Solar RRL最新文献

筛选
英文 中文
Claw-Inspired Molecular Anchoring for Perovskite Lattice Stabilization 钙钛矿晶格稳定的爪形分子锚定
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-12 DOI: 10.1002/solr.202500190
Husheng Yang, Huiyi Zong, Lizhi Ren, Yizhe Tang, Tao Ye, Jin Qian, Shengzhong (Frank) Liu, Jin Huang, Kai Wang, Dong Yang
{"title":"Claw-Inspired Molecular Anchoring for Perovskite Lattice Stabilization","authors":"Husheng Yang,&nbsp;Huiyi Zong,&nbsp;Lizhi Ren,&nbsp;Yizhe Tang,&nbsp;Tao Ye,&nbsp;Jin Qian,&nbsp;Shengzhong (Frank) Liu,&nbsp;Jin Huang,&nbsp;Kai Wang,&nbsp;Dong Yang","doi":"10.1002/solr.202500190","DOIUrl":"https://doi.org/10.1002/solr.202500190","url":null,"abstract":"<p>Metal halide perovskites are highly promising for next-generation photovoltaic devices, but their commercialization is hindered by instability, particularly due to the weakness of undercoordinated A-site and B-site cations (e.g., FA<sup>+</sup> and Pb<sup>2+</sup>) at lattice edges and grain boundaries. Inspired by the robust gripping mechanism of bird claws, which utilize minimal yet geometrically efficient structures to firmly secure targets, we produce a “molecular claw” strategy at the grain boundaries of the perovskite lattice. This approach introduces a claw-like molecule capable of multisite anchoring at grain boundaries, effectively stabilizing metastable terminal groups and mitigating failure pathways. Perovskite solar cells employing this strategy achieve exceptional efficiency and stability, with a stabilized efficiency of 24.63% compared to 21.08% for control devices, as well as 1400% increased lifetime of T80 compared to control devices. This claw-inspired protocol represents a novel example of mechanical structural mimetics applied at the molecular level to anchor active atomic groups, effectively stabilizing the intrinsically unstable soft lattice of perovskites to promote their photovoltaic commercialization process.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144219946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controllable Growth of Silver Crystallites on the Rear Ag–Si Contact Interface of TOPCon Solar Cells Through an Electrochemical Reduction Reaction Triggered by Laser-Enhanced Contact Optimization 通过激光增强接触优化触发的电化学还原反应在TOPCon太阳能电池Ag-Si后接触界面上可控生长银晶
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-12 DOI: 10.1002/solr.202500233
Yongsheng Li, Rui Zhou, Minghan Yu, Yanhong Tian, Yuan Lin, Feng Pan
{"title":"Controllable Growth of Silver Crystallites on the Rear Ag–Si Contact Interface of TOPCon Solar Cells Through an Electrochemical Reduction Reaction Triggered by Laser-Enhanced Contact Optimization","authors":"Yongsheng Li,&nbsp;Rui Zhou,&nbsp;Minghan Yu,&nbsp;Yanhong Tian,&nbsp;Yuan Lin,&nbsp;Feng Pan","doi":"10.1002/solr.202500233","DOIUrl":"https://doi.org/10.1002/solr.202500233","url":null,"abstract":"<p>Achieving a balance between passivation and contact has always been crucial for enhancing crystalline silicon (c-Si) solar cells, especially for the currently mainstream N-type TOPCon solar cells. The laser-enhanced contact optimization (LECO) technology improved both the quality and reliability of the front-side Ag–Si contacts in TOPCon solar cells. However, its impact on the rear-side Ag–Si contacts has been overlooked. By investigating LECO, its impact was revealed that electrochemical reduction reaction occurred at the rear-side Ag–Si interface during LECO. This reaction makes it possible for the controlled directional growth of Ag crystallites, thereby optimizing the Ag–Si contact quality. By adjusting the sintering temperature and applying LECO, a balance between passivation and conductivity is achieved, enabling the fabrication of TOPCon solar cells with high open-circuit voltage (<i>V</i><sub>oc</sub>) and low series resistor (<i>R</i><sub>s</sub>). This study not only clarifies the role of LECO in optimizing the rear-side Ag–Si contact of TOPCon solar cells but also provides valuable guidance for metallization optimization and power conversion efficiency enhancement of devices.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144219945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-Cost and Stable Semitransparent Crystalline Silicon Solar Cells via Two-Step Laser Processing 低成本和稳定的半透明晶体硅太阳能电池通过两步激光加工
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-09 DOI: 10.1002/solr.202500221
Haodong Chen, Honghua Zhang, Yinuo Zhou, Yunren Luo, Junlin Du, Guangyuan Wang, Anjun Han, Jianhua Shi, Wenjie Zhao, Fanying Meng, Zhengxin Liu, Wenzhu Liu, Liping Zhang
{"title":"Low-Cost and Stable Semitransparent Crystalline Silicon Solar Cells via Two-Step Laser Processing","authors":"Haodong Chen,&nbsp;Honghua Zhang,&nbsp;Yinuo Zhou,&nbsp;Yunren Luo,&nbsp;Junlin Du,&nbsp;Guangyuan Wang,&nbsp;Anjun Han,&nbsp;Jianhua Shi,&nbsp;Wenjie Zhao,&nbsp;Fanying Meng,&nbsp;Zhengxin Liu,&nbsp;Wenzhu Liu,&nbsp;Liping Zhang","doi":"10.1002/solr.202500221","DOIUrl":"https://doi.org/10.1002/solr.202500221","url":null,"abstract":"<p>Semitransparent (ST) solar cells hold promise for application in building-integrated photovoltaics and vehicles, but current ST solar cells often exhibit problems such as color uniformity, low efficiency, and poor stability. This study proposes a novel method of fabricating ST crystalline silicon solar cells with average visible transmittance (AVT) controlled via hexagon-arranged microhole patterns using two-step laser processing. The optimal configuration of microholes was evaluated, with the AVT as functions of microhole diameter and distance. The two steps of laser processing, avoiding the shunt problem during cell fabrication with one-step laser to form microholes, were individually performed. Thus, 80% and 20% of the thickness of silicon wafer were respectively removed via melting before and after cell fabrication. The advanced fabrication of a silicon heterojunction solar cell was thus conducted, and a wet procedure was responsible for removing the damage caused by first-step laser processing. Therefore, the performance of the cell mainly depended on the damage due to second-step laser processing. We finally prepared ST silicon solar cells with power conversion efficiency of 10.2% at AVT of 13%, damp-heat endurance, and neutral colors. This fabrication strategy represents a significant step toward the development of efficient ST solar cells and their application.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nonvolatile Solid Additive with a Simple Structure for Nonfullerene Organic Solar Cells 非富勒烯有机太阳能电池结构简单的非挥发性固体添加剂
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-09 DOI: 10.1002/solr.202500230
Do Hui Kim, Dong Chan Lee, Sujung Park, Jiwoo Yeop, Sung-Yeon Jang, Jin Young Kim, Shinuk Cho
{"title":"Nonvolatile Solid Additive with a Simple Structure for Nonfullerene Organic Solar Cells","authors":"Do Hui Kim,&nbsp;Dong Chan Lee,&nbsp;Sujung Park,&nbsp;Jiwoo Yeop,&nbsp;Sung-Yeon Jang,&nbsp;Jin Young Kim,&nbsp;Shinuk Cho","doi":"10.1002/solr.202500230","DOIUrl":"https://doi.org/10.1002/solr.202500230","url":null,"abstract":"<p>In organic solar cells (OSCs), precise control over the bulk heterojunction (BHJ) morphology is critical for optimizing device performance. A widely adopted strategy for regulating BHJ morphology involves the incorporation of small amounts of additives. However, employing volatile solid additives necessitates precise volatilization control, which remains challenging. While nonvolatile solid additives with high boiling points have been explored, most exhibit large and structurally complex architectures, raising concerns regarding their role in OSCs and their potential impact on charge transport. Thus, a nonvolatile solid additive with both a high boiling point and a simple molecular structure is highly desirable. In this study, 4-bromobiphenyl (BBP), a nonvolatile solid additive with a high boiling point and a simple chemical structure, was incorporated into OSCs to modulate BHJ morphology. The addition of BBP enhanced donor–acceptor miscibility, suppressed excessive aggregation, and promoted a uniform morphology with improved crystallinity. Consequently, the power conversion efficiency significantly increased to 18.11%, surpassing that of OSCs incorporating volatile solid additives while also enhancing long-term stability. This work provides a promising strategy for achieving stable BHJ morphology and improving OSC performance through nonvolatile solid additives.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500230","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Short-Circuit Current Density in Non-Fullerene-Based Ternary Organic Solar Cells by Incorporating Machine Learning Algorithms with Effective Descriptors 基于有效描述符的机器学习算法研究非富勒烯基三元有机太阳能电池的短路电流密度
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-08 DOI: 10.1002/solr.202500167
Min-Hsuan Lee, Ying-Chun Chen, Yi-Ming Chang, Bo Hou
{"title":"Investigation of Short-Circuit Current Density in Non-Fullerene-Based Ternary Organic Solar Cells by Incorporating Machine Learning Algorithms with Effective Descriptors","authors":"Min-Hsuan Lee,&nbsp;Ying-Chun Chen,&nbsp;Yi-Ming Chang,&nbsp;Bo Hou","doi":"10.1002/solr.202500167","DOIUrl":"https://doi.org/10.1002/solr.202500167","url":null,"abstract":"<p>Non-fullerene acceptor (NFA)-based ternary organic solar cells (OSCs) are emerging as promising devices for converting sunlight into electricity, contributing to environmental solutions. However, selecting the third component remains a significant challenge, as it plays a critical role in achieving high short-circuit current density (<i>J</i><sub>sc</sub>) in NFA-based ternary OSCs (comprising donors, acceptors, and the third component). Traditional trial-and-error experimental methods face substantial limitations, including high energy consumption, cost, and time demands, which may not be sufficient for investigating the quantitative relationships between material properties and <i>J</i><sub>sc</sub> in ternary OSCs. In this study, we examine the effects of the highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gap (ΔHOMO and ΔLUMO) between different organic materials, considering these as effective molecular descriptors, on the primary photovoltaic parameter (<i>J</i><sub>sc</sub>) in NFA-based ternary OSCs. The eXtreme Gradient Boosting (XGBoost) algorithm yields reasonable predictions, with an <i>R</i><sup>2</sup> value of 0.76. Additionally, three NFA-based ternary OSCs are fabricated and characterized experimentally to validate the predictions made by the proposed model. Using three different NFA-based ternary OSCs as inputs, the model demonstrates good predictive accuracy for <i>J</i><sub>sc</sub> values. The proposed interpretable model and effective molecular descriptors offer a practical machine-learning approach for accelerating the development of NFA-based ternary OSCs with targeted <i>J</i><sub>sc</sub> values and can also be extended to other organic electronic applications.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 10","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Naphthalene-Quinone Electron Donor–Acceptor Covalent Organic Polymers for Hydrogen Peroxide Photosynthesis in Pure Water 用于纯水过氧化氢光合作用的萘-醌电子供体-受体共价有机聚合物
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-06 DOI: 10.1002/solr.202500125
Yongxia Li, Jiafan Chu, Xingyu Zhang, Wenbo Li, Aiguo Kong
{"title":"Naphthalene-Quinone Electron Donor–Acceptor Covalent Organic Polymers for Hydrogen Peroxide Photosynthesis in Pure Water","authors":"Yongxia Li,&nbsp;Jiafan Chu,&nbsp;Xingyu Zhang,&nbsp;Wenbo Li,&nbsp;Aiguo Kong","doi":"10.1002/solr.202500125","DOIUrl":"https://doi.org/10.1002/solr.202500125","url":null,"abstract":"<p>A 2,3-diaminonaphthalene (DAN) 1,3,5-triformylphloroglucinol (TP) β-ketoenamine-linked covalent organic polymer with naphthalene-quinone electron donor (D)–acceptor (A) structure (DAN-TP-CKP) was synthesized using a one-pot method. It exhibited a high H<sub>2</sub>O<sub>2</sub> production rate of 1120 μmol g<sub>cat</sub><sup>−1</sup> h<sup>−1</sup> in O<sub>2</sub>-saturated water under visible light, together with better durability. The efficiency is attributed to its crystalline framework, large specific surface area (212 m<sup>2</sup> g<sup>−1</sup>), strong visible-light absorption, and efficient charge separation properties arising from its dense electron D–A structures. A two-step single-electron oxygen reduction reaction pathway with a probable four-step mechanism further elucidates its H<sub>2</sub>O<sub>2</sub> generation process. This work highlights D–A-type naphthalene–quinone metal-free polymer photocatalysts with efficient and durable H<sub>2</sub>O<sub>2</sub> photosynthesis performance.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 10","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “Comparative Study of Different Passivation Layers for n-i-P Perovskite Solar Cell for Indoor Applications” 对“室内应用n-i-P钙钛矿太阳能电池不同钝化层的比较研究”的更正
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-05 DOI: 10.1002/solr.202500286
{"title":"Correction to “Comparative Study of Different Passivation Layers for n-i-P Perovskite Solar Cell for Indoor Applications”","authors":"","doi":"10.1002/solr.202500286","DOIUrl":"https://doi.org/10.1002/solr.202500286","url":null,"abstract":"<p>U. A. Shah, G. Shankar, C. Malerba, P. P. Bonaccini, F. Zarotti, V. Novelli, Y. Keriti, A. Di Carlo, A. Mittiga, F. Biccari, E. Calabrò, <i>Solar RRL</i> 2025;9:e2400849. https://doi.org/10.1002/solr.202400849</p><p>Dr. Yasmina Keriti was inadvertently omitted from the author list. The correct author list with the relative affiliations is:</p><p>Usman Ali Shah<sup>1,2,3,4</sup>, Gyanendra Shankar<sup>3</sup>, Claudia Malerba<sup>5</sup>, Pier Paolo Bonaccini<sup>1,2</sup>, Francesca Zarotti<sup>3</sup>, Vittoria Novelli<sup>4,5</sup>, Yasmina Keriti<sup>1,2</sup>, Aldo Di Carlo<sup>3,6</sup>, Alberto Mittiga<sup>5</sup>, Francesco Biccari<sup>1,2</sup>, Emanuele Calabrò<sup>4</sup></p><p><sup>1</sup>Department of Physics and Astronomy, University of Florence, Sesto Fiorentino, Italy</p><p><sup>2</sup>European Laboratory for Nonlinear Spectroscopy (LENS), University of Florence, Sesto Fiorentino, Italy</p><p><sup>3</sup>C.H.O.S.E. (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata, Rome, Italy</p><p><sup>4</sup>Halocell Europe, Rome, Italy</p><p><sup>5</sup>ENEA, Casaccia Research Center, Department of Renewable and Sustainable Energies - Photovoltaic Labs, Rome, Italy</p><p><sup>6</sup>Istituto di Struttura della Materia (CNR-ISM), National Research Council, Rome, Italy</p><p>The Acknowledgment section also should be modified accordingly:</p><p>U.A.S. acknowledges the Italian Ministry of University and Research (MUR) for sponsoring his doctoral scholarship via the ‘PON RICERCA E INNOVAZIONE 2014–2020’ program, call ‘DM 1061/2021 AZIONE IV.5 ‘DOTTORATI SU TEMATICHE GREEN’’ and Halocell Europe, Italy, for sponsoring his industrial internship. G.S. acknowledges support from the MUR Program (CUP E83C22003460008). A.D.C. Acknowledges the support of the project ‘Network 4 Energy Sustainable Transition—NEST’, Spoke 1 (PE0000021), funded under the National Recovery and Resilience Plan (NRRP), Mission 4, Component 2, Investment 1.3—of Ministero dell’Universitá e della Ricerca (MUR); funded by the European Union—NextGenerationEU. P.P.B. and F.B. acknowledge the European Union (NextGenerationEU), the Italian Ministry of University and Research (MUR), and Fondazione Cassa di Risparmio di Firenze (FCRF) for funding this work within the project PUPO (CUP B95F21002470003); the European Union (NextGenerationEU), for funding this research through the research project National Quantum Science and Technology Institute (NQSTI). F.B. and Y.K. acknowledge Fondazione Cassa di Risparmio di Firenze for funding this work within the project Photonic Future (2021.1508). F.B. acknowledges the European Union (NextGenerationEU), for funding this research through the research project Integrated Infrastructure Initiative in Photonic and Quantum Sciences (i-PHOQS).</p><p>We apologize for this error.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500286","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Optimization and TCAD Simulation of Hole Transport and Passivation Layer In Narrow-Bandgap Perovskite Solar Cells 窄带隙钙钛矿太阳能电池空穴传输和钝化层的混合优化与TCAD模拟
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-05 DOI: 10.1002/solr.202500181
Tzu-Yu Huang, Chien-Chen Li, Yu-Hsuan Lai, Xin-Kai Gao, Yu-Chuan Huang, Chung-Chi Yang, Tien-Lin Wu, Chih-Shan Tan
{"title":"Hybrid Optimization and TCAD Simulation of Hole Transport and Passivation Layer In Narrow-Bandgap Perovskite Solar Cells","authors":"Tzu-Yu Huang,&nbsp;Chien-Chen Li,&nbsp;Yu-Hsuan Lai,&nbsp;Xin-Kai Gao,&nbsp;Yu-Chuan Huang,&nbsp;Chung-Chi Yang,&nbsp;Tien-Lin Wu,&nbsp;Chih-Shan Tan","doi":"10.1002/solr.202500181","DOIUrl":"https://doi.org/10.1002/solr.202500181","url":null,"abstract":"<p>Exploring the compatibility of Poly[(2,4,6-trimethylphenyl)diphenylamine] (PTAA) with narrow-bandgap perovskite solar cells, addressing the challenges posed by PTAA's hydrophobic nature. We combined two optimization techniques—phenethylammonium iodide (PEAI) passivation and UV-Ozone (UVO) treatment—to develop a hybrid approach. Contact angle measurements confirmed improved hydrophilicity, while atomic force microscopy and scanning electron microscopy showed smoother films with fewer defects. X-ray diffraction revealed enhanced grain size and crystallinity, supporting the benefits of hybrid optimization, particularly when PEAI was applied before UVO treatment. Technology computer-aided design (TCAD) simulations further validated that the hybrid optimization not only enhanced processing conditions but also boosted the device's overall power conversion efficiency (PCE) by improving band alignment. The results are supported with numerous simulated data, including potential profile, hole density, and recombination rate, hence unveiling the mechanism underlying the enhancement of PCE. This work presents a promising approach for advancing narrow-bandgap perovskite solar cells, using both experimental and simulated methods to show the impact of passivation, offering higher efficiency and reduced experimental costs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 10","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500181","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Blade-Coating Perovskites for Tandem Devices: Liquid Mechanism, Film Formation, and Performance 用于串联装置的叶片涂覆钙钛矿:液体机制,薄膜形成和性能
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-05-03 DOI: 10.1002/solr.202500149
Xuke Yang, Yongxin Zhu, Shuyu Yan, Haojun Hu, Chao Chen, Jiang Tang
{"title":"Blade-Coating Perovskites for Tandem Devices: Liquid Mechanism, Film Formation, and Performance","authors":"Xuke Yang,&nbsp;Yongxin Zhu,&nbsp;Shuyu Yan,&nbsp;Haojun Hu,&nbsp;Chao Chen,&nbsp;Jiang Tang","doi":"10.1002/solr.202500149","DOIUrl":"https://doi.org/10.1002/solr.202500149","url":null,"abstract":"<p>Perovskite solar cells have achieved a high efficiency and exhibited great potential for commercialization. Blade- and slot-die-coating techniques are regarded as the most competitive approaches for the future industrialization due to their capability for large-area fabrication. In contrast to the simple spin-coating method employed in lab-scale fabrication, the blade- and slot-die-coating techniques involve complex fluid dynamics and film growth processes, thereby leading to inferior film quality and device performance. In this review, we comprehensively analyze the influence of fluid mechanisms involved in all the blade-coating process and summarize the key points for preparing large-scale and uniform perovskite films. Subsequently, we highlight the influence of different solvent extraction techniques on the nucleation and crystallization processes of perovskite films. Moreover, a comprehensive assessment is performed to present the current states and challenges faced by both single-junction wide- and narrow-bandgap solar cells as well as all-perovskite tandem solar cells. Finally, we present a discussion aimed at advancing the development of large-area perovskite solar cells.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 10","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Metallization of P-Type Polysilicon in Bifacial TOPCon Structure Silicon Solar Cells Enabled by Ag–Ga Alloy Ag-Ga合金在双面TOPCon硅太阳电池中实现p型多晶硅的高效金属化
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-04-30 DOI: 10.1002/solr.202500107
Weipeng Lu, Qi Wang, Guizhong Yang, Guofa Yang, Yusheng Wang, Baoquan Sun
{"title":"Efficient Metallization of P-Type Polysilicon in Bifacial TOPCon Structure Silicon Solar Cells Enabled by Ag–Ga Alloy","authors":"Weipeng Lu,&nbsp;Qi Wang,&nbsp;Guizhong Yang,&nbsp;Guofa Yang,&nbsp;Yusheng Wang,&nbsp;Baoquan Sun","doi":"10.1002/solr.202500107","DOIUrl":"https://doi.org/10.1002/solr.202500107","url":null,"abstract":"<p>The development of bifacial tunnel oxide passivated contact (TOPCon) structure crystal silicon (c-Si) solar cells presents significant challenges, particularly regarding the metallization of p-type polysilicon (poly-Si (P)). The Al-containing Ag paste to achieve low contact resistivity atop poly-Si (P) may generate Ag–Al super spikes after sintering, penetrating the poly-Si (P) and degrading surface passivation. This study investigates gallium (Ga) as an alternative element alloying with Ag for poly-Si (P) metallization by mimicking screening-printing conducting paste with a facile thermal evaporation process at the proof-of-concept level. The enhanced doping concentration on the poly-Si (P) surface due to the Ga diffusion and the GaO<sub><i>x</i></sub> interlayer with high negative fixed charge density would facilitate the transport of holes from poly-Si (P) to the metal electrode, resulting in a low contact resistivity of 1.72 mΩ cm<sup>2</sup>. Besides, since the solid solubility of Si in Ga is significantly lower than that in Al, it is highly likely to avoid any overly grown spikes at the high-temperature sintering process. These findings provide valuable insights for developing effective poly-Si (P) metallization strategies in bifacial TOPCon structure c-Si solar cells by incorporating Ga into industrial screen-printed pastes.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 10","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信