Advanced Materials Interfaces最新文献_第5页

Bimetallic Ruthenium-Cobalt Catalyst Supported on Carbon Nanotubes: Synthesis, Characterization, and Application in Electrochemical Sensing of Isoleucine 碳纳米管负载的双金属钌钴催化剂：合成、表征及其在异亮氨酸电化学传感中的应用

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-05 DOI: 10.1002/admi.202400707

Omrüye Ozok Arıcı, Aykut Caglar, Bassam A. Najri, Nahit Aktaş, Arif Kivrak, Hilal Kivrak

{"title":"Bimetallic Ruthenium-Cobalt Catalyst Supported on Carbon Nanotubes: Synthesis, Characterization, and Application in Electrochemical Sensing of Isoleucine","authors":"Omrüye Ozok Arıcı, Aykut Caglar, Bassam A. Najri, Nahit Aktaş, Arif Kivrak, Hilal Kivrak","doi":"10.1002/admi.202400707","DOIUrl":"https://doi.org/10.1002/admi.202400707","url":null,"abstract":"In this work, a bimetallic Ru-Co catalyst based on carbon nanotubes (Ru-Co/CNT) with a Ru to Co ratio of 95:5 is developed. The catalyst, featuring a total metal loading of 3% on the CNTs, is synthesized using the NaBH4 reduction method. Several analytical analyses are used to detect the properties of the Ru-Co/CNT catalyst. X-ray diffraction (XRD) provides information on crystal structures of the catalysts, high-resolution transmission electron microscopy (HR-TEM) reveals particle size and distribution, inductively coupled plasma mass spectrometry (ICP-MS) measures the elemental composition, and X-ray photoelectron spectroscopy (XPS) use to investigate the chemical oxidation states. In addition, thermal techniques including temperature-programmed reduction (TPR), temperature-programmed oxidation (TPO), and temperature-programmed desorption (TPD) are used to recognize the active sites on the catalyst's surface and the acidity. Then, the Ru-Co/CNT catalyst is applied as a sensor for isoleucine amino acid for the first time. It shows high performance with these parameters, sensitivity (0.002 mA cm−2 mm), LOD – limit of detection (0.04 µm), and LOQ – limit of quantification (0.12 µm). Moreover, the interferences of common serum blood including (D-glucose, uric acid, ascorbic acid, and L-tryptophan) are studied. The findings indicated that the sensor is applicable to work in complex biological systems.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 7","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400707","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Characterization of Coated CoFe2O4 Nanoparticles with Biocompatible Compounds and In Vitro Toxicity Assessment on Glioma Cell Lines 生物相容性包被CoFe2O4纳米颗粒的合成、表征及对胶质瘤细胞系的体外毒性评价

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-05 DOI: 10.1002/admi.202400613

Sevil Ozer, Nurcan Dogan, Sezen Canim-Ates, Ayhan Bingolbali

{"title":"Synthesis and Characterization of Coated CoFe2O4 Nanoparticles with Biocompatible Compounds and In Vitro Toxicity Assessment on Glioma Cell Lines","authors":"Sevil Ozer, Nurcan Dogan, Sezen Canim-Ates, Ayhan Bingolbali","doi":"10.1002/admi.202400613","DOIUrl":"https://doi.org/10.1002/admi.202400613","url":null,"abstract":"Rapid advances in the development of nanotechnology in recent years have led to functional magnetic nanoparticle types (MNPs) with different properties. The diverse applications of these nanoparticles make them a desirable candidate for use in biomedical areas due to their exclusive chemical and physical properties. The present work is conducted to study the in vitro biocompatibility of CoFe2O4@shell with different surface coatings (shell: ascorbic acid (AA), dextran (DEX), and polyethyleneimine (PEI). The cytotoxicity of coated nanoparticles is screened toward the glioma cancer line (C6) and fibroblast cell line (L929) using an MTT assay. CoFe2O4 NPs are synthesized using the co-precipitation method together with hydrothermal synthesis and characterized regarding their structural and magnetic properties using state-of-the-art techniques. Results showed the particles are consistent with the crystal structure of CoFe2O4 and the average crystallite size in the range of 16–18 nm. For the coated NPs, only a slight increase in the Hc is found except for the CoFe2O4@PEI NPs. The comparative analysis of the cytotoxic effects of CoFe2O4@shell NPs on L929 fibroblast and glioma cells shows that the cytotoxicity of samples is much more specific in brain tumor cells, especially it also indicates the significant efficacy of CoFe2O4@PEI in cancer cells.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 5","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400613","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Easy Direct Functionalization of 2D MoS2 Applied in Covalent Hybrids with PANI as Dual Blend Supercapacitive Materials (Adv. Mater. Interfaces 1/2025) 二维MoS2的直接功能化及其在聚苯胺共价杂化材料中的应用接口1/2025)

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-03 DOI: 10.1002/admi.202570001

Matteo Crisci, Felix Boll, Sara Domenici, Jaime Gallego, Bernd Smarsly, Mengjiao Wang, Francesco Lamberti, Andrea Rubino, Teresa Gatti

引用次数: 0

Your Clean Graphene is Still Not Clean (Adv. Mater. Interfaces 1/2025) 你干净的石墨烯仍然不干净。接口1/2025)

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-03 DOI: 10.1002/admi.202570004

Ondrej Dyck, Aisha Okmi, Kai Xiao, Sidong Lei, Andrew R. Lupini, Stephen Jesse

引用次数: 0

Optoelectric-Driven Wetting Transition on Artificially Micropatterned Surfaces With Long-Range Virtual Electrodes (Adv. Mater. Interfaces 1/2025) 远距离虚拟电极在人工微图案化表面上的光电驱动润湿转变。接口1/2025)

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-03 DOI: 10.1002/admi.202570002

Riccardo Zamboni, Debdatta Ray, Cornelia Denz, Jörg Imbrock

引用次数: 0

Next-Generation Materials for Multifunctional Applications: Design Progress and Prospects of 2D MXene-Enabled Hybrid Architectures 多功能应用的下一代材料：二维mxene混合架构的设计进展和前景

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-02 DOI: 10.1002/admi.202400681

Md. Rubel Alam, Mitu Gharami, Barshan Dev, Md Ashikur Rahman, Tarikul Islam

{"title":"Next-Generation Materials for Multifunctional Applications: Design Progress and Prospects of 2D MXene-Enabled Hybrid Architectures","authors":"Md. Rubel Alam, Mitu Gharami, Barshan Dev, Md Ashikur Rahman, Tarikul Islam","doi":"10.1002/admi.202400681","DOIUrl":"https://doi.org/10.1002/admi.202400681","url":null,"abstract":"The rapid development and widespread use of smart, portable, high-bandwidth wearable, and flexible electronic devices have led to an equivocally increased demand for multifunctional nanomaterials. The intriguing nature of the unique layered structure, chemical diversity, and outstanding physiochemical behaviors of 2D MXenes (transition metal carbides/nitrides)-based hybrid architectures with other low-dimensional materials can open a new doorfor multifunctional applications. Achieving high performance with MXenes, such as Ti3C2Tx, often requires a large quantity of material, which can be impractical, and hybrid compositions can alleviate this issue quickly. So, combining MXenes with other low-dimensional materials to form hybrid architectures can offer novel solutions with increased physical, mechanical, chemical, and electrochemical properties. However, practical and large-scale applications of these hybrid architectures, especially for targeted applications, still need to be explored. This comprehensive study reviews the design progress and prospects of 2D MXene-enabled hybrid structures, focusing on combinations with graphene, carbon nanotubes, polyaniline, boron, silicon, and metal oxides. It also explores multifunctional applications, including wearable electronic devices, intelligent tunable sensors, new energy electrodes, and biomedical applications. Additionally, it offers a critical discussion (architectures–properties–applications), identifies research gaps, and provides pressing challenges with solutions for the frontier applications of 2D MXene-enabled hybrid architectures.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 6","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400681","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143646152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Semiconductor Zinc Sulfide Nanospheres for Improving Piezoresistive Sensing Behavior of Melt-Mixed Poly(vinylidene fluoride)/Carbon Nanotube Composites 改善熔融混合聚偏氟乙烯/碳纳米管复合材料压阻传感性能的半导体硫化锌纳米球的合成

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-02 DOI: 10.1002/admi.202400633

Müslüm Kaplan, Emre Alp, Beate Krause, Regine Boldt, Petra Pötschke

{"title":"Synthesis of Semiconductor Zinc Sulfide Nanospheres for Improving Piezoresistive Sensing Behavior of Melt-Mixed Poly(vinylidene fluoride)/Carbon Nanotube Composites","authors":"Müslüm Kaplan, Emre Alp, Beate Krause, Regine Boldt, Petra Pötschke","doi":"10.1002/admi.202400633","DOIUrl":"https://doi.org/10.1002/admi.202400633","url":null,"abstract":"Studies have increasingly aimed at improving the piezoresistive behavior of polymer-based conductive composites (CPCs) for strain-sensing, with inorganic nanomaterial enhancement offering research opportunities. This study investigates the impact of incorporating zinc sulfide nanospheres (ZnS NSs, 1–7 wt.%), synthesized via a one-step hydrothermal method, into a poly(vinylidene fluoride) (PVDF) polymer matrix together with multi-walled carbon nanotubes (MWCNTs). Field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD) analyses reveal that ZnS NSs comprise a mixture of ZnS0.96O0.04 and S phases. While of ZnS NSs minimally impact tensile properties of the PVDF/MWCNT composites, they reduce elongation at break at 5 wt.%. During 15-cycle strain sensing up to 3% strain, ZnS NSs-enhanced composites outperformed PVDF/1 wt.% MWCNT. The reference sample's resistance change ratio (ΔR/R0) decreased below 1% with increased cycles, while 1 wt.% ZnS NSs increased ΔR/R0 to 3%, reducing changes upon cycle increments. Higher ZnS NSs levels (3–7 wt.%) resulted in ΔR/R0 exceeding 4–5%, indicating enhanced strain sensing performance. Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) showed limited impact of ZnS NSs on the thermal properties and microstructure of the composites.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 5","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400633","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Protein-Inspired Polymers with Tunable Microphase Structures toward Autonomous Self-Healing in Aqueous Environments 具有可调微相结构的蛋白质激发聚合物在水环境中实现自主自修复

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-01-02 DOI: 10.1002/admi.202400703

Yanwen Hu, Yan Song, Guo Liang Li

{"title":"Protein-Inspired Polymers with Tunable Microphase Structures toward Autonomous Self-Healing in Aqueous Environments","authors":"Yanwen Hu, Yan Song, Guo Liang Li","doi":"10.1002/admi.202400703","DOIUrl":"https://doi.org/10.1002/admi.202400703","url":null,"abstract":"The self-healing of polymer materials in aqueous environments remains a significant challenge. Herein, a protein-inspired strategy for hydrophobic/hydrophilic-induced microphase separation is proposed to construct self-healing polymers in an aqueous environment. During self-healing, the hydrophobic polydimethylsiloxane microphases in the damaged region reassociate with each other owing to the presence of dynamic hydrophobic interactions underwater. In addition, the hydrophilic carboxyl groups diffuse and penetrate to form hydrogen bonds. It is found that the microphase structure and self-healing efficiency can be adjusted by regulating the hydrophobic/hydrophilic components. The self-healing efficiencies of the as-synthesized polymers in deionized water and seawater environments reach to 99.1 and 98.7%, respectively. The molecular structures of the materials are characterized using Fourier-transform infrared spectroscopy and ultraviolet-visible spectroscopy while the aggregated structure of the as-synthesized polymers is examined using small angle X-ray scattering and atomic force microscopy (AFM). This design strategy, inspired by the biological sciences, will be expected to extend the application range of synthetic intrinsic self-healing polymers, especially in aqueous environments.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 7","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400703","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Controlled Stratification and Assembly of Cellulose Nanocrystals in Polymeric Films Toward Optically Active Coatings 纤维素纳米晶体在聚合物膜中的可控分层和组装，用于光学活性涂层

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2024-12-31 DOI: 10.1002/admi.202400608

Farid Khelifa, Heike M. A. Ehmann, Abderrahman Lamaoui, Mathieu Surin, Jenifer Rubio-Magnieto, Philippe Dubois, Youssef Habibi

{"title":"Controlled Stratification and Assembly of Cellulose Nanocrystals in Polymeric Films Toward Optically Active Coatings","authors":"Farid Khelifa, Heike M. A. Ehmann, Abderrahman Lamaoui, Mathieu Surin, Jenifer Rubio-Magnieto, Philippe Dubois, Youssef Habibi","doi":"10.1002/admi.202400608","DOIUrl":"https://doi.org/10.1002/admi.202400608","url":null,"abstract":"Nature's most brilliant hues arise from the interaction of light with multilayered- structures of aligned building blocks. Mimicking this hierarchical organization in highly-ordered thin films of liquid crystalline species has attracted increasing attention for potential applications in sensors and optical switching displays. Due to its intriguing ability to organize into optically active materials, cellulose nanocrystals (CNCs) are attracting a strong interest in the scientific community. This study demonstrates that the shear-driven convective assembly technique can be used to stratify in a controlled fashion highly ordered multilayers of rod-like CNC embedded in a protective hydrophobic polymer matrix leading to optically active thin films. The films remain fully transparent even after stratifying 50 layers. Atomic force microscopy analysis reveals that over 87% of the CNCs in the upper layer aligned within ±20° of the withdrawal direction. Notably, the stratification does not disrupt the organization of the underlying layers. The films exhibit strong selective reflections with uniform and intense colors, dependent on the number of stratified layers. This scalable appraoch enables precise control over the optical characteristics of CNC-polymer composite films, presenting opportunities for environmentally friendly applications in pigment-free coatings, security papers, and optical devices.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 7","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400608","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143787091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Removal of Natural Organic Matter Fractions by Kaolin/Fly Ash Ceramic Microfiltration Membrane in Drinking Water: Insights from a Laboratory Scale Application 高岭土/粉煤灰陶瓷微滤膜去除饮用水中天然有机物组分：实验室规模应用的见解

IF 4.3 3区材料科学

Advanced Materials Interfaces Pub Date : 2024-12-26 DOI: 10.1002/admi.202400777

Samkeliso S. Ndzimandze, Welldone Moyo, Oranso T. Mahlangu, Adolph A. Muleja, Thabo T. I. Nkambule, Alex T. Kuvarega

{"title":"Removal of Natural Organic Matter Fractions by Kaolin/Fly Ash Ceramic Microfiltration Membrane in Drinking Water: Insights from a Laboratory Scale Application","authors":"Samkeliso S. Ndzimandze, Welldone Moyo, Oranso T. Mahlangu, Adolph A. Muleja, Thabo T. I. Nkambule, Alex T. Kuvarega","doi":"10.1002/admi.202400777","DOIUrl":"https://doi.org/10.1002/admi.202400777","url":null,"abstract":"The high cost of precursor materials has hindered commercialization of ceramic membranes (CM). In this work, a microfiltration ceramic disc (≈50 mm in diameter and 4 mm thick) is prepared from low-cost materials, kaolin, and fly ash (≈67 and 26 wt.%, respectively) by pressing at 200 bar and calcining at 900 °C. Membrane characterization involved physicochemical properties, NOM removal efficiency, and fouling propensity analysis. Furthermore, the efficiency of the CM is tested on samples collected from four drinking water treatment plants (DWTPs) in KwaZulu-Natal Province of South Africa. The NOM removal efficiencies ranged from 18.5–33.4% higher than that achieved by the sand filtration step of all the DWTPs. Fluorescence excitation-emission matrix (FEEM) studies show dominance of terrestrial humic-like and fulvic-like NOM fractions in the raw water and are amenable to removal by CM at all the DWTPs (up to 64.7% higher than removal by sand filters at the respective plants). This study demonstrates the utility of ceramic membranes fabricated from rudimentary materials and presents an opportunity to upscale and retrofit the technology to target the removal of NOM fractions at conventional drinking water treatment plants.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 8","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400777","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0