Current Opinion in Electrochemistry最新文献_第8页

Time: The potentially powerful, often-overlooked variable in electrochemical sensing of per- and polyfluoroalkyl substances 时间：全氟烷基和多氟烷基物质电化学传感中潜在的强大的、经常被忽视的变量

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-10-01 Epub Date: 2025-07-02 DOI: 10.1016/j.coelec.2025.101726

Samantha C. Cullom , Jeffrey E. Dick

{"title":"Time: The potentially powerful, often-overlooked variable in electrochemical sensing of per- and polyfluoroalkyl substances","authors":"Samantha C. Cullom , Jeffrey E. Dick","doi":"10.1016/j.coelec.2025.101726","DOIUrl":"10.1016/j.coelec.2025.101726","url":null,"abstract":"<div><div>Modern electrochemistry places a heavy emphasis on the importance of thermodynamic measurements for environmental sensing. While most electrochemical sensors require some type of binding mechanism, analytes do not bind to sensors instantaneously; the binding process takes time, suggesting that we must examine reaction kinetics as well. With emerging environmental pollutants of concern, such as per- and polyfluoroalkyl substances (PFAS), electrochemists must consider the kinetic relationship between the electrochemical sensor and the analyte. Various types of environmental electrochemical sensors, such as enzymes, antibodies, aptamers, and molecularly imprinted polymers (MIPs), exist. Each type of sensor can be used in the environment, but MIPs have recently demonstrated strong potential to qualitatively and quantitatively detect and identify PFAS species at the earliest onset of environmental contamination. Additionally, the mathematical and experimental approaches to MIP binding have room to expand beyond the thermodynamic isotherm models and into a time-dependent kinetic model.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"53 ","pages":"Article 101726"},"PeriodicalIF":6.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144780048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Reactor designs for pH-swing electrochemical CO2 capture ph -摆动电化学CO2捕获反应器设计

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-10-01 Epub Date: 2025-07-19 DOI: 10.1016/j.coelec.2025.101731

Yuesheng Zhang, Haoxiang Bai, Yuhang Wang

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Portable electrochemical sensors for per- and polyfluoroalkyl substances: Design, challenges, and opportunities for field deployment 用于全氟烷基和多氟烷基物质的便携式电化学传感器：现场部署的设计、挑战和机遇

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-10-01 Epub Date: 2025-07-01 DOI: 10.1016/j.coelec.2025.101725

Nishi Gondhiya, Abd Ur Rehman, Daniel Andreescu, Silvana Andreescu

{"title":"Portable electrochemical sensors for per- and polyfluoroalkyl substances: Design, challenges, and opportunities for field deployment","authors":"Nishi Gondhiya, Abd Ur Rehman, Daniel Andreescu, Silvana Andreescu","doi":"10.1016/j.coelec.2025.101725","DOIUrl":"10.1016/j.coelec.2025.101725","url":null,"abstract":"<div><div>The widespread presence of per- and polyfluoroalkyl substances (PFAS) in the environment presents a complex global challenge due to their persistence, resistance to degradation, and harmful effects. Electrochemical sensors offer the sensitivity needed to detect PFAS at regulatory limits and show promise for large-scale environmental monitoring without the need for costly laboratory equipment. This review highlights recent advances in electrochemical sensing technologies and their potential as field-deployable devices for rapid screening and on site PFAS detection. Examples include sensor platforms based on redox-active reporters, molecularly imprinted polymers (MIPs), redox dyes, metal organic frameworks (MOFs), covalent organic frameworks (COFs), nanoparticle impacts, and nanobubble and nanopore technologies, coupled with direct or indirect signal transduction strategies. We discuss promising sensor designs and detection mechanisms and outline the key challenges and future directions needed to advance their practical deployment in environmental monitoring applications.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"53 ","pages":"Article 101725"},"PeriodicalIF":7.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144711093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Organic and molecular electrochemistry: Tools, interfaces and interdisciplinary frontiers 有机和分子电化学：工具、界面和跨学科前沿

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-10-01 Epub Date: 2025-07-22 DOI: 10.1016/j.coelec.2025.101735

Serena Arnaboldi, Sara Grecchi

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Surface electrochemistry of low-dimensional materials 低维材料的表面电化学

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-06-02 DOI: 10.1016/j.coelec.2025.101720

Enrique Herrero, Galina Tsirlina

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The role of water and cations in shaping electrified interfaces: Insights from Raman and FTIR spectroscopy 水和阳离子在形成带电界面中的作用：来自拉曼和FTIR光谱的见解

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-04-28 DOI: 10.1016/j.coelec.2025.101701

Jéssica Alves Nogueira, Lucas Dias Germano, Leonardo Domenico De Angelis, Susana Inés Córdoba de Torresi

{"title":"The role of water and cations in shaping electrified interfaces: Insights from Raman and FTIR spectroscopy","authors":"Jéssica Alves Nogueira, Lucas Dias Germano, Leonardo Domenico De Angelis, Susana Inés Córdoba de Torresi","doi":"10.1016/j.coelec.2025.101701","DOIUrl":"10.1016/j.coelec.2025.101701","url":null,"abstract":"<div><div>A detailed understanding of the structural dynamics of water at the electrode/electrolyte interface is essential for deciphering and improving electrocatalyst performance. This review highlights innovative uses of Raman and Fourier Transform Infrared spectroscopy to probe interfacial water under electrochemical conditions. Moving beyond conventional approaches, we discuss strategies that evaluate the influence of electrolyte composition and external stimuli—such as light irradiation—on the dynamics of interfacial species. These <em>in situ</em> techniques uncover changes in water orientation and coordination during critical reactions like CO<sub>2</sub> reduction and oxygen evolution. In alkaline environments, cations significantly influence interfacial dynamics: their hydration shells disrupt hydrogen bonding networks, modulating water adsorption, local electric fields, proton transport, and the stabilization of reaction intermediates. The creative application of advanced spectroscopic techniques to evaluate the effects of electrolytes, applied potentials, and/or irradiation on water structure provides novel insights that are reshaping our understanding of the electrified interface.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"52 ","pages":"Article 101701"},"PeriodicalIF":7.9,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144089846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Electrochemical analysis in micrometer and nanometer-sized droplets on a surface: From static toward dynamic 表面微米级和纳米级液滴的电化学分析：从静态到动态

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-05-03 DOI: 10.1016/j.coelec.2025.101704

Liang Liu

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Recent advances in all-iron flow batteries (AIFBs) 全铁液流电池的研究进展

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-05-01 DOI: 10.1016/j.coelec.2025.101702

Tiantian Lei , Yifeng Xu , Yao Li , Liyun Huang , Li Ma , Daiqiang Si , Kairui Wang , Fengmei Wang , Jiquan Liu , Lin Lei , Liping Cao , Ying Yang

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Single-entity electrochemistry: Unveiling nanoparticle behavior with advanced scanning probe electrochemical techniques 单实体电化学：揭示纳米粒子行为与先进的扫描探针电化学技术

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-05-22 DOI: 10.1016/j.coelec.2025.101710

Aruchamy Gowrisankar , Vishal Pandurang Bhandigare , Kyungsoon Park , Byung-Kwon Kim

{"title":"Single-entity electrochemistry: Unveiling nanoparticle behavior with advanced scanning probe electrochemical techniques","authors":"Aruchamy Gowrisankar , Vishal Pandurang Bhandigare , Kyungsoon Park , Byung-Kwon Kim","doi":"10.1016/j.coelec.2025.101710","DOIUrl":"10.1016/j.coelec.2025.101710","url":null,"abstract":"<div><div>The advancement of sophisticated electroanalytical techniques has attracted significant interest in investigating the fundamental properties of individual nanoparticles. This review highlights recent developments in scanning probe microscopy (SPM), including scanning electrochemical cell microscopy (SECCM), electrochemical scanning tunneling microscopy (EC-STM), and electrochemical atomic force microscopy (EC-AFM). These SPM techniques provide complementary insights into nanoparticle size, morphology, electronic structure, and surface reactivity. SECCM enables localized electrochemical analysis with high spatial resolution, while EC-STM and EC-AFM facilitate nanoscale imaging and the identification of active sites involved in electrocatalytic reactions. One of the most promising strategies involves integrating these techniques to establish structure–activity correlations at the single-nanoparticle level, thereby enhancing characterization capabilities. We demonstrate how hybrid characterization techniques can be employed to capture in situ information during complex electrochemical processes at the electrode–electrolyte interface. Specifically, we highlight the monitoring and measurement of local electrochemical processes using high-spatial-resolution imaging in correlation with single-entity electrochemistry techniques.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"52 ","pages":"Article 101710"},"PeriodicalIF":7.9,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144271840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Effect of cations on the electro-oxidation of alcohols and polyols on Pt: Activity, selectivity, and mechanistic insights 阳离子对醇和多元醇电氧化对铂的影响：活性、选择性和机理

IF 7.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-01 Epub Date: 2025-05-07 DOI: 10.1016/j.coelec.2025.101705

Victor Y. Yukuhiro , Alan J. Gibson , Elton Sitta , Angel Cuesta , Pablo S. Fernández

{"title":"Effect of cations on the electro-oxidation of alcohols and polyols on Pt: Activity, selectivity, and mechanistic insights","authors":"Victor Y. Yukuhiro , Alan J. Gibson , Elton Sitta , Angel Cuesta , Pablo S. Fernández","doi":"10.1016/j.coelec.2025.101705","DOIUrl":"10.1016/j.coelec.2025.101705","url":null,"abstract":"<div><div>Understanding the role of cations in the electro-oxidation of alcohols and polyols (EOAP) on Pt electrodes is essential for optimizing electrocatalytic processes in energy conversion and chemical production. This review explores how cations modulate activity, selectivity, and dynamic behavior during the EOAP. Larger cations, such as K<sup>+</sup>, enhance reaction rates and facilitate C–C bond cleavage, whereas smaller cations like Li<sup>+</sup> promote CO<sub>ad</sub> oxidation and the formation of inactive Pt oxides. The interplay between cations, adsorbed intermediates, and the electrode surface is analysed using complementary electrochemical and in situ spectroscopic techniques, covering hypotheses proposed to explain these observations. Despite progress, fundamental questions remain regarding the microscopic origins of cation effects, including the relative stabilities of key intermediates, how these stabilities influence their formation and oxidation, and ultimately how they govern the deactivation of Pt surfaces via the formation of inactive Pt oxides.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"52 ","pages":"Article 101705"},"PeriodicalIF":7.9,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0