用聚苯胺/甘蔗渣复合材料去除污染土壤洗涤提取物中的DDT、DDD和DDE。

IF 1.4 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Turkish Journal of Chemistry Pub Date : 2025-04-12 eCollection Date: 2025-01-01 DOI:10.55730/1300-0527.3731
Hop Quang Nguyen, Bach Xuan Nguyen, Thien Quang Tran, Anh Van Nguyen
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引用次数: 0

摘要

聚苯胺(PANi)与甘蔗渣(BG)杂化处理了造成环境污染的持久性有机污染物(POPs)二氯二苯三氯乙烷(DDT)、二氯二苯二氯乙烯(DDE)和二氯二苯二氯乙烷化合物。以过硫酸铵和硫酸为原料合成了聚苯胺/甘蔗渣(PA/BG)复合材料,在聚苯胺单体与甘蔗渣的比例不同的情况下,合成效率在82.63% ~ 86.92%之间。利用红外光谱(IR)和扫描电镜(SEM)对合成材料进行了表征。考察了不同吸附剂类型、吸附时间、吸附剂用量和吸附质浓度对DDT、DDD和DDE化合物的吸附能力。采用Langmuir和Freundlich等温线模型对吸附过程进行了评价,结果表明,这两个模型都适用于描述聚苯乙烯/甘蔗渣复合材料对DDT、DDD和DDE的吸附。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Removal of DDT, DDD, and DDE from washing extracts of contaminated soil using polyaniline/bagasse composite material.

Removal of DDT, DDD, and DDE from washing extracts of contaminated soil using polyaniline/bagasse composite material.

Removal of DDT, DDD, and DDE from washing extracts of contaminated soil using polyaniline/bagasse composite material.

Removal of DDT, DDD, and DDE from washing extracts of contaminated soil using polyaniline/bagasse composite material.

Polyaniline (PANi) was hybridized with a bagasse (BG) substrate to treat Dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethylene (DDE), and dichlorodiphenyldichloroethane compounds, which are persistent organic pollutants (POPs) causing environmental contamination. The PANi/bagasse (PA/BG) composite was synthesized using ammonium persulfate and sulfuric acid, achieving efficiencies ranging from 82.63% to 86.92% with different ratios of PANi monomer to BG. Infrared spectroscopy (IR) and scanning electron microscopy (SEM) were used to characterize the synthesized materials. The adsorption capacities of DDT, DDD, and DDE compounds were investigated under various conditions, including adsorbent type, adsorption time, adsorbent dosage, and adsorbate concentration. Both Langmuir and Freundlich isotherm models were applied to evaluate the adsorption process, and the results indicated that both models were suitable for describing the adsorption of DDT, DDD, and DDE by the PANi/bagasse composite material.

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来源期刊
Turkish Journal of Chemistry
Turkish Journal of Chemistry 化学-工程:化工
CiteScore
2.40
自引率
7.10%
发文量
87
审稿时长
3 months
期刊介绍: The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.
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