Current Opinion in Electrochemistry最新文献

Improving the selectivity of electrochemical CO2 reduction to multicarbon chemicals through microenvironment engineering 通过微环境工程提高电化学CO2还原对多碳化合物的选择性

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-09-15 DOI: 10.1016/j.coelec.2025.101759

Shouzhong Zou

{"title":"Improving the selectivity of electrochemical CO2 reduction to multicarbon chemicals through microenvironment engineering","authors":"Shouzhong Zou","doi":"10.1016/j.coelec.2025.101759","DOIUrl":"10.1016/j.coelec.2025.101759","url":null,"abstract":"<div><div>Electrochemical carbon dioxide reduction reaction (eCO<sub>2</sub>RR) is a promising approach to reduce the concentration of CO<sub>2</sub> in the atmosphere and produce value-added chemicals. Due to the high stability of CO<sub>2</sub> and the complex reaction pathways, the selectivity and reaction rate of converting CO<sub>2</sub> into high-value chemicals, especially multicarbon products, remain unsatisfactory for viable commercial applications. In conjunction with developing catalysts with high intrinsic activity and selectivity, engineering the microenvironment to which the catalysts are exposed has become a versatile and effective means to steer the reaction pathway toward desirable C<sub>2+</sub> products with high selectivity and at a practically viable current density. This review provides an overview of recent advancements in steering eCO<sub>2</sub>RR toward C<sub>2+</sub> on Cu-based catalysts through microenvironment engineering in the past two years. Selective examples are used to illustrate the efficacy of each microenvironment engineering approach. Perspectives on future research directions are also provided.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"54 ","pages":"Article 101759"},"PeriodicalIF":6.9,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145262909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A critical review of electrosynthesized molecularly imprinted polymers in electrochemical sensing: Pros and cons 电合成分子印迹聚合物在电化学传感中的应用综述：利弊

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-09-12 DOI: 10.1016/j.coelec.2025.101752

Abdellatif Ait Lahcen , Kawtar Saidi , Aziz Amine

引用次数: 0

Electroanalysis of proteins and peptides via amino acid residues 通过氨基酸残基对蛋白质和多肽进行电分析

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-09-10 DOI: 10.1016/j.coelec.2025.101751

Elena V. Suprun

引用次数: 0

Electrochemical lateral flow assays: A new frontier for rapid and quantitative biosensing 电化学横向流动测定：快速定量生物传感的新前沿

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-28 DOI: 10.1016/j.coelec.2025.101750

Vernalyn Abarintos, Andrew Piper, Arben Merkoci

{"title":"Electrochemical lateral flow assays: A new frontier for rapid and quantitative biosensing","authors":"Vernalyn Abarintos, Andrew Piper, Arben Merkoci","doi":"10.1016/j.coelec.2025.101750","DOIUrl":"10.1016/j.coelec.2025.101750","url":null,"abstract":"<div><div>Electrochemical lateral flow assays (eLFAs) have emerged as a promising alternative to traditional colorimetric LFAs, particularly for applications requiring quantitative readouts and improved sensitivity. Over the past two years, significant advancements have been made in eLFA design, fabrication, and analytical performance, positioning them as promising candidates for decentralized diagnostics and point-of-care (POC) testing. This review highlights recent advances in electrode integration techniques, redox-based signal amplification strategies, and the incorporation of wireless and battery-free electrochemical readout platforms. Multiplexed detection and real-time wireless data transmission have also been demonstrated, further increasing the utility of eLFAs in clinical and field settings. Additionally, innovative strategies to control contact pressure, optimize sample flow, and maintain device stability are being explored to improve reproducibility and usability. Despite these advancements, challenges remain, including biofouling, variability in sample matrices, and the need for standardized protocols across platforms.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"54 ","pages":"Article 101750"},"PeriodicalIF":6.9,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent trends in electrochemical methods for real-time detection of heavy metals in water and soil: A review 电化学方法实时检测水和土壤中重金属的研究进展

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-26 DOI: 10.1016/j.coelec.2025.101749

Pythagore L. Kyabutwa , Nadiah Alyamni , Jandro L. Abot , Alexander G. Zestos

{"title":"Recent trends in electrochemical methods for real-time detection of heavy metals in water and soil: A review","authors":"Pythagore L. Kyabutwa , Nadiah Alyamni , Jandro L. Abot , Alexander G. Zestos","doi":"10.1016/j.coelec.2025.101749","DOIUrl":"10.1016/j.coelec.2025.101749","url":null,"abstract":"<div><div>Heavy trace elements (HTEs), including toxic metals such as lead (Pb), mercury (Hg), cadmium (Cd), and arsenic (As), present a growing environmental and public health concern due to their persistence and bioaccumulation in water and soil systems. Driven by increased demand for strategic and rare earth metals in emerging technologies, anthropogenic activities such as mining, industrial discharge, and agriculture have intensified environmental contamination. Traditional detection methods such as (<em>in situ</em> and online) applications. This review highlights recent advances in standard electrochemical techniques, particularly voltammetric ones such as square wave voltammetry (SWV), differential pulse voltammetry (DPV), and anodic stripping voltammetry (ASV), in addition to being non-voltammetric including electrochemical impedance spectroscopy (EIS) and chronopotentiometry methods enhanced by nanomaterials, including carbon nanomaterials: single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs); metal and metal oxide nanoparticles; polymer and hybrid nanocomposites; and metal organic frameworks (MOFs). These materials improve sensor sensitivity, selectivity, stability, and portability of standard electrochemical methods, making them ideal for real-time and <em>in situ</em> and online for HTEs. In this review article, current innovations in standard electrochemical techniques with nanomaterials and hybrid nanocomposites improving sensor architecture, functionalization, sensitivity and selectivity are discussed alongside performance metrics and limitations.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"54 ","pages":"Article 101749"},"PeriodicalIF":6.9,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Implantable electrochemical biosensors: Challenges, strategies, and applications 植入式电化学生物传感器：挑战、策略和应用

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-19 DOI: 10.1016/j.coelec.2025.101745

Sondes Ben-Aissa, Suryasnata Tripathy, Anthony Edward George Cass

引用次数: 0

Metallic nanoparticle-based glassy carbon electrodes for smart biosensing 用于智能生物传感的金属纳米颗粒基玻碳电极

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-16 DOI: 10.1016/j.coelec.2025.101748

Supratim Mahapatra, Daphika S. Dkhar, Ankur Singh, Pranjal Chandra

{"title":"Metallic nanoparticle-based glassy carbon electrodes for smart biosensing","authors":"Supratim Mahapatra, Daphika S. Dkhar, Ankur Singh, Pranjal Chandra","doi":"10.1016/j.coelec.2025.101748","DOIUrl":"10.1016/j.coelec.2025.101748","url":null,"abstract":"<div><div>Glassy carbon electrodes (GCEs) remain a cornerstone in electrochemical biosensing due to their conductivity, stability, and reliability for surface modifications. Incorporation of metallic nanoparticles (MNPs) onto GCEs has significantly improved biosensor performance, particularly in terms of sensitivity, selectivity, and signal transduction. Despite extensive applications using noble and transition metal nanostructures, a systematic understanding of how MNP characteristics such as morphology, composition, and deposition methods impact biosensing across enzymatic, immunological, and nucleic acid platforms remains underexplored. This review critically examines recent advances in MNP-GCE systems, emphasizing nanomaterial design, surface functionalization strategies, and incorporating emerging smart biosensing trends. It discusses the integration of artificial intelligence (AI), machine learning (ML), and Internet of Things (IoT) technologies for next-generation smart sensing applications. Key challenges such as reproducibility, real-sample compatibility, and commercial scalability are highlighted, along with future directions for advancing robust, intelligent biosensors for point-of-care and digital healthcare applications.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"54 ","pages":"Article 101748"},"PeriodicalIF":6.9,"publicationDate":"2025-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Confined electrochemistry in nanocavities: Perspective and techniques 纳米空腔中的受限电化学：观点与技术

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-14 DOI: 10.1016/j.coelec.2025.101747

Din Zelikovich , Pavel Savchenko , Daniel Mandler

引用次数: 0

Decoupling activity and selectivity in catalysis reactions with plasma electrochemical systems 等离子体电化学系统催化反应的去耦活性和选择性

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-13 DOI: 10.1016/j.coelec.2025.101746

Janiennid Alicea Tirado , Gina DelMonache , Shwetha Prakash, Pratahdeep Gogoi, Xiaoli Ge, Yuguang C. Li

{"title":"Decoupling activity and selectivity in catalysis reactions with plasma electrochemical systems","authors":"Janiennid Alicea Tirado , Gina DelMonache , Shwetha Prakash, Pratahdeep Gogoi, Xiaoli Ge, Yuguang C. Li","doi":"10.1016/j.coelec.2025.101746","DOIUrl":"10.1016/j.coelec.2025.101746","url":null,"abstract":"<div><div>Electrochemical systems are considered key technologies for integrating directly with renewable energy sources. However, the development and industrial adoption of certain electrochemical systems are hindered by low efficiencies and current densities, particularly for the activation of inert chemical bonds. Plasma-electrochemical systems have emerged as a transformative approach to overcoming these challenges by decoupling the requirement for bond activation and reaction selectivity. This hybrid configuration allows plasma to drive the activation of strong chemical bonds, while the electrochemical interface controls product formation. As a result, activity and selectivity can be optimized independently, offering a significant advantage over conventional approaches. Plasma-electrochemical systems have been successfully applied in ammonia synthesis, CO<sub>2</sub> reduction, methane activation, and environmental pollutant remediation. This review discusses recent advancements in plasma-electrochemical experimental setups and key chemical mechanisms involved in various catalytic conversions.</div></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"54 ","pages":"Article 101746"},"PeriodicalIF":6.9,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144921562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biomedical field applications of electrochemical biosensors as diagnostic tools: A short review 电化学生物传感器作为诊断工具在生物医学领域的应用：简要综述

IF 6.9 2区化学

Current Opinion in Electrochemistry Pub Date : 2025-08-05 DOI: 10.1016/j.coelec.2025.101738

Ahmet Cetinkaya , S. Irem Kaya , Sibel A. Ozkan

引用次数: 0