{"title":"晶界工程和高Cr含量增强了双相多主成分合金的抗氧化性","authors":"Huijie Wei , Ping Huang , Fei Wang","doi":"10.1016/j.corsci.2025.113369","DOIUrl":null,"url":null,"abstract":"<div><div>The oxidation behavior of dual-phase FeCrNiAlTi multi-principal component alloys (MCAs) with tailored grain/phase boundaries (GBs/PBs) lengths was systematically investigated by isothermal oxidation at 800℃ in air. Experimental results demonstrate that GBs/PBs engineering, when coupled with chemical composition tuning, yields a significant enhancement of oxidation resistance. The alternating distribution of face-centered cubic (FCC) and body-centered cubic (BCC) grains with short interphase distances facilitates lateral oxide growth along boundaries, promoting the formation of a continuous oxide film. Specifically, prolonged GBs/PBs lengths (up to 320.472 mm⁻¹) and high Cr content in BCC phases (54.20 %) accelerate the diffusion kinetics of protective elements (Al/Cr) during initial oxidation, enabling rapid formation of dense, continuous oxidation scales composed of Al<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub>. Notably, the continuous Al<sub>2</sub>O<sub>3</sub> layer acts as an effective barrier, suppressing subsequent outward Cr diffusion and inward oxygen ingress, thereby decelerating oxidation kinetics (parabolic rate constant <em>k</em><sub><em>p</em></sub> = 0.19 ×10⁻<sup>3</sup> mg<sup>2</sup>·cm⁻<sup>4</sup>·h⁻<sup>1</sup>) and outperforming many previously reported MCAs. This work highlights that GBs/PBs engineering, coupled with chemical composition adjustment, offers a viable pathway for developing high-performance MCAs for high-temperature structural applications.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113369"},"PeriodicalIF":7.4000,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Grain/phase boundary engineering and high Cr contents enhancing oxidation resistance of dual-phase multi-principal component alloys\",\"authors\":\"Huijie Wei , Ping Huang , Fei Wang\",\"doi\":\"10.1016/j.corsci.2025.113369\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The oxidation behavior of dual-phase FeCrNiAlTi multi-principal component alloys (MCAs) with tailored grain/phase boundaries (GBs/PBs) lengths was systematically investigated by isothermal oxidation at 800℃ in air. Experimental results demonstrate that GBs/PBs engineering, when coupled with chemical composition tuning, yields a significant enhancement of oxidation resistance. The alternating distribution of face-centered cubic (FCC) and body-centered cubic (BCC) grains with short interphase distances facilitates lateral oxide growth along boundaries, promoting the formation of a continuous oxide film. Specifically, prolonged GBs/PBs lengths (up to 320.472 mm⁻¹) and high Cr content in BCC phases (54.20 %) accelerate the diffusion kinetics of protective elements (Al/Cr) during initial oxidation, enabling rapid formation of dense, continuous oxidation scales composed of Al<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub>. Notably, the continuous Al<sub>2</sub>O<sub>3</sub> layer acts as an effective barrier, suppressing subsequent outward Cr diffusion and inward oxygen ingress, thereby decelerating oxidation kinetics (parabolic rate constant <em>k</em><sub><em>p</em></sub> = 0.19 ×10⁻<sup>3</sup> mg<sup>2</sup>·cm⁻<sup>4</sup>·h⁻<sup>1</sup>) and outperforming many previously reported MCAs. This work highlights that GBs/PBs engineering, coupled with chemical composition adjustment, offers a viable pathway for developing high-performance MCAs for high-temperature structural applications.</div></div>\",\"PeriodicalId\":290,\"journal\":{\"name\":\"Corrosion Science\",\"volume\":\"258 \",\"pages\":\"Article 113369\"},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2025-09-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010938X25006973\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X25006973","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Grain/phase boundary engineering and high Cr contents enhancing oxidation resistance of dual-phase multi-principal component alloys
The oxidation behavior of dual-phase FeCrNiAlTi multi-principal component alloys (MCAs) with tailored grain/phase boundaries (GBs/PBs) lengths was systematically investigated by isothermal oxidation at 800℃ in air. Experimental results demonstrate that GBs/PBs engineering, when coupled with chemical composition tuning, yields a significant enhancement of oxidation resistance. The alternating distribution of face-centered cubic (FCC) and body-centered cubic (BCC) grains with short interphase distances facilitates lateral oxide growth along boundaries, promoting the formation of a continuous oxide film. Specifically, prolonged GBs/PBs lengths (up to 320.472 mm⁻¹) and high Cr content in BCC phases (54.20 %) accelerate the diffusion kinetics of protective elements (Al/Cr) during initial oxidation, enabling rapid formation of dense, continuous oxidation scales composed of Al2O3 and Cr2O3. Notably, the continuous Al2O3 layer acts as an effective barrier, suppressing subsequent outward Cr diffusion and inward oxygen ingress, thereby decelerating oxidation kinetics (parabolic rate constant kp = 0.19 ×10⁻3 mg2·cm⁻4·h⁻1) and outperforming many previously reported MCAs. This work highlights that GBs/PBs engineering, coupled with chemical composition adjustment, offers a viable pathway for developing high-performance MCAs for high-temperature structural applications.
期刊介绍:
Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies.
This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.