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CO2 hydrate sequestration in unsealed submarine sediments: A 4D pore-scale experimental investigation 未密封海底沉积物中CO2水合物固存:4D孔隙尺度实验研究
Gas Science and Engineering Pub Date : 2025-07-16 DOI: 10.1016/j.jgsce.2025.205734
Yanfang Li , Tong Zhang , Liang Yuan , Ming Tang , Ruilong Li , Yongqiang Chen , Wen Luo , Chuanjiu Zhang
{"title":"CO2 hydrate sequestration in unsealed submarine sediments: A 4D pore-scale experimental investigation","authors":"Yanfang Li ,&nbsp;Tong Zhang ,&nbsp;Liang Yuan ,&nbsp;Ming Tang ,&nbsp;Ruilong Li ,&nbsp;Yongqiang Chen ,&nbsp;Wen Luo ,&nbsp;Chuanjiu Zhang","doi":"10.1016/j.jgsce.2025.205734","DOIUrl":"10.1016/j.jgsce.2025.205734","url":null,"abstract":"<div><div>CO<sub>2</sub> hydrate sequestration in marine sediments has been identified as a safe, large-scale, long-term carbon removal method. Influenced by the high pressure and low temperature, the dynamic formation of CO<sub>2</sub> hydrate has not been fully investigated. We thus design and construct a low-field nuclear magnetic resonance (LF-NMR) apparatus to investigate the <em>in-situ</em> dynamic process of CO<sub>2</sub> hydrate formation. The temporal-spatial evolution of CO<sub>2</sub> hydrate formation is analyzed to reveal the generation and distribution of CO<sub>2</sub> hydrate as a function of pressure and initial water saturation. The results reveal that CO<sub>2</sub> hydrate mainly forms in macropores, where water-to-hydrate conversion rate exceeds 81 %, while the conversion rate is below 27 % in micropores. The spatial distribution of CO<sub>2</sub> hydrate exhibits strong heterogeneity, and the hydrate formation preferentially occurs where the ratio of gas-water volume is 0.2–0.8. Increased injection pressure improved the heterogeneity, as evidenced by the increased heterogeneity index from 6.18 to 12.8. The increased injection pressure cannot enhance CO<sub>2</sub>-to-hydrate conversion at similar water saturation levels although improving the conversion rate of water-to-hydrate. Regardless of the initial water saturation, lower injection pressure has a higher CO<sub>2</sub>-to-hydrate conversion, approximately 95.2 % (3 MPa) and 86.5 % (4 MPa), respectively. This study advances the understanding of CO<sub>2</sub> hydrate formation dynamics and demonstrates that lower injection pressure is more favorable for hydrate-based marine CO<sub>2</sub> sequestration strategies.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205734"},"PeriodicalIF":0.0,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144672687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel fully coupled thermal-hydraulic-mechanical model for hydrogen storage in depleted gas reservoirs 枯竭气藏储氢的全耦合热-水力-力学模型
Gas Science and Engineering Pub Date : 2025-07-15 DOI: 10.1016/j.jgsce.2025.205733
Jing Fu , Keni Zhang , Hongjun Yin , Philip H. Winterfeld , Yu-Shu Wu
{"title":"A novel fully coupled thermal-hydraulic-mechanical model for hydrogen storage in depleted gas reservoirs","authors":"Jing Fu ,&nbsp;Keni Zhang ,&nbsp;Hongjun Yin ,&nbsp;Philip H. Winterfeld ,&nbsp;Yu-Shu Wu","doi":"10.1016/j.jgsce.2025.205733","DOIUrl":"10.1016/j.jgsce.2025.205733","url":null,"abstract":"<div><div>Underground hydrogen storage (UHS) in depleted gas reservoirs provides a scalable solution for addressing energy supply-demand imbalances across short- and long-term operational horizons. Reliable prediction of hydrogen storage performance in depleted gas reservoirs requires accurate representation of coupled thermal, hydraulic, and mechanical processes. In this study, we introduce a new, fully coupled THM simulation capability for UHS by directly modifying the source code of the TOUGH2-CSM simulator. TOUGH2-CSM was originally designed for modeling CO<sub>2</sub> sequestration in saline aquifers and lacked support for hydrogen-specific thermophysical behavior. We extend its functionality through the development and integration of a new equation-of-state (EOS) module for multicomponent hydrogen storage systems, enabling modeling of multicomponent mixtures in multiphase, non-isothermal flow conditions. The geomechanical coupling distinguishes it from hydrogen-enabled TOUGH family EOS modules, which does not account for stress-strain interactions, addressing a critical gap and enhancing its relevance for practical UHS applications.</div><div>Model validation was performed using thermophysical property data from the National Institute of Standards and Technology (NIST), ensuring accurate prediction of gas behavior across a wide range of pressure-temperature conditions. The model achieves an average deviation of less than 5 % in thermophysical property predictions compared to NIST reference values. Experimental datasets further confirm its accuracy, with simulation results aligning within 5 % of measured data. Benchmark tests with existing simulator ensured consistency in pure hydrogen storage. Geomechanical consistency is validated via analytical verification against Terzaghi's one-dimensional consolidation theory, with an error of less than 1 %, confirming proper coupling of fluid flow and stress evolution. Additionally, the model's applicability is illustrated through a preliminary application case study of hydrogen storage in a depleted gas field, highlighting its potential for real-world implementation.</div><div>Future work will focus on applying the developed model to real field scenarios for the design of injection and production strategies. The framework will also be extended to incorporate chemical reactions relevant to underground hydrogen storage.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205733"},"PeriodicalIF":0.0,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144653853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Proxy model-driven optimization of CO2 operating condition and hydraulic fracturing design for maximizing EGR-CCS performance in the Duvernay shale formation, Canada 代理模型驱动的CO2工况优化和水力压裂设计,以最大限度地提高加拿大Duvernay页岩地层EGR-CCS性能
Gas Science and Engineering Pub Date : 2025-07-14 DOI: 10.1016/j.jgsce.2025.205731
Inwook Baek , Le Viet Nguyen , Namhwa Kim , Hyundon Shin , Thotsaphon Chaianansutcharit
{"title":"Proxy model-driven optimization of CO2 operating condition and hydraulic fracturing design for maximizing EGR-CCS performance in the Duvernay shale formation, Canada","authors":"Inwook Baek ,&nbsp;Le Viet Nguyen ,&nbsp;Namhwa Kim ,&nbsp;Hyundon Shin ,&nbsp;Thotsaphon Chaianansutcharit","doi":"10.1016/j.jgsce.2025.205731","DOIUrl":"10.1016/j.jgsce.2025.205731","url":null,"abstract":"<div><div>Shale gas is a prominent unconventional resource because of the advances in horizontal drilling and hydraulic fracturing, especially in North America. Shale gas reservoirs have also been considered for carbon capture and storage (CCS) to help mitigate CO<sub>2</sub> emissions and allow additional gas production. Enhanced gas recovery with CCS (EGR-CCS) injects CO<sub>2</sub> to displace methane (CH<sub>4</sub>), leveraging the higher adsorption capacity of CO<sub>2</sub> in shale. On the other hand, cumulative CH<sub>4</sub> production and CO<sub>2</sub> stored amount depend heavily on the timing of the injection, while economic factors such as natural gas prices and CO<sub>2</sub> tax credits also play a role—often overlooked in previous studies. This study developed a machine learning-based proxy model to predict the net present value (NPV) of an EGR-CCS project by integrating the CO<sub>2</sub> operating conditions, hydraulic fracturing designs, and economic factors. Based on data from the Duvernay shale reservoir, 200 scenarios were simulated to generate a training dataset. Five regression algorithms were tested. Of these five, extreme gradient boosting (XGB) yielded the highest accuracy, predicting CO<sub>2</sub> stored amount, cumulative CH<sub>4</sub> production, and NPV with R<sup>2</sup> &gt; 0.9. A complete factorial design was then implemented to optimize the EGR-CCS process under varying economic conditions. This comprehensive framework aids decision-making to maximize the economics of EGR-CCS, highlighting the potential of the Duvernay shale formation as a geological carbon storage target.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205731"},"PeriodicalIF":0.0,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144632105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of synergy between extended oil recovery and hydrogen storage in a producing field using the Norne reservoir model 利用Norne储层模型研究生产油田提高采收率与储氢之间的协同作用
Gas Science and Engineering Pub Date : 2025-07-14 DOI: 10.1016/j.jgsce.2025.205729
Behzad Amiri , Pål Østebø Andersen , Mojtaba Ghaedi , Xiaodong Luo
{"title":"Investigation of synergy between extended oil recovery and hydrogen storage in a producing field using the Norne reservoir model","authors":"Behzad Amiri ,&nbsp;Pål Østebø Andersen ,&nbsp;Mojtaba Ghaedi ,&nbsp;Xiaodong Luo","doi":"10.1016/j.jgsce.2025.205729","DOIUrl":"10.1016/j.jgsce.2025.205729","url":null,"abstract":"<div><div>This research investigates the feasibility and effectiveness of combining Underground Hydrogen Storage (UHS) with enhanced oil recovery (EOR) and carbon dioxide (CO<sub>2</sub>) sequestration in an active oil reservoir, utilizing the Norne field as a case study.</div><div>CO<sub>2</sub>-water-alternating-gas (CO<sub>2</sub>-WAG), continuous gas (CO<sub>2</sub>) and water flooding (CGWF), and water flooding (WF) are utilized for oil extraction. UHS is executed in six scenarios: three during oil extraction and three post-depletions. The UHS efficiency, oil recovery, and H<sub>2</sub> recovery efficiency in the two UHS systems are first examined by employing an EOR well converted into a UHS well. Subsequent examination of UHS during oil production utilizing CO<sub>2</sub>-WAG investigates the impacts of elevated UHS well rates, well positioning, prior well applications, and the use of smart wells to limit H<sub>2</sub> breakthrough.</div><div>The low rate UHS cases with H<sub>2</sub> constraint did not adversely impact oil recovery. CO<sub>2</sub>-WAG had the highest efficacy in EOR and could store around 60 % of the injected CO<sub>2</sub>, and resulted in the maximum efficiency for UHS during oil production, as CO<sub>2</sub> reduced H<sub>2</sub> dissolution in oil and residual trapping. Conversely, the WF method yielded the highest H<sub>2</sub> recovery for storing H<sub>2</sub> in the depleted reservoir, owing to a lower pressure near the H<sub>2</sub> well and higher pressure in distant areas compared to the two other cases. Additionally, 22 % of H<sub>2</sub> was produced by the oil wells. Smart oil wells, constraining H<sub>2</sub> production, improved UHS well H<sub>2</sub> recovery from 73.6 % to 80.2 %. The efficiency of oil recovery and UHS is contingent upon the interplay of well location and H<sub>2</sub> injection and production rate. Implementing UHS during oil production with CO<sub>2</sub>-WAG could boost oil recovery, UHS, and CO<sub>2</sub> sequestration. The optimization of H<sub>2</sub> injection and production rates, H<sub>2</sub> well placement, and cushion gas volume is essential, alongside proper monitoring of the oil production stream.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205729"},"PeriodicalIF":0.0,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144662580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CO2-enhanced methane recovery in deep coalbeds: Displacement and diffusion/pressure-driven behaviors 深层煤层气co2增强甲烷采收率:驱替和扩散/压力驱动行为
Gas Science and Engineering Pub Date : 2025-07-14 DOI: 10.1016/j.jgsce.2025.205730
Yaning Liu , Xiaoxiao Sun , Yanbin Yao , Dameng Liu , Yongkai Qiu
{"title":"CO2-enhanced methane recovery in deep coalbeds: Displacement and diffusion/pressure-driven behaviors","authors":"Yaning Liu ,&nbsp;Xiaoxiao Sun ,&nbsp;Yanbin Yao ,&nbsp;Dameng Liu ,&nbsp;Yongkai Qiu","doi":"10.1016/j.jgsce.2025.205730","DOIUrl":"10.1016/j.jgsce.2025.205730","url":null,"abstract":"<div><div>With the development and production breakthrough of deep coalbed methane (CBM), research on CO<sub>2</sub> enhanced methane (CO<sub>2</sub>-ECBM) under high temperature and pressure in deep coal seams is gaining increasing attention. In this study, molecular dynamic simulation (MD) are employed to investigate the occurrence of methane and CO<sub>2</sub> in pores of various sizes of deep coal bed, considering both adsorption and pore-bound states. Furthermore, CO<sub>2</sub>-ECBM CH<sub>4</sub> is simulated, with three distinct mechanisms-displacement, diffusion-driven displacement, and pressure-driven displacement-analyzed at different burial depths. The results show that, the adsorption density of CH<sub>4</sub> increases and then stabilizes with burial depth, while the adsorption density of CO<sub>2</sub> first increases and then slightly decreases. The self-diffusion of methane decreases and eventually stabilizes, while the self-diffusion coefficient of CO<sub>2</sub> initially decreases and then increases. The turning depth for both processes is at 1200 m. The displacement of methane by CO<sub>2</sub> increases with CO<sub>2</sub> pressure and decreases with smaller pore sizes. For CO<sub>2</sub> diffusion-driven methane displacement, elevated temperatures promote CO<sub>2</sub> diffusion, enhancing CO<sub>2</sub>-ECBM below 1200 m. The greater the injected CO<sub>2</sub> pressure, the stronger the pressure-driven displacement. However, in small pores, the displacement process is less sensitive to pressure differences. Therefore, in deep coal seams, high temperatures favor CO<sub>2</sub>-ECBM, meanwhile, coal beds with well-developed micropores are not conducive to CO<sub>2</sub>-ECBM.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205730"},"PeriodicalIF":0.0,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144653851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A unified volume translation model in SRK EOS for dry gas constituents SRK EOS中干气组分的统一体积平移模型
Gas Science and Engineering Pub Date : 2025-07-14 DOI: 10.1016/j.jgsce.2025.205732
Changxu Wu , Jialin Shi , Huazhou Li
{"title":"A unified volume translation model in SRK EOS for dry gas constituents","authors":"Changxu Wu ,&nbsp;Jialin Shi ,&nbsp;Huazhou Li","doi":"10.1016/j.jgsce.2025.205732","DOIUrl":"10.1016/j.jgsce.2025.205732","url":null,"abstract":"<div><div>Dry gas, mainly made of light hydrocarbons (such as methane and ethane), is an important type of natural gases. The PVT properties of dry gas constituents (e.g., compressibility factor) play an important role in the various stages of dry gas recovery. In this study, we develop an improved distance-function-based volume translation model in Soave-Redlich-Kwong equation of state (SRK EOS) for dry gas constituents (including carbon dioxide, nitrogen, methane, ethane, propane, n-butane, isobutane, n-pentane, isopentane, and neopentane). This model not only accurately replicates the critical compressibility factor for a specific dry gas component but also maintains strong performance across a broad range of pressures and temperatures (i.e., pressure range: from triple-point pressure to 300 MPa; temperature range: from triple-point temperature to 600 K). For the 10 dry gas constituents considered in this study, the new volume-translated SRK EOS yields an %AAD of 1.27 in reproducing saturation pressure, while it yields %AADs of 0.73, 0.38, 0.69, 1.72, and 1.55 in reproducing the liquid-phase, vapor-phase, saturated-liquid-phase, saturated-vapor-phase, and supercritical-phase compressibility factors, respectively. Moreover, the new volume-translated rescaled SRK EOS (VTR-SRK EOS) does not lead to crossover of pressure-volume isotherms within the tested pressure/temperature ranges.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205732"},"PeriodicalIF":0.0,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144653852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geophysical monitoring technology and simulation in CO2 geological storage: A comprehensive review 二氧化碳地质封存的地球物理监测技术与模拟研究综述
Gas Science and Engineering Pub Date : 2025-07-10 DOI: 10.1016/j.jgsce.2025.205725
Wenke Tang , Wuqin Li , Zitian Lin , Jun Zhu , Siyao Zhou , Yangmin Kuang , Yanpeng Zheng
{"title":"Geophysical monitoring technology and simulation in CO2 geological storage: A comprehensive review","authors":"Wenke Tang ,&nbsp;Wuqin Li ,&nbsp;Zitian Lin ,&nbsp;Jun Zhu ,&nbsp;Siyao Zhou ,&nbsp;Yangmin Kuang ,&nbsp;Yanpeng Zheng","doi":"10.1016/j.jgsce.2025.205725","DOIUrl":"10.1016/j.jgsce.2025.205725","url":null,"abstract":"<div><div>Carbon capture, utilization, and storage (CCUS) is a promising method for carbon emission reduction, but safe and efficient storage remains challenging. Geophysical methods can monitor CO<sub>2</sub> storage, yet face issues like technical obstacles, data complexity, environmental impact and cost. This review summarizes CCUS projects, geophysical principles, forward and inverse methods. It is proposed to construct an integrated carbon storage monitoring network based on seismic, electromagnetic, and gravimetric monitoring. Additionally, by establishing an optical fiber data transmission platform and leveraging artificial intelligence, data collection efficiency and algorithm accuracy can be improved, thereby optimizing the overall monitoring system.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205725"},"PeriodicalIF":0.0,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144679264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impacts of permeability heterogeneities on foam flow in porous media: Uncertainty quantification and sensitivity analysis 渗透率非均质性对多孔介质泡沫流动的影响:不确定度量化和敏感性分析
Gas Science and Engineering Pub Date : 2025-07-04 DOI: 10.1016/j.jgsce.2025.205710
Berilo de Oliveira Santos , Rodrigo Weber dos Santos , Iury Igreja , Grigori Chapiro , Bernardo Martins Rocha
{"title":"Impacts of permeability heterogeneities on foam flow in porous media: Uncertainty quantification and sensitivity analysis","authors":"Berilo de Oliveira Santos ,&nbsp;Rodrigo Weber dos Santos ,&nbsp;Iury Igreja ,&nbsp;Grigori Chapiro ,&nbsp;Bernardo Martins Rocha","doi":"10.1016/j.jgsce.2025.205710","DOIUrl":"10.1016/j.jgsce.2025.205710","url":null,"abstract":"<div><div>Foam injection in porous media has been extensively studied for its ability to improve sweep efficiency by mitigating nonlinear phenomena such as gravitational segregation and viscous fingering. However, modeling foam flow remains a significant challenge, mainly due to the complex interactions between foam and heterogeneous geological formations, which are often difficult to characterize. In particular, the spatial distribution of absolute permeability is difficult to obtain, due to scarce data and strong heterogeneity. These challenges introduce uncertainties into predictive models. In particular, the relationship between foam flow and uncertainties related to absolute permeability fields remains underexplored in the literature. This work performs uncertainty propagation studies to investigate the influence of permeability heterogeneity on foam flow in porous media. This is achieved by coupling the Karhunen-Loève expansion (KLE), which generates Gaussian random permeability fields, with Polynomial Chaos Expansion (PCE), a method for propagating uncertainties in a computationally efficient manner. This approach allows for the evaluation of permeability variations impact on key quantities of interest (QoIs) related to flow performance. The results, derived from uncertainty quantification (UQ) and sensitivity analysis (SA), reveal that foam behavior is highly sensitive to the spatial correlation structures of permeability, with important implications for optimizing foam flow processes. The integration of KLE and PCE provides the first systematic framework for uncertainty propagation in foam flow analysis, unveiling previously unexplored correlations and behaviors. These findings highlight the importance of incorporating permeability uncertainties into modeling to improve the reliability and efficiency of both subsurface flow applications, including resource recovery and carbon sequestration efforts. The proposed methodology can be particularly beneficial in practical scenarios such as enhanced oil recovery or CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> sequestration, where foam is used to improve mobility control in complex formations.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"142 ","pages":"Article 205710"},"PeriodicalIF":0.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic characterize of interface and mass transfer of CO2-brine during CO2 storage in saline aquifer 含盐含水层CO2-卤水储集界面及传质动力学特征
Gas Science and Engineering Pub Date : 2025-07-03 DOI: 10.1016/j.jgsce.2025.205717
Shaohua Li , Xin Wang , Lanlan Jiang , Lei Wang , Yi Zhang , Bohao Wu , Yongchen Song
{"title":"Dynamic characterize of interface and mass transfer of CO2-brine during CO2 storage in saline aquifer","authors":"Shaohua Li ,&nbsp;Xin Wang ,&nbsp;Lanlan Jiang ,&nbsp;Lei Wang ,&nbsp;Yi Zhang ,&nbsp;Bohao Wu ,&nbsp;Yongchen Song","doi":"10.1016/j.jgsce.2025.205717","DOIUrl":"10.1016/j.jgsce.2025.205717","url":null,"abstract":"<div><div>Understanding the mass transfer characteristics between CO<sub>2</sub> and brine is essential for advancing CO<sub>2</sub> saline aquifer storage technology. The study visualizes supercritical CO<sub>2</sub> (scCO<sub>2</sub>) dissolution into brine in porous media under high temperature and pressure by using micro-computed tomography. The dynamic evolution of interphase interface of CO<sub>2</sub>-brine was innovatively investigated in three dimensions and quantified over time. The conclusions showed that the residual saturation of CO<sub>2</sub> was negatively correlated with the flow rate. Five distinct forms of CO<sub>2</sub> cluster evolution were identified, resulting in the non-uniform spatial distribution of the CO<sub>2</sub>-brine interface. Then a novel classification of four interface types between CO<sub>2</sub> and brine was proposed and it exhibits non-monotonic evolution due to the combined effects of pore filling and snap-off events. Both local and spatial mass transfer coefficients (MTC) were calculated based on the quantified interfacial area, showing strong heterogeneity along porous media. Additionally, the local MTC of scCO<sub>2</sub> was found to be from 10<sup>−10</sup> to 10<sup>−6</sup> m/s, with a broader range of magnitudes compared to its gaseous state (10<sup>−9</sup> to 10<sup>−8</sup> m/s). Finally, the mass transfer model for trapped-phase dissolution in porous media is extended on the basis of the Sherwood number, Reynolds number and Schmidt number. Understanding the evolution of these interfaces and models of dissolution mass transfer of trapped phase can aid in predicting CO<sub>2</sub> behavior in saline aquifers, optimizing storage strategies, and ensuring CO<sub>2</sub> dissolution trapping and long-term storage stability.</div></div>","PeriodicalId":100568,"journal":{"name":"Gas Science and Engineering","volume":"143 ","pages":"Article 205717"},"PeriodicalIF":0.0,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144587709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Date palm leaves-derived activated carbon as a sustainable support for catalytic methane dry reforming 枣椰叶衍生活性炭作为催化甲烷干重整的可持续支持物
Gas Science and Engineering Pub Date : 2025-07-01 DOI: 10.1016/j.jgsce.2025.205716
Nada Abounahia , Alessandro Sinopoli , Yongfeng Tong , Abdulaziz Al-Emadi , Ahmed Abotaleb
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