Corrosion Science最新文献_第5页

Corrosion behaviors of Fe50Mn30Co10Cr10 high-entropy alloy wires with different processing states in various aqueous environments 不同加工状态下Fe50Mn30Co10Cr10高熵合金丝在不同水环境中的腐蚀行为

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-15 DOI: 10.1016/j.corsci.2025.113318

Xiaoyang Zhang , Jinchen Yang , Pengya Lei , Ruifeng Dong , Hua Hou , Yuhong Zhao

{"title":"Corrosion behaviors of Fe50Mn30Co10Cr10 high-entropy alloy wires with different processing states in various aqueous environments","authors":"Xiaoyang Zhang , Jinchen Yang , Pengya Lei , Ruifeng Dong , Hua Hou , Yuhong Zhao","doi":"10.1016/j.corsci.2025.113318","DOIUrl":"10.1016/j.corsci.2025.113318","url":null,"abstract":"<div><div>The electrochemical corrosion behavior and passive film characteristics of a low-stacking-fault-energy high-entropy alloy (HEA) cold-drawn wire with the composition of Fe<sub>50</sub>Mn<sub>30</sub>Co<sub>10</sub>Cr<sub>10</sub> were studied in acidic, alkaline, and saline solutions with three different processing states: deformation, recovery, and recrystallization. In NaCl solutions, the cold-drawn sample exhibits the best corrosion resistance, attributed to its high dislocation density and the formation of stable Mn-rich passive films. In contrast, the recrystallized sample shows the highest corrosion susceptibility. In low concentration H<sub>2</sub>SO<sub>4</sub> solution, the cold-drawn sample demonstrates the best corrosion resistance, with high dislocation density enhancing passive film stability. However, as the H<sub>2</sub>SO<sub>4</sub> concentration increases to 1 M, corrosion resistance deteriorates, with the recrystallized sample showing the best performance. At 2 M H<sub>2</sub>SO<sub>4</sub>, the recovered sample performs relatively better. X-ray photoelectron spectroscopy (XPS) analysis reveals that the Cr<sub>2</sub>O<sub>3</sub> content on the alloy surface is influenced by both the microstructure and acid concentration, which together regulate the competition between oxidation and dissolution kinetics. In alkaline solutions, corrosion resistance improves with increasing NaOH concentration, with the cold-drawn sample exhibiting the best performance due to enhanced passivation stability. This study establishes a framework for tailoring HEA wire processing strategies to achieve enhanced durability in diverse corrosive environments by elucidating the critical relationships between microstructure, processing history, and corrosion resistance.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"257 ","pages":"Article 113318"},"PeriodicalIF":7.4,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145099694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The performance and mechanisms of imidazoline phosphonate inhibitors in mitigating sulfate-reducing bacteria-induced under deposit corrosion 咪唑啉膦酸盐抑制剂抑制沉积物腐蚀中硫酸盐还原菌诱导的性能及机理

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-13 DOI: 10.1016/j.corsci.2025.113317

Ting Xu, Min Du, Gengxin Li

引用次数: 0

Synergistic acceleration of galvanic corrosion by selective D. vulgaris colonization on the heat-affected zone of steel welds 钢焊缝热影响区中普通弧菌选择性定植对电偶腐蚀的协同加速作用

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-12 DOI: 10.1016/j.corsci.2025.113316

Yunlong Bai , Jin Xu , Kaihui Dong , Guanlun Guo , Feng Tian , Boxin Wei , Changkun Yu , Cheng Sun

{"title":"Synergistic acceleration of galvanic corrosion by selective D. vulgaris colonization on the heat-affected zone of steel welds","authors":"Yunlong Bai , Jin Xu , Kaihui Dong , Guanlun Guo , Feng Tian , Boxin Wei , Changkun Yu , Cheng Sun","doi":"10.1016/j.corsci.2025.113316","DOIUrl":"10.1016/j.corsci.2025.113316","url":null,"abstract":"<div><div>The study reveals that <em>D. vulgaris</em> (sulfate-reducing bacteria, SRB) selectively accelerate galvanic corrosion in the heat-affected zone (HAZ) of X80 steel under thin liquid films, using electrochemical tests, scanning vibrating electrode technology (SVET), ultraviolet photoelectron spectroscopy (UPS), and finite element simulation (FES). UPS confirmed that the HAZ exhibits a lower work function, which not only enhances its anodic activity but also promotes the adsorption of <em>D. vulgaris</em>. Furthermore, galvanic coupling between the HAZ and other regions intensifies this selective bacterial colonization. The concentrated metabolic activities of the adsorbed <em>D. vulgaris</em> further amplify the driving force for galvanic corrosion. Collectively, these synergistic effects result in a significantly increased anodic current density of 14.38 μA·cm<sup>−2</sup> in the HAZ, which is 3.94 times higher than the control group, thereby enhancing the susceptibility to localized corrosion.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"257 ","pages":"Article 113316"},"PeriodicalIF":7.4,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145099691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Superior hydrogen embrittlement resistance of 1.9 GPa-grade precipitation hardening stainless steel achieved by multi-phase precipitation engineering 采用多相沉淀法使1.9 gpa级沉淀硬化不锈钢具有优异的抗氢脆性能

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-12 DOI: 10.1016/j.corsci.2025.113315

Zhe Yang , Boxuan Cao , Zhenbao Liu , Yilu Zhao , Jun Wei

{"title":"Superior hydrogen embrittlement resistance of 1.9 GPa-grade precipitation hardening stainless steel achieved by multi-phase precipitation engineering","authors":"Zhe Yang , Boxuan Cao , Zhenbao Liu , Yilu Zhao , Jun Wei","doi":"10.1016/j.corsci.2025.113315","DOIUrl":"10.1016/j.corsci.2025.113315","url":null,"abstract":"<div><div>Overcoming the inherent high susceptibility of hydrogen embrittlement (HE) remains an enduring objective in the development of precipitation hardening stainless steels. This study demonstrates how multi-phase precipitation engineering synergistically enhances hydrogen resistance in duplex-aged Ferrium S53 steel through coupled experiments and simulations. TDS analysis identifies three distinct hydrogen desorption peaks corresponding to trapping at martensitic substructures, austenite interfaces, and nanoprecipitates, with the secondary-aged condition showing enhanced trapping capacity. Microstructural engineering through optimized aging generates high-density <em>M</em>₂C/α'<sub>Cr</sub> nanoprecipitates and stabilized austenite, shifting hydrogen desorption peaks to higher altitudes and reducing mobile hydrogen populations. Fracture analysis demonstrates the competing roles of plasticity-mediated and decohesion mechanisms, with their relative dominance evidenced by hybrid fracture features combining intergranular cracking with localized plasticity markers. First-principles calculations reveal Mo-modified carbides exhibit reduced vacancy formation barriers while increased hydrogen binding energy. The coordinated microstructure design achieves superior embrittlement resistance through: (i) TDS-verified hydrogen capture at engineered reversible traps, (ii) dislocation pinning that impedes hydrogen transport, and (iii) suppression of critical hydrogen accumulation at vulnerable interfaces. These findings establish a microstructure-property framework for developing hydrogen-resistant alloys via precipitation engineering.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"257 ","pages":"Article 113315"},"PeriodicalIF":7.4,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145099690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrogen microprinting revealing role of strain-induced defects on hydrogen distribution near austenite crack tip 氢微印揭示应变缺陷对奥氏体裂纹尖端附近氢分布的影响

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-11 DOI: 10.1016/j.corsci.2025.113314

Weijie Wu , Chenwei Xia , Zhicheng Fang , Xuewei Zhang , Xiaowei Wang , Jianming Gong , Jinxu Li

引用次数: 0

Designing ultra-high corrosion resistance Mg alloys by passivating cathodic activity and promoting RE oxide films 通过钝化阴极活性和促进稀土氧化膜来设计超高耐蚀性镁合金

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-10 DOI: 10.1016/j.corsci.2025.113312

Ye Tian , Zhihao Yang , Junsheng Wang , Chi Zhang , Chengpeng Xue , Hui Su , Yisheng Miao , Zhongyao Li , Wenbo Wu , Xinghai Yang

{"title":"Designing ultra-high corrosion resistance Mg alloys by passivating cathodic activity and promoting RE oxide films","authors":"Ye Tian , Zhihao Yang , Junsheng Wang , Chi Zhang , Chengpeng Xue , Hui Su , Yisheng Miao , Zhongyao Li , Wenbo Wu , Xinghai Yang","doi":"10.1016/j.corsci.2025.113312","DOIUrl":"10.1016/j.corsci.2025.113312","url":null,"abstract":"<div><div>Many studies on improving the corrosion resistance of Mg alloys have been focusing on identifying certain elements which can reduce the corrosion rate of Mg alloys. However, without quantitative analysis of individual contributions of alloying elements and their combined effects, the corrosion resistance alloy design is always performed by trial-and-error process. In this study, we have quantified the effects of binary, ternary and quaternary additions of Y, Ce, and Mn to Mg alloys and found that their electrochemical performances are not only a function of simple dissolution but also their existing states by microstructure quantification before and after immersion tests. Using first-principles calculations, we have found that the beneficial effects of Rare Earth (RE) elements, such as Ce, and Y, can only be effective when they form secondary phases and act as the anode to form oxide films in front of Mg matrix; while dissolution of Mn can actually passivate the cathodic activity and improve the work function of the matrix (from 3.66 eV to 3.80 eV). Measurements of as-cast Mg-2Y-0.5Ce-0.5Mn alloy exhibit the best corrosion resistance (0.395 mm/y), due to both reduction of galvanic corrosion sites and protection of RE-containing oxides. Therefore, ultra-high corrosion-resistant Mg alloys have been successfully developed by passivating cathodic activity and promoting RE oxide films, further illuminating a new route for stainless Mg alloy development.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"257 ","pages":"Article 113312"},"PeriodicalIF":7.4,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of CaO/MgO bilayer film formation on nonflammability and oxidation resistance of Mg–Al–Ca alloys determined by high-temperature in situ residual stress measurement CaO/MgO双层膜形成对高温原位残余应力测定Mg-Al-Ca合金不燃性和抗氧化性的影响

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-09 DOI: 10.1016/j.corsci.2025.113311

Shin-ichi Inoue , Loku Singgappulige Rosantha Kumara , Yoshihito Kawamura

引用次数: 0

Enhanced corrosion resistance and mechanism of a novel Mg-4Li-6Zn-1Y-0.2Ca alloy through cross-rolling and Ca microalloying 交叉轧制和Ca微合金化对新型Mg-4Li-6Zn-1Y-0.2Ca合金耐蚀性能的增强及其机理研究

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-09 DOI: 10.1016/j.corsci.2025.113293

Zihao Liu , Shidong Wang , Baojie Wang , Daokui Xu , Wanqing Chang , Chuanqiang Li , Shuo Wang , Hongzhi Cui , Bolv Xiao , Zongyi Ma

{"title":"Enhanced corrosion resistance and mechanism of a novel Mg-4Li-6Zn-1Y-0.2Ca alloy through cross-rolling and Ca microalloying","authors":"Zihao Liu , Shidong Wang , Baojie Wang , Daokui Xu , Wanqing Chang , Chuanqiang Li , Shuo Wang , Hongzhi Cui , Bolv Xiao , Zongyi Ma","doi":"10.1016/j.corsci.2025.113293","DOIUrl":"10.1016/j.corsci.2025.113293","url":null,"abstract":"<div><div>In this study, a novel Ca-microalloyed Mg-4Li-6Zn-1Y-0.2Ca alloy was developed to address corrosion issues associated with the fragmentation of icosahedral quasicrystalline phase (I-phase) eutectic pockets and the non-uniform distribution of precipitates in conventionally processed Mg-Li-Zn-Y alloys. The effects of cross-rolling (CR) at reduction ratios of 20 %, 40 %, and 80 % on the microstructural evolution and corrosion behavior were systematically investigated. Cross-rolling significantly promoted dynamic recrystallization, reducing the average grain size from 59.6 μm in the annealed state to 2.4 μm at 80 % reduction. It also fragmented and dispersed coarse secondary phases (I-Mg<sub>3</sub>Zn<sub>6</sub>Y, W-Mg<sub>3</sub>Zn<sub>3</sub>Y<sub>2</sub>, and Ca<sub>2</sub>Mg<sub>6</sub>Zn<sub>3</sub>), while promoting the uniform precipitation of nanoscale LiMgZn particles. As the reduction ratio increased, corrosion behavior shifted from severe localized attack to more uniform degradation. Annealed samples formed loose and discontinuous Mg(OH)<sub>2</sub>/CaCO<sub>3</sub> corrosion layers that provided limited protection, whereas the CR80 % samples developed compact and continuous Mg(OH)<sub>2</sub>-based layers incorporating CaCO<sub>3</sub> and Li<sub>2</sub>CO<sub>3</sub>. Consequently, the corrosion rate of the CR80 % sample decreased to 1.34 mm/y, representing a 77 % reduction compared to the annealed state (5.71 mm/y). This improvement is attributed to the refined microstructure and uniform distribution of LiMgZn precipitates, which enhanced the compactness and integrity of the corrosion product layer, thereby improving corrosion resistance.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"257 ","pages":"Article 113293"},"PeriodicalIF":7.4,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145060027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of an MAO/PMTMS composite coating on the electrochemical corrosion and stress corrosion cracking behavior of an AZ80 magnesium alloy MAO/PMTMS复合涂层对AZ80镁合金电化学腐蚀和应力腐蚀开裂行为的影响

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-08 DOI: 10.1016/j.corsci.2025.113308

Xing Qi , Zihan Zhuo , Yafeng He , Xiang Su , Cheng Yang , Bo Jiang , Renguo Song

引用次数: 0

Mechanism modeling and prediction of Ag electrochemical migration failure in ultra-thin liquid film 超薄液膜中银电化学迁移失效机理建模与预测

IF 7.4 1区材料科学

Corrosion Science Pub Date : 2025-09-08 DOI: 10.1016/j.corsci.2025.113309

Jing Liu , Yabin Jing , Ran Wei , Jingjing Peng , Xian Zhang , Lin Cheng , Tao Zhang

引用次数: 0