Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes最新文献_第4页

Effect of ph on migration patterns and degradation pathways of sulfamethazine in soil systems. ph 对磺胺甲基嘧啶在土壤系统中迁移模式和降解途径的影响。

IF 1.4 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-06-07 DOI: 10.1080/03601234.2024.2363580

Xin Li, Haifang Wang, Zhumei Sun, Xia Cao, Junli Zhang, Qihua Chen, Rui Ma

{"title":"Effect of ph on migration patterns and degradation pathways of sulfamethazine in soil systems.","authors":"Xin Li, Haifang Wang, Zhumei Sun, Xia Cao, Junli Zhang, Qihua Chen, Rui Ma","doi":"10.1080/03601234.2024.2363580","DOIUrl":"10.1080/03601234.2024.2363580","url":null,"abstract":"Sulfonamide antibiotics (SAs) are widely used antimicrobial agents in livestock and aquaculture, and most of them entering the animal's body will be released into the environment as prodrugs or metabolites, which ultimately affect human health through the food chain. Both acid deposition and salinization of soil may have an impact on the migration and degradation of antibiotics. Sulfamethazine (SM2), a frequently detected compound in agricultural soils, has a migration and transformation process in the environment that is closely dependent on environmental pH. Nevertheless, scarcely any studies have been conducted on the effect of soil pH changes on the environmental behavior of sulfamethazine. We analyzed the migration and degradation mechanisms of SM2 using simulation experiments and ultra-high performance liquid chromatography-quadrupole time-of-flight mass spectrometry (UHPLC-Q-TOF-MS) techniques. The results showed that acidic conditions limited the vertical migration of sulfadimidine, and SM2 underwent different reaction processes under different pH conditions, including S-C bond breaking, S-N bond hydrolysis, demethylation, six-membered heterocyclic addition, methyl hydroxylation and ring opening. The study of the migration pattern and degradation mechanism of SM2 under different pH conditions can provide a solid theoretical basis for assessing the pollution risk of sulfamethazine degradation products under acid rain and saline conditions, and provide a guideline for remediation of antibiotic contamination, so as to better prevent, control and protect groundwater resources.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"425-436"},"PeriodicalIF":1.4,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141283806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pesticide contamination pattern of surface water in an urban-agricultural mediterranean watershed (Wadi Guenniche, Bizerte Lagoon, Northern Tunisia). 地中海城市-农业流域地表水的农药污染模式（突尼斯北部比泽特泻湖 Wadi Guenniche）。

IF 1.4 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-07-13 DOI: 10.1080/03601234.2024.2375905

Olivier Grünberger, Radhouane Hamdi, Manon Lagacherie, Hanene Chaabane

{"title":"Pesticide contamination pattern of surface water in an urban-agricultural mediterranean watershed (Wadi Guenniche, Bizerte Lagoon, Northern Tunisia).","authors":"Olivier Grünberger, Radhouane Hamdi, Manon Lagacherie, Hanene Chaabane","doi":"10.1080/03601234.2024.2375905","DOIUrl":"10.1080/03601234.2024.2375905","url":null,"abstract":"Two years of monthly sampling and hydrological monitoring were performed at the outlet of a Mediterranean watershed in northern Tunisia to determine the contents of 469 pesticide active ingredients and metabolites in water and evaluate their behavior. Wadi Guenniche is a tributary of the Bizerte coastal lagoon, with a watershed area of 86 km2, which exhibits pluvial cereal, legume, and orchid cultivation and irrigated market gardening. Twenty-nine pesticide active ingredients and 2 metabolites were detected in water. Twenty-four pesticide active ingredients were authorized for use in Tunisia. Among them, 14 had never been mentioned in previous farmer surveys. Five herbicides and their metabolites were the most frequently detected: aminomethylphosphonic acid (AMPA) (100%), glyphosate (94%), simazine (94%), 2,4-D (70%), and deisopropylatrazine (DIA) (47%). The detection frequency and concentration range suggested that the phytosanitary pressure and resulting water contamination are close to those on the northern Mediterranean shore. These results, in addition to characterizing the pollution state, emphasized the need for additional studies on the use and fate of pesticides on the southern shore of the Mediterranean Sea, particularly in Tunisia.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"521-539"},"PeriodicalIF":1.4,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141603730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Efficacy of weed control and selectivity in soybean in the application of preemergent herbicides and their carryover in sorghum and maize. 苗期前除草剂对大豆杂草的防治效果和选择性及其在高粱和玉米上的延续。

IF 1.4 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-12-13 DOI: 10.1080/03601234.2024.2432167

Paulo Vinicius da Silva, Elias Silva de Medeiros, Bruna Ferrari Schedenffeldt, Carolina Cristina Bicalho Medeiros, Munir Mauad, Fernando Cesar Munaro, Pedro Antônio Vougodo Salmazo, Roque de Carvalho Dias, Patricia Andrea Monquero, Lucas Yuji Shirota

{"title":"Efficacy of weed control and selectivity in soybean in the application of preemergent herbicides and their carryover in sorghum and maize.","authors":"Paulo Vinicius da Silva, Elias Silva de Medeiros, Bruna Ferrari Schedenffeldt, Carolina Cristina Bicalho Medeiros, Munir Mauad, Fernando Cesar Munaro, Pedro Antônio Vougodo Salmazo, Roque de Carvalho Dias, Patricia Andrea Monquero, Lucas Yuji Shirota","doi":"10.1080/03601234.2024.2432167","DOIUrl":"10.1080/03601234.2024.2432167","url":null,"abstract":"Further studies are necessary to evaluate not only the effectiveness of preemergent herbicides for weed control and selectivity in soybeans but also the potential carryover damage to crops planted in succession, such as sorghum and maize. This study aimed to assess the efficacy of preemergent herbicides in controlling Euphorbia heterophylla L. and Digitaria insularis L., as well as their selectivity in soybeans (Glycine max L.) and the residual effects on crops sown in succession, including maize (Zea mays L.) and sorghum (Sorghum bicolor (L.) Moench). Two field experiments were conducted with soybean, both in a randomized block design, consisting of the following treatments: sulfentrazone + diuron, flumioxazin + imazethapyr, diclosulam, sulfentrazone, s-metolachlor and flumioxazin, in addition to weeded controls and without weeding, with four replicates. Subsequently, the sowing of maize and sorghum was performed. Visual evaluations of weed control were performed at 14, 21, 28, 35 and 42 days after application of the treatments (DAA) and of phytotoxicity in soybean, sorghum and maize at 14, 21, 28, 35 and 42 days after planting emergence (DAE), and at the end, yield estimate. It was found that the sulfentrazone, sulfentrazone + diuron and imazethapyr + flumioxazin treatments were effective in controlling D. insularis and E. heterophylla up to 42 DAA. For sorghum and maize, no significant injury levels were observed for any treatment, with the exception of sulfentrazone alone, which provided significant reductions in productivity.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"792-802"},"PeriodicalIF":1.4,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142824350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Occurrence of organotin compounds in food: increasing challenge of phenyltin compounds. 食品中有机锡化合物的出现:增加苯基锡化合物的挑战。

IF 2 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2023-12-07 DOI: 10.1080/03601234.2023.2278385

Yan Li, Xuezhe Huang, Na Ge, Jinjie Zhang, Yanzhong Cao, Zongyan Cui

{"title":"Occurrence of organotin compounds in food: increasing challenge of phenyltin compounds.","authors":"Yan Li, Xuezhe Huang, Na Ge, Jinjie Zhang, Yanzhong Cao, Zongyan Cui","doi":"10.1080/03601234.2023.2278385","DOIUrl":"10.1080/03601234.2023.2278385","url":null,"abstract":"Concentrations and distribution for 16 organotin compounds were studied in all kinds of foods, including seafood, agricultural products, and wine. Meanwhile, the degradation of the TBT or TPhT was also evaluated. Concentrations of total organotins in seafood, agricultural products, and wine were 1047.2, 469.4, and 13.5 μg Sn/kg. Meanwhile, the most frequently detected organotin in three kinds of samples were TPhT, MPhT, and MPhT, respectively. The results demonstrated that phenyltin may probably become an emerging organotin pollutant. Regarding seafood, organotin concentrations of fish and mollusks were much higher than those of crustaceans. At the same time, a significant positive correlation was observed between the concentrations of TBT and MBT (p < 0.05), and between DBT and MBT(p < 0.0001). Moreover, TPhT was significantly and positively associated with DPhT (p < 0.0001), suggesting that TPhT was the precursor of DPhT. Apart from the likely illegal use of OTs as biocides in antifouling paints for ships, anthropogenic activity like agricultural activity or industrial activity also caused organotin contamination. Further research and more effective measures should be formulated to protect the food safety. Meanwhile, monitoring of the organotin contamination should not only in Qinhuangdao, but also expand to the cities along Bohai Bay.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"9-14"},"PeriodicalIF":2.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92154725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dissipation pattern of tetraniliprole in/on green chilies. 青辣椒中/上的四硝基虫螨消散模式。

IF 2 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-05-22 DOI: 10.1080/03601234.2024.2343617

Vinothkumar B, Monica S S, Preethi S, Arulkumar G, Muralidharan V, Karthik P

引用次数: 0

Microbiome analyses of poultry feeds: Part II. Comparison of different poultry feeds. 家禽饲料的微生物组分析：第二部分。不同家禽饲料的比较。

IF 1.4 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-06-05 DOI: 10.1080/03601234.2024.2361596

E G Olson, D K Dittoe, A C Micciche, D A Stock, P M Rubinelli, Michael J Rothrock, S C Ricke

{"title":"Microbiome analyses of poultry feeds: Part II. Comparison of different poultry feeds.","authors":"E G Olson, D K Dittoe, A C Micciche, D A Stock, P M Rubinelli, Michael J Rothrock, S C Ricke","doi":"10.1080/03601234.2024.2361596","DOIUrl":"10.1080/03601234.2024.2361596","url":null,"abstract":"Within the realm of poultry feed mill operations, the persistent concern over microbial feed quality necessitates the establishment of a robust baseline for enhancing and sustaining the standards of commercial feeds. This dual-phase investigation, comprising Parts I, was previously published, and the current study presented here as Part II aimed to illuminate this baseline using 16S rRNA gene sequencing. In Part II, nine distinct commercial poultry feeds formulated as starters, growers, starter/growers, or supplements, the selected feeds underwent genomic DNA extraction, amplification with custom dual-indexed primers, and subsequent Illumina MiSeq sequencing. Through data analysis in QIIME2-2021.4 and R Studio, the study unveils alpha (Kruskal-Wallis) and beta (ANOSIM) diversity, taxonomic differences (ANCOM), and core microbiomes (core_members), deeming main and pairwise effects statistically significant at p < 0.05 and Q < 0.05. Notably, the investigation identified 30% common core microbial members across the nine feed types, shedding light on potential foodborne poultry pathogens such as Helicobacter and Campylobacter. Probiotic-associated feeds exhibited distinct microbial communities, emphasizing the need to explore their impact on the early poultry gastrointestinal tract (GIT) further.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"448-482"},"PeriodicalIF":1.4,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141261752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The effect of formulation composition and adjuvant type on difenoconazole dislodgeable foliar residue. 制剂成分和佐剂类型对苯醚甲环唑可脱落叶面残留的影响。

IF 1.4 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-06-13 DOI: 10.1080/03601234.2024.2361595

Mohamed H Badawy, Darragh Murnane, Kathleen A Lewis, Neil Morgan

{"title":"The effect of formulation composition and adjuvant type on difenoconazole dislodgeable foliar residue.","authors":"Mohamed H Badawy, Darragh Murnane, Kathleen A Lewis, Neil Morgan","doi":"10.1080/03601234.2024.2361595","DOIUrl":"10.1080/03601234.2024.2361595","url":null,"abstract":"Rigorous risk assessments for those exposed to pesticides are carried out to satisfy crop protection regulatory requirements. Non-dietary risk assessments involve estimating the amount of residue which can be transferred from plant foliage to the skin or clothes, known as dislodgeable foliar residues (DFRs). DFR data are less available than crop residue data as studies are costly and limited by seasonality. European regulatory authorities are reticent to allow extrapolation of study data to different scenarios as the contributory factors have hitherto been poorly identified. This study is the first to use a new laboratory DFR method to investigate how one such factor, pesticide formulation, may affect DFR on a variety of crops. The study used the active substance difenoconazole as both an emulsifiable concentrate (EC 10%) and a wettable powder (WP 10%) with and without adjuvants (Tween 20 and organophosphate tris(2-ethylhexyl)phosphate TEHP) on tomato, French bean and oilseed rape. A comparable DFR% was retained from the WP and EC formulation on most crops except for tomato, where lower DFR% was retained in the case of WP (39 ± 4.7%) compared to EC (60 ± 1.2%). No significant effect of adjuvant addition was observed for either formulation except when mixing TEHP (0.1% w/v) to the EC 10% on French bean, resulting in 8% DFR reduction compared to the EC formulation alone. This research demonstrates the value of a unique DFR laboratory technique in investigating the importance of the formulation and in-tank adjuvants as factors that affect DFR.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"437-447"},"PeriodicalIF":1.4,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141310774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Prospects for application of microorganisms in bioremediation of soils contaminated with pesticides. 微生物在农药污染土壤生物修复中的应用前景。

IF 2 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2023-12-07 DOI: 10.1080/03601234.2023.2281197

Lyudmila A Belovezhets, Aleksey A Levchuk, Ekaterina O Pristavka

{"title":"Prospects for application of microorganisms in bioremediation of soils contaminated with pesticides.","authors":"Lyudmila A Belovezhets, Aleksey A Levchuk, Ekaterina O Pristavka","doi":"10.1080/03601234.2023.2281197","DOIUrl":"10.1080/03601234.2023.2281197","url":null,"abstract":"The contamination of soil with residual amounts of pesticides remains an urgent challenge for human community. The most efficient approach to address this challenge is the direct microbial degradation of a pesticide in agricultural lands. To this end, the selected microorganisms, which quickly and completely utilize pesticides, are employed. In the present work, two herbicides belonging to different classes of chemical compounds, that is, imazamox and chlorsulfuron were used. The screening of promising microorganisms was carried out among different strains of bacteria and fungi in a liquid mineral medium containing a pesticide as the only source of carbon. It was found that the most active microorganisms were capable of utilizing up to 90% of the active substance for a short time. The dynamics of pesticides degradation indicated that the maximum destruction of the studied substances occurred during the first two weeks of cultivation. Further, the rate of degradation dramatically dropped or stopped at all. An increase in the concentration of pesticides in the cultivation medium almost completely suppressed their degradation. It is interesting that the bacteria were more suitable for the degradation of imazamox, while the fungi rendered the destruction of chlorsulfuron.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"15-20"},"PeriodicalIF":2.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"107591362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dissipation behaviors of deltamethrin, emamectin benzoate and hexythiazox in grape under field conditions. 田间条件下溴氰菊酯、苯甲酸阿维菌素和噻螨酮在葡萄中的消散行为。

IF 2 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-01-29 DOI: 10.1080/03601234.2024.2308487

Tarık Balkan, Adem Yağcı, Kenan Kara

{"title":"Dissipation behaviors of deltamethrin, emamectin benzoate and hexythiazox in grape under field conditions.","authors":"Tarık Balkan, Adem Yağcı, Kenan Kara","doi":"10.1080/03601234.2024.2308487","DOIUrl":"10.1080/03601234.2024.2308487","url":null,"abstract":"The objective of this study was to evaluate the dissipation kinetics of deltamethrin, emamectin benzoate, and hexythiazox in grapes. The QuEChERS method was employed and validated for the precise determination of these three pesticides using liquid chromatography-tandem mass spectrometry (LC-MS/MS). Excellent linearity was observed with regression coefficients exceeding 0.998. Notably, the limits of quantification (LOQ) were significantly lower than the maximum residue limits (MRLs) established for grapes by the European Union. The QuEChERS method l recovered 93.23% of the pesticides with an acceptable RSD of 5.35% (n = 180), demonstrating its suitability for quantifying them in grapes. Half-lives of deltamethrin, emamectin benzoate, and hexythiazox in grapes were 2.62-2.68 days, 8.15-7.30 days, and 3.24-4.01 days, respectively, for both single and double doses. Residues of all pesticides fell below the MRLs by the preharvest interval. This suggests that their application can be considered safe for grapes, ensuring both pest control and consumer safety.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"123-129"},"PeriodicalIF":2.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139574806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Residue analysis and dietary risk assessment of picoxystrobin in potato (Solanum tuberosum), citrus fruit (Citrus reticulata Blanco), and Dendrobium officinale Kimura et Migo. 马铃薯（Solanum tuberosum）、柑橘（Citrus reticulata Blanco）和铁皮石斛中吡蚜酮的残留分析和膳食风险评估 Kimura et Migo.

IF 2 4区农林科学

Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes Pub Date : 2024-01-01 Epub Date: 2024-02-12 DOI: 10.1080/03601234.2024.2313424

Wen Dou, Yuting Chen, Hui Ye, Nan Fang, Yuqin Luo, Xiangyun Wang, Yanjie Li, Hongmei He, Youpu Cheng, Changpeng Zhang

{"title":"Residue analysis and dietary risk assessment of picoxystrobin in potato (Solanum tuberosum), citrus fruit (Citrus reticulata Blanco), and Dendrobium officinale Kimura et Migo.","authors":"Wen Dou, Yuting Chen, Hui Ye, Nan Fang, Yuqin Luo, Xiangyun Wang, Yanjie Li, Hongmei He, Youpu Cheng, Changpeng Zhang","doi":"10.1080/03601234.2024.2313424","DOIUrl":"10.1080/03601234.2024.2313424","url":null,"abstract":"Picoxystrobin is a systemic fungicide widely used on potato, citrus fruit, and Dendrobium officinale. To provide information for the risk assessment of potato, citrus, and Dendrobium officinale, field experiments combined with QuEChERS and HPLC-MS/MS were performed to detect picoxystrobin. Picoxystrobin had good linearity (R2 > 0.99), the average recovery rate was 75 - 102%, and the relative standard deviation was 1 - 11%. Picoxystrobin was utilized as the test agent in field experiments, and samples were evaluated and analyzed at various times after the final application utilizing random sampling. The results showed that picoxystrobin residuals in potato and citrus (orange meat) were ˂ 0.01 mg kg-1, whereas those in citrus whole fruit, D. officinale (fresh), and D. officinale (dried) were < 0.05 - 0.084, 0.16 - 3.82, and 0.34 - 9.05 mg kg-1, respectively. Based on these results, both the acute risk quotient (2.77%) and chronic risk quotient (8.7%) were ˂100%, and the dietary risk assessment indicated that the intake of picoxystrobin residues in potato, citrus fruit, and D. officinale did not pose a health risk. This study can guide the reasonable use of picoxystrobin in potato, citrus fruit, and D. officinale.","PeriodicalId":15720,"journal":{"name":"Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes","volume":" ","pages":"152-159"},"PeriodicalIF":2.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139722880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0