Yijie Tong , Ruijin Wang , Shifeng Wang , Zefei Zhu
{"title":"Experimental study on the influence of operating parameters of plug flow on thermal efficiency of direct absorption solar collector with Fe3O4 nanofluid","authors":"Yijie Tong , Ruijin Wang , Shifeng Wang , Zefei Zhu","doi":"10.1016/j.psep.2024.11.033","DOIUrl":"10.1016/j.psep.2024.11.033","url":null,"abstract":"<div><div>In this paper, the influence of operating parameters of plug flow on thermal efficiency of direct absorption solar collector (DASC) using Fe<sub>3</sub>O<sub>4</sub> nanofluid (0.05–0.2 wt%) was experimentally studied, the DASC is a device that directly converts sunlight into heat by using a working fluid with high thermal conductivity. As a result, the outlet temperature and efficiency of DASC was affected by the ratio of length of liquid plug to the inner diameter of the tube, the working time of air compressor, the mass flow rate, the inlet temperature, solar radiation and concentration of the Fe<sub>3</sub>O<sub>4</sub> nanofluid. When the plug flow mode was implemented, the energy gained and stored exhibited a notable enhancement compared to the regular flow mode. Furthermore, the DASC exhibited the highest efficiency when the L/D were 1.7 which was 27.7 % higher than that of regular flow mode. In addition, the inlet temperature was inversely proportional to the efficiency cause the heat loss to the environment.The maximum performance of the direct absorption solar collector was obtained when 0.1 wt% Fe<sub>3</sub>O<sub>4</sub> nanofluid was used as the working fluid with plug flow mode.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 148-157"},"PeriodicalIF":6.9,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Continuous bioethanol production from glucose-rich hydrolysate derived from wheat straw using a unique fed-batch cultivation method in a bioreactor","authors":"Pritam Singh, Pratibha Gangwar, Nikhil Kumar, Sanjoy Ghosh","doi":"10.1016/j.psep.2024.11.047","DOIUrl":"10.1016/j.psep.2024.11.047","url":null,"abstract":"<div><div>The present study provides solutions to the bioethanol industry’s main issues of the absence of production of maximum fermentable sugars from lignocellulosic biomass, the unsuitability of a single microorganism to convert the fermentable sugars (xylose and glucose) together to bioethanol, and the unavailability of fermentation technique to run the process unlimitedly with consistent yield and productivity. A novel fractional acid hydrolysis technology was demonstrated in this study, which produced more than 90 % (w/w) of available glucose in wheat straw as glucose-rich hydrolysate (GRH). This hydrolysate was then made acid-free using a membrane-based acid separation unit to reuse the separated acid to make the hydrolysis process environmentally safe and chemically inexpensive. Thereafter, this acid-free GRH was fermented to bioethanol using a unique constant volume fed-batch fermentation technique under an optimum glucose-feeding strategy. Remarkably, this fermentation technique yielded optimal average bioethanol productivity (g/Lh), yield (g/g), and titer (g/L) of 7.147±0.533, 0.508±0.002, and 58.835±0.766; 5.722±0.529, 0.501±0.006, and 33.748±0.322, respectively, with more than 99 % glucose utilization during ten fed-batch cycles of synthetic and GRH glucose. Notably, the high production of GRH from lignocellulosic biomass, acid separation and reuse, and continuous and consistent bioethanol production sets this study apart as a pioneering endeavor. Furthermore, the bioethanol profit of USD 0.019/kg biomass from the second batch onwards at a bioethanol selling price of USD 0.745/L suggests the feasibility of the current study for industrial-scale bioethanol production from lignocellulosic biomass.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 74-86"},"PeriodicalIF":6.9,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recycling gold mine tailings into eco-friendly backfill material for a coal mine goaf: Performance insights, hydration mechanism, and engineering applications","authors":"Tianhua Wu , Yongtao Gao , Maowei Ji , Jingkui Zhou , Changfu Huang , Meng Zhang , Yulong Zou , Yu Zhou","doi":"10.1016/j.psep.2024.11.045","DOIUrl":"10.1016/j.psep.2024.11.045","url":null,"abstract":"<div><div>Recycling gold mine overflow tailings for coal mine filling is crucial for sustainable mining. In this work, an eco-friendly, performance-controllable overflow tailings-fly ash-based backfill material is developed for coal mine filling. The effects of three critical factors, namely, the slurry concentration (SC), cement-sand ratio (C:S), and tailings-fly ash ratio (T:F), on the workability and uniaxial compressive strength (UCS) properties of the novel backfill material are thoroughly investigated, and an optimization of the corresponding formulation is conducted. The optimal formula for the backfill is determined to be a CS of 60 %, a C:S of 0.10, and a T:F of 6:6. The hydration mechanism of the chosen typical mixtures is analyzed via X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy, and the results show that a needle-like Aft gel, identified as the major gelatinous product, is intricately intertwined to create an intricate network structure. As the T:F increases, the content of calcium and silicon oxide initially decreases but then increases, and the optimal mixture reaches a minimum value of 63.66 %. The optimum specimen exhibits a peak wavenumber at 1109.46 cm<sup>−1</sup> involving a Si-O stretching vibration bond. A comprehensive filling program at the Liangjia Coal Mine is successfully implemented. Approximately 0.27 tons of overflow tailings are utilized for every ton of backfills. The underground core-pulling backfill achieves a peak uniaxial compressive strength (UCS) of 7.56 MPa after 28 d, surpassing design requirements and showing promise for coal mine filling applications. This study is expected to achieve the transformation of a coal mine goaf into a gold mine tailings pond.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 95-114"},"PeriodicalIF":6.9,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhenning Liu , Zhenan Jin , Linlin Tong , Jiangping Huang , Tenghao Yang
{"title":"A non-isothermal kinetic study on the extraction of metals from spent lithium iron phosphate batteries using the NH2SO3H roasting process","authors":"Zhenning Liu , Zhenan Jin , Linlin Tong , Jiangping Huang , Tenghao Yang","doi":"10.1016/j.psep.2024.11.043","DOIUrl":"10.1016/j.psep.2024.11.043","url":null,"abstract":"<div><div>The non-isothermal kinetics of retired lithium iron phosphate (LiFePO<sub>4</sub>) battery powder and amino sulfonic acid (NH<sub>2</sub>SO<sub>3</sub>H) roasting were studied using TG-DSC. The results show that there are three stages of weight loss: loss of adsorbed water, decomposition and reaction of NH<sub>2</sub>SO<sub>3</sub>H (stage Ⅱ), and formation and growth of Li and Fe sulfate nuclei (stage Ⅲ). The apparent activation energy (E) and pre-exponential factor (ln(A)) of NH<sub>2</sub>SO<sub>3</sub>H decomposition and reaction were 159.85 kJ/mol and 32.02 S<sup>−1</sup>, respectively. Similarly, the apparent E and ln(A) formed by Li and Fe sulfate were 113.89 kJ/mol and 11.55 S<sup>−1</sup>, respectively. Furthermore, the formation of new phases in the second stage reaction is controlled by nucleation and growth. The nucleation and growth of Li and Fe sulfates in the third stage not only occur at this stage, but their rates are also controlled by diffusion. The dynamic equations for the second and third stages are as follows:</div><div><span><math><mrow><mo>[</mo><msup><mrow><mo>−</mo><mi>ln</mi><mo>(</mo><mn>1</mn><mo>−</mo><mi>α</mi><mo>)</mo><mo>]</mo></mrow><mrow><mfrac><mrow><mn>1</mn></mrow><mrow><mn>3</mn></mrow></mfrac></mrow></msup></mrow></math></span>=8.06<span><math><mrow><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>13</mn></mrow></msup></mrow></math></span>exp(-<span><math><mfrac><mrow><mn>1.60</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>5</mn></mrow></msup></mrow><mrow><mi>RT</mi></mrow></mfrac></math></span>)t</div><div><span><math><mrow><mo>[</mo><msup><mrow><mo>−</mo><mi>ln</mi><mo>(</mo><mn>1</mn><mo>−</mo><mi>α</mi><mo>)</mo><mo>]</mo></mrow><mrow><mfrac><mrow><mn>2</mn></mrow><mrow><mn>3</mn></mrow></mfrac></mrow></msup></mrow></math></span>=1.04<span><math><mrow><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>5</mn></mrow></msup></mrow></math></span>exp(-<span><math><mfrac><mrow><mn>1.14</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>5</mn></mrow></msup></mrow><mrow><mi>RT</mi></mrow></mfrac></math></span>)t</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 87-94"},"PeriodicalIF":6.9,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhenlan Dou , Chunyan Zhang , Dongmin Yu , Zihua Ye , Songcen Wang , Siyuan Fan
{"title":"A new co-production (biogas& biodiesel) plant under a microalgae-to-biofuel process designed under a hydrothermal disintegration/ deep eutectic solvent process","authors":"Zhenlan Dou , Chunyan Zhang , Dongmin Yu , Zihua Ye , Songcen Wang , Siyuan Fan","doi":"10.1016/j.psep.2024.11.016","DOIUrl":"10.1016/j.psep.2024.11.016","url":null,"abstract":"<div><div>Microalgae-to-biofuel process can be introduced as one of the promising alternatives to non-renewable resources due to its outstanding advantages. However, the industrial feasibility of employing deep eutectic solvents (DESs) for pretreatment of microalgae remains a relatively uncharted territory, which had been acknowledged as a noteworthy research gap in the literature. The purpose of the article is to develop life cycle and energetic analyzes of a co-production (biogas& biodiesel) plant under a microalgae-to-biofuel process. The proposed biofuel production process is based on a hydrothermal disintegration (HD)/DES cycle. An in-depth analysis and comparison between HD/DES of microalgae for the concurrent production and the conventional HD process is developed. Additionally, the effectiveness of recrystallization and membrane filtration for DES recovery was developed. Finally, the sensitivity analyses, focusing on variables like lipid recovery, DES usage quantity, the efficiency of DES recovery, and biogas yield, are provided. When compared to traditional HD, the incorporation of DES during HD led to a substantial 36.8 % improvement in energy output. However, this came at the cost of higher energy input, resulting in a rise in ratio of net energy by 28 %, primarily due to the energy-intensive nature of DES synthesis. Additionally, the introduction of DES contributed to a slight increase in overall released GHG, from −25.86–25.72 g CO<sub>2</sub> (eq.) per MJ. Notably, a combination approach involving both membrane filtration and recrystallization yielded promising results, achieving a low ratio of net energy of 0.46 and even negative overall released GHG. The sensitivity analyses findings emphasized the need for reducing energy utilization in DES synthesis and addressing more energy-efficient recovery processes to further enhance the HD/DES process's environmental performance and energy efficiency. This study provides valuable insights into optimizing the co-production plant under a microalgae-to-biofuel process through HD/DES, highlighting avenues for sustainability improvements in this promising approach.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 54-73"},"PeriodicalIF":6.9,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wukui Zheng , Jinfeng Sun , Tian Cui , Yingying Hu , Yuxuan Yang , Hui Li
{"title":"Influence of core-shell structure design on the preparation of oil-contaminated soil ceramsite and the pollutant decomposition effect","authors":"Wukui Zheng , Jinfeng Sun , Tian Cui , Yingying Hu , Yuxuan Yang , Hui Li","doi":"10.1016/j.psep.2024.11.039","DOIUrl":"10.1016/j.psep.2024.11.039","url":null,"abstract":"<div><div>With the growing severity of oil-contaminated soil, its remediation technology has received increased attention. In this study, oil-contaminated soil is granulated into a core, covered with a layer of clean material, and sintered at a high temperature to make a core-shell structured ceramsite that can be used as building aggregates. The results showed that the cylinder compression strength, bulk density and 1 h water absorption of the sintered core-shell structure ceramsite is 9.1 MPa, 1134 kg/m<sup>3</sup> and 4.36 %. Furthermore, in comparison with the conventional ceramsite, the core-shell structure process generated 26.9 % more CO<sub>2</sub>. This indicates that the design of the core-shell structure makes it easier for the organic gases in the oil-contaminated soil to crack and release CO<sub>2</sub> and H<sub>2</sub>O, reducing the tail gas pollution problem. After the process, the alkane organic matter in the ceramsite was removed, and the C content was significantly reduced. This method provides a new approach for the preparation of ceramsite for organic contaminated soil.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"192 ","pages":"Pages 1525-1533"},"PeriodicalIF":6.9,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ke Xue, Hai Liu, Dingchao Fan, Yu Wang, Wenguang Zhu, Zhaoyou Zhu, Jianguang Qi, Yinglong Wang, Peizhe Cui
{"title":"Selective recovery of lithium from aqueous solution with hydrophobic deep eutectic solvent based on quantum chemical calculations and experimental investigation","authors":"Ke Xue, Hai Liu, Dingchao Fan, Yu Wang, Wenguang Zhu, Zhaoyou Zhu, Jianguang Qi, Yinglong Wang, Peizhe Cui","doi":"10.1016/j.psep.2024.11.040","DOIUrl":"https://doi.org/10.1016/j.psep.2024.11.040","url":null,"abstract":"Developing green and efficient extractants for selectively recovering lithium from salt lake brine is beneficial for alleviating the increasingly growing demand for lithium resources. This study developed a novel hydrophobic deep eutectic solvent (HDES) for selective recovery of Li<ce:sup loc=\"post\">+</ce:sup> from simulated salt lake brine solutions. Under the optimal experimental parameters, the single extraction efficiency of Li<ce:sup loc=\"post\">+</ce:sup> was 70.18 %, β (Li<ce:sup loc=\"post\">+</ce:sup>/ Na<ce:sup loc=\"post\">+</ce:sup>) and β (Li<ce:sup loc=\"post\">+</ce:sup>/Mg<ce:sup loc=\"post\">2+</ce:sup>) were 22.32 and 947.58, respectively. Cycle experiments verified the high stability and good cycle performance of HDES. The conditions affecting the extraction efficiency of Li⁺ were optimized through experiments, and the high stability and good cyclic performance of HDES were verified. The extraction ability and mechanism of HDES for different metal ions were studied based on FTIR spectra combined with density functional theory. The calculation results showed that the order of extraction capacity of HDES for metal ions was: Li<ce:sup loc=\"post\">+</ce:sup>>Na<ce:sup loc=\"post\">+</ce:sup>>Mg<ce:sup loc=\"post\">2+</ce:sup>. This calculation results were identical to the experimental results. This research will help develop HDES for the selective recovery of lithium from aqueous solutions containing high concentrations of Mg<ce:sup loc=\"post\">2+</ce:sup>, helping to address the urgent global demand for lithium resources.","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"76 1","pages":""},"PeriodicalIF":7.8,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spatial and temporal variation in energy-based carbon dioxide emissions and their predictions at city scale in future, China","authors":"Yuxin Xie , Ran Liu , Min Fan","doi":"10.1016/j.psep.2024.11.032","DOIUrl":"10.1016/j.psep.2024.11.032","url":null,"abstract":"<div><div>In this study, following the calculation of energy-based CO<sub>2</sub> emissions at the provincial scale, a downscaling method is employed to derive CO<sub>2</sub> emissions at city scale in China. Subsequently, an innovative model is developed to forecast CO<sub>2</sub> emissions for each city from 2020 to 2030. Our findings suggest that: (1) High CO<sub>2</sub> emission provinces and cities are primarily situated in the North China Plain and coastal regions. (2) There exists a distinct linear relationship between energy-based CO<sub>2</sub> emissions and nighttime lights (NTLs) across provinces on an annual scale. (3) Between 2020 and 2030, the emergence of high CO<sub>2</sub> emission regions in central and western China is anticipated, and a predicted decline in CO<sub>2</sub> emissions for 70 cities over this period. The methodology outlined in this study can be adapted for use in other countries and regions to assist local governments in formulating policies for carbon reduction and addressing climate change.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"193 ","pages":"Pages 1-25"},"PeriodicalIF":6.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Degradation of hemihydrate phosphogypsum-based backfill in underground mining: Mechanical and microstructural insights on the effects of pH and temperature of mine water","authors":"Zhikai Wang, Yiming Wang, Giovanna Antonella Dino, Lianfu Zhang, Zhuen Ruan, Minzhe Zhang, Jianqiu Li, Aixiang Wu","doi":"10.1016/j.psep.2024.11.003","DOIUrl":"https://doi.org/10.1016/j.psep.2024.11.003","url":null,"abstract":"The mechanical properties of hemihydrate phosphogypsum-based backfill (HPG-backfill) are significantly influenced by the temperature and pH of mine water (MW), impacting the stability of underground mining operations. This study evaluates the effects of MW at different temperatures (20°C, 30°C, and 40°C) and pH levels (3, 5, and 7) on HPG-backfill’s mechanical strength. A comprehensive analysis, including uniaxial compressive strength (UCS) testing, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric and differential thermogravimetric (TG-DTG), and nuclear magnetic resonance (NMR), was employed to explore degradation mechanisms. The results indicate a significant decline in the mechanical performance of HPG-backfill when exposed to MW. This degradation becomes particularly pronounced under more acidic conditions and at elevated temperatures. A polynomial relationship between strength and pH, and a linear correlation with temperature, were identified. Interaction effects between temperature and pH on 28-day strength degradation were observed, diminishing with increased temperature or decreased pH. Gray relational analysis highlights pH as a more critical factor than temperature in degradation. Strength degradation is primarily attributed to gypsum dissolution and the pressure induced by recrystallization, which leads to the formation of fatigue cracks. Additionally, acidic conditions accelerate premature crystallization, altering both the crystal morphology and the pore structure. These insights advance the understanding of HPG-backfill degradation, guiding the developing of more resilient backfill materials for extreme mining environments.","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"255 1","pages":""},"PeriodicalIF":7.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Insights to the roles of nitrogen-doped biochar in anaerobic digestion","authors":"Zhang-Wei He, Sheng-Jie Sun, Ai-Hua Li, Cong-Cong Tang, Ai-Juan Zhou, Yong-Xiang Ren, Zhi-Hua Li, Ai-Jie Wang, Wen-Zong Liu","doi":"10.1016/j.psep.2024.11.038","DOIUrl":"https://doi.org/10.1016/j.psep.2024.11.038","url":null,"abstract":"Biochar has been proven as a promising additive to enhance methane production from anaerobic digestion (AD). To further improve the roles of biochar, nitrogen-doped biochar (NBC) has been widely prepared and studied. This review systematically summarized the current research progress of NBC in AD. Regarding internal nitrogen contained in bio-wastes or introducing external nitrogen sources are the two nitrogen sources for NBC preparation. The physical and chemical characteristics of NBC like adsorption, electrical conductivity, pH buffering, and redox, affect AD through improving operation conditions, promoting organic matters conversion performances, optimizing microbial community structures, and accelerating electron transfer performances. Moreover, chemical nitrogen forms like amino and oxidized nitrogen on the surface of NBC and structural nitrogen forms like pyrrolic nitrogen, pyridinic nitrogen, and graphitic nitrogen in carbon skeleton all play important roles in regulating AD process. Thus, how to quantify nitrogen forms and how the different nitrogen forms affect the enrichment performance and syntrophic relationships of electroactive microorganisms are needed to reveal the structure-efficiency relationship between NBC and AD. Overall, it is an effective alternative to evaluate the potentials of NBC in AD regarding performance evaluation, environment analysis, and economic assessment from NBC preparation to its role in AD for the industrialization of NBC.","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"34 1","pages":""},"PeriodicalIF":7.8,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}