{"title":"表面活性剂组件指导对流马兰戈尼流泵的化学传递级联","authors":"Dimitrios Karagrigoriou, Peter A. Korevaar","doi":"10.1002/admi.202500508","DOIUrl":null,"url":null,"abstract":"<p>Convective Marangoni flow pumps can drive liquid streams in microfluidic devices and allow static channel layouts to be replaced by “virtual” boundaries that emerge in the liquid phase. However, while transfer from location A → location B can be modified easily via physicochemical control over the surface tension gradients involved, it remains a challenge to establish chemical transfer cascades A → B → C, which is prerequisite to more complex reconfigurable liquid systems. Here, a bottom-up approach is presented for convective Marangoni flow pumps, combining the self-assembly of a linear amphiphile into myelin filaments with the emulsification of oil microdroplets and the occurrence of Marangoni backflows underneath the air/water interface. The system allows chemical transfer over multiple steps amongst droplets that are positioned at the air/water interface. This concept provides a toolbox for the design of controllable surface tension gradients and triggered release of emulsified microdroplets as chemical signal carriers that travel along Marangoni flow patterns emerging in reconfigurable all-in-liquid microfluidics.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 18","pages":""},"PeriodicalIF":4.4000,"publicationDate":"2025-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500508","citationCount":"0","resultStr":"{\"title\":\"Surfactant Assemblies Directing Chemical Transfer Cascades in Convective Marangoni Flow Pumps\",\"authors\":\"Dimitrios Karagrigoriou, Peter A. Korevaar\",\"doi\":\"10.1002/admi.202500508\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Convective Marangoni flow pumps can drive liquid streams in microfluidic devices and allow static channel layouts to be replaced by “virtual” boundaries that emerge in the liquid phase. However, while transfer from location A → location B can be modified easily via physicochemical control over the surface tension gradients involved, it remains a challenge to establish chemical transfer cascades A → B → C, which is prerequisite to more complex reconfigurable liquid systems. Here, a bottom-up approach is presented for convective Marangoni flow pumps, combining the self-assembly of a linear amphiphile into myelin filaments with the emulsification of oil microdroplets and the occurrence of Marangoni backflows underneath the air/water interface. The system allows chemical transfer over multiple steps amongst droplets that are positioned at the air/water interface. This concept provides a toolbox for the design of controllable surface tension gradients and triggered release of emulsified microdroplets as chemical signal carriers that travel along Marangoni flow patterns emerging in reconfigurable all-in-liquid microfluidics.</p>\",\"PeriodicalId\":115,\"journal\":{\"name\":\"Advanced Materials Interfaces\",\"volume\":\"12 18\",\"pages\":\"\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2025-08-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500508\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://advanced.onlinelibrary.wiley.com/doi/10.1002/admi.202500508\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials Interfaces","FirstCategoryId":"88","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/admi.202500508","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Surfactant Assemblies Directing Chemical Transfer Cascades in Convective Marangoni Flow Pumps
Convective Marangoni flow pumps can drive liquid streams in microfluidic devices and allow static channel layouts to be replaced by “virtual” boundaries that emerge in the liquid phase. However, while transfer from location A → location B can be modified easily via physicochemical control over the surface tension gradients involved, it remains a challenge to establish chemical transfer cascades A → B → C, which is prerequisite to more complex reconfigurable liquid systems. Here, a bottom-up approach is presented for convective Marangoni flow pumps, combining the self-assembly of a linear amphiphile into myelin filaments with the emulsification of oil microdroplets and the occurrence of Marangoni backflows underneath the air/water interface. The system allows chemical transfer over multiple steps amongst droplets that are positioned at the air/water interface. This concept provides a toolbox for the design of controllable surface tension gradients and triggered release of emulsified microdroplets as chemical signal carriers that travel along Marangoni flow patterns emerging in reconfigurable all-in-liquid microfluidics.
期刊介绍:
Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018.
The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface.
Advanced Materials Interfaces covers all topics in interface-related research:
Oil / water separation,
Applications of nanostructured materials,
2D materials and heterostructures,
Surfaces and interfaces in organic electronic devices,
Catalysis and membranes,
Self-assembly and nanopatterned surfaces,
Composite and coating materials,
Biointerfaces for technical and medical applications.
Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.