, and limited material recovery. Robust physical separation pretreatment technologies can increase material purity for recycling. This study shows the utilization of electrostatic and magnetic separation processes across four distinct commercial cathode chemistries to produce high-grade cathodic and anodic electrode products. Production scrap and end-of-life cells are used, with LiMn2O4–LiNi0.8Co0.15Al0.05O2 (LMO/NCA), LiFePO4 (LFP), LiCoO2 (LCO), and LiNi0.5Mn0.3Co0.2O2 (NMC532) cathode chemistries, all partnered with graphite anodes. The application of these two separation technologies significantly improves the separation efficiency of shredded electrodes, leading to >98% recovery of shredded NMC cathode electrodes, and with >99% recovery of LMO–NCA electrodes, and >98% recovery of LFP electrodes. LCO is not found to be suitable for these separation processes. These advanced pretreatment methods produce high-purity concentrates of valuable cathode feedstocks, which can support secondary (critical) material feedstocks, and ultimately will reduce subsequent energy consumption.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 9","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400366","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145062515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Supercapacitors: An Emerging Energy Storage System 超级电容器：一种新兴的储能系统

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-13 DOI: 10.1002/aesr.202400412

Muhammad Faisal Iqbal, Farooq Nasir, Fiza Shabbir, Zaheer Ud Din Babar, Muhammad Farooq Saleem, Kaleem Ullah, Nana Sun, Faizan Ali

引用次数: 0

Electrochemical Hybridization via Simultaneous Electrochemical Doping of Poly(3-Methoxythiophene) with Au Electrodeposition for Anodic Oxidation of 1-Propanol 聚（3-甲氧基噻吩）与金电沉积同时掺杂的电化学杂化研究

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-13 DOI: 10.1002/aesr.202400420

Tomoyuki Kurioka, Tso-Fu Mark Chang, Masato Sone

{"title":"Electrochemical Hybridization via Simultaneous Electrochemical Doping of Poly(3-Methoxythiophene) with Au Electrodeposition for Anodic Oxidation of 1-Propanol","authors":"Tomoyuki Kurioka, Tso-Fu Mark Chang, Masato Sone","doi":"10.1002/aesr.202400420","DOIUrl":"10.1002/aesr.202400420","url":null,"abstract":"\u0000Hybrid materials composed of gold (Au) and conducting polymers (CP) are promising electrode materials to facilitate anodic oxidation of low-carbon alcohols, such as ethanol and 1-propanol (1-PrOH). The anodic oxidation of these alcohols is used in many industries. Hybridization of CP with Au particles via electrodeposition of Au using a CP-coated electrode as a working electrode is a simple and powerful technique. On the other hand, depending on the applied potential, electrochemical doping of CPs competes with the electrodeposition of Au. The electrochemical doping changes their optoelectronic properties, and drives Au particle precursors, such as tetrachloroaurate(III) (AuCl4−) ions, to penetrate into the CP as dopants. Therefore, the applied potential is expected to affect the electrocatalytic properties of the hybrid materials fabricated by the electrodeposition techniques. Here, the effects of the applied potential for the electrochemical hybridization process on the electrocatalytic properties of the Au/poly(3-methoxythiophene) (Au/P3MeOT) for the anodic oxidation of 1-PrOH are reported. Their electrocatalytic properties are enhanced by performing the electrochemical hybridization of P3MeOT with Au under the potential, where the electrochemical doping of P3MeOT and the electrodeposition of Au proceed simultaneously.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 7","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400420","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144589750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mn-Doped Tuned NiC/NiO Heterostructure for Efficient Electron Transfer in Hydrogen Evolution Reaction mn掺杂调谐NiC/NiO异质结构在析氢反应中的高效电子转移

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-12 DOI: 10.1002/aesr.202400391

Tianyi Li, Ailing Fan, Yuanyuan Li, Yaqi Quo, Yang Zhu, Haijiao Xie

{"title":"Mn-Doped Tuned NiC/NiO Heterostructure for Efficient Electron Transfer in Hydrogen Evolution Reaction","authors":"Tianyi Li, Ailing Fan, Yuanyuan Li, Yaqi Quo, Yang Zhu, Haijiao Xie","doi":"10.1002/aesr.202400391","DOIUrl":"10.1002/aesr.202400391","url":null,"abstract":"Economical and efficient catalysts for the hydrogen evolution reaction are critical for realizing the large-scale application of water splitting. Herein, a floral microspheres heterostructure of Mn-doped NiC/NiO catalyst, synthesized using a simple hydrothermal and vapor deposition method, is reported. The results demonstrate that doping Mn into NiC/NiO can regulate both the microstructure and electronic structure, significantly improving the catalytic performance for electrochemical hydrogen evolution reaction. In the 1 M KOH solution, the current density of 10 mA cm−2 required overpotential is only 56 mV, its Tafel slope is 56.4 mV dec−1, and the higher current density 100 mA cm−2 required overpotential is only 200 mV. Also, the Mn–NiC/NiO catalyst exhibit a considerable stability. After 24 h catalytic hydrogen evolution test, its microstructure and potential show negligible change under 200 mA cm−2. The study provides a method to develop Mn-doped nickel-based heterostructure as an efficient and potential hydrogen evolution reaction catalyst.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400391","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Doped Zinc Oxide-Based Piezoelectric Devices for Energy Harvesting and Sensing 用于能量收集和传感的掺杂氧化锌基压电器件

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-12 DOI: 10.1002/aesr.202500017

Congran Jin, Junhu Zhou, Ziqian Wu, John X. J. Zhang

引用次数: 0

Structural Battery Electrolytes Based on a Cross-Linked Methacrylate Polymer and a Protic Ionic Liquid: Is There an Optimal Composition? 基于交联甲基丙烯酸酯聚合物和质子离子液体的结构电池电解质：是否存在最佳组合？

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-11 DOI: 10.1002/aesr.202500013

Nicole Abdou, Achilleas Pipertzis, Richa Chaudhary, Lars Evenäs, Johanna Xu, Leif E. Asp, Jan Swenson, Anna Martinelli

{"title":"Structural Battery Electrolytes Based on a Cross-Linked Methacrylate Polymer and a Protic Ionic Liquid: Is There an Optimal Composition?","authors":"Nicole Abdou, Achilleas Pipertzis, Richa Chaudhary, Lars Evenäs, Johanna Xu, Leif E. Asp, Jan Swenson, Anna Martinelli","doi":"10.1002/aesr.202500013","DOIUrl":"10.1002/aesr.202500013","url":null,"abstract":"Within the development of structural batteries, finding the optimal electrolyte composition, that is, one that offers both high ionic conductivity and mechanical stiffness, is essential. Structural batteries are multifunctional composites able to store electrical energy within load-bearing elements of devices. Their use results in a significant mass reduction, thereby improving fuel efficiency and enabling a shift to sustainable energy. In this work, structural battery electrolytes consisting of a methacrylate-based polymer, 1-ethylimidazolium bis(trifluoromethylsulfonyl)imide protic ionic liquid, and a lithium salt are investigated. Interestingly, the transport properties of the confined liquid electrolyte seem primarily limited by the percolation of the polymer network. Furthermore, upon confinement, a decrease in the glass transition temperature of the polymer phase and weaker intermolecular interactions are observed, which correlate to faster local dynamics. The self-diffusivity of the Li ions keeps high with respect to the other diffusing ions and tends to decouple from the anions upon increased temperature. The composite sample with 50 wt% of liquid electrolyte shows an ionic conductivity of ≈0.1 mS cm−1 with a shear storage modulus of ≈150 MPa and was thus selected for proof-of-concept tests by electrochemical methods. Overall, this comprehensive study highlights the versatility of these biphasic systems for various applications.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 5","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202500013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal Sulfides as Potential Materials for Next Generation Lithium Ion Batteries: A Review 金属硫化物作为下一代锂离子电池潜在材料的研究进展

IF 5.7

Advanced Energy and Sustainability Research Pub Date : 2025-03-11 DOI: 10.1002/aesr.202400448

Muhammad Ali Martuza, Lutz Mädler, Suman Pokhrel

{"title":"Metal Sulfides as Potential Materials for Next Generation Lithium Ion Batteries: A Review","authors":"Muhammad Ali Martuza, Lutz Mädler, Suman Pokhrel","doi":"10.1002/aesr.202400448","DOIUrl":"10.1002/aesr.202400448","url":null,"abstract":"\u0000Lithium-ion batteries (LIBs) are indispensable in modern electronic instruments and electric vehicles because of their high energy density and long cycle life. However, the performance of traditional LIBs is constrained by limited theoretical specific capacities and structural stabilities, failing to meet the demands of next-generation high-performance applications. Transition metal sulfides are emerging as promising electrode materials due to their low cost, high theoretical capacities, and superior intrinsic properties. Compared to oxides, metal sulfides exhibit enhanced electrical conductivity, faster ion diffusion, and multi-electron transfer capabilities, which collectively enable higher energy density, better rate performance, and improved cycling stability. Flame spray pyrolysis (FSP) offers a scalable, cost-effective method for synthesizing functional structured electrode materials. This one-step process facilitates precise control over particle composition, and morphology, enabling complex modifications such as doping, homogeneous mixing, coating, and noble metal promotion/functionalization. FSP also produces metastable nanoparticle phases and allows direct deposition of materials onto electrodes without binders or solvents, streamlining electrode fabrication. The integration of FSP synthesis with electrode production in a continuous process chain holds immense potential for large-scale manufacturing of LIB electrodes. This approach is anticipated to revolutionize energy storage technologies, addressing the challenges of cost, performance, and scalability.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 8","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400448","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144782388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0