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Pore-scale modeling of multiphase reactive transport in porous media during geological carbon storage in saline aquifers: Mechanisms, progress, and challenges 盐碱层地质储碳过程中多孔介质多相反应输运的孔隙尺度建模:机制、进展和挑战
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-09-25 DOI: 10.1016/j.jgsce.2025.205784
Jinlei Wang , Yongfei Yang , Gloire Imani , Jie Liu , Huaisen Song , Hai Sun , Lei Zhang , Junjie Zhong , Kai Zhang , Jun Yao
{"title":"Pore-scale modeling of multiphase reactive transport in porous media during geological carbon storage in saline aquifers: Mechanisms, progress, and challenges","authors":"Jinlei Wang ,&nbsp;Yongfei Yang ,&nbsp;Gloire Imani ,&nbsp;Jie Liu ,&nbsp;Huaisen Song ,&nbsp;Hai Sun ,&nbsp;Lei Zhang ,&nbsp;Junjie Zhong ,&nbsp;Kai Zhang ,&nbsp;Jun Yao","doi":"10.1016/j.jgsce.2025.205784","DOIUrl":"10.1016/j.jgsce.2025.205784","url":null,"abstract":"<div><div>Geological carbon storage (GCS) represents a promising strategy for atmospheric CO<sub>2</sub> reduction and climate change mitigation, with deep saline aquifers standing out as suitable storage sites due to their wide distribution and large storage capacity. The intricate CO<sub>2</sub>-brine-rock interactions during GCS in saline aquifers encompass coupled multiphase flow dynamics, multi-component reactive transport, aqueous-phase homogeneous reactions, and fluid/mineral heterogeneous reactions processes. These processes underpin four primary trapping mechanisms: structural trapping, capillary trapping, dissolution trapping, and mineral trapping. Pore-scale modeling bridges the microscopic and macroscopic scales by providing detailed three-dimensional distributions of physical fields within pore spaces while capturing the evolution of porous media due to geochemical reactions. This comprehensive review not only examines the mechanisms and physicochemical processes underlying CO<sub>2</sub> trapping, but also discusses recent advancements in GCS research within saline aquifers from a pore-scale modeling perspective. Furthermore, challenges and future research directions are discussed. This review provides fundamental insights into multiphase reactive transport at pore scale, supporting the development of predictive models that can enhance the safety and efficiency of long-term CO<sub>2</sub> storage in deep saline aquifers.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205784"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145222253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comparative study on the occurrence and pore structure characteristics of CH4 and CO2 hydrates in sandy sediments using SEM-EDS technology 利用SEM-EDS技术对比研究砂质沉积物中CH4和CO2水合物赋存状态及孔隙结构特征
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-11-15 DOI: 10.1016/j.jgsce.2025.205803
Lujun Wang , Haochen Yang , Chuanqi Sun , Jianye Sun , Xiluo Hao , Chengfeng Li , Bin Zhu , Yunmin Chen
{"title":"A comparative study on the occurrence and pore structure characteristics of CH4 and CO2 hydrates in sandy sediments using SEM-EDS technology","authors":"Lujun Wang ,&nbsp;Haochen Yang ,&nbsp;Chuanqi Sun ,&nbsp;Jianye Sun ,&nbsp;Xiluo Hao ,&nbsp;Chengfeng Li ,&nbsp;Bin Zhu ,&nbsp;Yunmin Chen","doi":"10.1016/j.jgsce.2025.205803","DOIUrl":"10.1016/j.jgsce.2025.205803","url":null,"abstract":"<div><div>CH<sub>4</sub>-CO<sub>2</sub> replacement is a novel method that simultaneously enables CH<sub>4</sub> exploitation and CO<sub>2</sub> sequestration. The pore structure of sediments and the microscopic occurrence characteristics of CH<sub>4</sub> and CO<sub>2</sub> hydrates in sediments are key factors that influence the exploitation efficiency and reservoir stability of CH<sub>4</sub> hydrate. In this study, scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDS) was employed to conduct microscopic observations and elemental analysis of CH<sub>4</sub> and CO<sub>2</sub> hydrate-bearing sediments. A comparative analysis of their occurrence characteristics and pore structure was performed, and the formation mechanisms of the two hydrates in sediment pores were investigated. The results indicate significant differences in the occurrence patterns of CH<sub>4</sub> and CO<sub>2</sub> hydrates in sediments, which are probably related to the solubility in water of the two gases. CH<sub>4</sub> gas with lower solubility tends to form granular, pore-filling hydrates, while CO<sub>2</sub> gas with higher solubility tends to form flaky or massive cemented and load bearing hydrates. As hydrate saturation increases, the occurrence pattern of CH<sub>4</sub> hydrates shifts from pore-filling to patchy. In contrast, that of CO<sub>2</sub> hydrates transitions from cemented to load bearing and further to patchy. Hydrate saturation significantly affects the pore structure characteristics of sediments. With increasing hydrate saturation, large pores are gradually divided into medium, fine, and micropores, and the pore fractal dimension initially increases and then decreases. The evolution patterns of hydrate occurrence and sediment pore structure characteristics during CH<sub>4</sub>-CO<sub>2</sub> replacement are examined in this study, providing valuable insights into efficient hydrate exploitation and reservoir stability analysis.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205803"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145579304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting in-situ CO2 solubility in formation brines using Raman spectroscopy and machine learning: Implications for offshore geological carbon storage 利用拉曼光谱和机器学习预测地层盐水中CO2的原位溶解度:对海上地质碳储存的影响
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-10-09 DOI: 10.1016/j.jgsce.2025.205794
Ying Teng , Yiqi Chen , Xiran Lin , Mingkun Bai , Senyou An , Shuyang Liu , Pengfei Wang , Tao Zhang , Songbai Han , Jinlong Zhu , Jianbo Zhu , Heping Xie
{"title":"Predicting in-situ CO2 solubility in formation brines using Raman spectroscopy and machine learning: Implications for offshore geological carbon storage","authors":"Ying Teng ,&nbsp;Yiqi Chen ,&nbsp;Xiran Lin ,&nbsp;Mingkun Bai ,&nbsp;Senyou An ,&nbsp;Shuyang Liu ,&nbsp;Pengfei Wang ,&nbsp;Tao Zhang ,&nbsp;Songbai Han ,&nbsp;Jinlong Zhu ,&nbsp;Jianbo Zhu ,&nbsp;Heping Xie","doi":"10.1016/j.jgsce.2025.205794","DOIUrl":"10.1016/j.jgsce.2025.205794","url":null,"abstract":"<div><div>Accurate estimation of in-situ CO<sub>2</sub> solubility in brine is essential for predicting dissolution trapping efficiency and ensuring the long-term security of geological carbon storage, particularly in deep saline aquifers and offshore reservoirs. Existing experimental and thermodynamic approaches often suffer from limited applicability under high salinity, multi-ion conditions, and diverse reservoir environments, leading to substantial prediction uncertainties. To address this gap, we experimentally determined CO<sub>2</sub> solubility using Raman spectroscopy in both formation brines and synthetic brines under reservoir-relevant conditions (313.15–363.15 K, 7.5–17 MPa) and compiled a comprehensive dataset of 2733 literature entries covering wide salinity and ionic composition ranges. Six machine learning algorithms—LightGBM, XGBoost, CatBoost, SVR, ELM, and KNN—were trained and benchmarked, with LightGBM achieving the highest predictive accuracy. SHAP analysis revealed that pressure, total salinity, and temperature were the dominant factors governing solubility. Model applicability and reliability were confirmed through leverage statistics and Williams plots. Compared with a thermodynamic model, LightGBM delivered superior performance, especially under high-salinity conditions where conventional models often underpredict solubility. The resulting data-driven framework can be readily integrated into reservoir simulation workflows to enable rapid, accurate solubility predictions, optimize injection strategies, and enhance risk assessment for CCS projects in complex geological settings.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205794"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145269900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cyclic CO2/N2 injection enhances CO2 storage and CH4 recovery in anthracite by optimizing pore structure and competitive adsorption 循环注入CO2/N2通过优化孔隙结构和竞争吸附来提高无烟煤的CO2储存和CH4回收
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-09-14 DOI: 10.1016/j.jgsce.2025.205779
Yunzhong Jia , Jiaqi Yi , Xinyu Wang , Zhaolong Ge , Wenyu Fu , Yiyu Lu , Caiyun Xiao
{"title":"Cyclic CO2/N2 injection enhances CO2 storage and CH4 recovery in anthracite by optimizing pore structure and competitive adsorption","authors":"Yunzhong Jia ,&nbsp;Jiaqi Yi ,&nbsp;Xinyu Wang ,&nbsp;Zhaolong Ge ,&nbsp;Wenyu Fu ,&nbsp;Yiyu Lu ,&nbsp;Caiyun Xiao","doi":"10.1016/j.jgsce.2025.205779","DOIUrl":"10.1016/j.jgsce.2025.205779","url":null,"abstract":"<div><div>Synergistically optimizing coalbed methane recovery rate and CO<sub>2</sub> sequestration efficiency remains a core bottleneck in CO<sub>2</sub>/N<sub>2</sub>-ECBM engineering. The competitive adsorption mechanisms underlying the differential impacts of varying CO<sub>2</sub>/N<sub>2</sub> ratios on recovery and sequestration are key factors influencing ECBM project performance. Therefore, this study focuses on simulating competitive adsorption mechanisms driven by CO<sub>2</sub>/N<sub>2</sub> ratio variations in deep coal reservoir environments to elucidate their critical influence on ECBM efficiency. This study proposes synergistic injection of high-concentration CO<sub>2</sub> from industrial flue gas with associated N<sub>2</sub> into deep coal seams, leveraging N<sub>2</sub>-assisted CO<sub>2</sub> delivery through connected pores to improve total storage capacity, thereby realizing cost-effective CO<sub>2</sub> geological storage coupled with coalbed methane stimulation. Through breakthrough adsorption experiments, low-temperature liquid nitrogen adsorption, and nuclear magnetic resonance (NMR) techniques, we investigate the impacts of varying CO<sub>2</sub>/N<sub>2</sub> ratios and injection modes (constant pressure/cyclic) on the pore structure and adsorption characteristics of anthracite. Results demonstrate that cyclic injection mode enhances CO<sub>2</sub> adsorption capacity by 28.74 %–40.01 % compared to constant-pressure injection, with a strong positive correlation between micropore volume and adsorption capacity. Although increased N<sub>2</sub> proportion induces pore compression effects, cyclic pressure fluctuations significantly improve macropore porosity (5.67 % increase) and connectivity, facilitating gas diffusion. A three-stage competitive adsorption model is proposed: CO<sub>2</sub> preferentially occupies high-affinity sites, N<sub>2</sub> optimizes transport pathways through pore network expansion, ultimately forming a storage pattern dominated by micropore adsorption and macropore diffusion under dynamic equilibrium. Our results indicate that a 4:1 CO<sub>2</sub>/N<sub>2</sub> ratio combined with cyclic injection mode and enhanced meso-macropore porosity synergistically improves both storage efficiency and methane recovery, providing theoretical guidance for gas proportioning and process optimization in CO<sub>2</sub>/N<sub>2</sub>-ECBM projects.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205779"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145108868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of leakage characteristics and leakage point diameter prediction in supercritical CO2 pipeline 超临界CO2管道泄漏特性分析及泄漏点直径预测
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-09-16 DOI: 10.1016/j.jgsce.2025.205780
Zheyuan Liu , Jiming He , Kang Li , Shi Shen , Huiyong Liang , Xin Lv , Zaixing Liu
{"title":"Analysis of leakage characteristics and leakage point diameter prediction in supercritical CO2 pipeline","authors":"Zheyuan Liu ,&nbsp;Jiming He ,&nbsp;Kang Li ,&nbsp;Shi Shen ,&nbsp;Huiyong Liang ,&nbsp;Xin Lv ,&nbsp;Zaixing Liu","doi":"10.1016/j.jgsce.2025.205780","DOIUrl":"10.1016/j.jgsce.2025.205780","url":null,"abstract":"<div><div>This study systematically investigates supercritical CO<sub>2</sub> pipeline leakage dynamics using an integrated experimental platform. Real-time multi-sensor monitoring and high-speed photography reveal continuous phase transitions during leakage, with pressure and temperature exhibiting three distinct stages: stable phase, rapid decline phase, and slow stabilization phase. The Joule-Thomson effect dominates temperature variations, with cooling intensity scaling proportionally to flow velocity. The leakage orifice size significantly influences leakage dynamics: orifices lead to exponentially increasing pressure drops. A relationship between orifice diameter (D) and pressure drop (△P) is established. Jet development is categorized into three stages—slow growth, rapid expansion, and stabilization. Leakage orifice significantly affects jet outlet velocity; at an orifice of 1 mm, velocity changes from 6 m/s to 20 m/s in a short time, and larger orifices exacerbate this change. Variations in leakage orifice diameter exert a more pronounced influence on the jet expansion angle (<em>θ</em><sub><em>c</em></sub>). When the orifice diameter increases from 0.5 mm to 3 mm, <em>θ</em><sub><em>c</em></sub> rises from 16.365° to 40.965°. In contrast, the core contraction angle (<em>θ</em><sub><em>d</em></sub>) demonstrates higher sensitivity to pressure fluctuations: as pressure increases from 8.7 MPa to 9.31 MPa, <em>θ</em><sub><em>d</em></sub> increases from 4.844° to 8.615°. These findings provide critical data support for safety design, risk assessment, and emergency response strategies of supercritical CO<sub>2</sub> pipelines.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205780"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145108869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Capillary trapping in CO2 storage Sites: A traffic light system for preliminary leakage risk assessment 二氧化碳储存地点的毛细管捕获:初步泄漏风险评估的交通灯系统
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-11-19 DOI: 10.1016/j.jgsce.2025.205807
Mojtaba Ghaedi , Raoof Gholami , Spyros Bellas , Emmanuel Stamatakis
{"title":"Capillary trapping in CO2 storage Sites: A traffic light system for preliminary leakage risk assessment","authors":"Mojtaba Ghaedi ,&nbsp;Raoof Gholami ,&nbsp;Spyros Bellas ,&nbsp;Emmanuel Stamatakis","doi":"10.1016/j.jgsce.2025.205807","DOIUrl":"10.1016/j.jgsce.2025.205807","url":null,"abstract":"<div><div>Geological storage of CO<sub>2</sub> offers a promising solution to mitigate global warming. In this context, the structural trapping capacity of subsurface formations is crucial. This study investigates the CO<sub>2</sub> storage capacity of shale caprocks under static conditions by estimating the maximum safe column height of the CO<sub>2</sub> plume beneath them. A modified formulation was developed to incorporate capillary pressure contributions from the reservoir rock. Depth-dependent variations in CO<sub>2</sub>–water interfacial tension, wettability, and fluid density were calculated using experimental data and established correlations. Particular attention was given to the effect of total organic content (TOC) on the wettability of caprocks, as some organic-rich source rocks may serve as potential seals for CO<sub>2</sub> storage. Simple and practical equations were proposed to relate wettability to TOC and depth. The results indicate that the capillary pressure of the reservoir rock can often be neglected when estimating CO<sub>2</sub> column height, particularly when the ratio of the reservoir to caprock pore radius exceeds 50. However, neglecting these contributions can lead to overestimations in storage sites when reservoir rock is dense or the caprock is not strongly water-wet. For shale with low TOC (e.g., 0.1 wt%), the optimum storage depth at which the maximum mass of CO<sub>2</sub> can be stored is approximately 1500 m. However, as the TOC of the shale increases, the optimal storage depth and the corresponding mass of CO<sub>2</sub> that can be safely stored decrease significantly. A practical guideline and a traffic light system for preliminary assessment were then proposed to assess the risk of CO<sub>2</sub> capillary leakage. These risks are particularly significant when i) the lowest CO<sub>2</sub> injection point exceeds the safe column height, ii) the gravitational number is less than 0.5, iii) rocks with poor properties hinder horizontal plume propagation beneath the caprock, or iv) CO<sub>2</sub> leakage occurs from underlying formations.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205807"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145579303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Real-time prediction and inverse design of multiphase CO2 trapping in deep saline aquifers using machine learning enhanced by SHAP analysis 基于SHAP分析增强机器学习的深层盐水含水层多相CO2捕获实时预测与逆设计
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-09-18 DOI: 10.1016/j.jgsce.2025.205782
Shixuan Cheng , Kai Zhang , Yihao Li , Zhangxin Chen
{"title":"Real-time prediction and inverse design of multiphase CO2 trapping in deep saline aquifers using machine learning enhanced by SHAP analysis","authors":"Shixuan Cheng ,&nbsp;Kai Zhang ,&nbsp;Yihao Li ,&nbsp;Zhangxin Chen","doi":"10.1016/j.jgsce.2025.205782","DOIUrl":"10.1016/j.jgsce.2025.205782","url":null,"abstract":"<div><div>Accurate forecasting of multiphase CO<sub>2</sub> behavior is critical for safe large-scale deployment of carbon capture and storage projects. A total of 9835 high fidelity CMG GEM simulations, covering geological and operational uncertainties in deep saline aquifers, were generated and subsequently used to benchmark thirteen c algorithms for the concurrent prediction of CO<sub>2</sub> trapping mechanisms. Attention based tabular networks TabTransformerLite and SAINTLite together with the decision ensemble NODELite outperformed linear, support vector, tree ensemble, and fully connected neural network baselines. TabTransformerLite secured the best performance with nRMSE of 0.033, R<sup>2</sup> of 0.92, and minimal fold to fold variability. Shapley value analysis placed depth and permeability as primary controls on dissolved, residual, and mineral precipitated CO<sub>2</sub> compared to the injection rate and porosity. An inverse design workflow used the trained model to identify operating windows that lift mineral trapping above the ninetieth percentile, indicating optimal depth near 2.25 km, permeability above 1.6 Darcy, and injection rates between 7.5 and 14.7 × 10<sup>3</sup> m<sup>3</sup>/day. The resulting framework connects model predictions to geographic information systems for site screening and to real time digital twin optimization, providing a scalable millisecond speed alternative to physics-based simulation for CO<sub>2</sub> storage planning and monitoring.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205782"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145108864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of dynamic production characteristics and identification of segmentation nodes in decline models for deep coalbed methane using physics-informed neural networks 基于物理信息神经网络的深部煤层气产量动态特征分析及递减模型分割节点识别
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-10-04 DOI: 10.1016/j.jgsce.2025.205786
Danqun Wang , Jingtao Lai , Tiantian Zhang , Zhiping Li , Jianping Guo
{"title":"Analysis of dynamic production characteristics and identification of segmentation nodes in decline models for deep coalbed methane using physics-informed neural networks","authors":"Danqun Wang ,&nbsp;Jingtao Lai ,&nbsp;Tiantian Zhang ,&nbsp;Zhiping Li ,&nbsp;Jianping Guo","doi":"10.1016/j.jgsce.2025.205786","DOIUrl":"10.1016/j.jgsce.2025.205786","url":null,"abstract":"<div><div>Deep coalbed methane (CBM) offers clean, sustainable energy, but its low-carbon potential and resource value require enhanced production. Conventional data-driven models lack physical interpretability and often miss key reservoir dynamics. This study presents a physics-informed neural network (PINN) long short-term memory (LSTM) model that embeds decline-curve analysis (DCA) and the Langmuir adsorption–desorption equation as physical constraints. Production time-series from six Ordos Basin wells were used for training and validation. Hyperbolic, stretched-exponential production decline (SEPD), Duong, and Langmuir constraints were systematically evaluated and linked to production–extraction mechanisms. A time-varying coupling strategy divides the production cycle into segments, applying the optimal decline model in each stage. Compared to a standard LSTM, the PINN-LSTM delivers higher accuracy, robustness, and interpretability. Early-stage fluctuating wells gain from Langmuir regularization, while mid-to-late-life wells see improved precision under hyperbolic and Duong constraints. The coupling strategy reduces prediction error by 10 % and raises R<sup>2</sup> by 0.11. Temporal segmentation pinpoints transition nodes and captures operational fluctuations. These results guide intelligent CBM production control and future model enhancements.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205786"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145333695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of cracks caused by hydrogen damage in HSLA X70 in sour gas media using conventional and non-destructive techniques 采用常规和非破坏性技术分析HSLA X70在酸性气体介质中氢损伤引起的裂纹
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-09-27 DOI: 10.1016/j.jgsce.2025.205778
Janeth M. Quispe-Avilés , Roger Imata-Condori , Gonzalo Aurelio Mamani-Quiñones , Hugo Canahua-Loza , Elvis G. Gonzales-Condori , Edwan Anderson Ariza-Echeverri
{"title":"Analysis of cracks caused by hydrogen damage in HSLA X70 in sour gas media using conventional and non-destructive techniques","authors":"Janeth M. Quispe-Avilés ,&nbsp;Roger Imata-Condori ,&nbsp;Gonzalo Aurelio Mamani-Quiñones ,&nbsp;Hugo Canahua-Loza ,&nbsp;Elvis G. Gonzales-Condori ,&nbsp;Edwan Anderson Ariza-Echeverri","doi":"10.1016/j.jgsce.2025.205778","DOIUrl":"10.1016/j.jgsce.2025.205778","url":null,"abstract":"<div><div>High-strength low-alloy (HSLA) steels are widely used in the oil industry for manufacturing durable and efficient pipelines due to their exceptional mechanical properties, including high strength, toughness, ductility, and weldability. However, their long-term reliability in sour gas environments remains a critical concern, particularly due to their susceptibility to hydrogen-induced cracking (HIC), which can compromise pipeline integrity and lead to catastrophic failures. While advanced crack detection methods provide high-resolution analysis, they are costly, time-consuming, and require specialized equipment, limiting their application in large-scale pipeline monitoring and failure prevention. This study explores liquid penetrant inspection as a low-cost, non-destructive alternative for detecting HIC in HSLA X70 steel exposed to sour gas conditions (NACE TM0284). By integrating both conventional techniques (optical microscopy, scanning electron microscopy, electrochemical testing, and Brinell hardness measurements) and non-destructive methods, this research provides a comprehensive evaluation of crack initiation, propagation, and detection strategies. The findings demonstrate that corrosion was most severe under H<sub>2</sub>S-saturated conditions; however, oxygenated environments also induced a significant corrosion rate of a similar order of magnitude, underscoring its underestimated role in accelerating hydrogen damage. Furthermore, liquid penetrant inspection proved effective as a rapid, cost-efficient, and industrially viable technique for crack detection, offering a scalable solution for failure analysis and preventive maintenance in the oil and gas sector.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"145 ","pages":"Article 205778"},"PeriodicalIF":5.5,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145424808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of discontinuous fluid interfaces on pressure drops and relative permeabilities for gas-liquid two-phase flow in porous media 不连续流体界面对多孔介质中气液两相流压降和相对渗透率的影响
IF 5.5
Gas Science and Engineering Pub Date : 2026-01-01 Epub Date: 2025-10-29 DOI: 10.1016/j.jgsce.2025.205795
Jiafan Guo , Zhechao Wang , Liping Qiao , Hao Feng , Wei Li
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