Journal of the American Oil Chemists Society最新文献_第4页

Exploring the Application of Waxes and Their Mixtures Oleogels in Ice Cream 蜡及其混合油凝胶在冰淇淋中的应用探讨

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-04-21 DOI: 10.1002/aocs.70085

Ana Paula Lima Ribeiro, Sérgio Augusto Sousa de Campos, Natália Leite Oliveira, Cleiton Antônio Nunes, Sandra Maria Pinto, Thais Lomonaco Teodoro da Silva, João de Deus Souza Carneiro

{"title":"Exploring the Application of Waxes and Their Mixtures Oleogels in Ice Cream","authors":"Ana Paula Lima Ribeiro, Sérgio Augusto Sousa de Campos, Natália Leite Oliveira, Cleiton Antônio Nunes, Sandra Maria Pinto, Thais Lomonaco Teodoro da Silva, João de Deus Souza Carneiro","doi":"10.1002/aocs.70085","DOIUrl":"https://doi.org/10.1002/aocs.70085","url":null,"abstract":"<p>The objective of this work was to produce ice cream using waxes oleogels, aiming to improve its nutritional value while maintaining its physical-chemistry characteristics. Five ice cream formulations were manufactured using (1) milk fat, (2) canola oil, and (3–5) canola oil-oleogels. The oleogels were produced with beeswax (BEW), carnauba wax (CRW), candelilla wax (CLW), and their ternary blend in equal proportions. The ice creams were analyzed according to their overrun, meltdown, microscopic analysis, viscosity, and fatty acid profile. The ice cream produced with CRW-oleogel stood out for its lower melting rates and higher overrun, while the BEW-oleogel-based ice cream showed higher melting rates. The samples with CLW and CRW formed smaller ice crystals, while the ternary blend had a low overrun. The lipid profile of the ice creams produced with oleogels showed lower amounts of saturated fatty acids than samples produced with milk fat did, showing that waxes oleogels are a technological and healthy viable alternative to replace milk fat in ice cream. Although not performed, sensory analysis would be extremely important to further evaluate sensory acceptance of the new ice cream produced.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"719-728"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aocs.70085","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rapid and Non-Destructive Quantification of Trace-Level Lignans in Sesame Oil Using FT-NIR Spectroscopy and Chemometric Modeling 利用FT-NIR光谱和化学计量建模快速无损定量芝麻油中痕量木脂素

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-04-16 DOI: 10.1002/aocs.70090

Yurika Otoki, Sho Ogisu, Shiori Watanabe, Shunji Kato, Daitaro Ishikawa, Kenichi Miyazaki, Yukihiro Ozaki, Kiyotaka Nakagawa

{"title":"Rapid and Non-Destructive Quantification of Trace-Level Lignans in Sesame Oil Using FT-NIR Spectroscopy and Chemometric Modeling","authors":"Yurika Otoki, Sho Ogisu, Shiori Watanabe, Shunji Kato, Daitaro Ishikawa, Kenichi Miyazaki, Yukihiro Ozaki, Kiyotaka Nakagawa","doi":"10.1002/aocs.70090","DOIUrl":"https://doi.org/10.1002/aocs.70090","url":null,"abstract":"<div>\u0000 \u0000 <p>Lignans are bioactive polyphenols in sesame oil that contribute to its antioxidant and metabolic health benefits. Their composition changes drastically during roasting and refining, but conventional methods such as HPLC–UV are time-consuming and require organic solvents. Here, we established a rapid and non-destructive near-infrared (NIR) spectroscopic method coupled with partial least squares regression (PLSR) to simultaneously quantify six lignan species—sesamin, sesamolin, episesamin, diasesamin, sesaminol, and sesamol—in sesame oil. A total of 100 samples, including both roasted and refined oils, were analyzed. Reference data were obtained by HPLC–UV, and PLSR models were constructed using second-derivative NIR spectra. The models achieved excellent predictive accuracy (<i>R</i><sup>2</sup> = 0.970–0.996; RMSE = 0.0008%–0.020%), even for trace-level lignans such as sesamol (0.005%–0.03%) and diasesamin (< 0.04%). The approach successfully distinguished structurally similar lignans and revealed spectral regions (around 7400 cm<sup>−1</sup>) linked to processing-induced compositional changes. The proposed method provides a powerful, solvent-free platform for rapid lignan profiling, allowing analysis within minutes without sample pretreatment, and offers strong potential for industrial quality control and process monitoring.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"709-718"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aquafaba (Chickpea Cooking Water) as a Natural Emulsifier in the Development of Plant-Based Coffee Whitener 鹰嘴豆煮水作为天然乳化剂在植物性咖啡增白剂开发中的应用

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-04-21 DOI: 10.1002/aocs.70092

Sinem Ece Bekdemir, Cansu Ekin Bonacina

{"title":"Aquafaba (Chickpea Cooking Water) as a Natural Emulsifier in the Development of Plant-Based Coffee Whitener","authors":"Sinem Ece Bekdemir, Cansu Ekin Bonacina","doi":"10.1002/aocs.70092","DOIUrl":"https://doi.org/10.1002/aocs.70092","url":null,"abstract":"<p>In this study, the possibility of using aquafaba powder, derived from chickpea cooking water, as a natural emulsifier in the formulation of plant-based coffee whitener was evaluated. For this purpose, coffee whiteners, which are emulsion type products, are obtained by high-shear mixing followed by high-pressure homogenization of the aqueous phase (90% w/w) consisting of aquafaba powder (8%, 8.5%, 9%, 9.5%, and 10% w/w) and maltodextrin (0.2%, 0.5%, 1%, and 1.5% w/w) in different proportions and the oil phase (10% w/w) consisting of palm kernel oil. The model coffee whiteners were evaluated in terms of pH, color, particle size, and physical stability, using the creaming index. According to the stability results, it was determined that emulsion formulations containing 9% aquafaba powder and 1% maltodextrin, and 8.5% aquafaba powder and 1.5% maltodextrin, had no creaming index similar to the commercial dairy-based coffee whitener. Stability results showed that the addition of maltodextrin to the structure of model emulsions had a positive effect on their structural integrity. The addition of maltodextrin supported the stability of the emulsion and reduced the average particle size values. Lastly, a sensory evaluation of coffee samples containing the most stable plant-based coffee whitener emulsions was carried out, comparing them with a commercial dairy-based coffee whitener. A coffee sample with 8.5% aquafaba powder and 1.5% maltodextrin content had the closest acceptability score compared to the commercial coffee whitener. According to all the data obtained from the study, the use of aquafaba as a natural emulsifier in the formulation of plant-based coffee whitener was found appropriate.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"729-739"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aocs.70092","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Air Frying Pretreatment on Quality and Antioxidant Activities of Rapeseed Oil 空气煎炸预处理对菜籽油品质及抗氧化活性的影响

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-08 DOI: 10.1002/aocs.70096

Jinghan Miao, Dan Wang, Hua Zhang, Hong Chen, Fang Wei

{"title":"Effect of Air Frying Pretreatment on Quality and Antioxidant Activities of Rapeseed Oil","authors":"Jinghan Miao, Dan Wang, Hua Zhang, Hong Chen, Fang Wei","doi":"10.1002/aocs.70096","DOIUrl":"https://doi.org/10.1002/aocs.70096","url":null,"abstract":"<div>\u0000 \u0000 <p>Air frying is an emerging pretreatment technology in the food processing industry. This study investigated the effects of air frying pretreatment on the microstructure of rapeseed, as well as on the fatty acid composition, functional components, and antioxidant activity of the resulting pressed oil. Compared with microwave and roasting, air frying pretreatment (190°C, 15 min) induced a greater degree of oil body coalescence within rapeseed cells, which correlated with enhanced oil release and extraction of functional components. Under these conditions, the pressed oil exhibited the highest nutritional value: total phytosterol content reached 7174.39 mg/kg and total phenolic content was 2474.30 mg/kg, both significantly higher than those from microwave pretreated, roasted, or untreated rapeseed. Although oxidation indices increased after pretreatment, all values remained within national safety limits. Moreover, rapeseed oil pressed from air fried rapeseed also demonstrated the strongest antioxidant capacity in DPPH, ABTS, •OH, and <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msubsup>\u0000 <mrow>\u0000 <mo>•</mo>\u0000 <mi>O</mi>\u0000 </mrow>\u0000 <mn>2</mn>\u0000 <mo>−</mo>\u0000 </msubsup>\u0000 </mrow>\u0000 </semantics></math> assays. Statistical analysis revealed a significant positive correlation between antioxidant activity and total phenolic content (<i>p</i> ≤ 0.01). These results indicate that air frying is an effective pretreatment for enhancing the release of functional compounds and improving the antioxidant quality of rapeseed oil.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"809-821"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable Biodiesel Production From High-FFA Chicken Waste Oil: RSM-Based Optimization of Esterification and Transesterification Processes 高游离脂肪酸鸡废油可持续生产生物柴油：基于rsm的酯化和酯交换工艺优化

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-12 DOI: 10.1002/aocs.70099

Shekhar Chauhan, Atanu Kumar Paul, Vaibhav V. Goud

{"title":"Sustainable Biodiesel Production From High-FFA Chicken Waste Oil: RSM-Based Optimization of Esterification and Transesterification Processes","authors":"Shekhar Chauhan, Atanu Kumar Paul, Vaibhav V. Goud","doi":"10.1002/aocs.70099","DOIUrl":"https://doi.org/10.1002/aocs.70099","url":null,"abstract":"<div>\u0000 \u0000 <p>Growing concerns over environmental impact and limited fossil fuel reserves have led to the urgent need for sustainable and renewable energy alternatives, such as biodiesel, to decrease pollution and ensure long-term energy security. This study focused on utilizing chicken waste oil, a cost-effective by-product of the food industry with high free fatty acid (FFA) content (> 25%), to produce biodiesel that aids waste management. A two-step process involving acid esterification followed by base transesterification was employed. Response surface methodology (RSM) was applied to optimize key process parameters with the aim of improving efficiency and reducing reactant usage. The esterification process reduced the acid value to 1.32 mg KOH g<sup>−1</sup>, making it optimum for the transesterification process. A maximum biodiesel yield of 98.9% was achieved with reduced reaction time and lower reactant consumption compared to conventional processes, enhancing the process's environmental sustainability and cost-effectiveness. The produced biodiesel exhibited favorable fuel properties, including density (at 20°C), viscosity, and calorific value, satisfying ASTM standards. Chicken waste oil, despite its high FFA content, demonstrates strong potential as a biodiesel feedstock, contributing to reduced CO<sub>2</sub> emissions and supporting climate change mitigation.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"823-840"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148372997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green Preparation of Naproxen-Loaded Solid Lipid Nanoparticles Based on Glyceryl Behenate to Improve Transdermal Absorption 绿色制备含萘普生的固体脂质纳米颗粒提高透皮吸收

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-04-28 DOI: 10.1002/aocs.70086

Katayoun Morteza-Semnani, Jafar Akbari, Marzieh Ebrahimi, S. Sohrab Rostamkalaei, Kimia Saeedi, Majid Saeedi

{"title":"Green Preparation of Naproxen-Loaded Solid Lipid Nanoparticles Based on Glyceryl Behenate to Improve Transdermal Absorption","authors":"Katayoun Morteza-Semnani, Jafar Akbari, Marzieh Ebrahimi, S. Sohrab Rostamkalaei, Kimia Saeedi, Majid Saeedi","doi":"10.1002/aocs.70086","DOIUrl":"https://doi.org/10.1002/aocs.70086","url":null,"abstract":"<div>\u0000 \u0000 <p>Naproxen is one of the non-steroidal anti-inflammatory drugs which show some side effects via oral administration. Percutaneous delivery of this drug can reduce these adverse effects. The bioavailability of naproxen could be promoted by several methods including administration of naproxen-loaded nanoparticles. In this research solid lipid nanoparticles (SLN) based on glyceryl behenate were developed as drug carriers and after characterization, the percutaneous absorption of optimum nanoparticles was compared with plain topical naproxen preparation. Naproxen-loaded SLNs were prepared by emulsification followed by ultrasonication method. Several nanoparticles were formulated with different amounts of glyceryl behenate as lipid phase and some ratios of Tween 60 and Span 80 as emulsifiers. Selected formulation showed a mean particle size of 259.6 ± 10.2 nm, a polydispersity index (PDI) of 0.39 ± 0.04, a zeta potential of −10.7 ± 0.6 mV and a drug loading of 63.9% ± 5.6%. These data were confirmed by SEM (Scanning Electron Microscope) analysis. DSC (Differential Scanning Calorimetry) and FTIR (Fourier Transform Infrared) spectroscopy proved the drug loading and showed no chemical interaction between formulation ingredients. The percutaneous absorption study via rat skin showed significant drug absorption of naproxen SLN after 24 h via rat skin which was 261.22 ± 86.25 μg/cm<sup>2</sup> of rat skin, in comparison with simple naproxen solution, 41.66 ± 10.88 μg/cm<sup>2</sup> of rat skin (<i>p</i> < 0.0001). This observation was made regarding the drug retained in the skin after 24 h (<i>p</i> < 0.0001). These results indicated SLN prepared based on glyceryl behenate can improve naproxen permeation via skin and can be used as a novel system for dermal drug delivery.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"763-771"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Role of Temperature and Duration in Roasting Camellia Oleifera Seeds for Quality Improvement of the Oil 温度和时间对油茶籽品质改善的作用

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-05 DOI: 10.1002/aocs.70095

Zhenglin Zhou, Xin Luo, Shu Wang, Xinghe Zhang, Jiaojiao Yin, Pan Gao

{"title":"The Role of Temperature and Duration in Roasting Camellia Oleifera Seeds for Quality Improvement of the Oil","authors":"Zhenglin Zhou, Xin Luo, Shu Wang, Xinghe Zhang, Jiaojiao Yin, Pan Gao","doi":"10.1002/aocs.70095","DOIUrl":"https://doi.org/10.1002/aocs.70095","url":null,"abstract":"<div>\u0000 \u0000 <p>Roasting is a critical factor that determines the functional quality of <i>Camellia oleifera</i> seed oil (CSO); however, the synergistic effects of roasting temperature and duration on oxidative stability and bioactive compositions of CSO remain unexplored. Herein, Camellia seeds were roasted across temperatures ranging from 90°C to 180°C for 20–60 min to elucidate the dynamic competition mechanism that governs CSO quality. Physicochemical properties, antioxidant capacity, and minor-component profiles of the resultant CSO were evaluated using a multi-dimensional approach. Hierarchical cluster analysis identified that temperature was the dominant factor for quality variation. The condition of 120°C/20 min showed optimized oxidative stability, antioxidant capacity, and α-tocopherol retention. Notably, phytosterols exhibited structural duality: sitosterol was positively correlated with oxidative stability index and FRAP reducing activity functioning as an antioxidant, whereas conjugated sterols (stigmasta-3,5-diene-3-ol, clerosterol) showed a pro-oxidative tendency. Roasting temperatures above 150°C induced sterol isomerization and lipid oxidation. Principal component analysis confirmed 120°C/20 min as the optimal condition. This work established sterol structural duality as a predictive biomarker for CSO quality, which is quantifiable using multiple linear regression, and proposed a temperature-duration equilibrium concept to guide industrial roasting optimization.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"785-797"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Isolation and Purification of Lipase From Soybean Sprouts for Biodiesel Production 大豆芽脂肪酶的分离纯化及生物柴油生产

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-08 DOI: 10.1002/aocs.70098

Alicia Fiorenza, Pugoh Santoso, Tuti Wukirsari

引用次数: 0

Sustainable Production and First-Principles Evaluation of Kapok Oil Methyl Esters as an Alternative Diesel Fuel 木棉油甲酯替代柴油的可持续生产及第一性原理评价

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-04-09 DOI: 10.1002/aocs.70088

J. Subashini, T. Senthilkumar, S. Sahaya Jude Dhas

{"title":"Sustainable Production and First-Principles Evaluation of Kapok Oil Methyl Esters as an Alternative Diesel Fuel","authors":"J. Subashini, T. Senthilkumar, S. Sahaya Jude Dhas","doi":"10.1002/aocs.70088","DOIUrl":"https://doi.org/10.1002/aocs.70088","url":null,"abstract":"<div>\u0000 \u0000 <p>This study proposes the acid-catalyzed pretreatment followed by alkaline-catalyzed transesterification technique for the successful production and characterization of kapok oil methyl ester (biodiesel), and demonstrates its potential as a viable feedstock due to its high free fatty acid (FFA) content. The entire procedure was systematically monitored to determine the optimum conditions for biodiesel production. The biodiesel yield depends on the type of alcohol used, the molar ratio of alcohol to oil, the type and concentration of catalyst, reaction time, and the water content of the oils and fats. The viscosity of kapok methyl ester (KME) was reduced by approximately 85% compared to raw kapok seed oil. The flash and fire points of KME are higher than those of conventional diesel fuel. Additionally, the calorific value, cetane number, and other fuel properties of KME are comparable to those of diesel. The oxidative stability of KME was found to be 12.3 h, which is higher than the specified values in ASTM D6751. This indicates greater resistance to oxidation, improved storage stability, longer shelf life, and a lower risk of deposit formation. These results validate kapok seed oil as a sustainable, nonedible, and affordable feedstock for the generation of biodiesel. Further research on engine performance, emission profiles, and long-term stability is suggested in order to confirm KME's viability for practical energy applications. It has been established that the KME satisfies the fuel characteristics requirements, making it a highly appropriate substitute for diesel.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"675-683"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Composition-Driven Structural and Viscoelastic Properties of Beeswax–Carnauba Wax Oleogels 蜂蜡-巴西棕榈蜡油凝胶的组成驱动结构和粘弹性特性

IF 2.4 4区农林科学

Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-02 DOI: 10.1002/aocs.70093

Neuvis Alejandro Pino, Fernando Pschunder, Yanina B. Bava, Lucas Marchetti, Lisandro J. Giovanetti, Gabriel Lorenzo

{"title":"Composition-Driven Structural and Viscoelastic Properties of Beeswax–Carnauba Wax Oleogels","authors":"Neuvis Alejandro Pino, Fernando Pschunder, Yanina B. Bava, Lucas Marchetti, Lisandro J. Giovanetti, Gabriel Lorenzo","doi":"10.1002/aocs.70093","DOIUrl":"https://doi.org/10.1002/aocs.70093","url":null,"abstract":"<div>\u0000 \u0000 <p>Oleogels (OG) offer the possibility of incorporating into the diet unsaturated fats with physical properties similar to those of saturated fats without altering their chemical composition. This study investigates the synergistic effects of beeswax (BW) and carnauba wax (CW) binary blends on the structural and rheological properties of oleogels. Rheological analysis revealed that wax mixtures enhanced OG elastic moduli (<i>G</i>′) by up to 10-fold compared to single-wax OG, forming a robust network at lower temperatures (4°C–25°C). SAXS/WAXS studies linked these improvements to microstructural differences: BW-rich OG exhibited ordered lamellar nanostructures (6.4–7.6 nm), while CW-rich systems formed disordered aggregates (9–15 nm). BBC sample (1:3 BW:CW) showed exceptional homogeneity, correlating with superior mechanical strength. Thermal behavior depended on wax ratios, with CW increasing gelation temperatures (e.g., 63°C for CCC vs. 52°C for BBB) and BW accelerating crystallization. Stress relaxation tests confirmed binary OG retained 50× higher residual elasticity than single-wax systems. These findings demonstrate the potential of BW-CW blends to tailor OG for saturated fat replacement in foods, balancing texture, stability, and functionality.</p>\u0000 </div>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"103 7","pages":"773-783"},"PeriodicalIF":2.4,"publicationDate":"2026-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148373343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0