{"title":"High-Efficiency Perovskite/Silicon Tandem Solar Cells with Flexibility","authors":"Hirotaka Shishido, Ryo Sato, Daisuke Ieki, Gakuto Matsuo, Kimihiko Saito, Makoto Konagai, Ryousuke Ishikawa","doi":"10.1002/solr.202570110","DOIUrl":"https://doi.org/10.1002/solr.202570110","url":null,"abstract":"<p>Tandem Solar Cells</p><p>In article number 2400899, Ryousuke Ishikawa and co-workers develop flexible perovskite/silicon tandem solar cells by fabricating perovskite cells on thin, bendable silicon substrates. By optimizing surface microtexturing and processing, an efficiency of 26.5% was achieved. These findings suggest that flexible, high-efficiency solar cells could be deployed in situations where traditional silicon cells are not practical.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202570110","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-27DOI: 10.1002/solr.202500030
Marcel Placidi, Arnau Torrens, Zacharie Jehl Li-Kao, Alex Lopez-Garcia, Oriol Segura, Yuancai Gong, Alex Jimenez-Arguijo, Ivan Caño, Sergio Giraldo, Edgardo Saucedo, Gustavo Alvarez, Yudania Sanchez, Nicolae Spalatu, Ilona Oja, Elisa Artegiani, Alessandro Romeo, Romain Scaffidi, Alejandro Perez-Rodriguez
{"title":"Benchmarking Inorganic Thin-Film Photovoltaics Technologies for Indoor Applications","authors":"Marcel Placidi, Arnau Torrens, Zacharie Jehl Li-Kao, Alex Lopez-Garcia, Oriol Segura, Yuancai Gong, Alex Jimenez-Arguijo, Ivan Caño, Sergio Giraldo, Edgardo Saucedo, Gustavo Alvarez, Yudania Sanchez, Nicolae Spalatu, Ilona Oja, Elisa Artegiani, Alessandro Romeo, Romain Scaffidi, Alejandro Perez-Rodriguez","doi":"10.1002/solr.202500030","DOIUrl":"https://doi.org/10.1002/solr.202500030","url":null,"abstract":"<p>The growing demand for sustainable power solutions for Internet of Things (IoT) systems, projected to reach billions of units in the near future, highlights the limitations of battery reliance due to maintenance, environmental concerns, and supply constraints. Inorganic thin-film photovoltaics (PV) technologies (including cadmium telluride, kesterite, antimony chalcogenide, nanometric silicon, and elemental selenium) emerge as promising candidates for indoor applications due to their suitable bandgap energies and very high robustness and stability, as well as their potential to achieve higher efficiencies at indoor illumination conditions. The work reported here compares the optoelectronic performance of several technologies under relevant indoor illumination conditions using a consistent characterization methodology, that encompasses the needs of indoor PV, including a benchmark with commercial state-of-the-art (SoA) a-Si devices. The results show many devices performing surprisingly well indoors, which corroborates their potential for achieving high efficiencies. However, the performance of these devices is compromised at very low irradiance conditions, and this is attributed to the need for optimization of both the shunt resistance and saturation current density.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-16DOI: 10.1002/solr.202500173
Dan Yang, Xinrui Dong, Minyong Du, Xu Zhang, Kai Wang, Shengzhong Liu
{"title":"Enhancing the Performance of Perovskite/Silicon Tandem Solar Cells via Cation-π Interaction","authors":"Dan Yang, Xinrui Dong, Minyong Du, Xu Zhang, Kai Wang, Shengzhong Liu","doi":"10.1002/solr.202500173","DOIUrl":"https://doi.org/10.1002/solr.202500173","url":null,"abstract":"<p>Perovskite/silicon tandem solar cells have garnered significant attention due to their potential to surpass the Shockley–Queisser limit of single-junction solar cells. However, the fabrication of perovskite films on commercially textured silicon substrates still faces challenges, including difficulty in controlling crystal orientation, high defect density, and insufficient stability. This study innovatively introduces 5-chloro-7-azaindole (5C7A) as a functional additive in the perovskite layer. Through its unique cation-π interactions and Lewis acid–base synergistic passivation mechanism, 5C7A enables a multidimensional optimization of perovskite films. The 5C7A significantly enhances perovskite crystallinity and grain size while anchoring uncoordinated Pb<sup>2</sup><sup>+</sup> and halide vacancies, thereby reducing trap state density. Additionally, 5C7A effectively releases internal stress in the perovskite film, increases the ion migration energy barrier, and extends carrier lifetime, leading to an improvement in the power conversion efficiency of inverted single-junction devices to 23.25% along with significantly enhanced photostability. Furthermore, the fabricated perovskite/silicon tandem solar cells achieve an impressive efficiency of 30.59%. This study proposes a new paradigm for regulating perovskite films via noncovalent interactions from a molecular engineering perspective, providing a key material strategy for the industrial development of high-efficiency and stable tandem solar cells.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Two-Dimensional Phosphorene for Solution-Processed Thin-Film Solar Cells","authors":"Wenhao Guo, Jingkun Wang, Zongyang Li, Yuxuan Cheng, Bowen Li, Chenxi Zhang, Shiqi Li, Yukun Wu, Min Zhao, Yifan Huang, Yuying Hao","doi":"10.1002/solr.202500165","DOIUrl":"https://doi.org/10.1002/solr.202500165","url":null,"abstract":"<p>Two-dimensional phosphorene (2D phosphorene) exhibits significant advantages in the field of solar cells due to its tunable bandgap, high carrier mobility, and high light absorption. They can serve as electrodes, hole transport layers (HTLs), electron transport layers (ETLs), and functional additives in the active layer, significantly enhancing the optoelectronic performance of devices. This paper reviews the basic properties and provides a comprehensive summary of the synthesis methods of 2D phosphorene. Furthermore, the impact of 2D phosphorene as an electrode, charge transport layer, and additive in the active layer of solution-processed thin-film solar cells is highlighted. Although the application of phosphorene in solar cells has achieved initial success, its stability issues and challenges of large-scale preparation still need to be further addressed. It is believed that 2D phosphorene is anticipated to have a significant impact on the commercial application of high-efficiency solar cells.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-15DOI: 10.1002/solr.202500153
Appiagyei Ewusi Mensah, Saif Ahmed, Farihatun Jannat Lima, Md. Mahbubur Rahman, Francis Kwaku Asiam, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Jae-Joon Lee
{"title":"Effective Defect Passivation with an Amino-Pyrazine Compound for Performance Improvement in Perovskite Solar Cells","authors":"Appiagyei Ewusi Mensah, Saif Ahmed, Farihatun Jannat Lima, Md. Mahbubur Rahman, Francis Kwaku Asiam, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Jae-Joon Lee","doi":"10.1002/solr.202500153","DOIUrl":"https://doi.org/10.1002/solr.202500153","url":null,"abstract":"<p>Aminopyrazine (APz), a bifunctional additive with nitrogen-rich content and aromatic character, is investigated for its effectiveness in enhancing the stability and performance of perovskite solar cells (PSCs). When incorporated into the perovskite precursor solution, APz provides dual benefits: it strengthens the perovskite framework through hydrogen-bonding with halides and Lewis base coordination with under-coordinated lead to reduce defects at the surface and grain boundaries. The high nitrogen content and aromatic nature of APz further contribute to improved structural stability and moisture resistance in the perovskite films, enhancing charge transport. Optimized PSCs with APz achieve a power conversion efficiency (PCE) of 21.31% and retain over 94% of their initial PCE after 20 days of ambient storage. These findings highlight APz's potential as an additive, demonstrating that nitrogen-rich, aromatic additives can significantly improve PSC stability and efficiency, advancing their practical application.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-15DOI: 10.1002/solr.202500041
Soroush Ghasemi, Iman Sadeghkhani
{"title":"Toward Sustainable Energy-Agriculture Synergies: A Review of Agrivoltaics Systems for Modern Farming Practices","authors":"Soroush Ghasemi, Iman Sadeghkhani","doi":"10.1002/solr.202500041","DOIUrl":"https://doi.org/10.1002/solr.202500041","url":null,"abstract":"<p>Agrivoltaics (AV), the innovative integration of solar photovoltaic and agricultural practices, has emerged as a sustainable solution to address global challenges related to energy, food security, and climate change. By enabling dual land use, AV systems enhance land-use efficiency, reduce greenhouse gas emissions, and optimize water usage while supporting renewable energy deployment. This review provides a comprehensive exploration of AV systems, including their historical development, technological advancements, environmental and economic benefits, policy frameworks, and alignment with the United Nations Sustainable Development Goals. Key findings highlight the potential of AV systems to improve microclimatic conditions, protect crops from adverse environmental factors, and generate dual income streams for farmers. Case studies illustrate successful implementations across diverse geographies, showcasing the adaptability of AV systems to varying climatic and agricultural conditions. Despite their promise, AV systems face significant challenges, including high initial costs, technical complexities, and land-use conflicts. Future research directions emphasize the integration of advanced technologies such as artificial intelligence, the Internet of Things, energy storage, and autonomous robotics, alongside hybrid renewable energy systems, to enhance the scalability and resilience of AV solutions. This study underscores the necessity of interdisciplinary research, targeted policy support, and stakeholder collaboration to overcome existing barriers and fully realize the potential of AV systems as a cornerstone of sustainable energy and agricultural strategies.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhanced Performance of Fabricated Iodine-Rich Perovskite Solar Cells via Reverse-Biasing","authors":"Yingfeng Li, Zixuan Wang, Peici Yu, Yuewen Chen, Rongxin Wu, Xing Zhao, Peng Cui, Hao Huang, Meicheng Li","doi":"10.1002/solr.202500066","DOIUrl":"https://doi.org/10.1002/solr.202500066","url":null,"abstract":"<p>Perovskite solar cells (PSCs) are undergoing rapid development and exhibit considerable potential for commercialization. Recent studies have shown that reverse bias can improve the open-circuit voltage (<i>V</i><sub>OC</sub>) of PSCs by ≈0.06 V due to the migration of iodine ions filling vacancies at the electron transport layer (ETL)/perovskite interface. It can be deduced that in iodine-rich PSCs, the potential for reverse-biasing to enhance <i>V</i><sub>OC</sub> is limited due to the suppression of iodine vacancies by excess iodine atoms. This work confirms that, in iodine-rich PSCs, reverse bias has a minimal effect on <i>V</i><sub>OC</sub>, but leads to a ≈3.9% increase in short-circuit current density (<i>J</i><sub>SC</sub>), from 25.40 to 26.40 mA/cm<sup>2</sup>, and an enhancement of ≈3.2% in power conversion efficiency from 23.00% to 23.74%. The improved <i>J</i><sub>SC</sub> can be attributed to reduced carrier recombination near the ETL/perovskite interface, as evidenced by enhanced external quantum efficiency and increased recombination resistance in the short-wavelength region. These insights suggest a practical posttreatment strategy for high-performance PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-13DOI: 10.1002/solr.202500108
Soe Ko Ko Aung, Hanmandlu Chintam, Priyabrata Sadhukhan, Bowen Yang, Gerrit Boschloo
{"title":"Improved Efficiency of Carbon-Based Perovskite Solar Cells by Using Alternative Solvent for Doping-Free P3HT","authors":"Soe Ko Ko Aung, Hanmandlu Chintam, Priyabrata Sadhukhan, Bowen Yang, Gerrit Boschloo","doi":"10.1002/solr.202500108","DOIUrl":"https://doi.org/10.1002/solr.202500108","url":null,"abstract":"<p>Low-temperature-processed carbon-based perovskite solar cells (C-PSCs) are a potential candidate for industrial development, due to their low cost, high stability, and easy preparation methods. However, their power conversion efficiencies still lag behind that of metal-contact-based PSCs, due to poor compatibility of the carbon electrode with the underlying layers. Here, we introduce a doping-free poly(3-hexylthiophene) (P3HT) hole-transport layer deposited from chloroform to improve solar cell performance of PSCs that are prepared in ambient air. The resulting P3HT films have a lower roughness and a higher conductivity. A champion device with power conversion efficiency of 19.4% was obtained with negligible hysteresis and a remarkably enhanced fill factor (FF) of 80.2%. Unencapsulated devices maintained 70% of initial efficiency value after 350 hr under thermal stress at 85°C in dark and ambient air.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500108","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-13DOI: 10.1002/solr.202500129
Xiaole Li, Helen Bristow, Stefaan De Wolf, Gilles Lubineau
{"title":"Response to the Comment on “Mitigating Delamination in Perovskite/Silicon Tandem Solar Modules”","authors":"Xiaole Li, Helen Bristow, Stefaan De Wolf, Gilles Lubineau","doi":"10.1002/solr.202500129","DOIUrl":"https://doi.org/10.1002/solr.202500129","url":null,"abstract":"<p>In response to the comment on article ‘Mitigating Delamination in Perovskite/Silicon Tandem Solar Modules’, we address each specific concern raised, including the assumptions made in the analysis of the peel test data and the methodology used in conducting the peel tests. We believe that this is a good opportunity to clarify some fundamental aspects of peel tests that the community may sometimes find confusing. So we hope this extensive response, formatted as a discussion, will help the community to make better usage of this testing protocol.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar RRLPub Date : 2025-05-12DOI: 10.1002/solr.202500215
Christoph Klein, Robin Lang, Jens Ohlmann, Frank Dimroth, David Lackner
{"title":"Metalorganic Vapor-Phase Epitaxy Growth of GaAs Rear-Heterojunction Solar Cells at 94 µm/h","authors":"Christoph Klein, Robin Lang, Jens Ohlmann, Frank Dimroth, David Lackner","doi":"10.1002/solr.202500215","DOIUrl":"https://doi.org/10.1002/solr.202500215","url":null,"abstract":"<p>In this study, a GaAs single-junction solar cell with an absorber layer grown at a very high rate of 94 µm/h via metalorganic vapor-phase epitaxy (MOVPE) is demonstrated, employing a low V/III ratio of 5. This approach enables the deposition of a 2.4 µm thick absorber layer in just 100 s, drastically lowering production time compared to conventional MOVPE rates below 10 µm/h. The solar cell achieves an excellent open-circuit voltage of 1061 mV and a fill factor of 83.2% using optimized growth conditions, matching the performance of state-of-the-art GaAs cells on bulk substrates grown at slow rates with much higher V/III ratios. At these high growth rates, increased defect densities of EL2 for electrons and HM1 for holes have been observed leading to promoted non-radiative recombination lowering the device performance. The GaAs absorber layer is engineered to minimize the impact of those defects, such that high solar cell efficiency is successfully maintained, despite the accelerated growth rate of 94 mm/h. This work not only showcases the feasibility of high-throughput, cost-effective production of high-efficiency III–V solar cells via MOVPE but also highlights potential environmental benefits from reduced material use and waste treatment.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 11","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.202500215","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144219947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}