Current Opinion in Electrochemistry最新文献_第7页

Ultra-sensitive electrochemical immunosensors for clinically important biomarker detection: Prospects, opportunities, and global trends 用于临床重要生物标记物检测的超灵敏电化学免疫传感器：前景、机遇和全球趋势

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-17 DOI: 10.1016/j.coelec.2024.101524

Anton Popov , Benediktas Brasiunas , Katazyna Blazevic , Asta Kausaite-Minkstimiene , Almira Ramanaviciene

引用次数: 0

Collision electrochemistry: A simple methodology for investigating complex processes 碰撞电化学：研究复杂过程的简单方法

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-15 DOI: 10.1016/j.coelec.2024.101518

Si-Min Lu , Jean-Marc Noël , Jean-François Lemineur

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引用次数: 0

Editorial overview: Electrochemical materials and engineering (2023), multidisciplinary by essence 编辑概述：Electrochemical Materials and Engineering (2023) , Multidisciplinary by essence

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-15 DOI: 10.1016/j.coelec.2024.101519

Frédéric Jaouen, Chang Hyuck Choi

引用次数: 0

Exploring failure mechanism studies for lithium-sulfur battery pouch cells 探索锂硫电池袋电池的失效机理研究

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-15 DOI: 10.1016/j.coelec.2024.101516

Osbert Leo A. Privaldos , Chaehyeong Lee , Jin Won Kim , Jaeyoung Lee

引用次数: 0

Electrocatalysts for ammonia synthesis: How close are we to the Haber-Bosch process? 氨合成的电催化剂以及我们距离哈伯-博什合成还有多远？

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-15 DOI: 10.1016/j.coelec.2024.101520

Nikhil George Mohan, Kothandaraman Ramanujam

引用次数: 0

Computational screening and descriptors for the ion mobility in energy storage materials 储能材料中离子迁移率的计算筛选和描述符

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-12 DOI: 10.1016/j.coelec.2024.101494

Mohsen Sotoudeh , Axel Groß

引用次数: 0

Editorial overview: Surface electrochemistry for everyone 编辑概述：面向所有人的表面电化学

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-10 DOI: 10.1016/j.coelec.2024.101510

Carlos M. Sánchez-Sánchez, Fethi Bedioui

引用次数: 0

Diving deep into solid oxide-based CO2 electrolysis: Operando insights 深入研究基于固体氧化物的二氧化碳电解：操作见解

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-09 DOI: 10.1016/j.coelec.2024.101514

Vipin Kamboj, Soham Raychowdhury, Chinmoy Ranjan

{"title":"Diving deep into solid oxide-based CO2 electrolysis: Operando insights","authors":"Vipin Kamboj, Soham Raychowdhury, Chinmoy Ranjan","doi":"10.1016/j.coelec.2024.101514","DOIUrl":"10.1016/j.coelec.2024.101514","url":null,"abstract":"<div>CO2 reduction to fuels using solid oxide electrodes is a promising approach due to high faradaic and energy efficiencies. CO2 reducing electrodes (cathodes) form the central challenge in enabling solid oxide technology for CO2 electrolysis. Typical cathodes can comprise of both oxides such as perovskites and metals such as Ni and Fe. Efforts at improving the activity, selectivity, and stability of the electrodes continue. Operando methods provide direct access to active sites during the reaction and provide valuable information such as the identity of catalytic material, nature of reaction intermediates, oxidation state of catalytic ions, etc. These methods have created a deeper mechanistic understanding, unravelled new performance indicators, and increasingly enabling a deep diagnostic based systematic development of catalysts and processes. This study summarises and analyses data from operando approaches to develop an understanding of CO2 reduction mechanism on certain commonly studied electrodes. In particular, this review discusses CO2 reduction mechanism on electrodes such as Ni-YSZ, CeO2-x and perovskites such as La1-xSrxFeOy. The CO2 reduction on these surfaces essentially progresses on an oxide terminated surface via formation of a three coordinated carbon (carbonate type) intermediate formed at oxygen defect sites. Metal electrodes such as Ni-YSZ were found to oxidize in situ in presence of CO2 and the reaction proceeded via oxide mediated mechanism. In electrodes such as La1-x SrxFeOy, exsolution of metals was essentially found to have no direct impact on CO2 electrolysis. In the context of catalyst coking on CeOx electrodes, new descriptors, such as the number of reduced sites (Ce3+), and the existence of metal carbonyl species “Ce3+ – CO” have emerged.</div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":null,"pages":null},"PeriodicalIF":8.5,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140770337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancing electrochemical CO2 reduction: Insights from operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy analysis 推进电化学二氧化碳还原：操作步长衰减全反射表面增强红外吸收光谱分析的启示

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-09 DOI: 10.1016/j.coelec.2024.101515

Sojung Park, Wooyul Kim

引用次数: 0

Biomass-derived carbon electrodes: Key parameters for understanding the electrocatalytic performance 生物质衍生碳电极：了解电催化性能的关键参数

IF 8.5 2区化学

Current Opinion in Electrochemistry Pub Date : 2024-04-09 DOI: 10.1016/j.coelec.2024.101511

Tingwei Sun , Ali Fayad , Alicia Gomis-Berenguer , Conchi Ania

{"title":"Biomass-derived carbon electrodes: Key parameters for understanding the electrocatalytic performance","authors":"Tingwei Sun , Ali Fayad , Alicia Gomis-Berenguer , Conchi Ania","doi":"10.1016/j.coelec.2024.101511","DOIUrl":"https://doi.org/10.1016/j.coelec.2024.101511","url":null,"abstract":"<div>The conversion of biomass into carbon materials has become an essential pillar of sustainability in electrochemical technologies. However, biomass-derived carbons and their electrodes are complex materials. This opinion article raises concerns about the need to correlate physicochemical properties of these carbon materials with those of the biomass precursor, the electrode composition, and the electrode/electrolyte interface to rationalize the comprehension of their electrocatalytic performance. The electrocatalytic activity of biomass-derived carbons in aqueous environments is discussed for several reactions of interest in terms of the nature and stability of electroactive sites and the ability to form radicals. All these are strongly related to the characteristics of the carbon material (composition, type of functional groups, porosity, structural order) and the manufacture of those electrodes. Concerns are also raised about the ambiguities and misconceptions associated with the lack of consensual terminology on biomass-derived carbons. Finally, recommendations are presented when reporting the electrocatalytic activity of biomass-derived carbons; emphasis should be paid to demonstrate the reproducibility of biomass-derived carbon electrodes and their stability through long-term electrocatalytic assays.</div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":null,"pages":null},"PeriodicalIF":8.5,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2451910324000723/pdfft?md5=5ef359b4ac5db89121d0683e84b9d321&pid=1-s2.0-S2451910324000723-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140645676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0