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Correction to “Surface p-Type Self-Doping Facilitating the Enhanced Performance of Air-Processed Carbon-Based Perovskite Solar Cells” 更正“表面p型自掺杂促进空气处理碳基钙钛矿太阳能电池性能的提高”
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-26 DOI: 10.1002/solr.202500687
{"title":"Correction to “Surface p-Type Self-Doping Facilitating the Enhanced Performance of Air-Processed Carbon-Based Perovskite Solar Cells”","authors":"","doi":"10.1002/solr.202500687","DOIUrl":"https://doi.org/10.1002/solr.202500687","url":null,"abstract":"<p>Zhensang Tong, Kaihang Sang, Huanyi Zhou, Dongqi Wu, Suxin Zhao, Junfang Zhang, Ye Yang, Qi Pang, Anxiang Guan, Liya Zhou, Hanchi Cheng, and Peican Chen. Surface p-Type Self-Doping Facilitating the Enhanced Performance of Air-Processed Carbon-Based Perovskite Solar Cells. <i>Solar RRL.</i> 2025, 9(2): 2400712.</p><p>It has come to our attention that some errors have been found in Figure 4 in our original article. The error originated from an inadvertent mistake in data organization, which led to the use of incorrect data in Figure 4b. Figure 4c,d is derived from the dataset shown in Figure 4b. Below is the corrected Figure 4. The correction does not affect any other results or the scientific conclusions.</p><p>In the second paragraph on page 5, the text “The calculated conduction band minimum (CBM) and valence band maximum (VBM) for the control perovskite film were found to be –4.03 and –5.62 eV, respectively.” was incorrect. This should have read: “The calculated conduction band minimum (CBM) and valence band maximum (VBM) for the control perovskite film were found to be –4.09 and −5.68 eV, respectively.” Moreover, the text “After MATFB treatment, the work function of the film increases from 4.30 to 4.49 eV,” was incorrect. This should have read: “After MATFB treatment, the work function of the film increases from 4.33 to 4.49 eV,”</p><p>We apologize for this error.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500687","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficiency Boost in Highly Flexible Cu(In, Ga)Se2 Solar Cells on Mica by One-Step Sputtering with Rear-Side Modification 云母上高柔性Cu(in, Ga)Se2太阳能电池的一步溅射及后侧修饰
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-23 DOI: 10.1002/solr.70122
Maliya Syabriyana, Yung-Hsun Chen, Hsin-Fang Chang, Duc-Chau Nguyen, De-Shiang Liou, Ying-Hao Chu, Tzu-Ying Lin, Chih-Huang Lai
{"title":"Efficiency Boost in Highly Flexible Cu(In, Ga)Se2 Solar Cells on Mica by One-Step Sputtering with Rear-Side Modification","authors":"Maliya Syabriyana,&nbsp;Yung-Hsun Chen,&nbsp;Hsin-Fang Chang,&nbsp;Duc-Chau Nguyen,&nbsp;De-Shiang Liou,&nbsp;Ying-Hao Chu,&nbsp;Tzu-Ying Lin,&nbsp;Chih-Huang Lai","doi":"10.1002/solr.70122","DOIUrl":"https://doi.org/10.1002/solr.70122","url":null,"abstract":"<p><b>Perovskite Solar Cells</b></p><p>In article number 2500333, Tzu-Ying Lin, Chih-Huang Lai, and co-workers present a breakthrough in flexible Cu(In, Ga)Se<sub>2</sub> (CIGS) solar cells on mica substrates by one-step sputtering, featuring back-side modification with a TiN buffer layer. This design enhances adhesion, crystallinity of Mo, CIGS, and rear-junction. The cells demonstrate remarkable mechanical durability, maintaining 98% efficiency after 3000 bending cycles, highlighting mica’s potential for scalable manufacturing of flexible CIGS solar modules.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 18","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.70122","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficiency Boost in Highly Flexible Cu(In, Ga)Se2 Solar Cells on Mica by One-Step Sputtering with Rear-Side Modification 云母上高柔性Cu(in, Ga)Se2太阳能电池的一步溅射及后侧修饰
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-23 DOI: 10.1002/solr.70122
Maliya Syabriyana, Yung-Hsun Chen, Hsin-Fang Chang, Duc-Chau Nguyen, De-Shiang Liou, Ying-Hao Chu, Tzu-Ying Lin, Chih-Huang Lai
{"title":"Efficiency Boost in Highly Flexible Cu(In, Ga)Se2 Solar Cells on Mica by One-Step Sputtering with Rear-Side Modification","authors":"Maliya Syabriyana,&nbsp;Yung-Hsun Chen,&nbsp;Hsin-Fang Chang,&nbsp;Duc-Chau Nguyen,&nbsp;De-Shiang Liou,&nbsp;Ying-Hao Chu,&nbsp;Tzu-Ying Lin,&nbsp;Chih-Huang Lai","doi":"10.1002/solr.70122","DOIUrl":"https://doi.org/10.1002/solr.70122","url":null,"abstract":"<p><b>Perovskite Solar Cells</b></p><p>In article number 2500333, Tzu-Ying Lin, Chih-Huang Lai, and co-workers present a breakthrough in flexible Cu(In, Ga)Se<sub>2</sub> (CIGS) solar cells on mica substrates by one-step sputtering, featuring back-side modification with a TiN buffer layer. This design enhances adhesion, crystallinity of Mo, CIGS, and rear-junction. The cells demonstrate remarkable mechanical durability, maintaining 98% efficiency after 3000 bending cycles, highlighting mica’s potential for scalable manufacturing of flexible CIGS solar modules.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 18","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.70122","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring Charge Transport and Hysteresis Effects in Perovskite Solar Cells Through Dynamic Measurements and Analytical Modeling 通过动态测量和分析建模探索钙钛矿太阳能电池中的电荷输运和滞后效应
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-21 DOI: 10.1002/solr.202500562
Gabriel L. Nogueira, Victor Lopez-Richard, Luiz A. Meneghetti Jr., Fabian Hartmann, Carlos F. O. Graeff
{"title":"Exploring Charge Transport and Hysteresis Effects in Perovskite Solar Cells Through Dynamic Measurements and Analytical Modeling","authors":"Gabriel L. Nogueira,&nbsp;Victor Lopez-Richard,&nbsp;Luiz A. Meneghetti Jr.,&nbsp;Fabian Hartmann,&nbsp;Carlos F. O. Graeff","doi":"10.1002/solr.202500562","DOIUrl":"https://doi.org/10.1002/solr.202500562","url":null,"abstract":"<p>Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, already achieving efficiencies surpassing 26%. However, effects such as hysteresis are commonly observed due to the interplay of ionic and electronic transport occurring over different timescales. In this work, we presented a unified analytical framework for characterizing charge transport and hysteresis in PSCs, validated through experiments on standard n-i-p mesoporous devices. Beyond small-signal impedance spectroscopy, our model also explains the large-signal response under pulsed and sinusoidal voltage inputs. Sinusoidal I–V analysis combined with the Fourier transform revealed the system's transition from capacitive to inductive-like response, depending on excitation frequency. Therefore, this work provides not only theoretical insights but also a step-by-step methodology. By combining small- and large-signal experiments within a single interpretive framework, our approach offers a physically grounded and experimentally accessible strategy for decoding and managing nonlinear and memory-driven effects in PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500562","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inferring Material Parameters from Current–Voltage Curves in Organic Solar Cells via Neural Network-Based Surrogate Models 基于神经网络的替代模型从有机太阳能电池的电流-电压曲线推断材料参数
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-16 DOI: 10.1002/solr.202500648
Eunchi Kim, Paula Hartnagel, Barbara Urbano, Leonard Christen, Thomas Kirchartz
{"title":"Inferring Material Parameters from Current–Voltage Curves in Organic Solar Cells via Neural Network-Based Surrogate Models","authors":"Eunchi Kim,&nbsp;Paula Hartnagel,&nbsp;Barbara Urbano,&nbsp;Leonard Christen,&nbsp;Thomas Kirchartz","doi":"10.1002/solr.202500648","DOIUrl":"https://doi.org/10.1002/solr.202500648","url":null,"abstract":"<p>Machine learning has emerged as a promising approach for estimating material parameters in solar cells. Traditional methods for parameter extraction often rely on time-consuming numerical simulations that fail to capture the full complexity of the parameter space and discard valuable information from suboptimal simulations. In this study, we introduce a workflow for parameter estimation in organic solar cells based on a combination of numerical simulations and neural networks. The workflow begins with the selection of an appropriate experimental dataset, followed by the definition of a device model that accurately describes the experiment. To reduce computational complexity, the number of variable parameters and their boundaries are carefully selected. Instead of directly fitting the experimental data using a numerical model, a neural network was trained on a large dataset of simulated results, allowing for efficient exploration of the high-dimensional parameter space. This approach not only accelerates the parameter estimation process but also provides valuable insights into the likelihood and uncertainty of the estimated parameters. We demonstrate the effectiveness of this method on organic solar cells based on the material systems PBDB-TF-T1:BTP-4F-12 and PM6:L8-BO, demonstrating the potential of machine learning for rapid and comprehensive characterization of emerging photovoltaic materials.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500648","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bilayer of Atomic Layer Deposition and Solution-Processed Tin Dioxide as a Pathway to High-Performance Electron Transport Layers for Perovskite Solar Cells 双层原子层沉积和溶液处理二氧化锡作为钙钛矿太阳能电池高性能电子传输层的途径
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-15 DOI: 10.1002/solr.202500617
Joshua Sraku Adu, George Kwesi Asare, Byungha Shin, David J. Fermin, Helen Hejin Park
{"title":"Bilayer of Atomic Layer Deposition and Solution-Processed Tin Dioxide as a Pathway to High-Performance Electron Transport Layers for Perovskite Solar Cells","authors":"Joshua Sraku Adu,&nbsp;George Kwesi Asare,&nbsp;Byungha Shin,&nbsp;David J. Fermin,&nbsp;Helen Hejin Park","doi":"10.1002/solr.202500617","DOIUrl":"https://doi.org/10.1002/solr.202500617","url":null,"abstract":"<p>This perspective explores the transformative potential of atomic layer deposition (ALD) in fabricating high-performance tin dioxide (SnO<sub>2</sub>) electron transport layers (ETLs) for perovskite solar cells (PSCs). ALD ensures conformal coatings with atomic-scale precision, reducing surface roughness and recombination sites while enhancing the structural and electronic properties of complementary SnO<sub>2</sub> layers. Furthermore, ALD's capacity to optimize energy-level alignment and foster high-quality perovskite crystallization improves charge transport, reduces trap-assisted recombination, and enhances device performance. Despite the advantages of ALD, most high-performance ALD SnO<sub>2</sub>-based PSCs are combined with sol–gel deposition of SnO<sub>2</sub>, chemical bath deposition of SnO<sub>2</sub>, or nanoparticle SnO<sub>2</sub> (<i>np</i>-SnO<sub>2</sub>), commonly referred to as bilayer ETLs. Bilayer ETLs address key challenges, including surface uniformity, defect mitigation, and energy alignment, which significantly impact PSC efficiency and stability. This perspective highlights the recent advances in ALD SnO<sub>2</sub>/solution-processed SnO<sub>2</sub> (SP-SnO<sub>2</sub>) bilayer ETLs in PSCs and explores the mechanisms for the superior photovoltaic performance of these bilayer approaches compared to single-layer ALD SnO<sub>2</sub>. The perspective also identifies remaining challenges, including interface defects and scalability issues, and explores solutions like in situ passivation and interfacial engineering.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500617","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Zwitterion Molecule Passivates the Charged Defects for High-Performance Inverted Perovskite Solar Cells 两性离子分子钝化高性能倒钙钛矿太阳能电池的带电缺陷
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-15 DOI: 10.1002/solr.202500566
Tong Wang, Xingyu Pu, Jiabao Yang, Junpeng Li, Junchao Liu, Ningning Zhao, Qian Zhang
{"title":"A Zwitterion Molecule Passivates the Charged Defects for High-Performance Inverted Perovskite Solar Cells","authors":"Tong Wang,&nbsp;Xingyu Pu,&nbsp;Jiabao Yang,&nbsp;Junpeng Li,&nbsp;Junchao Liu,&nbsp;Ningning Zhao,&nbsp;Qian Zhang","doi":"10.1002/solr.202500566","DOIUrl":"https://doi.org/10.1002/solr.202500566","url":null,"abstract":"<p>Defects originating from the ionic nature of perovskite film are major factors that degrade the performance of perovskite solar cells (PSCs), and mitigating or removing them is essential for the implementation of high-performance PSCs. Herein, an additive 4-toluenesulfonic acid ammonium salt (TAAS) has been used to modify the perovskite film. The sulfonic acid groups (SO<sub>3</sub><sup>−</sup>) as an electron donor can not only regulate the growth of perovskite crystals, but also effectively passivate the positively charged defects caused by under-coordinated Pb<sup>2+</sup>. The ammonium ions (NH<sub>4</sub><sup>+</sup>) can effectively passivate cation vacancies through electrostatic interactions. Furthermore, the benzene ring can trap trace I<sub>2</sub> generated by oxidation in the perovskite active layer and reduce the I<sub>2</sub>-induced acceptor defects. The power conversion efficiency of PSCs based on the optimized perovskite is significantly improved from 24.70% to 26.02%, and the stability of PSCs is also advanced.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Optimization of Band Alignment and Defects in CsPbI2Br Perovskite Solar Cells via SCAPS-1D Simulation: Achieving >20% Efficiency 基于SCAPS-1D模拟的CsPbI2Br钙钛矿太阳能电池能带对准和缺陷协同优化:达到>20%效率
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-15 DOI: 10.1002/solr.202500549
Yizhou He, Yinuo Hou, Chi Zhang, Liming Jiang, Xiaowei Guo, Shaorong Li, Xiaodong Liu
{"title":"Synergistic Optimization of Band Alignment and Defects in CsPbI2Br Perovskite Solar Cells via SCAPS-1D Simulation: Achieving >20% Efficiency","authors":"Yizhou He,&nbsp;Yinuo Hou,&nbsp;Chi Zhang,&nbsp;Liming Jiang,&nbsp;Xiaowei Guo,&nbsp;Shaorong Li,&nbsp;Xiaodong Liu","doi":"10.1002/solr.202500549","DOIUrl":"https://doi.org/10.1002/solr.202500549","url":null,"abstract":"<p>CsPbI<sub>2</sub>Br is a promising material for efficient and stable perovskite solar cells (PSCs), owing to its excellent photothermal stability and suitable bandgap. However, severe energy band misalignment at interfaces combined with high interfacial and bulk defect densities critically limit device performance. In this work, we modeled CsPbI<sub>2</sub>Br PSCs using SCAPS-1D and performed synergistic optimization of band alignment and defects. The procedure sequentially addressed the electron transport layer/perovskite (ETL/PVSK) interface, the PVSK/hole transport layer (HTL) interface, and bulk defects within the CsPbI<sub>2</sub>Br layer. The obtained optimal parameters include a band offset of −0.3 eV and an interfacial defect density of 1.0 × 10<sup>10</sup> cm<sup>−2</sup> for both interfaces (ETL/PVSK and PVSK/HTL), with a bulk defect density of 1.0 × 10<sup>13</sup> cm<sup>−3</sup>. The optimized device achieved a <i>V</i><sub>OC</sub> of 1.544 V, a <i>J</i><sub>SC</sub> of 15.00 mA/cm<sup>2</sup>, a fill factor (FF) of 87.22%, and a power conversion efficiency (PCE) of 20.20%. Mechanistic studies reveal that the optimal band offsets become more negative at low interfacial defect densities, facilitating carrier extraction and reducing recombination. Positive offsets lead to losses in quasi-Fermi level splitting (QFLS), with the ETL/PVSK interface being particularly sensitive to this loss mechanism. This study offers key design insights for high-performance CsPbI<sub>2</sub>Br PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bandgap Engineering, Device Optimization, and Performance Analysis of a Perovskite Solar Cell using Sr-Doped La2NiMnO6 as an Absorber Layer: A Promising Material for Next-Generation Perovskite Solar Cells 利用掺锶La2NiMnO6作为吸收层的钙钛矿太阳能电池的带隙工程、器件优化和性能分析:下一代钙钛矿太阳能电池的一种有前途的材料
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-15 DOI: 10.1002/solr.202500467
Aarif Ul Islam Shah, Edson L. Meyer, Mohd Ikram, Nicholas Rono, Chinedu Ahia, Mojeed A. Agoro
{"title":"Bandgap Engineering, Device Optimization, and Performance Analysis of a Perovskite Solar Cell using Sr-Doped La2NiMnO6 as an Absorber Layer: A Promising Material for Next-Generation Perovskite Solar Cells","authors":"Aarif Ul Islam Shah,&nbsp;Edson L. Meyer,&nbsp;Mohd Ikram,&nbsp;Nicholas Rono,&nbsp;Chinedu Ahia,&nbsp;Mojeed A. Agoro","doi":"10.1002/solr.202500467","DOIUrl":"https://doi.org/10.1002/solr.202500467","url":null,"abstract":"<p>The study explored the role of doping Sr in double perovskite La<sub>2</sub>NiMnO<sub>6</sub> to tune the bandgap of the host material thereby revealing a considerable decrease, indicating its usefulness in solar cell device fabrication. To authenticate the experimental findings revealing the bandgap tuning to 1.37 eV by Sr doping, close to 1.4 eV, an optimum value for achieving better efficiencies in solar cell devices, we focus on the performance analysis of Sr-doped based perovskite solar cell by performing the device optimization using LNMO and Sr-doped LNMO as the light-absorbing material in the SCAPS-1D simulation tool. The best SC configuration during device optimization turned out to be FTO/WS<sub>2</sub>/LNMO/CFTS/C, where FTO was the substrate, WS<sub>2</sub> was the electron transport layer, LNMO was the absorber, CFTS was the hole transport layer, and C was the carbon contact. The SC was optimized for the thickness of all these constituent layers to obtain the best PV parameters. The impact of Sr-doped LNMO in the devices was very significant, as it enhanced the power conversion efficiency (PCE) from 13.90% in the pure LNMO to 19.62% in the Sr-doped LNMO, supporting the experimental results. The cell parameters of the Sr-doped-based optimized SC device were V<sub>OC</sub> = 1.15 V, J<sub>SC</sub> = 31.96 mA/cm<sup>2</sup>, FF = 53.48%, and PCE = 19.62%, in comparison to those of the pure LNMO-based optimized SC device, which were V<sub>OC</sub> = 1.35V, J<sub>SC</sub> = 21.99 mA/cm<sup>2</sup>, FF = 46.74%, and PCE = 13.90%, showing a considerable enhancement in the efficiency of the device. Significant variation in photovoltaic parameters with the density of defects of absorber layer reveals that the optimal doping along with minimum defect density is important to maximizing perovskite solar cell efficiency.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 20","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500467","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145341604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of CIGS Absorber and Sputtered InxSy:Na Buffer Composition on Solar Cell Performance CIGS吸收剂和溅射InxSy:Na缓冲成分对太阳能电池性能的影响
IF 6 3区 工程技术
Solar RRL Pub Date : 2025-09-14 DOI: 10.1002/solr.202500375
Dimitrios Hariskos, Rico Gutzler, Ana Kanevce, Wolfram Hempel, Stefan Paetel, Wolfram Witte
{"title":"Impact of CIGS Absorber and Sputtered InxSy:Na Buffer Composition on Solar Cell Performance","authors":"Dimitrios Hariskos,&nbsp;Rico Gutzler,&nbsp;Ana Kanevce,&nbsp;Wolfram Hempel,&nbsp;Stefan Paetel,&nbsp;Wolfram Witte","doi":"10.1002/solr.202500375","DOIUrl":"https://doi.org/10.1002/solr.202500375","url":null,"abstract":"<p>We report on sodium containing indium sulfide (In<sub>x</sub>S<sub>y</sub>:Na) buffer layer in combination with a Cu(In,Ga)Se<sub>2</sub> (CIGS) absorber and investigate the mutual interaction and influence of them on the thin-film solar cell device performance. We examine a variety of absorber layers including CIGS with RbF post-deposition treatment (PDT), CIGS without PDT, and Ag-alloyed CIGS without PDT, each with three different copper concentrations. All absorber layers are prepared by in-line coevaporation of the elements using a multistage industrially relevant process. The In<sub>x</sub>S<sub>y</sub>:Na buffer layers are deposited by magnetron sputtering from three different indium sulfide targets containing 0 mol%, 2 mol%, and 10 mol% NaF.</p><p>Devices in which the In<sub>x</sub>S<sub>y</sub>:Na layer is combined with CIGS with RbF-PDT have the highest power conversion efficiencies. The presence of sodium in In<sub>x</sub>S<sub>y</sub> can contribute to a higher cell efficiency depending on the quality of the absorber used. Sodium likely has a positive effect if the alkali doping in the absorber is insufficient and can be compensated by the sodium supplied from the buffer. We demonstrate cell efficiencies up to 19.1% with a sodium-free In<sub>2</sub>S<sub>3</sub> buffer combined with a high-quality RbF-PDT CIGS absorber with a comparably high copper content.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 19","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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