Journal of the American Oil Chemists Society最新文献

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High protein sunflower-based edible coating to preserve roasted sunflower seeds 以高蛋白向日葵为基础的可食用涂层,用于保存烤葵花籽
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2025-01-15 DOI: 10.1002/aocs.12936
María Cecilia Valentinuzzi, Ornella Francina Camiletti, Nelson Rubén Grosso
{"title":"High protein sunflower-based edible coating to preserve roasted sunflower seeds","authors":"María Cecilia Valentinuzzi,&nbsp;Ornella Francina Camiletti,&nbsp;Nelson Rubén Grosso","doi":"10.1002/aocs.12936","DOIUrl":"https://doi.org/10.1002/aocs.12936","url":null,"abstract":"<p>The application of edible coatings allows the shelf life of food products to be extended, since they provide physical resistance, reduce the moisture exchange of the product, and also reduce oxygen permeability, avoiding chemical changes such as nutrient oxidation. The objective of this study was to develop an edible coating made from sunflower protein flour and apply it to roasted sunflower seeds as a preservation procedure for this food product. Roasted sunflower seeds were prepared with and without sunflower coating and stored for 60 days at room temperature. Samples were extracted every 15 days to determine the peroxide values (PV), conjugated dienes (CD) and volatile compounds. The uncoated seeds showed the highest PV (83.7 mEqO<sub>2</sub>/kg at Day 15 and 149.2 mEqO<sub>2</sub>/kg at Day 60), while the coated seeds presented lower values (39.2 and 69.3 mEqO<sub>2</sub>/kg at 15 and 60 days, respectively). Regarding the DC values, this parameter also showed the same behavior as PV. Thirteen volatile compounds were identified in analyzed samples (by GC–MS), where hexanal, 2-octenal and nonanal showed significant variations. The uncoated sunflower seeds showed a greater release of volatile compounds. According to the correlation analysis, hexanal presented the highest correlation value between CD and PV in coated (0.76 and 0.79, respectively) and uncoated seeds (0.70 and 0.91, respectively). The obtained results suggest that, although the oxidative reactions occur in roasted sunflower seeds, the application of the coating delays this deterioration process, slows down the oxidation of lipids and contributes to prolonging the useful life of this product.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"885-892"},"PeriodicalIF":1.9,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143914690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photochemical versus thermal thiol-ene “click chemistry” for renewable polyols with application in polyurethanes 可再生多元醇的光化学与热巯基“点击化学”在聚氨酯中的应用
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2025-01-15 DOI: 10.1002/aocs.12937
Maha L. Shrestha, Juganta K. Roy, Mihail Ionescu, Jerzy Leszczynski
{"title":"Photochemical versus thermal thiol-ene “click chemistry” for renewable polyols with application in polyurethanes","authors":"Maha L. Shrestha,&nbsp;Juganta K. Roy,&nbsp;Mihail Ionescu,&nbsp;Jerzy Leszczynski","doi":"10.1002/aocs.12937","DOIUrl":"https://doi.org/10.1002/aocs.12937","url":null,"abstract":"<p>The primary goal of the study was to compare the efficacy of two approaches, photochemical and thermal, in producing polyols from renewable soybean oil through thiol-ene reactions. The thiol-ene reaction was initiated with UV light in the presence of 2-hydroxy-2-methylpropiophenone as a photo-initiator or via a thermal pathway utilizing radical initiator 2,2′-Azobis(2-methylpropionitrile). The resulting polyols were analyzed using standard analytical techniques including Fourier transform infrared (FT-IR) and nuclear magnetic resonance (NMR) spectroscopies. It was observed that the polyols obtained through the photochemical route exhibited better outcome compared with those synthesized using the thermal treatment. Additionally, we employed computational chemistry technique using density functional theory (DFT) calculation to get insights into various product yields. The DFT results revealed that the hydrogen bond network likely contributed to the improved stability, hence obtained higher product yield of the polyol MSBO-TMPAE compared with that of MSBO-GAE. Our study also focuses on applying the synthesized polyols in polyurethane rigid foams and casts. The polyurethanes prepared from these polyols have comparable thermal and mechanical properties to that of the commercially available polyurethanes.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 6","pages":"973-983"},"PeriodicalIF":1.9,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144213881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing the efficiency of ethyl acetate for lipid extraction as an alternative to the Folch method in selected marine low-trophic species 在选定的海洋低营养物种中,评估乙酸乙酯作为Folch法的替代品进行脂肪提取的效率
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2025-01-15 DOI: 10.1002/aocs.12935
Ying Wang, Karl-Erik Eilertsen, Edel Oddny Elvevoll, Mari Johannessen Walquist
{"title":"Assessing the efficiency of ethyl acetate for lipid extraction as an alternative to the Folch method in selected marine low-trophic species","authors":"Ying Wang,&nbsp;Karl-Erik Eilertsen,&nbsp;Edel Oddny Elvevoll,&nbsp;Mari Johannessen Walquist","doi":"10.1002/aocs.12935","DOIUrl":"https://doi.org/10.1002/aocs.12935","url":null,"abstract":"<p>The recognized health benefits associated with marine omega-3 polyunsaturated fatty acids (PUFAs) have increased their demands and prices, prompting the search for new marine materials as lipid sources. Considering stricter health, safety, and environmental regulations, it is crucial to advocate the transition from chlorinated solvents like chloroform and dichloromethane to sustainable alternatives. This study aimed to assess the lipid extraction efficiency of the ethyl acetate (EtOAc) method compared to the Folch method across four marine resources. The tested species were Atlantic salmon (<i>Salmo salar</i> Linnaeus, 1758) and three low-trophic species: the zooplankton <i>Calanus finmarchicus</i> (Gunnerus, 1770), the microalgae <i>Porosira glacialis</i> (Grunow) Jörgensen, 1905, and the macroalgae <i>Saccharina latissima</i> (Linnaeus). Our results indicated that the EtOAc method is as efficient as the Folch method in extracting lipids from Atlantic salmon fillets and freeze-dried <i>C. finmarchicus</i> (<i>p</i> &gt; 0.05). However, the relative lipid yields from frozen and freeze-dried <i>P. glacialis</i> and <i>S. latissima</i> were 49.5% and 27.3%, respectively, when substituting the Folch method with the EtOAc method. Therefore, we recommend the adoption of EtOAc as a sustainable alternative for materials high in neutral lipids to avoid the underestimation of polar and complex lipids. However, the proportion of PUFAs in the extracted lipids was determined not only by the choice of solvent but also by the biological composition of the materials. We encourage future efforts to choose a suitable lipid extraction method considering the characteristics of the raw materials and their composing lipids, in addition to the trade-offs between extraction efficiency and sustainability.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"871-883"},"PeriodicalIF":1.9,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aocs.12935","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143914691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soybean oil fatty acid alkyl ester estolides to enhance the functionality of poly(lactic) acid 大豆油脂肪酸烷基酯酯类增强聚乳酸功能
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2025-01-05 DOI: 10.1002/aocs.12923
Madison M. Dunbar, Lucas J. Stolp, Dharma R. Kodali
{"title":"Soybean oil fatty acid alkyl ester estolides to enhance the functionality of poly(lactic) acid","authors":"Madison M. Dunbar,&nbsp;Lucas J. Stolp,&nbsp;Dharma R. Kodali","doi":"10.1002/aocs.12923","DOIUrl":"https://doi.org/10.1002/aocs.12923","url":null,"abstract":"<p>Five soybean oil-derived fatty acid alkyl ester estolide plasticizers were synthesized with methyl, ethylene glycol, and propylene glycol ester head groups. The required fatty acid alkyl ester estolides were synthesized by transesterification of alcohols with soybean oil fatty acid methyl esters followed by epoxidation and subsequent ring opening and acetylation. Experimental plasticizers were compounded with PLA for the evaluation of their thermal, mechanical, and water vapor barrier properties compared to those of commercial plasticizer, triethyl citrate (TEC). Experimental plasticizers were divided into low and high molecular weight groups based on similarities in structure and size. High molecular weight plasticizers had poor compatibility with PLA and showed inferior mechanical and water vapor barrier properties. Low molecular weight plasticizers demonstrated good plasticization and depression of glass transition temperature comparable to TEC at low concentrations along with improved water vapor barrier properties at higher concentrations, indicating suitability for more cost-effective applications requiring better water vapor barrier functionality.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"855-869"},"PeriodicalIF":1.9,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143914480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of immobilized lipases for medium and long-chain triacylglycerols preparation through solvent-free acidolysis 无溶剂酸解制备中长链三酰甘油固定化脂肪酶的制备
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-30 DOI: 10.1002/aocs.12926
Shuping Lin, Can Zeng, Qiangyue Zhang, Nanjing Zhong
{"title":"Fabrication of immobilized lipases for medium and long-chain triacylglycerols preparation through solvent-free acidolysis","authors":"Shuping Lin,&nbsp;Can Zeng,&nbsp;Qiangyue Zhang,&nbsp;Nanjing Zhong","doi":"10.1002/aocs.12926","DOIUrl":"https://doi.org/10.1002/aocs.12926","url":null,"abstract":"<p>The present study aims to fabricate efficient immobilized lipases for medium and long-chain triacylglycerols preparation through acidolysis. Eighteen novel materials, including five mesoporous materials, four organic groups modified SBA-15 samples (R-SBA-15) and nine macroporous resins, were employed as matrices for lipases immobilization. Lipases of TLL, AOL, RML and CALB were evaluated. Results indicated that TLL exhibited better acidolysis performance and decanoic acid content from 30% to 45% could be obtained; while other lipases (CALB, RML, and AOL) showed poor performance. In addition, macroporous resins of DA-201, ADS-17, D3520, and mesoporous silicas of SBA-15, Al-MCM-41, HMS, were suitable for TLL immobilization. TLL@SBA-15 was selected for acidolysis and the reaction conditions were optimized through single factors study and orthogonal design. The optimum conditions for the acidolysis were: lipase amount 6 wt%, decanoic acid: camellia oil molar ratio 14:1, reaction time 12 h and temperature 50°C. Under these conditions, decanoic acid content at 59.87%, oleic acid content 33.99% and <i>sn</i>-2 decanoic acid content 7.41% was obtained (the mentioned fatty acids here were the fatty acids combined to oil molecules, not free fatty acids).</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"831-841"},"PeriodicalIF":1.9,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143914703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Raphia sese unconventional oil from the Congo Basin: Comparison between chemical and screw press extraction 刚果盆地的非常规石油:化学和螺旋榨取的比较
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-30 DOI: 10.1002/aocs.12932
Mignon Prince Exaucé Taty, Bob Wilfrid Loumouamou, Michel Elenga, Bruno Baréa, Nathalie Barouh, Jean-Paul Danflous, Jean Mathurin Nzikou, Maria Cruz Figueroa-Espinoza
{"title":"Raphia sese unconventional oil from the Congo Basin: Comparison between chemical and screw press extraction","authors":"Mignon Prince Exaucé Taty,&nbsp;Bob Wilfrid Loumouamou,&nbsp;Michel Elenga,&nbsp;Bruno Baréa,&nbsp;Nathalie Barouh,&nbsp;Jean-Paul Danflous,&nbsp;Jean Mathurin Nzikou,&nbsp;Maria Cruz Figueroa-Espinoza","doi":"10.1002/aocs.12932","DOIUrl":"https://doi.org/10.1002/aocs.12932","url":null,"abstract":"<p>This study highlights the importance of adding value to <i>Raphia sese</i> (raffia) from the Congo Basin, by using a screw press to extract its pulp oil that can be used in agri-food industry. A 2<sup>k</sup> factorial experiment was used to study the influence of the intrinsic parameters of the press (rotation speed and diameter of the output die) on the oil extraction efficiency. Screw press extraction efficiency yield was of 43.3 ± 1.7%, representing an extraction rate of 80.8 ± 6.2%. Mechanical extracted raffia oil was chemically characterized measuring acidity and peroxide values; fatty acid (FA), tocopherol, and sterol compositions, and carotenoids content. These results were compared to those obtained from the analysis of a solvent-extracted oil. The screw press extracted raffia oil exhibited good quality (richer in monounsaturated FA and total sterols; similar total contents in unsaturated FA, tocopherols, and carotenoids; lower acidity and peroxide values), surpassing the solvent-extracted one. Raffia oil's composition would offer a promising alternative to palm oil (obtained from the pulp of <i>Elaeis guineensis</i> fruit). Compared to palm oil, the press- and solvent-extracted raffia oils presented a similar content in saturated FA, ~3.3-fold less monosaturated FA, ~3.4-fold more polyunsaturated FA, 3.5-fold more linoleic acid, and between 2.4 and 2.8-fold more linolenic acid. Raffia oil's use in food products as a replacement for palm oil would thus allow to diversify edible oil sources, stimulate the local economy, and promote healthier and more sustainable diets.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"843-854"},"PeriodicalIF":1.9,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aocs.12932","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143914704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of supercritical carbon dioxide-ethanol cocoa butter addition in cocoa butter-based salad dressings 超临界二氧化碳乙醇可可脂添加对可可脂色拉酱的影响
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-29 DOI: 10.1002/aocs.12929
Norhayati Hussain, Syahida Maarof, Roiaini Mohamad, Komati Rajentran, Nasiru Bilkisu Umar
{"title":"Effects of supercritical carbon dioxide-ethanol cocoa butter addition in cocoa butter-based salad dressings","authors":"Norhayati Hussain,&nbsp;Syahida Maarof,&nbsp;Roiaini Mohamad,&nbsp;Komati Rajentran,&nbsp;Nasiru Bilkisu Umar","doi":"10.1002/aocs.12929","DOIUrl":"https://doi.org/10.1002/aocs.12929","url":null,"abstract":"<p>Addition of cocoa butter containing phytosterols and antioxidants into food products can provide additional health benefit towards consumers. This work aimed to extract cocoa butter from cocoa beans using supercritical fluid extraction to formulate salad dressing containing blends of soybean oil and cocoa butter and compared it with commercial salad dressing. The most similar (insignificant different) characteristics as the control sample in terms of consistency index, flow index, apparent viscosity and crossover value were 10%–35% cocoa butter salad dressing (CBSD). In contrast, the 30% CBSD shows insignificant difference of emulsion stability compared to commercial salad dressing. The most desirable ratio of cocoa butter to be added into salad dressing was 30%. The findings may benefit the local cocoa and salad dressing producer on product diversification.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 4","pages":"823-828"},"PeriodicalIF":1.9,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Extraction and bioactivity assessment of bio-oil from Kappaphycus alvarezii biomass using the Bligh, Dyer and Soxhlet method Bligh - Dyer - Soxhlet法提取木耳生物油及其生物活性评价
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-27 DOI: 10.1002/aocs.12931
Jerin James, Nishesh Sharma, Harish Chandra Joshi, Sanjay Kumar, Avvaru Praveen Kumar, Afzal Hussain
{"title":"Extraction and bioactivity assessment of bio-oil from Kappaphycus alvarezii biomass using the Bligh, Dyer and Soxhlet method","authors":"Jerin James,&nbsp;Nishesh Sharma,&nbsp;Harish Chandra Joshi,&nbsp;Sanjay Kumar,&nbsp;Avvaru Praveen Kumar,&nbsp;Afzal Hussain","doi":"10.1002/aocs.12931","DOIUrl":"https://doi.org/10.1002/aocs.12931","url":null,"abstract":"<p>The lipid composition and algal oil content in red macroalgae play a crucial role in sustainable biofuel and bioactive compound production. In the present study, various extraction methods including biomass pretreatment through ultrasonication and conventional lipid extraction techniques such as Bligh &amp; Dyer and Soxhlet were employed for lipid extraction from <i>Kappaphycus alvarezii</i>. Among these methods, pretreatment of ultrasonication combined with solvent extraction (PT + SE) resulted in highest extraction yield of 21.5% ± 0.38%, surpassing the yield achieved by the Bligh-Dyer method (PT + BD) and the control method, which yielded 19.42% ± 0.1% and 10.7% ± 0.15%, respectively. PT + SE oil possesses lower values in molecular weight, viscosity, and density when compared to PT + BD oil. The trans-esterified samples of PT + BD (T1) and PT + SE (T2) respectively demonstrated greater efficiency in converting methyl esters, with T2 achieving a conversion rate of 92% ± 0.21%, while T1 achieved 84.15% ± 0.15%. It was observed that T2 had a high scavenging rate of 86.42% ± 0.22% indicating its significant ability to neutralize free radicals. In contrast, T1 exhibited a slightly lower scavenging rate of 69.56% ± 0.1%, when compared to T2. T2 sample demonstrated remarkable proteinase inhibition of 79.16% ± 0.18, comparable to salicylic acid, indicating the presence of potent anti-inflammatory salicylic acid analogues in the algal oil. Both lipid-extracted oil (T1and T2) showcased significant antioxidant and anti-inflammatory activities, with T2 oil demonstrating superior inhibition of free radicals and proteinase enzymes.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 4","pages":"811-822"},"PeriodicalIF":1.9,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxidative stability of optimized nanostructured lipid carriers containing thymoquinone-rich oil 富百里醌油纳米结构脂质载体的氧化稳定性研究
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-18 DOI: 10.1002/aocs.12930
Aulia Ardhi, Sri Raharjo, Wisnu Arfian Anditya Sudjarwo, Matthias Schreiner
{"title":"Oxidative stability of optimized nanostructured lipid carriers containing thymoquinone-rich oil","authors":"Aulia Ardhi,&nbsp;Sri Raharjo,&nbsp;Wisnu Arfian Anditya Sudjarwo,&nbsp;Matthias Schreiner","doi":"10.1002/aocs.12930","DOIUrl":"https://doi.org/10.1002/aocs.12930","url":null,"abstract":"<p>Lipid-based nanodelivery systems are now widely used in the pharmaceutical and food industries to enhance the delivery of bioactive compounds by leveraging the properties of lipids. Nanostructured lipid carriers (NLC), as one of the lipid-based nano-delivery systems, employs a blend of solid and liquid lipids, which improves the solubility, stability, and bioavailability of bioactive substances. This study aimed to optimize the NLC containing thymoquinone-rich oil (NLC-TQO) formulation using the Box–Behnken design; assess its antioxidant activity and oxidative stability by measuring 2,2-diphenyl−1-picrylhydrazyl (DPPH) radical scavenging activity, thymoquinone (TQ), and tocopherol contents over 28-day storage; and evaluate the impact of incorporating beta-carotene as singlet oxygen quencher on the oxidative stability of the NLC-TQO. The optimized formulation involved 4.16% lipids (glyceryl monostearate and TQO), 5.85% Tween 80 as the surfactant, and 8.20 min of ultrasonication. NLC formulations demonstrated better DPPH activity retention than the emulsions, with cold and dark storage conditions being the most effective for preserving antioxidant activity. TQ stability in the NLC was observed at elevated temperatures without light, with around 50% remaining intact. However, TQ degraded rapidly under light, almost entirely by day 7. Gamma-tocopherol exhibited better stability than alpha-tocopherol, especially under light. The addition of beta-carotene enhanced NLC-TQO's oxidative stability. These findings revealed the potential of the NLC formulation as an effective delivery system for TQ with better oxidative protection compared to emulsions, making it a promising option for pharmaceutical and food industry applications.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 4","pages":"793-810"},"PeriodicalIF":1.9,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aocs.12930","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Changes in phytochemicals, antioxidant activities, and oxidative stability of oil from germinated peanuts 花生发芽油的植物化学物质、抗氧化活性和氧化稳定性的变化
IF 1.9 4区 农林科学
Journal of the American Oil Chemists Society Pub Date : 2024-12-16 DOI: 10.1002/aocs.12928
Moon Haeng Huh, Junsoo Lee, Hana Lee
{"title":"Changes in phytochemicals, antioxidant activities, and oxidative stability of oil from germinated peanuts","authors":"Moon Haeng Huh,&nbsp;Junsoo Lee,&nbsp;Hana Lee","doi":"10.1002/aocs.12928","DOIUrl":"https://doi.org/10.1002/aocs.12928","url":null,"abstract":"<p>Germination is a promising technique for enhancing the nutritional and functional properties of seeds. Among the nuts, peanuts are composed of approximately 50% oil, which is abundant in unsaturated fatty acids, tocopherols, and phytosterols. This study investigated the changes in phytochemical profile, antioxidant capacity, and oxidative stability of oil from germinated peanuts. Peanuts were germinated over 0, 2, 4, 6, and 8 days. The oil from germinated peanuts exhibited increased levels of α-tocopherol, phytosterols, and carotenoids, while the γ-tocopherol, oleic acid, and linoleic acid levels were reduced. Notably, the oil from germinated peanuts at Day 8 exhibited substantially improved antioxidant activity and oxidative stability compared with oil from ungerminated peanuts. These enhancements were attributed to the elevated phytochemical content of the peanut oil resulting from germination. These results highlight that germination of peanut seeds is an effective strategy for enhancing peanut oil's phytochemical content and oxidative stability, thereby presenting potential benefits for health-conscious consumers.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 4","pages":"785-791"},"PeriodicalIF":1.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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