Advanced Energy and Sustainability Research最新文献

Piezo-Electro-Catalytic Hydrogen Production via Piezoelectric Fluoropolymers 压电含氟聚合物压电电催化制氢

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-06-11 DOI: 10.1002/aesr.70018

Peter Cameron Sherrell, Fangxi Xie, Alexander Corletto, Anders Barlow, Donghyuck Park, Jizhen Zhang, Ken Aldren S. Usman, Diego Chaparro, Eirini Goudeli, Andris Šutka, Joselito Razal, Joseph D. Berry, Amanda V. Ellis

引用次数: 0

Structural Battery Electrolytes Based on a Cross-Linked Methacrylate Polymer and a Protic Ionic Liquid: Is There an Optimal Composition? 基于交联甲基丙烯酸酯聚合物和质子离子液体的结构电池电解质：是否存在最佳组合？

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-05-06 DOI: 10.1002/aesr.202570041

Nicole Abdou, Achilleas Pipertzis, Richa Chaudhary, Lars Evenäs, Johanna Xu, Leif E. Asp, Jan Swenson, Anna Martinelli

引用次数: 0

Piezo-Electro-Catalytic Hydrogen Production via Piezoelectric Fluoropolymers 压电含氟聚合物压电电催化制氢

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-04-13 DOI: 10.1002/aesr.202500045

Peter Cameron Sherrell, Fangxi Xie, Alexander Corletto, Anders Barlow, Donghyuck Park, Jizhen Zhang, Ken Aldren S. Usman, Diego Chaparro, Eirini Goudeli, Andris Šutka, Joselito Razal, Joseph D. Berry, Amanda V. Ellis

{"title":"Piezo-Electro-Catalytic Hydrogen Production via Piezoelectric Fluoropolymers","authors":"Peter Cameron Sherrell, Fangxi Xie, Alexander Corletto, Anders Barlow, Donghyuck Park, Jizhen Zhang, Ken Aldren S. Usman, Diego Chaparro, Eirini Goudeli, Andris Šutka, Joselito Razal, Joseph D. Berry, Amanda V. Ellis","doi":"10.1002/aesr.202500045","DOIUrl":"https://doi.org/10.1002/aesr.202500045","url":null,"abstract":"Producing future fuels, such as green hydrogen, using less external energy input is a key factor in making such fuels truly environmentally friendly. In addition, the requirement of reducing the amount of catalyst used per mass of fuel produced is key for resource stability, particularly for platinum group metals which dominate such catalysis fields. Herein, a proof-of-principle approach is demonstrated to achieve both targets through piezo-electro-catalysis from chemically stable, flexible, fluoropolymers. Highly polarized MXene-poly(vinylidene-difluoride)-co-(trifluoro-ethylene) interfaces, with an embedded platinum mesh electrode, are shown to decrease the onset overpotential of the mesh by 200 mV, thus lowering the overall energy and Pt required to produce a given mass of hydrogen. The simple approach used herein can be applied to other, advanced catalysts, to boost performance and efficiency.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202500045","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Energy Harvesting from CO2 Emission Exploiting Ionic Liquid-Based Electrochemical Capacitor 利用离子液体基电化学电容器从二氧化碳排放中收集能量

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-04-06 DOI: 10.1002/aesr.202500019

Davide Molino, Federico Raffone, Pietro Zaccagnini, Alessandro Pedico, Simone Martellone, Giuseppe Ferraro, Sergio Bocchini, Giancarlo Cicero, Andrea Lamberti

{"title":"Energy Harvesting from CO2 Emission Exploiting Ionic Liquid-Based Electrochemical Capacitor","authors":"Davide Molino, Federico Raffone, Pietro Zaccagnini, Alessandro Pedico, Simone Martellone, Giuseppe Ferraro, Sergio Bocchini, Giancarlo Cicero, Andrea Lamberti","doi":"10.1002/aesr.202500019","DOIUrl":"https://doi.org/10.1002/aesr.202500019","url":null,"abstract":"When two solutions with different compositions are mixed, the free mixing energy is released. This principle is exploited in salinity gradient power technologies like capacitive mixing (CapMix), where mixing occurs in a supercapacitor. Since this energy release holds true also for gases, research moves in the direction of harvesting energy from anthropic CO2. To do so, it is proposed for the first time to exploit an ionic liquid (IL), both as an electrolyte and CO2 absorbing medium in a CapMix cell. The mechanism consists in flowing a CO2-rich gas stream, alternated to a N2 stream, during the charging/discharging of two electrodes. The CO2 strongly affects the electrode/IL interface and the IL physicochemical properties thereby converting the released mixing energy into electrical energy. Unlike water-based systems, where energy harvesting relies on electric double-layer expansion, we propose a new mechanism based on electrochemical potential variations during CO2 capture/release, supported by molecular dynamics modeling. Key results include maximum voltage rise of 40 mV and energy and power densities of 40 μWh m−2 and 0.8 mW m−2. These findings clarify the mechanism behind the electrochemical phenomena occurring when CO2 interacts with IL and open the way to a new generation of electrochemical systems to harvest energy from CO2 emission.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202500019","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144255822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Estimating the State of Charge in Lithium Primary Batteries: Recent Advances and Critical Insights 估计锂一次电池的充电状态：最新进展和关键见解

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-04-03 DOI: 10.1002/aesr.202570031

Sydney Roth, Daniel Wesolowski, David Schrock, Noah Schorr, Sakineh Chabi

引用次数: 0

Structured Electrodes for Lithium-Ion Batteries and Their Impact on Cell Energy Density and Power Density: A Review 锂离子电池结构电极及其对电池能量密度和功率密度的影响

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-03-25 DOI: 10.1002/aesr.202400377

Fatjon Maxharraj, Karsten Voigt, Anton Werwein, Christian Heubner, Kristian Nikolowski, Mareike Partsch, Alexander Michaelis

{"title":"Structured Electrodes for Lithium-Ion Batteries and Their Impact on Cell Energy Density and Power Density: A Review","authors":"Fatjon Maxharraj, Karsten Voigt, Anton Werwein, Christian Heubner, Kristian Nikolowski, Mareike Partsch, Alexander Michaelis","doi":"10.1002/aesr.202400377","DOIUrl":"https://doi.org/10.1002/aesr.202400377","url":null,"abstract":"In various applications, including modern electric vehicles, the demand for batteries with high gravimetric and volumetric energy density is growing, driving the need for new production concepts to meet this requirement. Enhancing the energy and power density of lithium-ion batteries is a crucial goal, as it refers to how much energy can be stored in a given volume or mass and how quickly that energy can be delivered, which are key factors determining the performance of batteries. In pursuit of higher energy density and fast-charging capability, recent attention has been drawn toward strategies that emphasize optimizing the characteristics of composite electrode structures, such as porosity, conductivity, or tortuosity, achieved through restructuring the matrix composition of lithium-ion battery electrode films. This review highlights the importance of structuring, explores recent advances in electrode design, and critically evaluates them in terms of energy and power density using a computational tool (Ragone calculator). Employing the Ragone calculator enables the evaluation of electrodes with different designs on the cell level. Various electrode designs created using different techniques, including laser, multilayer structuring, and interdigitated approaches are evaluated. The insights from this review can help the reader to assess the actual improvements from the structuring technique.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400377","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative Life Cycle Assessment of Perovskite Solar Cell Production: Mesoporous n-i-p Versus Inverted p-i-n Architectures 钙钛矿太阳能电池生产的生命周期比较评估：介孔n-i-p与倒p-i-n结构

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-03-19 DOI: 10.1002/aesr.202400368

Joana Príncipe, Luísa Andrade, Teresa M. Mata, António A. Martins

{"title":"Comparative Life Cycle Assessment of Perovskite Solar Cell Production: Mesoporous n-i-p Versus Inverted p-i-n Architectures","authors":"Joana Príncipe, Luísa Andrade, Teresa M. Mata, António A. Martins","doi":"10.1002/aesr.202400368","DOIUrl":"https://doi.org/10.1002/aesr.202400368","url":null,"abstract":"Perovskite solar cells (PSCs) offer a viable alternative to silicon-based technologies. Assessing their environmental performance is essential for a responsible development. This study compares the life cycle impacts of two PSC architectures, mesoporous n-i-p and inverted p-i-n, using the life cycle assessment methodology. The functional unit (FU) is a PSC with an active area of 2.88 cm2. The life cycle inventory uses primary production data complemented with literature, the EcoInvent v3.9.1 database, and process modeling. Environmental impacts are evaluated using the ReCiPe 2016 method in SimaPro v9.5.0.1. Results indicate that producing mesoporous PSCs has a higher environmental impact than producing inverted PSCs, due to differences in material and energy consumption. Specifically, mesoporous PSCs require about 132 MJ/FU compared to 25 MJ/FU for inverted PSCs, leading to carbon footprints of 14.1 kg CO2 eq./FU and 2.31 kg CO2 eq./FU, respectively. For inverted PSCs, energy consumption dominates the environmental impacts, accounting for around 80% of the total impact, while for mesoporous PSCs, depending on the environmental category, both materials and energy can dominate. Results highlight that energy consumption is critical and could be significantly reduced by using fully renewable electricity and/or minimizing the presence of metal in the back-contact.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400368","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mn-Doped Tuned NiC/NiO Heterostructure for Efficient Electron Transfer in Hydrogen Evolution Reaction mn掺杂调谐NiC/NiO异质结构在析氢反应中的高效电子转移

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-03-12 DOI: 10.1002/aesr.202400391

Tianyi Li, Ailing Fan, Yuanyuan Li, Yaqi Quo, Yang Zhu, Haijiao Xie

{"title":"Mn-Doped Tuned NiC/NiO Heterostructure for Efficient Electron Transfer in Hydrogen Evolution Reaction","authors":"Tianyi Li, Ailing Fan, Yuanyuan Li, Yaqi Quo, Yang Zhu, Haijiao Xie","doi":"10.1002/aesr.202400391","DOIUrl":"https://doi.org/10.1002/aesr.202400391","url":null,"abstract":"Economical and efficient catalysts for the hydrogen evolution reaction are critical for realizing the large-scale application of water splitting. Herein, a floral microspheres heterostructure of Mn-doped NiC/NiO catalyst, synthesized using a simple hydrothermal and vapor deposition method, is reported. The results demonstrate that doping Mn into NiC/NiO can regulate both the microstructure and electronic structure, significantly improving the catalytic performance for electrochemical hydrogen evolution reaction. In the 1 M KOH solution, the current density of 10 mA cm−2 required overpotential is only 56 mV, its Tafel slope is 56.4 mV dec−1, and the higher current density 100 mA cm−2 required overpotential is only 200 mV. Also, the Mn–NiC/NiO catalyst exhibit a considerable stability. After 24 h catalytic hydrogen evolution test, its microstructure and potential show negligible change under 200 mA cm−2. The study provides a method to develop Mn-doped nickel-based heterostructure as an efficient and potential hydrogen evolution reaction catalyst.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 6","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400391","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural Battery Electrolytes Based on a Cross-Linked Methacrylate Polymer and a Protic Ionic Liquid: Is There an Optimal Composition? 基于交联甲基丙烯酸酯聚合物和质子离子液体的结构电池电解质：是否存在最佳组合？

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-03-11 DOI: 10.1002/aesr.202500013

Nicole Abdou, Achilleas Pipertzis, Richa Chaudhary, Lars Evenäs, Johanna Xu, Leif E. Asp, Jan Swenson, Anna Martinelli

{"title":"Structural Battery Electrolytes Based on a Cross-Linked Methacrylate Polymer and a Protic Ionic Liquid: Is There an Optimal Composition?","authors":"Nicole Abdou, Achilleas Pipertzis, Richa Chaudhary, Lars Evenäs, Johanna Xu, Leif E. Asp, Jan Swenson, Anna Martinelli","doi":"10.1002/aesr.202500013","DOIUrl":"https://doi.org/10.1002/aesr.202500013","url":null,"abstract":"Within the development of structural batteries, finding the optimal electrolyte composition, that is, one that offers both high ionic conductivity and mechanical stiffness, is essential. Structural batteries are multifunctional composites able to store electrical energy within load-bearing elements of devices. Their use results in a significant mass reduction, thereby improving fuel efficiency and enabling a shift to sustainable energy. In this work, structural battery electrolytes consisting of a methacrylate-based polymer, 1-ethylimidazolium bis(trifluoromethylsulfonyl)imide protic ionic liquid, and a lithium salt are investigated. Interestingly, the transport properties of the confined liquid electrolyte seem primarily limited by the percolation of the polymer network. Furthermore, upon confinement, a decrease in the glass transition temperature of the polymer phase and weaker intermolecular interactions are observed, which correlate to faster local dynamics. The self-diffusivity of the Li ions keeps high with respect to the other diffusing ions and tends to decouple from the anions upon increased temperature. The composite sample with 50 wt% of liquid electrolyte shows an ionic conductivity of ≈0.1 mS cm−1 with a shear storage modulus of ≈150 MPa and was thus selected for proof-of-concept tests by electrochemical methods. Overall, this comprehensive study highlights the versatility of these biphasic systems for various applications.","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 5","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202500013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating the Existence of a Cathode Electrolyte Interphase on Graphite in Dual-Ion Batteries with LiPF6-Based Aprotic Electrolytes and Unraveling the Origin of Capacity Fade 用lipf6基非质子电解质研究双离子电池石墨上阴极电解质界面的存在及容量衰减的原因

IF 6.2

Advanced Energy and Sustainability Research Pub Date : 2025-03-05 DOI: 10.1002/aesr.202570021

Lukas Haneke, Felix Pfeiffer, Katharina Rudolf, Pranti Sutar, Masoud Baghernejad, Martin Winter, Tobias Placke, Johannes Kasnatscheew

引用次数: 0