Turkish Journal of Chemistry最新文献

{"title":"A new turn off fluorescent NIR probe for hypochlorous acid and its applications.","authors":"Ayten Ibrahimova, Ayşe Nur Önem, Mehmet Altun, Emin Ahmet Yeşil, Aslı Baysal, Hasan Saygin, Ahu Soyocak, Mustafa Özyürek","doi":"10.55730/1300-0527.3725","DOIUrl":"10.55730/1300-0527.3725","url":null,"abstract":"<p><p>Hypochlorous acid (HOCl) is a potent nonradical oxidant involved in various physiological processes, particularly within the human immune system. In this study, we introduce a novel, rapid, and highly efficient fluorometric method for the detection of HOCl. The method utilizes a near-infrared (NIR)-based fluorescent probe, NIR-QBH, which is characterized by its high sensitivity and chemical stability. NIR-QBH, containing olefinic C=C bonds, exhibits strong NIR emission at 660 nm (λ_ex = 618 nm). The detection mechanism relies on the oxidation of the C=C bond in the NIR-QBH structure by HOCl, resulting in the formation of non-fluorescent products. With a detection limit of 0.23 μM, the probe demonstrates a fast response time of 4 min. Glutathione (GSH), an essential biothiol, was employed as a reference HOCl scavenger, and its HOCl scavenging activity was evaluated with an IC₅₀ value of 8.97 μM. Furthermore, the developed fluorometric assay was successfully applied for the detection of HOCl in fetal bovine serum (FBS) and aqueous solutions.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"241-253"},"PeriodicalIF":1.3,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068673/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144012037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ecofriendly synthesis and characterization of oxygen-enriched g-C₃N₄ from diverse precursors for efficient organic dye decontamination.","authors":"Muchammad Tamyiz","doi":"10.55730/1300-0527.3724","DOIUrl":"10.55730/1300-0527.3724","url":null,"abstract":"<p><p>Industrial wastewater from sectors such as textiles, printing, and pharmaceuticals contain harmful pollutants, including nonbiodegradable dyes, which pose significant challenges for environmental safety. Neutral red, a cationic dye commonly found in wastewater, obstructs photosynthesis in aquatic ecosystems and carries potential toxicity. Traditional methods of dye removal often prove ineffective due to the chemical stability of these compounds. In this study, oxygen-doped graphitic carbon nitride (O-doped g-C₃N₄) was synthesized as an innovative photocatalyst for the degradation of neutral red dye under visible light. The material was synthesized through a sustainable process involving the calcination of urea, dicyandiamide, and oxalic acid, and its characteristics were evaluated using various techniques, including XRD, FT-IR, UV-Vis spectroscopy, and SEM. Photocatalytic degradation of neutral red was analysed using a custom photoreactor under visible light. The results demonstrated that O-doped g-C₃N₄ exhibited enhanced photocatalytic efficiency compared to pure g-C₃N₄, reducing the recombination of electron-hole pairs and effectively degrading the dye. Adsorption kinetics followed a pseudo-2nd-order model, while adsorption isotherms suggested that the Langmuir model best described the adsorption process, indicating monolayer adsorption. The maximum adsorption capacity of O-doped g-C₃N₄ for neutral red was 9.643 mg g^-1, surpassing pure g-C₃N₄. The photocatalytic performance of OCN-UD was assessed under visible light, revealing a significant degradation efficiency of 86% for neutral red after 60 min, compared to 51% for pure g-C₃N₄. Kinetic studies indicated that the adsorption of neutral red onto OCN-UD primarily followed a pseudo-2nd-order model, demonstrating chemical adsorption processes. The synergistic effects of adsorption and photocatalysis were evident, as the initial adsorption phase concentrated dye molecules near active sites, facilitating efficient photocatalytic degradation through reactive oxygen species generation. This study highlights the potential of O-doped g-C₃N₄ as an efficient, eco-friendly solution for the treatment of dye-laden wastewater.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"228-240"},"PeriodicalIF":1.3,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068676/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144043956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"WO₃/α-Fe₂O₃/Bi₂S₃ ternary photoanode for improved oxygen evolution reaction in photoelectrochemical water splitting.","authors":"Fatih Tezcan, Abrar Ahmad, Gülfeza Kardaş","doi":"10.55730/1300-0527.3720","DOIUrl":"10.55730/1300-0527.3720","url":null,"abstract":"<p><p>This study presents a ternary WO₃/α-Fe₂O₃/Bi₂S₃ photoanode system suitable for photoelectrochemical water-splitting applications. WO₃/α-Fe₂O₃ heterojunction is obtained using a hydrothermal approach, while Bi₂S₃ is deposited onto WO₃/α-Fe₂O₃ via the successive ionic layer adsorption and reaction (SILAR) method. The cycle count is adjusted to determine the optimal photocatalytic photoanode. X-ray diffraction analysis confirms different morphologies and phases for the photoelectrodes: WO₃ is deposited as plates with monoclinic phases, α-Fe₂O₃ as nanorods with hexagonal phases, and Bi₂S₃ in the form of nanoparticles (NPs) with orthorhombic phases. Solar light absorption spectra indicate that ternary WO₃/α-Fe₂O₃/Bi₂S₃ photoanodes absorb a larger portion of the solar spectrum and display a large red shift in wavelength compared to binary WO₃/α-Fe₂O₃ photoanodes. Chronoamperometric and electrochemical impedance spectroscopy measurements indicate that the as-prepared WO₃/α-Fe₂O₃/Bi₂S₃ photoanode exhibits notable stability and low charge transfer resistance (R_ct) compared to binary electrodes and pristine WO₃ plates in faradaic photoelectrochemical conversion for the oxygen evolution reaction and S^-2/S² processes. Linear sweep voltammetry studies show that the WO₃/α-Fe₂O₃/Bi₂S₃ photoanode, sensitized with 8 SILAR cycles, achieves the maximum photocurrent density of 5.777 mA.cm^-2 at 1.0 V vs. RHE under 100 mW cm^-2 simulated solar irradiation.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"176-190"},"PeriodicalIF":1.3,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068670/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144012042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation of the interaction conditions of As₂S₅ and CuCl₂ compounds in water and ethylene glycol medium.","authors":"Huseyn Imanov, Mahnur Jafarli","doi":"10.55730/1300-0527.3722","DOIUrl":"10.55730/1300-0527.3722","url":null,"abstract":"<p><p>The article presents the results of the interaction conditions of CuCl₂ and As₂S₅ in ethylene glycol and aquatic medium. Besides, the results of the obtained samples' physicochemical properties are given by X-ray diffraction (XRD), differential thermogravimetric (DTG), thermogravimetric (TG), elemental, and scanning electron microscope (SEM) methods. It was found that when ethylene glycol and water are used as a solvent and CuCl₂ and As₂S₅ as the initial components, Cu₃AsS₄ is obtained at a temperature of 323-353 K. According to the results of DTA analysis, it was found that the melting point of obtained samples was 964.4 K contrary to the reactions carried out to obtain Cu₃(AsS₄)₂ compounds both in ethylene glycol and water medium. Elemental analysis of the compounds was carried out, energy-dispersion spectrum, mass, and atomic ratios of copper, arsenic, and sulfur were determined, and the stoichiometric composition of Cu₃AsS₄ was determined. Furthermore, X-ray analysis of the obtained samples confirmed that peaks on the graphs correspond to the standard intensity maxima of the Cu₃AsS₄ compound.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"204-214"},"PeriodicalIF":1.3,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068193/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143988357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of thiazole-integrated pyrrolotriazinones: evaluations of cytotoxicity and effects on PI3K levels in cancer cells.","authors":"Eylem Kuzu, Ege Arzuk, Fuat Karakuş, Burak Kuzu, Hasan Genç","doi":"10.55730/1300-0527.3723","DOIUrl":"10.55730/1300-0527.3723","url":null,"abstract":"<p><p>The synthesis of novel heterocyclic compounds, particularly those targeting critical signaling pathways in cancer, represents a promising approach to drug development. In this study, we designed and synthesized a series of thiazole-integrated pyrrolotriazinone derivatives, aiming to combine the antiproliferative properties of thiazole with the PI3K inhibitory activity of pyrrolotriazinones. The PI3K pathway, which plays a critical role in regulating cell growth, proliferation, and survival, is frequently dysregulated in cancer, making it an attractive target for therapeutic intervention. The synthesized derivatives were evaluated for their cytotoxic activities against MCF-7, A549, and HepG2 cancer cell lines. Their effect on PI3K protein levels was assessed to evaluate their potential as PI3K inhibitors. Preliminary results indicate that these thiazole-pyrrolotriazinone hybrids exhibit significant cytotoxic effects and may reduce PI3K protein levels in cancer cells. Furthermore, drug-likeness assessments and pre-ADMET evaluations demonstrated that the compounds exhibited promising characteristics, supporting their potential as viable drug candidates. Overall, this study highlights the potential of these novel compounds in cancer therapy and provides valuable insights into the design of small molecules that can target key regulatory pathways involved in cancer progression.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"215-227"},"PeriodicalIF":1.3,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068666/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144050325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A hindered phenol containing PVC/CuO nanocomposites; study on the mechanical and thermooxidative properties.","authors":"Mohsen Hajibeygi, Alireza Ghasemi","doi":"10.55730/1300-0527.3708","DOIUrl":"10.55730/1300-0527.3708","url":null,"abstract":"<p><p>The effect of synthesized 5-((4-hydroxy-3,5-di-tert-butylphenyl)diazenyl)isophthalic acid (HBA) containing a hindered phenol derivative on the thermooxidation, hydrochloric acid release time, and mechanical strength of PVC/CuO nanocomposites was studied. Moreover, 5-((4-hydroxy-2,5-dimethylphenyl)diazenyl)isophthalic acid (HMA) was synthesized for comparison of corresponding PVC nanocomposite properties. PVC nanocomposite thin films were prepared through in situ surface modification of CuO nanoparticles with HBA and HMA, individually, in the PVC solution. The XRD and FE-SEM results clarified the desirable dispersion of CuO nanoparticles. The PVC sample with loading of 5 wt% from each HBA and CuO was found to be the most thermally stable, which was confirmed by thermogravimetric analysis in inert conditions. The thermooxidation and Congo red test results revealed that the simultaneous loading of HBA and CuO nanoparticles into the PVC matrix could increase the initial thermal degradation and the stability times. Moreover, the PVC sample containing 2.5 wt% each from HBA and CuO nanoparticles exhibited tensile strength almost 20 MPa more than that of neat PVC.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 1","pages":"29-44"},"PeriodicalIF":1.3,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11913362/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143658741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication of Au-Pd bimetallic dendrites and their catalytic application for 4-nitrophenol reduction.","authors":"Jun Liu, Xuanyan Liu, Hongguang Liao","doi":"10.55730/1300-0527.3721","DOIUrl":"10.55730/1300-0527.3721","url":null,"abstract":"<p><p>Bimetal nanocatalysts hold significant application potential in catalytic reactions due to their compositions, morphologies, and electronic structures. In the present work, a series of AuPd alloy dendrites were successfully prepared using sodium formate, without surfactants or templates. A systematic investigation was then conducted to analyze the composition of the AuPd bimetallic dendrites and the effects of preparation conditions on their structure and catalytic performance. The AuPd alloy dendrites were characterized through various techniques, including scanning electron microscopy, transmission electron microscopy, X-ray energy scattering spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The results showed that the Au:Pd ratio in the AuPd alloy dendrites closely matched the initial feeding ratio. The catalytic activity and stability of the AuPd alloy dendrites towards 4-nitrophenol reduction were remarkably higher compared to those of the single metal Au and Pd nanocatalysts. Specifically, the Au₁Pd₁ alloy dendrites exhibited the highest catalytic reduction activity for 4-nitrophenol, with a reaction rate constant of 1.05 × 10^-2. Moreover, the stability of the Au₁Pd₁ alloy dendrites was also examined. The results demonstrated that the catalytic stability of the Au₁Pd₁ alloy dendrites did not experience a significant decrease even after five cycles of operation.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 2","pages":"191-203"},"PeriodicalIF":1.3,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12068668/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144034034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A new water-soluble silicon phthalocyanine that catalyzes the photodegradation of pollutant dyes.","authors":"Damla Nur Kaya, Behice Şebnem Sesalan","doi":"10.55730/1300-0527.3715","DOIUrl":"10.55730/1300-0527.3715","url":null,"abstract":"<p><p>The removal of color arising from water-soluble dyes in wastewaters is necessary to counter the threat to health. Because of the difficulty in elimination of these dyes by conventional methods, their photodegradation using photosensitizers such as phthalocyanines (Pcs) has been employed recently. When compared to peripherally substituted derivatives, silicon Pcs are reported to be more biocompatible with low toxicity. Thus a new silicon Pc substituted with two quaternized dimethylamino phenoxy units (compound 1) and its quaternized derivative (compound 2) were synthesized to test its photocatalytic ability employing the dyes methylene blue (MB), eosin B (EB), erythrosine (ERB), sulforhodamine B (SRB), and brilliant blue FCF (BRB), some of whose absorption bands overlap with those of Pcs. The overlapped absorption bands were split using first-order derivative UV-vis spectra. The photodegradation rates of BRB, MB, and ERB were 41%, 38%, and 29%, respectively, under 30-s short time irradiation in the presence of compound <b>2</b>. The plots of the natural logarithm of the concentrations of dyes versus time fit the first-order reaction model. According to the experimental data, compound <b>2</b> could be used as a photocatalyst due to singlet oxygen generation for photodegradation of pollutant dyes MB, ERB, and BRB with higher photodegradation rates.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 1","pages":"118-132"},"PeriodicalIF":1.3,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11913358/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143658745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The magnetic beads-based sandwich-shaped immune complexes for rapid and sensitive amperometric detection of SOX2 protein.","authors":"Göksu Özçelikay Akyildiz, Mehmet Altay Ünal, Seçil Gülden, Sibel A Özkan","doi":"10.55730/1300-0527.3712","DOIUrl":"10.55730/1300-0527.3712","url":null,"abstract":"<p><p>Sex-Determining Region Y-box 2 (SOX2) is a transcription factor protein. SOX2 expression is related to lymph node metastasis and distant metastasis in colorectal carcinomas. SOX2 was determined with the first magnetic disposable immunoplatform. The designed sandwich-shaped immune complexes were formed by a capture antibody, SOX2 protein, and biotinylated secondary antibodies (dAb/HRP). The sandwich-shaped immune complex was linked to carboxylic acid functionalized magnetic beads (HOOC-MBs). This magnetic bioconjugate was dropped on the surface of the screen-printed carbon electrode (SPCE). The amperometric measurement was performed at -0.20 V in the presence of hydroquinone (HQ) and H₂O₂ against a silver pseudo-reference electrode. The optimization parameters affecting the immunoassay response were evaluated. The analytical evaluation of the magnetic disposable immunoplatform for the amperometric detection of SOX2 standards was done. The developed immunosensor shows high sensitivity (LOD of 1.37 ng mL^-1) and a short analysis time (15 min). Potential interfering compounds found in serum samples were tested. The storage stability of magnetic disposable immunoplatform was evaluated. The developed immunosensor was compared with the ELISA method.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 1","pages":"79-88"},"PeriodicalIF":1.3,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11913366/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143658848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and characterization of RhFe/g-C₃N₄ nanoparticles for efficient hydrolysis of sodium borohydride.","authors":"Merve Uçar Kaya, Mehmet Yurderi, Mehmet Zahmakiran","doi":"10.55730/1300-0527.3711","DOIUrl":"10.55730/1300-0527.3711","url":null,"abstract":"<p><p>Highly effective graphitic carbon nitride-supported RhFe nanoparticles (RhFe/g-C₃N₄) were prepared using a simple wet impregnation-reduction method for the hydrolysis of sodium borohydride (NaBH₄). The obtained Rh_0.48Fe_0.52/g-C₃N₄ catalyst was characterized using advanced analytical/spectroscopic techniques such as inductively coupled plasma-optical emission spectroscopy, scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, X-ray spectroscopy, and Fourier transform infrared spectroscopy. The catalytic activities of RhFe/g-C₃N₄ catalysts with varying Rh/Fe molar ratios were investigated, demonstrating superior catalytic activity compared to monometallic Rh and Fe. The initial turnover frequency value of the Rh_0.48Fe_0.52/g-C₃N₄ catalyst was calculated as 33.04 min^-1 and it showed an H₂ generation rate of <math> <mrow><mrow><mn>4214.02</mn> <mi> </mi> <mtext>mL </mtext> <msup><mrow><mtext>min</mtext></mrow> <mrow><mo>-</mo> <mn>1</mn></mrow> </msup> <mi> </mi> <msubsup><mtext>g</mtext> <mrow><mtext>cat</mtext></mrow> <mrow><mo>-</mo> <mn>1</mn></mrow> </msubsup> </mrow> </mrow> </math> at 298 K. Furthermore, the kinetic parameters (<i>E</i> _a ^#, Δ<i>H</i> ^#, Δ<i>S</i> ^#) of the hydrolysis of NaBH₄ catalyzed by the Rh_0.48Fe_0.52/g-C₃N₄ catalyst were elucidated. The findings demonstrated that the resulting Rh_0.48Fe_0.52/g-C₃N₄ catalyst was recyclable and retained 80.72% of the initial activity even after 10 runs.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"49 1","pages":"68-78"},"PeriodicalIF":1.3,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11913354/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143658821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}