Advanced Energy and Sustainability Research最新文献

筛选
英文 中文
The Influence of Discontinuity-Induced Fringing Effect on the Output Performance of Contact-Separation Mode Triboelectric Nanogenerators: Experiment and Modeling Studies 不连续引起的边缘效应对接触分离模式三电纳米发电机输出性能的影响:实验与建模研究
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-10-06 DOI: 10.1002/aesr.202470027
Teresa Cheng, Han Hu, Navid Valizadeh, Liu Qiong, Florian Bittner, Ling Yang, Timon Rabczuk, Xiaoning Jiang, Xiaoying Zhuang
{"title":"The Influence of Discontinuity-Induced Fringing Effect on the Output Performance of Contact-Separation Mode Triboelectric Nanogenerators: Experiment and Modeling Studies","authors":"Teresa Cheng,&nbsp;Han Hu,&nbsp;Navid Valizadeh,&nbsp;Liu Qiong,&nbsp;Florian Bittner,&nbsp;Ling Yang,&nbsp;Timon Rabczuk,&nbsp;Xiaoning Jiang,&nbsp;Xiaoying Zhuang","doi":"10.1002/aesr.202470027","DOIUrl":"https://doi.org/10.1002/aesr.202470027","url":null,"abstract":"<p><b>Triboelectric Nanogenerators</b>\u0000 </p><p>In article number 2400002, Teresa Cheng, Xiaoying Zhuang, and co-workers have investigate the effect of edge effects on the electrical outputs of triboelectric nanogenerators (TENGs). The enhanced surface charge and power density of TENGs due to the discontinuities can be useful for self-powering devices, such as boosting energy harvesting from cardiac muscle to supply pacemaker.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202470027","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Striking a Balance: Decentralized and Centralized Wastewater Treatment Systems for Advancing Sustainable Development Goal 6 取得平衡:推进可持续发展目标 6 的分散式和集中式废水处理系统
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-10-06 DOI: 10.1002/aesr.202470025
Fateme Saadatinavaz, Mohammed A. Alomari, Muhammad Ali, Pascal E. Saikaly
{"title":"Striking a Balance: Decentralized and Centralized Wastewater Treatment Systems for Advancing Sustainable Development Goal 6","authors":"Fateme Saadatinavaz,&nbsp;Mohammed A. Alomari,&nbsp;Muhammad Ali,&nbsp;Pascal E. Saikaly","doi":"10.1002/aesr.202470025","DOIUrl":"https://doi.org/10.1002/aesr.202470025","url":null,"abstract":"<p><b>Wastewater Treatment Systems</b>\u0000 </p><p>This perspective provides quantitative assessments of wastewater treatment systems. In densely populated areas, CWTS offers advantages of scale, while in low-density regions, DWTS offers scope benefits. While centralized systems benefit from scale economies, decentralized setups capitalize on compactness, offering multifunctionality and flexibility. Moreover, decentralized systems require less land, and their modular design allows for easy upgrades and scaling. More details can be found in article number 2400097 by Muhammad Ali, Pascal E. Saikaly, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202470025","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enabling Aqueous Processing of Ni-Rich Layered Oxide Cathodes via Systematic Modification of Biopolymer (Polysaccharide)-Based Binders 通过系统改性生物聚合物(多糖)基粘合剂实现富镍层状氧化物阴极的水性加工
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-09-09 DOI: 10.1002/aesr.202470023
Simon Albers, Jens Timmermann, Tobias Brake, Anindityo Arifiadi, Anna I. Gerlitz, Markus Börner, Martin Winter, Johannes Kasnatscheew
{"title":"Enabling Aqueous Processing of Ni-Rich Layered Oxide Cathodes via Systematic Modification of Biopolymer (Polysaccharide)-Based Binders","authors":"Simon Albers,&nbsp;Jens Timmermann,&nbsp;Tobias Brake,&nbsp;Anindityo Arifiadi,&nbsp;Anna I. Gerlitz,&nbsp;Markus Börner,&nbsp;Martin Winter,&nbsp;Johannes Kasnatscheew","doi":"10.1002/aesr.202470023","DOIUrl":"https://doi.org/10.1002/aesr.202470023","url":null,"abstract":"<p><b>Biopolymer (Polysaccharide)-Based Binders</b>\u0000 </p><p>Biopolymers like polysaccharides are a F-free alternative compared to state-of-the-art polyvinylidene difluoride (PVDF), can realize water processing and be beneficial in terms of recycling. The here shown dual binder approach enables a constant viscosity of cathode slurry (i.e., similar final composite network) paving way for systematic and comparable study of sugar-based binder modifications for Ni-rich LiNi<sub>x</sub>Co<sub>y</sub>Mn<sub>z</sub>O<sub>2</sub> (NCM) cathodes. More details can be found in article number 2400117 by Johannes Kasnatscheew and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202470023","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142165347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward High Specific Energy and Long Cycle Life Li/Mn-Rich Layered Oxide || Graphite Lithium-Ion Batteries via Optimization of Voltage Window 通过优化电压窗口实现高比能量和长循环寿命的 Li/Mn-Rich 层状氧化物 || 石墨锂离子电池
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-08-06 DOI: 10.1002/aesr.202470020
Anindityo Arifiadi, Tobias Brake, Feleke Demelash, Bixian Ying, Karin Kleiner, Hyuck Hur, Simon Wiemers-Meyer, Martin Winter, Johannes Kasnatscheew
{"title":"Toward High Specific Energy and Long Cycle Life Li/Mn-Rich Layered Oxide || Graphite Lithium-Ion Batteries via Optimization of Voltage Window","authors":"Anindityo Arifiadi,&nbsp;Tobias Brake,&nbsp;Feleke Demelash,&nbsp;Bixian Ying,&nbsp;Karin Kleiner,&nbsp;Hyuck Hur,&nbsp;Simon Wiemers-Meyer,&nbsp;Martin Winter,&nbsp;Johannes Kasnatscheew","doi":"10.1002/aesr.202470020","DOIUrl":"https://doi.org/10.1002/aesr.202470020","url":null,"abstract":"<p><b>Lithium-Ion Batteries</b>\u0000 </p><p>In article number 2400129, Johannes Kasnatscheew and co-workers show Li-ion-batteries with Li/Mn-rich cathodes, which have the potential to compete with state-of-the-art cathodes. Their well-known dilemma of poor cycle life at high upper-cut voltages (UCVs) and low specific energies at low UCVs can be reasonably compensated by adjusting voltage windows during formation and post formation cycles, as investigated and demonstrated for LMR || graphite cells.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202470020","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct Cation Stabilization Effects of CO Dimerization for Boosting C2 Pathways of CO2 Reduction on Noble Metal Surfaces 一氧化碳二聚化的直接阳离子稳定效应促进贵金属表面的二氧化碳还原 C2 途径
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-08-06 DOI: 10.1002/aesr.202470022
Hon Ho Wong, Mingzi Sun, Tong Wu, Lu Lu, Qiuyang Lu, Baian Chen, Cheuk Hei Chan, Bolong Huang
{"title":"Direct Cation Stabilization Effects of CO Dimerization for Boosting C2 Pathways of CO2 Reduction on Noble Metal Surfaces","authors":"Hon Ho Wong,&nbsp;Mingzi Sun,&nbsp;Tong Wu,&nbsp;Lu Lu,&nbsp;Qiuyang Lu,&nbsp;Baian Chen,&nbsp;Cheuk Hei Chan,&nbsp;Bolong Huang","doi":"10.1002/aesr.202470022","DOIUrl":"https://doi.org/10.1002/aesr.202470022","url":null,"abstract":"<p><b>CO Dimerization</b>\u0000 </p><p>The coupling of two CO intermediates represents a significant step in the formation of C<sub>2</sub> products during the carbon dioxide reduction reaction. In article number 2400110, Bolong Huang’s group demonstrates the linear correlation between the cation–dimer stabilization and reaction energy, supporting that the cations notably facilitate the C-C coupling step and enhance the production of C<sub>2</sub> products.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202470022","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Peroxymonosulfate Activation by Metallic Copper in TiO2–CaTiO3–Cu2O–Cu Anodes for Electrocatalytic Degradation of Organic Pollutants 金属铜在 TiO2-CaTiO3-Cu2O-Cu 阳极中高效活化过一硫酸盐,用于电催化降解有机污染物
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-08-01 DOI: 10.1002/aesr.202400102
Fida Tanos, Elissa Makhoul, Amr A. Nada, Maged F. Bekheet, Eddy Petit, Antonio Razzouk, Geoffroy Lesage, Marc Cretin, Mikhael Bechelany
{"title":"Efficient Peroxymonosulfate Activation by Metallic Copper in TiO2–CaTiO3–Cu2O–Cu Anodes for Electrocatalytic Degradation of Organic Pollutants","authors":"Fida Tanos,&nbsp;Elissa Makhoul,&nbsp;Amr A. Nada,&nbsp;Maged F. Bekheet,&nbsp;Eddy Petit,&nbsp;Antonio Razzouk,&nbsp;Geoffroy Lesage,&nbsp;Marc Cretin,&nbsp;Mikhael Bechelany","doi":"10.1002/aesr.202400102","DOIUrl":"https://doi.org/10.1002/aesr.202400102","url":null,"abstract":"<p>The development of heterogeneous electrodes with high conductivity and electrocatalytic activity is a crucial goal. Achieving this using a simple and low-cost method is essential for wastewater purification by anodic oxidation combined with peroxymonosulfate (PMS). Herein, TiO<sub>2</sub>–CaTiO<sub>3</sub>(CTO)-Cu<sub>2</sub>O–Cu heterojunction electrodes are prepared by mixing CaCu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> with different amounts of graphene oxide (GO). The different mixtures are pressed into pellets and sintered under inert atmosphere at 1100 °C for 3 h. The obtained pellets are used as anodes for PMS activation in the electrocatalysis. The efficiency of paracetamol (PCM) removal reaches its maximum (93%) after 90 min using the CTO–Cu–5GO electrode in a solution containing 10 ppm PCM, 210 mL sodium sulfate, and 0.5 mM PMS. The higher amount of metallic copper in this anode promotes the generation of radicals to effectively degrade PCM. In optimal conditions (1.2 V versus Ag/AgCl, 1 mM PMS, and 10 ppm PCM), PCM is completely removed in 45 min. According to the quenching test results, <sup>•</sup>O<sub>2</sub><sup>−</sup> and <sup>•</sup>OH are the radicals generated during PCM degradation, and <sup>•</sup>O<sub>2</sub><sup>−</sup> plays the main role. In this work, insights are provided into the rational combination of different metal oxides with TiO<sub>2</sub> as a heterostructure electrode to ensure high mineralization of pharmaceuticals by electrocatalysis.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400102","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integration of Renewable Energy in Microgrids and Smart Grids in Deregulated Power Systems: A Comparative Exploration 放松管制的电力系统中微电网和智能电网中的可再生能源整合:比较探索
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-08-01 DOI: 10.1002/aesr.202400088
Subhojit Dawn, A. Ramakrishna, M. Ramesh, Shreya Shree Das, K. Dhananjay Rao, Md. Minarul Islam, Taha Selim Ustun
{"title":"Integration of Renewable Energy in Microgrids and Smart Grids in Deregulated Power Systems: A Comparative Exploration","authors":"Subhojit Dawn,&nbsp;A. Ramakrishna,&nbsp;M. Ramesh,&nbsp;Shreya Shree Das,&nbsp;K. Dhananjay Rao,&nbsp;Md. Minarul Islam,&nbsp;Taha Selim Ustun","doi":"10.1002/aesr.202400088","DOIUrl":"https://doi.org/10.1002/aesr.202400088","url":null,"abstract":"<p>In recent years, the importance of deregulated power systems has grown significantly, resulting in positive effects on stability, reliability, innovation, and investment in new energy grid technology. The competitive landscape among energy providers and distributors has empowered consumers to not only save money on their energy bills but also incorporate sustainable energy sources into the grid. To efficiently manage electricity distribution, deregulated power systems must include a smart grid and microgrid (MG). Herein, the potential for sustainable expansion of these systems, as well as their economic and environmental implications, are examined. A comprehensive grid system that integrates smart grids and MGs can offer a complete solution, catering to the evolving energy needs of communities and businesses. The advantages of establishing such a system, including improved grid stability, reliability, and increased utilization of renewable energy sources (RES), are highlighted. Furthermore, the integration of MGs and smart grids enhances the management of distributed generation, allowing power companies to optimize system operations for profitability and efficiency. By following these suggestions, businesses and stakeholders in the power sector can enhance the efficiency and responsibility of their systems, resulting in benefits for both the economy and the environment.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400088","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142428901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of Dimethylformamide, Tetrahydrofuran, and Dimethyl Sulfoxide on Bulk Heterojunction Organic Solar Cells’ Efficiency and Environmental Footprint 二甲基甲酰胺、四氢呋喃和二甲基亚砜对块状异质结有机太阳能电池效率和环境足迹的影响
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-07-26 DOI: 10.1002/aesr.202400193
Fernando Rodríguez-Mas, David Valiente, Pablo Corral, José Luis Alonso, Susana Fernández de Ávila
{"title":"Impact of Dimethylformamide, Tetrahydrofuran, and Dimethyl Sulfoxide on Bulk Heterojunction Organic Solar Cells’ Efficiency and Environmental Footprint","authors":"Fernando Rodríguez-Mas,&nbsp;David Valiente,&nbsp;Pablo Corral,&nbsp;José Luis Alonso,&nbsp;Susana Fernández de Ávila","doi":"10.1002/aesr.202400193","DOIUrl":"10.1002/aesr.202400193","url":null,"abstract":"<p>Organic solar cells (OSCs), especially those employing bulk heterojunction architecture, present a promising avenue in renewable energy technology. These devices utilize organic materials and can be doped by solvents such as dimethylformamide (DMF), tetrahydrofuran (THF), and dimethyl sulfoxide (DMSO). Solvent doping (DMF, THF, and DMSO) is observed to augment the efficiency of OSCs. However, a trade-off exists between the volume of solvent used and the device's efficiency. The judicious selection of solvents is crucial as it directly impacts the environmental footprint of the fabrication process and the power conversion efficiency. Notably, the use of solvents in OSC fabrication contributes to reducing the environmental impact across various categories, in particular Abiotic Depletion, Global Warming, and Human Toxicity. Among the solvents studied, THF demonstrates the most significant reduction in environmental impact. Therefore, optimizing the choice and volume of solvents in OSC fabrication is paramount for achieving both enhanced device performance and minimal environmental footprint.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400193","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141799627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revisiting the Electrocatalyst Role on Lignin Depolymerization 重新审视电催化剂在木质素解聚过程中的作用
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-07-23 DOI: 10.1002/aesr.202400130
Lucie M. Lindenbeck, Vanessa C. Barra, Björn B. Beele, Bruno V. M. Rodrigues, Adam Slabon
{"title":"Revisiting the Electrocatalyst Role on Lignin Depolymerization","authors":"Lucie M. Lindenbeck,&nbsp;Vanessa C. Barra,&nbsp;Björn B. Beele,&nbsp;Bruno V. M. Rodrigues,&nbsp;Adam Slabon","doi":"10.1002/aesr.202400130","DOIUrl":"10.1002/aesr.202400130","url":null,"abstract":"<p>Replacing fossil resources as the primary source of carbon-based chemicals by alternative feedstocks, while implementing more sustainable production routes, has become imperative for environmental and resource sustainability. In this context, lignin, often treated as a biomass waste, emerges as an appealing candidate, considering the principles of circular economy. For this pursuit, depolymerization methods offer potential strategies to harness lignin to produce valuable organic chemicals, while electrocatalysis processes stand out especially in the context of sustainability, as they can be powered by electricity from renewable sources. This minireview article explores the pivotal role of various electrocatalysts in lignin depolymerization, investigating both oxidative and reductive pathways. Emphasizing recent advancements, the review delves into the diverse nature of electrocatalysts and their influence on lignin valorization. Highlighting current trends, the discussion encompasses the catalytic mechanisms and selectivity of electrochemical processes employed for lignin breakdown. Additionally, some insights into emerging technologies are also offered, emphasizing the need for sustainable and efficient strategies. By providing an overview of the field, this minireview aims to guide future research endeavors toward innovative electrocatalytic approaches for lignin depolymerization, paving the way for sustainable biorefinery processes.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400130","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Screening of Ultra-Efficient Visible Light Catalysts via Material Modification to Activate Electron Polarization Inside the Material 通过材料改性激活材料内部电子极化,筛选超高效可见光催化剂
IF 6.2
Advanced Energy and Sustainability Research Pub Date : 2024-07-17 DOI: 10.1002/aesr.202400175
Hong Tu, Ying Xu, Shun-shun Chen, Ya Wang, Sheng-xin Guo, Jian Wu
{"title":"Screening of Ultra-Efficient Visible Light Catalysts via Material Modification to Activate Electron Polarization Inside the Material","authors":"Hong Tu,&nbsp;Ying Xu,&nbsp;Shun-shun Chen,&nbsp;Ya Wang,&nbsp;Sheng-xin Guo,&nbsp;Jian Wu","doi":"10.1002/aesr.202400175","DOIUrl":"10.1002/aesr.202400175","url":null,"abstract":"<p>The high catalytic activity of photocatalysts is greatly influenced by the efficient separation of photogenerated charge carriers. In this study, six g-C<sub>3</sub>N<sub>4</sub>-based COFs are designed and synthesized, and CN-203 is identified as the most efficient photocatalyst through experimental screening. Quantitative measurements reveal that singlet oxygen production is ≈100 times that of ·O<sub>2</sub><sup>−</sup> and 5000 times that of ·OH. When combined with PMS, CN-203 exhibits degradation rates for RhB and TC that are ≈30 (<i>k</i> = 0.0293 s<sup>−1</sup>) and 10 (<i>k</i> = 0.2940 min<sup>−1</sup>) times faster than those of CN550(RhB, <i>k</i> = 0.0531 min<sup>−1</sup>; TC, <i>k</i> = 0.0301 min<sup>−1</sup>), respectively. Structural simulations and calculations show that the modified CN-203 have better electron–hole separation in the excited state, and the energy gap between HOMO and LUMO is significantly reduced after modification. The study also revealed the structure–function relationship between the modification of the same site with different functional groups and its effect on photocatalysis. Overall, this study provides valuable insights into the relationship between surface structure and photocatalytic applications.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":null,"pages":null},"PeriodicalIF":6.2,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400175","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141830508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信