Process Safety and Environmental Protection最新文献

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Highly efficient degradation of ethanol, acetaldehyde, and ethyl acetate removal by bio-trickling filter reactors with various fillers 使用各种填料的生物滴滤反应器高效降解乙醇、乙醛和去除乙酸乙酯
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-16 DOI: 10.1016/j.psep.2024.09.063
{"title":"Highly efficient degradation of ethanol, acetaldehyde, and ethyl acetate removal by bio-trickling filter reactors with various fillers","authors":"","doi":"10.1016/j.psep.2024.09.063","DOIUrl":"10.1016/j.psep.2024.09.063","url":null,"abstract":"<div><p>This study investigates the purification performance of bio-trickling filters (BTFs) using different media to treat ethanol, acetaldehyde, and ethyl acetate in kitchen waste malodorous gases. The media compared included a custom composite medium, pine bark, hollow polyhedral spheres, and ceramic particles. Over 25 days, the composite medium outperformed the traditional media, achieving removal rates of 90.13 % for ethanol, 63.89 % for acetaldehyde, and 82.56 % for ethyl acetate during the biofilm initiation phase, with the others below 60 %. Even under low empty bed residence time and high inlet concentrations, the maximum elimination capacity for ethanol, acetaldehyde, and ethyl acetate was 8.34–14.70 g/m<sup>3</sup>·h, 9.55–15.06 g/m<sup>3</sup>·h, and 6.18–10.45 g/m<sup>3</sup>·h. Kinetic analysis showed the Michaelis-Menten model fit well, indicating enhanced removal potential. High-throughput of 16S rDNA sequencing identified dominant microorganisms like <em>Enterobacteriaceae</em> (13.89 %), <em>Stenotrophomonas</em> (29.23 %), and <em>Acinetobacter</em> (4.09 %) in the composite medium, which thrived even at high pollutant concentrations. Principal component analysis (PCA) demonstrated differences in the microbial composition of the custom composite medium compared to traditional media under varying inlet concentrations and loads. This study provides technical support for the treatment of complex malodorous gas mixtures.</p></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142274478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting nickel catalyst deactivation in biogas steam and dry reforming for hydrogen production using machine learning 利用机器学习预测沼气蒸汽和干转化制氢过程中镍催化剂失活情况
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-16 DOI: 10.1016/j.psep.2024.09.020
{"title":"Predicting nickel catalyst deactivation in biogas steam and dry reforming for hydrogen production using machine learning","authors":"","doi":"10.1016/j.psep.2024.09.020","DOIUrl":"10.1016/j.psep.2024.09.020","url":null,"abstract":"<div><div>This study employs Random Forests (RF) and Artificial Neural Networks (ANN) to model the transient behavior of Ni catalyst deactivation during steam and dry reforming of model biogas containing H<sub>2</sub>S, with a focus on hydrogen production. Deactivation, induced by carbon deposition and sulfur poisoning, is a complex and transient phenomenon demanding precise kinetic mechanisms for accurately predicting Ni catalyst behavior in biogas reforming. Black-box machine learning (ML) models are developed, incorporating catalyst properties, biogas composition, and operating conditions. Encompassing both dry and steam reforming, the ML models aim to predict catalyst behavior, expressed in terms of packed bed reactor exit mole fractions (H<sub>2</sub>, CO, CH<sub>4</sub>, and CO<sub>2</sub>) and conversions (CH<sub>4</sub> and CO<sub>2</sub>). The ML models are trained and tested across a temperature range of 700–900 C with 0–145 ppm of H<sub>2</sub>S in model biogas (CH<sub>4</sub>/CO<sub>2</sub> ratio varying from 1.0 to 2.0). RF outperforms the ANN across all performance metrics, including overall R<sup>2</sup> and root mean squared error (RMSE). The RF achieves a mean overall R<sup>2</sup> of 0.979, with training and testing RMSE equal to <span><math><mrow><mn>6.7</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>3</mn></mrow></msup></mrow></math></span> and <span><math><mrow><mn>1.47</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></mrow></math></span> respectively. In contrast, the ANN achieves a mean overall R<sup>2</sup> of 0.939, with training and testing RMSE equal to <span><math><mrow><mn>2.6</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></mrow></math></span> and <span><math><mrow><mn>2.55</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>2</mn></mrow></msup></mrow></math></span> respectively. Moreover, pre-trained RF models are validated with unseen data of dry reforming of biogas containing 30 ppm of H<sub>2</sub>S (25 data points). It is suggested that 35 % of this unseen experimental data is required to train the RF model for it to predict catalyst deactivation, achieving a validation R sufficiently<sup>2</sup>&gt; 0.9. The mean overall R<sup>2</sup> values attained by the RF fine-tuned on 35 % of the unseen experiment data for both CH<sub>4</sub> and CO<sub>2</sub> conversions, as well as for all mole fraction predictions, are 0.952 and 0.948, respectively.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142327105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mass transfer characteristics of multi-pollutants in nano-pores of CeO2-TiO2 based SCR catalyst: A molecular dynamics study 基于 CeO2-TiO2 的 SCR 催化剂纳米孔隙中多种污染物的传质特性:分子动力学研究
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-16 DOI: 10.1016/j.psep.2024.09.065
{"title":"Mass transfer characteristics of multi-pollutants in nano-pores of CeO2-TiO2 based SCR catalyst: A molecular dynamics study","authors":"","doi":"10.1016/j.psep.2024.09.065","DOIUrl":"10.1016/j.psep.2024.09.065","url":null,"abstract":"<div><div>Molecular dynamics (MD) simulation was carried out to investigate the diffusion behaviors of NH<sub>3</sub> and flue gases on CeO<sub>2</sub>-TiO<sub>2</sub> (CT) catalyst for the selective catalytic reduction of NO with NH<sub>3</sub>. The influence of temperature, gas mixtures, and slit width of catalyst on the diffusivity of the target molecules were studied. The results showed that both temperature and the competitive diffusion of the target molecules substantially impact gas diffusion within nano-slits. The NH<sub>3</sub> diffusion was demonstrated to have heightened sensitivity to temperature fluctuations. SO<sub>2</sub> showed the greatest hindering effect in all of five gases. The negative effect on NH<sub>3</sub> diffusion was greater when H<sub>2</sub>O existed in the form of hydroxyl groups. Increasing the slit distance of catalyst significantly mitigated this effect, with a decrease in diffusion impedance from 32.51 % to 5.01 % as the distance expanded from 2.5 nm to 7.5 nm. As for NO, a similar suppressive effect was observed when mixed with SO<sub>2</sub>, but the influence of hydroxyl groups was notably less pronounced compared to NH<sub>3</sub>. Specifically, there was only a decrease of 15.14 % at a distance of 2.5 nm, followed by almost no decrease when the distance was increased to 7.5 nm.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142315445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the synergism and reaction pathway of ethyl acetate removal in DBD/absorption integrated reactor 揭示 DBD/吸收一体化反应器中去除乙酸乙酯的协同作用和反应途径
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-16 DOI: 10.1016/j.psep.2024.09.064
{"title":"Unveiling the synergism and reaction pathway of ethyl acetate removal in DBD/absorption integrated reactor","authors":"","doi":"10.1016/j.psep.2024.09.064","DOIUrl":"10.1016/j.psep.2024.09.064","url":null,"abstract":"<div><div>The experiment employs dielectric barrier discharge (DBD) combined with absorption integrated reactor (DCA<sup>IR</sup>) for higher concentration ethyl acetate removal and studies the synergism of DCA<sup>IR</sup> technology and the reaction pathway of ethyl acetate. Among three technologies of DCA<sup>IR</sup>, DBD and DBD combined with absorption series reactor (DCA<sup>SR</sup>), DCA<sup>IR</sup> achieved the highest removal efficiency (RE) of ethyl acetate at similar input power. Fixed gas flow rate of 1000 ml/min and <span><math><msubsup><mrow><mi>c</mi></mrow><mrow><msub><mrow><mi>C</mi></mrow><mrow><mn>4</mn></mrow></msub><msub><mrow><mi>H</mi></mrow><mrow><mn>8</mn></mrow></msub><msub><mrow><mi>O</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow><mrow><mi>in</mi></mrow></msubsup></math></span> of 5000 mg/m<sup>3</sup>, the average REs of DCA<sup>SR</sup> and DCA<sup>IR</sup> are higher than that of DBD by 31.2 % and 34.2 %, respectively. For the efficiency compensation mechanism, one of synergies in DCA<sup>IR</sup>, RE of ethyl acetate could exceed 80 % at the input power of 15 W. Energy consumption evaluation shows when RE &gt; 80 %, the max energy efficiency of three technologies is in the order 70.0 g/kWh (DCA<sup>IR</sup>) &gt; 5.1 g/kWh (DCA<sup>SR</sup>) &gt; 3.0 g/kWh (DBD). Tail gas and absorbent analysis reveals DCA<sup>IR</sup> can enhance mineralizing ethyl acetate and eliminating the secondary pollutants (e.g., O<sub>3</sub>, gaseous organic intermediates, and COD, etc.) effectively, due to its special structure of reactor. According to FT-IR spectra, the degradation mechanism and reaction pathway of ethyl acetate in DCA<sup>IR</sup> has been unveiled.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142322054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Promotion of silicon–oxygen control and green sustainable recovery from diamond wire saw silicon powder waste based on the viscous flow mechanism 基于粘流机理的金刚石绳锯硅粉废料硅氧调控与绿色可持续回收研究
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-15 DOI: 10.1016/j.psep.2024.09.045
{"title":"Promotion of silicon–oxygen control and green sustainable recovery from diamond wire saw silicon powder waste based on the viscous flow mechanism","authors":"","doi":"10.1016/j.psep.2024.09.045","DOIUrl":"10.1016/j.psep.2024.09.045","url":null,"abstract":"<div><p>Diamond wire saw silicon powder (DWSSP) waste is a highly promising secondary resource for recycling high-purity silicon, which is crucial for the sustainable development of the photovoltaic (PV) industry. However, because DWSSP is prone to oxidation, the purity and yield of the recovered silicon are generally low. In this study, the oxidation mechanism of DWSSP in water was systematically investigated, and kinetics analysis and microstructure analysis were conducted to determine the relationship between water diffusion and the growth of the oxide layer. The results indicated that oxidation was determined by the kinetic parameter <em>b</em> in the Reisman model. At <em>T</em> &lt; 328 K and particle size &gt; 1.56 μm, <em>b</em> was less than 1, indicating that the oxidation process was governed by the diffusion of H<sub>2</sub>O molecules. Through temperature regulation to achieve <em>b</em> &lt; 1, the oxidation was inhibited, which could enhance recovery efficiency. Overall, this study demonstrated the feasibility of inhibiting oxidation by regulating the viscous flow of SiO<sub>2</sub> molecules to promote the recycling of silicon resources and support sustainable development.</p></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142242742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical study of external explosion in vented hydrogen explosions 通风氢气爆炸中外部爆炸的数值研究
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-15 DOI: 10.1016/j.psep.2024.09.022
{"title":"Numerical study of external explosion in vented hydrogen explosions","authors":"","doi":"10.1016/j.psep.2024.09.022","DOIUrl":"10.1016/j.psep.2024.09.022","url":null,"abstract":"<div><p>In the current study, numerical study of vented hydrogen explosions was performed utilizing computational fluid dynamics (CFD) software GASFLOW-MPI. A turbulent combustion model based on Schmidt correlation was formulated. Within this model, flame instabilities resulted from two intrinsic effects, Hydrodynamic instability, and Landau-Darrieus and Thermal-Diffusive instabilities were incorporated. The numerical simulation results revealed the mechanism of overpressure evolution inside and outside the vessel. Notably, the mechanism of the overpressure peak induced by the external explosion was revealed. The effects of turbulence models on overpressure time profiles were investigated. Moreover, it was determined that heat transfer, arising from thermal radiation and convection, exerts only a negligible influence on the maximum internal overpressure. Subsequently, the performance of GASFLOW-MPI in simulating vented hydrogen explosions for different ignition locations (center and rear ignitions) and varying hydrogen concentrations (22%-38%) was assessed against experimental data. Comparative analysis revealed a close agreement between the predicted results and experimental data. Furthermore, the competency of GASFLOW in simulating medium-scale vented hydrogen explosions was validated against experimental data.</p></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142274481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanism and kinetics of scorodite formation in arsenic-bearing solutions using Fe(OH)3 as a solid iron source 以 Fe(OH)3 为固体铁源在含砷溶液中形成蝎尾石的机制和动力学
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-14 DOI: 10.1016/j.psep.2024.09.055
{"title":"Mechanism and kinetics of scorodite formation in arsenic-bearing solutions using Fe(OH)3 as a solid iron source","authors":"","doi":"10.1016/j.psep.2024.09.055","DOIUrl":"10.1016/j.psep.2024.09.055","url":null,"abstract":"<div><p>Recently, solid iron sources have been used for scorodite synthesis in arsenic-bearing wastewater from nonferrous metallurgy. Immobilising arsenic-solution as scorodite via iron hydroxide (Fe(OH)<sub>3</sub>) solid iron source is an important method for controlling arsenic pollution. The evolution behavior of scorodite during its formation in high arsenic solution have been rarely investigated. In this paper, the mechanism and kinetics of scorodite formation using Fe(OH)<sub>3</sub> in arsenic-bearing solution were investigated. This work was divided into three parts. Firstly, the influencing parameters were investigated, revealing that the dissolution of Fe(OH)<sub>3</sub> and scorodite generation accelerated at lower initial pH and higher reaction temperature. Increasing Fe/As ratio delayed scorodite crystallisation, which was in turn enhanced by elevating arsenic concentration. Secondly, the mechanism of scorodite formation was investigated, revealing that Fe(OH)<sub>3</sub> underwent acidic dissolution to form a precursor. Subsequent scorodite formation had a Δ<sub>r</sub>G<sub>m</sub><sup>θ</sup> ranging from −69.39 kJ·mol<sup>−1</sup> to −15.64 kJ·mol<sup>−1</sup>. Residual As was absorbed and converted into Fe(OH)<sub>3</sub>@scorodite. Thirdly, the chemical kinetics were investigated, showing that activation energy (Ea) for Fe(OH)<sub>3</sub> dissolution was 72.54 and 105.37 kJ·mol<sup>−1</sup> at Stages I and II, respectively, whereas it was 105.97 kJ·mol<sup>−1</sup> for residual As absorption-conversion at Stage III outweighing the Ea of As-Fe coprecipitation. The restrictive steps were Fe(OH)<sub>3</sub> dissolution and residual arsenic absorption-conversion. This proposed method can be applied for environment-friendly treatment of 10-40 g/L of arsenic-bearing industrial effluent for scorodite formation. Overall, this research confirmed the formation of scorodite via Fe(OH)<sub>3</sub> and can potentially provide feasible schemes for eliminating arsenic-bearing acidic waste, dust, and anode slime from nonferrous metallurgical processes.</p></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142242735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of the influence of dust particles in the peanut pickup harvester with a self-designed axial-flow dust-fall box on its dust suppression performance 带有自行设计的轴流式落尘箱的花生捡拾收割机中的尘粒对其抑尘性能的影响分析
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-14 DOI: 10.1016/j.psep.2024.09.049
{"title":"Analysis of the influence of dust particles in the peanut pickup harvester with a self-designed axial-flow dust-fall box on its dust suppression performance","authors":"","doi":"10.1016/j.psep.2024.09.049","DOIUrl":"10.1016/j.psep.2024.09.049","url":null,"abstract":"&lt;div&gt;&lt;p&gt;The atmospheric particulate pollution poses a serious threat to human health and ecological environment. The dust particle pollution caused by the operation of agricultural machinery is becoming increasingly severe and the peanut pickup harvesters are widely used in agricultural operation. Therefore, it is necessary to reduce the concentration of dust particles in the work of peanut pickup harvesters. In this study, a self-designed dust-fall box composed of multipleaxial flow cyclone tubes in parallel was integrated with the peanut pickup harvester. Based on the CFD-DPM model, simulation analysis was conducted to explore the effects of different inlet velocities, different numbers of swirling blades, and two types of exhaust port on the dust removal performance of the cyclone. The Box-Behnken design was used to determine the optimal structural parameters of the axial flow cyclone. The influence of the pressure distribution and velocity variations of the internal flow field on the dust removal efficiency of the two schemes was simulated and analyzed. Thereafter, a reasonable parallel scheme of multiple axial flow cyclone tubes in the dust-fall box was determined. The drone was used to monitor dust in peanut harvesting operations, and dust particle concentrations at 8 detection points under varying working conditions were recorded. The distribution and diffusion rules of dust in harvesting operations were explored through cluster analysis, and the test data obtained were compared with numerical calculation results to verify the accuracy of numerical calculation. The results showed that for a single axial flow cyclone, when the inlet wind speed was 6 m/s to 8 m/s and the number of swirling blades was 4, the structural parameters of the cyclone separator had significant influence on the separation efficiency. The influencing factors ranking in descending order were cylinder diameter, cylinder length, and exhaust pipe insertion depth, respectively. To be more precisely, the separation efficiency was best when the cylinder diameter was 60 mm, the cylinder length was 150 mm, the insertion depth of the exhaust pipe was 50 mm and the cone angle was 20°. It was more reasonable to use 8 axial flow cyclone tubes in parallel, and the maximum separation efficiency can reach 84.21 %. Field operations showed that the numerical calculation results were similar to the actual harvesting process. The dust particle concentration in the peanut harvesting operation equipped with a dust-fall box was always lower than 10 mg/m&lt;sup&gt;3&lt;/sup&gt;. The dust particle concentration was the highest at the rear of the whole machine and the lowest near the cab. Compared conventional harvesters, the harvester with a dust-fall box reduced its dust particle concentration by 64.37 %; the concentration of 30 μm dust particles was reduced by 69.31 %; the dust particle concentration at the rear of the whole machine also effectively reduced. This study can provide reference for control","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142242776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molybdenum as cathode materials: Paving the way for sustainable biohydrogen production in microbial electrolysis cells 作为阴极材料的钼:为微生物电解池可持续生物制氢铺平道路
IF 6.9 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-14 DOI: 10.1016/j.psep.2024.09.032
{"title":"Molybdenum as cathode materials: Paving the way for sustainable biohydrogen production in microbial electrolysis cells","authors":"","doi":"10.1016/j.psep.2024.09.032","DOIUrl":"10.1016/j.psep.2024.09.032","url":null,"abstract":"<div><div>Microbial electrolysis cells (MECs) have garnered significant attention for their potential in sustainable hydrogen production and wastewater treatment. Due to their unique electrochemical properties, molybdenum-based compounds have emerged as promising candidates among various cathode materials. This review explores the multifaceted role of molybdenum in MECs, focusing on its catalytic performance, synthesis strategies, and potential for enhancing H<sub>2</sub> evolution reactions. Various molybdenum-based materials, including molybdenum disulfide (MoS<sub>2</sub>), molybdenum phosphide (MoP), molybdenum carbide (Mo<sub>2</sub>C), and nickel-molybdenum alloys (NiMo), are discussed in terms of their synthesis methods, electrochemical performance, and scalability. Notably, molybdenum-based electrodes have demonstrated comparable or superior catalytic activity to traditional platinum-based cathodes, highlighting their potential as cost-effective alternatives. Future directions in this field include further optimization of synthesis methods, exploration of new molybdenum-based cathodes, mechanistic understanding of catalytic activity, and addressing scalability and stability challenges. Overall, molybdenum-based materials present promising opportunities for advancing MECs technology, driving progress toward sustainable hydrogen production and wastewater treatment.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":null,"pages":null},"PeriodicalIF":6.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142314991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Techno-economic analysis of a hybrid energy system for electrification using an off-grid solar/biogas/battery system employing HOMER: A case study in Vietnam 利用 HOMER 对使用离网太阳能/沼气/电池系统实现电气化的混合能源系统进行技术经济分析:越南案例研究
IF 7.8 2区 环境科学与生态学
Process Safety and Environmental Protection Pub Date : 2024-09-14 DOI: 10.1016/j.psep.2024.09.046
Van Giao Nguyen, Prabhakar Sharma, Bhaskor Jyoti Bora, Thi Minh Tu Bui, Cristina Efremov, Minh Ho Tran, Jerzy Kowalski, Sameh M. Osman, Dao Nam Cao, Van Huong Dong
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