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Effect of temperature on joint quality in wave soldering of Sn-9Zn-2.5Bi-1.5In lead-free solder alloy 温度对锡-9Zn-2.5Bi-1.5In 无铅焊料合金波峰焊接质量的影响
IF 2.6 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-25 DOI: 10.1016/j.mee.2024.112229
Vichea Duk, Anshi Ren, Gong Zhang
{"title":"Effect of temperature on joint quality in wave soldering of Sn-9Zn-2.5Bi-1.5In lead-free solder alloy","authors":"Vichea Duk,&nbsp;Anshi Ren,&nbsp;Gong Zhang","doi":"10.1016/j.mee.2024.112229","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112229","url":null,"abstract":"<div><p>Sn<img>Zn (tin‑zinc) solder has been regarded as a promising lead-free solder material with a low melting point of 198 °C, serving as a suitable alternative to both Sn<img>Pb solder due to its lack of hazardous substances and Sn-Ag-Cu solder because of the high cost associated with silver. Nonetheless, its susceptibility to oxidation hinders solderability and increases soldering defects such as bridging, insufficient fillings, and voids, limiting its use in commercial production. Devices designed with through-hole technology, in contrast to surface-mounted ones, continue to exhibit superior interconnection reliability in such applications. In this investigation on wave soldering, a newly developed lead-free solder, composed of 87% tin, 9% zinc, 2.5% bismuth, and 1.5% indium by weight, was employed under two conditions related to nitrogen content: 1) Ensuring that static oxygen content remained below 3000 ppm. 2) Maintaining soldering section oxygen content below 600 ppm at a conveyor speed of 1200 mm/min. The soldering results were examined at various temperatures of preheating and soldering. It proves that the measured peak temperature of liquid solder T<sub>pL</sub> over 230 °C makes the bridging defect rate lower than 0.30%. Additionally, setting the peak temperature of solder joint T<sub>pZ</sub> above 220 °C, along with specific preheating temperatures (105/115/135/145 °C), archives 100% vertical filling without significant voids in the solder joints. Moreover, optimizing wave soldering settings, specifically adjusting the wave soldering setting temperature T<sub>s</sub> to 235 °C, conveyor speed v<sub>c</sub> to 1000 mm/min, resolves soldering defects associated with Sn-9Zn-2.5Bi-1.5In alloy in wave process.</p></div><div><h3>Relevance summary</h3><p></p><ul><li><span>1.</span><span><p>T<sub>pL</sub> surpasses 230 °C, the total number of bridging defects per board decreases to fewer than 6, approximately 0.30%. T<sub>pZ</sub> values of 220 °C or higher results in 100% vertical fill and no significant large voids, demonstrating optimal filling effects</p></span></li><li><span>2.</span><span><p>Under the conditions of T<sub>S</sub> = 235 °C and v<sub>c</sub> = 1000 mm/min yield T<sub>pL</sub> &gt; 230 °C and T<sub>pZ</sub> &gt; 210.9 °C, it leads to a reduction in bridging defects.</p></span></li><li><span>3.</span><span><p>To maintain flux efficiency and minimize internal voids, an optimal selection of preheating temperatures (105/115/135/145 °C) is demonstrated.</p></span></li><li><span>4.</span><span><p>An integrated nitrogen content-controlled system is utilized to eliminate oxygen from the solder pot, aiming to prevent oxidation.</p></span></li></ul></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141484197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Needle scattered light guided chiplets-interfaced with AI for advanced biomedical application 针散射光引导芯片与人工智能相结合,用于先进的生物医学应用
IF 2.6 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-25 DOI: 10.1016/j.mee.2024.112228
Bakr Ahmed Taha , Ehsan M. Abbas , Ahmed C. Kadhim , Ahmad S. Azzahrani , Adawiya J. Haider , Vishal Chaudhary , Norhana Arsad
{"title":"Needle scattered light guided chiplets-interfaced with AI for advanced biomedical application","authors":"Bakr Ahmed Taha ,&nbsp;Ehsan M. Abbas ,&nbsp;Ahmed C. Kadhim ,&nbsp;Ahmad S. Azzahrani ,&nbsp;Adawiya J. Haider ,&nbsp;Vishal Chaudhary ,&nbsp;Norhana Arsad","doi":"10.1016/j.mee.2024.112228","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112228","url":null,"abstract":"<div><p>Recently, integrating artificial intelligence (AI) with needle scattered light (NSL)-guided chiplets (minuscule circuits) is emerging as a fascinating platform for advanced biomedical applications. This connectivity can facilitate real-time medical operations and generate accurate informatics for more competent telemedicine and enhanced healthcare delivery. To explore this technological concept and cover the related challenges, this comprehensive perspective article covers NSL technology, AI-powered chiplets designs, and the creation of a revolutionary biomedical platform to manage health wellness. For example, this report highlights the development of organs-on-chip, the advancement of remote robotics' human-machine interfaces, the incorporation of MHNN, the possibilities of brain-computer connections, and the challenges of keeping up with the exponential growth of AI and ML computing.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141480134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of low-temperature and low-pressure mild oxidation after plasma solidification on electrical properties and reliability in ultra-thin SiON MOSFETs 等离子固化后的低温低压温和氧化对超薄 SiON MOSFET 电性能和可靠性的影响
IF 2.6 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-19 DOI: 10.1016/j.mee.2024.112213
Qiao Teng , Yongyu Wu , Kai Xu , Dawei Gao
{"title":"Impact of low-temperature and low-pressure mild oxidation after plasma solidification on electrical properties and reliability in ultra-thin SiON MOSFETs","authors":"Qiao Teng ,&nbsp;Yongyu Wu ,&nbsp;Kai Xu ,&nbsp;Dawei Gao","doi":"10.1016/j.mee.2024.112213","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112213","url":null,"abstract":"<div><p>The impact of different SiON manufacturing processes on performance and reliability behaviors has been investigated for the MOSFETs. The performance of devices composed of an ultrathin SiON film fabricated by the novel low-temperature and low-pressure mild oxidation after the plasma solidification (LLMOPS) method can be enhanced compared to conventional processes, which is attributed to the increased mobility. It is observed from secondary ion mass spectrometry analysis that the distribution of nitrogen with the LLMOPS process moves toward the upper surface of SiON. As a result, the p-MOSFET manufactured by the LLMOPS process exhibits lower electrical performance degradation during the NBTI stress, indicating that a reduction in nitrogen concentration at the Si/SiO<sub>2</sub> interface contributes to improving NBTI behavior. It is also demonstrated that the inhibition of NBTI phenomena enhances the frequency stability on the ring oscillator with circuit simulation. Thus, the LLMOPS process is a promising approach to improve the performance and reliability of MOSFETs in mass production.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141607082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility study of fabricating 20 nm resolution dielectric Fresnel zone plates with ultrahigh aspect ratio for EUV optics 为超紫外光学元件制造具有超高长宽比的 20 nm 分辨率介质菲涅尔区板的可行性研究
IF 2.6 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-19 DOI: 10.1016/j.mee.2024.112227
Qingxin Wu , Qiucheng Chen , Hao Quan , Xujie Tong , Jun Zhao , Yifang Chen
{"title":"Feasibility study of fabricating 20 nm resolution dielectric Fresnel zone plates with ultrahigh aspect ratio for EUV optics","authors":"Qingxin Wu ,&nbsp;Qiucheng Chen ,&nbsp;Hao Quan ,&nbsp;Xujie Tong ,&nbsp;Jun Zhao ,&nbsp;Yifang Chen","doi":"10.1016/j.mee.2024.112227","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112227","url":null,"abstract":"<div><p>EUV light optics are either reflective or diffractive due to the substantial absorption characteristics by almost all materials. Despite great successes in manufacturing integrated circuit chips, reflective EUV optics are still unfriendly to small-to-medium enterprise (SME) because of the enormous costs. Recently, diffractive EUV optics has come to the light in hopes to be able to establish manufacturing nanoscale products and inspecting nanoscale structures. Diffractive zone plates with high resolution in EUV wavelengths are urgently needed. This paper reports our latest success in developing 20 nm resolution zone plates for focusing and imaging in the EUV and soft X-ray regions. It firstly discusses the diffraction efficiency of FZPs tailored for 13.5 nm wavelength to decide the essential height of the zone plate. Then, Monte Carlo simulation method was used to figure out the achievable zone plate parameters by high-resolution electron beam lithography (EBL). Finally, this work systematically explored the viability of nanofabricating top-tier 20 nm resolution hydrogen silsesquioxane (HSQ) zone plates with the duty cycle ratio nearing 1:1 and the aspect ratio approaching 13:1 on 50 nm thick Si<sub>3</sub>N<sub>4</sub> membranes.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141484198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rational design of CMUTs with annular electrodes for high ultrasonic emission via ESSE enabled stiffness adjustment 通过调整 ESSE 的硬度,合理设计带有环形电极的 CMUT,实现高超声波发射
IF 2.6 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-18 DOI: 10.1016/j.mee.2024.112224
Zhikang Li , Shiwang Zhang , Yihe Zhao , Shaohui Qin , Shiyu Bai , Jiawei Yuan , Jie Li , Zixuan Li , Beibei Sun , Qi Ma , Xuan Shi , Zilong Zhao , Zheng Yuan , Hefeng Qin , Min Li , Libo Zhao
{"title":"Rational design of CMUTs with annular electrodes for high ultrasonic emission via ESSE enabled stiffness adjustment","authors":"Zhikang Li ,&nbsp;Shiwang Zhang ,&nbsp;Yihe Zhao ,&nbsp;Shaohui Qin ,&nbsp;Shiyu Bai ,&nbsp;Jiawei Yuan ,&nbsp;Jie Li ,&nbsp;Zixuan Li ,&nbsp;Beibei Sun ,&nbsp;Qi Ma ,&nbsp;Xuan Shi ,&nbsp;Zilong Zhao ,&nbsp;Zheng Yuan ,&nbsp;Hefeng Qin ,&nbsp;Min Li ,&nbsp;Libo Zhao","doi":"10.1016/j.mee.2024.112224","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112224","url":null,"abstract":"<div><p>Capacitive micromechanical ultrasonic transducers (CMUTs) with high transmitting acoustic pressure are in urgent demand in the rapidly growing field of air-coupled and therapeutic ultras ound. However, most current CMUTs can rarely balance the performance improvement and batch fabrication capacity, which severely impedes their practical applications. This paper proposes novel CMUTs with annular electrodes that can implement significant improvement in multiple performances while featuring a simple structure and batch fabrication feasibility. The annular electrode configurated between the membrane edge and center areas can effectively soften the corresponding-area membrane stiffness through electrostatic spring softening effects, and leave the stiffness of the membrane central area unchanged, finally enabling the membrane to produce a piston-like deformation, thus improving average displacement and output acoustic pressure. A finite element method was employed to analyze the effect of annular electrodes on the CMUT main performance. The results demonstrated that the novel structure could achieve prominent enhancement in multiple performances, such as an average to maximum displacement rate of 0.46 (about 0.32 for conventional CMUTs), maximum improvements of 300%, 255%, and 11% in average displacement, acoustic pressure, and electromechanical coupling coefficients compared to those of conventional ones. Deep analyses of the variation of the main performances including acoustic pressure, receiving sensitivity, and collapse voltage suggested that an optimal electrode coverage range of 36% ∼ 55% can be used to achieve relatively high comprehensive performances. Meanwhile, the proposed CMUTs feature a simpler structure and fabrication process in comparison with previous ones, showing great promise in air-coupled and therapeutic ultrasound applications.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141484283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation of 2D ReS2/WSe2 based complementary field-effect transistors towards 1 nm technology node 模拟基于二维 ReS2/WSe2 的互补场效应晶体管实现 1 纳米技术节点
IF 2.3 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-14 DOI: 10.1016/j.mee.2024.112225
Chi Zhang, Enlong Li, Hongmiao Zhou, Chenhao Xu, Wenwu Li
{"title":"Simulation of 2D ReS2/WSe2 based complementary field-effect transistors towards 1 nm technology node","authors":"Chi Zhang,&nbsp;Enlong Li,&nbsp;Hongmiao Zhou,&nbsp;Chenhao Xu,&nbsp;Wenwu Li","doi":"10.1016/j.mee.2024.112225","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112225","url":null,"abstract":"<div><p>Advanced Integrated Circuit technology demands high-performance channel materials and innovative device architectures to sustain the scaling of field-effect transistors. In this study, we simulate the electrical performance of rhenium disulfide and tungsten diselenide nanosheet FETs (NSFETs) with gate lengths ranging from 12 nm to 8 nm using Technology Computer-Aided Design method. The simulated high performance including 393 μA/μm on-state current and over 10<sup>5</sup> on/off ratio can meet the criteria for integrated circuit applications in the 1 nm technology node. Complementary FET (CFET) simulations are conducted through the vertical stacking of ReS<sub>2</sub> and WSe<sub>2</sub> NSFETs, exhibiting a small parasitic capacitance of 1.0 fF/μm, and notable noise margin (&gt;235 mV) at different process corners. The construction and performance simulation of Static Random-Access Memory (SRAM) is realized through CFET interconnection, involving the calculation of read current and read/write noise margin. This research offers a forward-looking analysis of performance metrics for future 2D materials-based NSFETs, CFETs, and SRAMs.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141325157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on plasma-polymerized 1-(trimethylsilyl)pyrrolidine films deposited by plasma-enhanced chemical vapor deposition for use as a Cu diffusion barrier in multilevel metallization process 等离子体增强化学气相沉积法沉积的等离子体聚合 1-(三甲基硅基)吡咯烷薄膜在多级金属化工艺中用作铜扩散屏障的研究
IF 2.3 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-08 DOI: 10.1016/j.mee.2024.112192
Chanyong Seo , Namwuk Baek , Shinwon Kang , Gihoon Park , Jihwan Cha , Taesoon Jang , Seonhee Jang , Donggeun Jung
{"title":"Study on plasma-polymerized 1-(trimethylsilyl)pyrrolidine films deposited by plasma-enhanced chemical vapor deposition for use as a Cu diffusion barrier in multilevel metallization process","authors":"Chanyong Seo ,&nbsp;Namwuk Baek ,&nbsp;Shinwon Kang ,&nbsp;Gihoon Park ,&nbsp;Jihwan Cha ,&nbsp;Taesoon Jang ,&nbsp;Seonhee Jang ,&nbsp;Donggeun Jung","doi":"10.1016/j.mee.2024.112192","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112192","url":null,"abstract":"<div><p>As integration continues in the modern semiconductor industry, copper (Cu) is used for metal lines and low dielectric constant (low-<em>k</em>) films are used for intermetal dielectrics (IMD) to reduce signal delays occurring in device interconnects. A diffusion barrier is essential between the Cu metal lines and the IMD to prevent Cu diffusion, and silicon carbon-nitride (SiCN) films with relatively low dielectric constants are being widely studied. In this study, SiCN films deposited from 1-(trimethylsilyl)pyrrolidine (TSPD) precursor by plasma-enhanced chemical vapor deposition (PECVD) were investigated for use as a Cu diffusion barrier in multilevel metallization process. This plasma-polymerized TSPD (ppTSPD) monolayer film as SiCN was deposited in plasma powers ranging from 15 to 30 W. The electrical properties of ppTSPD were measured and the chemical properties were analyzed by Fourier-transform infrared spectroscopy (FTIR). The dielectric constant increased with increased plasma power. The lowest dielectric constant of 3.70 and leakage current density at 1 MV/cm of 2.27<span><math><mo>×</mo></math></span>10<sup>−8</sup> A/cm<sup>2</sup> were found for ppTSPD film deposited at 15 W. To verify the Cu diffusion barrier characteristics of the ppTSPD films, a ppTSPD/ppOMCTS bilayer was introduced by using plasma-polymerized octamethylcyclotetrasiloxane (ppOMCTS) as porous low-<em>k</em> SiCOH films. The time-dependent dielectric breakdown (TDDB) characteristic was enhanced around five times than ppOMCTS monolayer used as a reference. The ppTSPD was suggested for fabricating SiCN films for use as a Cu diffusion barrier in multilevel metallization process.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141294226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fractures of low-k materials in a RF package with integrated passive device based on TGV 基于 TGV 的集成无源器件射频封装中低 k 材料的断裂情况
IF 2.3 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-08 DOI: 10.1016/j.mee.2024.112195
Luchao Wu , Lei Wang , Jun Wang
{"title":"Fractures of low-k materials in a RF package with integrated passive device based on TGV","authors":"Luchao Wu ,&nbsp;Lei Wang ,&nbsp;Jun Wang","doi":"10.1016/j.mee.2024.112195","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112195","url":null,"abstract":"<div><p>The radio frequency (RF) chips and passive devices integrated on the through-glass-via (TGV) substrate meets the demands of miniaturization, high performance and low losses in the application. The RF chip and integrated passive devices (IPDs) are interconnected electrically by a redistribution layer (RDL) on the TGV substrate with the isolation low-k materials. The low-k materials, however, are susceptible to fracture during the thermal process in packaging due to their weak mechanical properties. In this study, the fractures of the low-k material were studied by experiments and the finite element analysis (FEA) for a RF package with integrated passive device based on TGV. The mechanical properties of the low-k material used in the FEA were tested by fabricating freestanding low-k films using microfabrication techniques. Then the fracture behaviors of the low-k material in the package and its impact factors under thermal loadings were examined. The impact factors, such as the initial defect location, direction and length, were investigated by evaluating the stress intensity factors (SIFs) at the defect tips. The results revealed that the most hazardous location in the low-k material is the region below the micro-joint of RF chip. The vertical defects along thickness in low-k film are more likely to propagate than horizontal ones. The SIF value increases linearly with the defect length both in heating and cooling conditions.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141294227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical structure characteristics of flexible low-k SiCOH thin films etched by inductively coupled plasma-reactive ion etching process using FTIR and XPS spectra analysis 利用傅立叶变换红外光谱和 XPS 光谱分析电感耦合等离子体反应离子蚀刻工艺蚀刻的柔性低 K 值 SiCOH 薄膜的化学结构特征
IF 2.3 4区 工程技术
Microelectronic Engineering Pub Date : 2024-06-04 DOI: 10.1016/j.mee.2024.112221
Thomas Poche , William Wirth , Seonhee Jang
{"title":"Chemical structure characteristics of flexible low-k SiCOH thin films etched by inductively coupled plasma-reactive ion etching process using FTIR and XPS spectra analysis","authors":"Thomas Poche ,&nbsp;William Wirth ,&nbsp;Seonhee Jang","doi":"10.1016/j.mee.2024.112221","DOIUrl":"https://doi.org/10.1016/j.mee.2024.112221","url":null,"abstract":"<div><p>Flexible low dielectric constant (low-<em>k</em>) SiCOH thin films were fabricated onto flexible indium tin oxide coated polyethylene naphthalate (ITO/PEN) substrates using plasma-enhanced chemical vapor deposition (PECVD) of a tetrakis(trimethylsilyloxy)silane (TTMSS) precursor. RF plasma powers of 20 and 60 W were utilized for the deposition. The <em>k</em>-values of the pristine SiCOH films deposited at 20 and 60 W were 2.46 and 2.00, respectively. Both films showed hydrophobic surfaces. An inductively coupled plasma-reactive ion etching (ICP-RIE) process was then performed on the flexible SiCOH thin films using CF<sub>4</sub>, CF<sub>4</sub> + O<sub>2</sub>, and CF<sub>4</sub> + Ar. The surface wettability of the films increased substantially following etching, with many of the etched films being considered hydrophilic. The Fourier transform infrared (FTIR) spectra of the pristine films identified four prominent absorption bands as CH<sub>x</sub> stretching, Si-CH<sub>3</sub> bending, Si-O-Si stretching, and Si-(CH<sub>3</sub>)<sub>x</sub> stretching vibration modes. After the etching process, the peak area ratios of Si-O-Si stretching mode increased and those of Si-(CH<sub>3</sub>)<sub>x</sub> stretching mode decreased. The X-ray photoelectron spectroscopy (XPS) spectra analysis determined significant concentration of fluorine on the surface of the film following etching. From the high-resolution XPS scan, it was found that the peak intensity of the C1s and Si2p peaks decreased after etching process and the peak center of the F1s peak shifted depending on etching chemistry. The <em>k</em>-values of the films at 20 W were fairly consistent while those of the films at 60 W increased significantly following the etching process. The increase in <em>k</em>-value after etching for the films at 60 W correlated with surface hydrophilicity, increase in the refractive index, and change in the peak area ratios of Si-O-Si and Si-(CH<sub>3</sub>)<sub>x</sub> stretching modes in the FTIR spectra.</p></div>","PeriodicalId":18557,"journal":{"name":"Microelectronic Engineering","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141291169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning of interface quality of Al/CeO2/Si device by post-annealing of sol-gel grown high-k CeO2 layers 通过对溶胶-凝胶生长的高k CeO2层进行后退火来调节铝/CeO2/硅器件的界面质量
IF 2.3 4区 工程技术
Microelectronic Engineering Pub Date : 2024-05-28 DOI: 10.1016/j.mee.2024.112212
G. Hari Priya , S.K. Srivastava , M.V. Shankar , K.M.K. Srivatsa , Amish G. Joshi , Koteswara Rao Peta
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