Carbon Neutralization最新文献

{"title":"Template-Free Synthesis of Carbon Matrix-Confined MoO2 Yolk–Shell Microspheres as Anode Materials for High-Performance Lithium Storage","authors":"Zihua Li,&nbsp;Yao Lu,&nbsp;Mengmeng Liu,&nbsp;Di Xiao,&nbsp;Kehua Dai,&nbsp;Jiangtao Xu,&nbsp;Guangfu Liao,&nbsp;Chunju Li","doi":"10.1002/cnl2.70013","DOIUrl":"https://doi.org/10.1002/cnl2.70013","url":null,"abstract":"<p>Molybdenum dioxide (MoO₂) is a hopeful anode material for high-performing lithium-ion batteries (LIBs), but the practical application is still impeded due to its huge volume variation and degraded capacity upon the cycling process. Herein, we present a reasonable design and synthesis of amorphous carbon matrix-confined MoO₂ yolk–shell microspheres (MoO₂/C-YSMs) by a simple solvothermal strategy and in situ carbonizing process. This unique carbon-restrained yolk–shell architecture can not only shorten Li⁺ ion/electron transfer pathways, but also relieve the large volume change of anode materials and further improve battery performance. Profit from steady yolk–shell structure and conductive carbon matrix, the obtained MoO₂/C-YSMs electrode demonstrates a high reversible specific capacity of 1034 mA h g^–1 at 100 mA g⁻¹ and 504 mA h g⁻¹ at 2000 mA g⁻¹ with good rate capability and long cycle performance. The study demonstrates a facile, feasible, and low-cost method to prepare high-performing electrodes via structural design, which reveals the potential of MoO₂/C-YSMs for using high-performance anode material for LIBs.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interphase Synergy Achieving Stable Cycling Performance for Aqueous Zn-MnO2 Battery","authors":"Dai-Huo Liu,&nbsp;Chunyan Xu,&nbsp;Fang Xu,&nbsp;Yaozhi Liu,&nbsp;Ao Wang,&nbsp;Cheng Yun,&nbsp;Mengqin Song,&nbsp;Jialin Zheng,&nbsp;Liang Wang","doi":"10.1002/cnl2.70014","DOIUrl":"https://doi.org/10.1002/cnl2.70014","url":null,"abstract":"<p>The lattice distortion resulting from the Jahn–Teller effect (JTE) at the Mn redox center typically induces irreversible phase transitions and structural degradation, which in turn diminishes the reversible capacity and long-term cycling performance. Here, N-doped carbon quantum dots (N-CDs) grafted to the surface of 3 × 3 tunnel todorokite-type MnO₂ (TMO) nanosheet (abbreviated to TMO@N-CDs) are designed. The adsorption of N-CDs promoted the charge transfer and redistribution between Mn and O and promoted the closer electron cloud overlap between Mn and O, thus enhancing the bonding strength of Mn–O bonds, stabilizing the lattice structure, inhibiting JTE, and realizing reversible H⁺/Zn²⁺ storage. Meanwhile, a significant amount of N-CDs can increase active sites of TMO nanosheet, enhance the binding ability with metal ions, and accelerate the ion diffusion kinetics, thus realizing stable electrochemical performances. The density functional theory (DFT) calculation shows that there is obvious orbital overlap between Mn and O in [MnO6] octahedron, which further quantifies the strong interaction between Mn and O through interphase synergy between N-CDs and TMO. The reversible (de)insertion behavior dominated by H⁺ during charging and discharging was proved by operando XRD and ex-situ SEM. As expected, the obtained TMO@N-CDs cathode exhibits remarkable electrochemical properties in terms of high reversible capacity, good rate performance, and satisfactory cycling stability (after 1000 cycles, the specific capacity remains 96.02%).</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70014","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress of LiMnyFe1−yPO4 Cathode Materials: From Mechanisms, Defects, Modification Methods to Applications","authors":"Hui Li,&nbsp;Xinli Xiao,&nbsp;Jiliang Wu,&nbsp;Xianyong Wu,&nbsp;Rong Chen,&nbsp;Yuliang Cao,&nbsp;Xinping Ai,&nbsp;Zhongxue Chen","doi":"10.1002/cnl2.70009","DOIUrl":"https://doi.org/10.1002/cnl2.70009","url":null,"abstract":"<p>Cathode materials play a vital role in determining the electrochemical performance of a lithium-ion battery. They have a direct impact on the energy density, cycle life, rate performance, and safety of the battery. LiMn_<i>y</i>Fe_1−<i>y</i>PO₄ (0 &lt; <i>y</i> &lt; 1, LMFP) inherits the advantages of high safety and low cost of LiFePO₄ (LFP) materials and also makes up for the shortcomings of the low energy density of LFP materials to a certain extent. It is considered to be a promising cathode material. However, LMFP exhibits extremely low ionic and electronic conductivity. Due to the Jahn–Teller effect, high Mn content will cause serious Mn dissolution and other problems, which seriously hinder the large-scale application of LMFP. This paper provides a comprehensive review of the structural characteristics, reaction mechanisms, and methods to enhance the electrical conductivity of LMFP cathode materials. It primarily focuses on the effects of particle size optimization, morphology control, surface coating, ion doping, and mixing with other layered cathode materials to improve the electrical conductivity of LMFP and their underlying mechanisms. These modification methods can improve the electron/ion transmission path between material particles and the conductivity of LMFP to a certain extent. However, these methods alone make it difficult to solve the problem of poor conductivity of LMFP cathode materials. To further improve the comprehensive electrochemical performance of LMFP materials, this paper provides a summary of the current research progress and presents future research ideas and development directions for LMFP. The strategy of combined modification by heteroatom-doped carbon material coating, short <i>b</i>-axis, morphology control, and ion doping is proposed, and the main development direction and research ideas of LMFP in the future are pointed out.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143879844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ten-Electron Count Rule of MXene-Supported Single-Atom Catalysts for Sulfur Reduction in Lithium–Sulfur Batteries","authors":"Lujie Jin,&nbsp;Yujin Ji,&nbsp;Youyong Li","doi":"10.1002/cnl2.70011","DOIUrl":"https://doi.org/10.1002/cnl2.70011","url":null,"abstract":"<p>Lithium–sulfur (Li–S) batteries are proposed as next-generation energy storage devices due to their high theoretical capacity and specific energy. However, the actual capacity utilization is greatly limited by the poor reactivity of the sulfur reduction reaction (SRR), which motivates us to develop corresponding high-efficient catalysts. Inspired by the application of MXene and single-atom catalysts (SACs) in improving SRR, a virtual screening on the MXene-supported SACs from the imp2d database is carried out. Finally, six kinds of top catalysts are identified for SRR, and most of them can be considered as variants of the previous representative SRR catalysts, which reflects the rationality of our screening. Meanwhile, the stability and reactivity metrics of the SACs are calculated by density functional theory (DFT) and show obvious trends depending on the type of adatom/MXene. For the critical intermediate binding that can tune SRR activity, further electronic structure analysis reveals the so-called 10-electron count rule, whose decisive role is also reflected by the Shapley value analysis from machine learning (ML). It is noteworthy that this count rule was used to analyze the SACs for hydrogen/carbon/nitrogen-related reactions before, and our successful attempt to optimize SRR further indicates its universality in catalysis fields. Overall, the 10-electron count rule not only rationalizes the nature of SAC–adsorbate interactions but also provides intuitive design guidance for novel SRR catalysts.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70011","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143836343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tuning the Electronic Structure of Niobium Oxyphosphate/Reduced Graphene Oxide Composites by Vanadium-Doping for High-Performance Na+ Storage Application","authors":"Zhongteng Chen,&nbsp;Tao Tao,&nbsp;Chenglong Shi,&nbsp;Xiaoyan Shi,&nbsp;Lianyi Shao,&nbsp;Junling Xu,&nbsp;Zhipeng Sun","doi":"10.1002/cnl2.70010","DOIUrl":"https://doi.org/10.1002/cnl2.70010","url":null,"abstract":"<p>Sodium-ion batteries have become a significant research focus in academia. As a novel sodium anode material, layered NbOPO₄, consisting of octahedral NbO₆ units sharing oxygen atoms with tetrahedral PO₄ units, exhibits stability due to strong phosphorus-oxygen covalent bonds that prevent oxygen loss from the framework. However, its inherently low electrical conductivity and sluggish charge transfer kinetics limit its electrochemical performance. To address these challenges, we designed and synthesized vanadium-doped niobium oxyphosphate coated with reduced graphene oxide (V-NbOPO₄@rGO) via a microwave hydrothermal method followed by calcination. Vanadium doping effectively modulated the electronic structure of NbOPO₄ and significantly enhanced its conductivity, as corroborated by density functional theory (DFT) calculations. Consequently, the V_0.15-NbOPO₄@rGO electrode demonstrated exceptional rate capability, achieving 418 mAh g⁻¹ at a low current density of 0.1 A g⁻¹ and maintaining a reversible capacity exceeding 100 mAh g⁻¹ even at an ultrahigh current density of 50 A g⁻¹. Furthermore, the reversible sodium storage mechanism of V_0.15-NbOPO₄@rGO was validated through in-situ XRD, TEM, and XPS analyses. This study provides an effective strategy for improving the electrochemical performance of NbOPO₄based anodes and deepens understanding of the sodium storage mechanism in V-doped NbOPO₄, emphasizing its potential for practical application in sodium-ion batteries.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143827008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"MnO2 Nanoflower Intercalation on Ti3C2Tx MXene With Expanded Interlayer Spacing for Flexible Asymmetric Supercapacitors","authors":"Yi Zhang,&nbsp;Can Tang,&nbsp;Shun Lu,&nbsp;Yi Zeng,&nbsp;Qingsong Hua,&nbsp;Yongxing Zhang","doi":"10.1002/cnl2.70006","DOIUrl":"https://doi.org/10.1002/cnl2.70006","url":null,"abstract":"<p>Supercapacitors are promising energy storage solutions known for their high-power density, fast charge–discharge rates, and long cycle life. Recently, Ti₃C₂T_x MXene, a member of the 2D MXene family, has emerged as a potential electrode material for supercapacitors. However, its limited interlayer spacing hinders broader applications. In this study, we introduce a novel δ-MnO₂@MXene heterostructure with expanded interlayer spacing, synthesized using a hydrothermal approach. This design enhances charge transfer efficiency and improves the contact between the components, significantly boosting supercapacitor performance. The unique nanoflower-like structure of δ-MnO₂ combined with MXene substantially improves capacitance retention and ion diffusion, surpassing the performance of each individual material. The sponge-like architecture of δ-MnO₂ increases accessible charge storage sites and widens the interlayer gaps in MXene, facilitating better ion migration. As a result, the δ-MnO₂@MXene electrode exhibits a capacitance 54 times greater than MXene alone (2.0 F g⁻¹), an impressive rate capability of 67.3% (after a 20-fold increase in current density), and exceptional cycling stability, maintaining 93% of its capacity after 10,000 cycles. This novel δ-MnO₂@MXene heterostructure significantly enhances electrochemical performance, making it a promising candidate for advanced energy storage applications.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Front Cover: Carbon Neutralization, Volume 4, Issue 3, May 2025","authors":"","doi":"10.1002/cnl2.70012","DOIUrl":"https://doi.org/10.1002/cnl2.70012","url":null,"abstract":"<p><b>Front cover image:</b> Single-crystal high-nickel (SC-HN) cathodes are promising for next-generation lithium-ion batteries, but suffer from air instability that leads to unique storage degradation pathways compared to their polycrystalline counterparts. This study presents a comprehensive, six-month multi-dimensional analysis tracking the evolution of structural and chemical changes. The results uncover a non-linear degradation of surface structure and composition, with surface reconstruction identified as the primary driver of performance loss. These insights advance the fundamental understanding of SC-HN air instability and offer a foundation for developing targeted strategies to improve storage stability.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70012","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling Long-Term Storage Failure Mechanisms of Single-Crystal High-Nickel Cathodes During Air Exposure","authors":"Ran An,&nbsp;Yuefeng Su,&nbsp;Yihong Wang,&nbsp;Yongjian Li,&nbsp;Enhua Dong,&nbsp;Jinglin Zhao,&nbsp;Pengfei Yan,&nbsp;Qing Huang,&nbsp;Meng Wang,&nbsp;Lai Chen,&nbsp;Feng Wu,&nbsp;Ning Li","doi":"10.1002/cnl2.70008","DOIUrl":"https://doi.org/10.1002/cnl2.70008","url":null,"abstract":"<p>Single-crystal high-nickel cathode (SC-HN) materials are promising candidates for advanced lithium-ion batteries due to their exceptional volumetric and gravimetric energy densities. However, SC-HN materials face air instability, causing distinct storage failure mechanisms compared to polycrystalline high-nickel cathode (PC-HN) materials. The characteristics of SC-HN, such as their lower specific surface area and reduced grain boundaries, make their failure mechanisms distinct and not directly applicable to PC-HN materials. To address these unique degradation pathways, this study systematically investigated the storage failure mechanisms of SC-HN material under ambient air exposure. Using advanced characterization techniques including soft X-ray absorption spectra (sXAS), wide-angle X-ray scattering (WAXS), aberration-corrected scanning transmission electron microscopy (STEM), and etching-based X-ray photoelectron spectroscopy (XPS), we conducted comprehensive multi-dimensional analyses over 6 months to track the evolution of chemical and structural changes. The results reveal that SC-HN materials experience a nonlinear progression of structural and surface composition degradation, and surface structural transformations are found to be the main cause of performance decline. The findings deepen understanding of SC-HN air instability and provide a basis for targeted strategies to enhance storage stability.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nickel Regulating Endows Fe7Se8 With Stable Potassium-Ion Storage","authors":"Qingyi Zhao,&nbsp;Fangrui Yu,&nbsp;Yizhi Yuan,&nbsp;Song Chen,&nbsp;Wei Chen,&nbsp;Hongli Deng,&nbsp;Xiangdong Guo,&nbsp;Hongtao Sun,&nbsp;Hao Chen,&nbsp;Jian Zhu","doi":"10.1002/cnl2.70007","DOIUrl":"https://doi.org/10.1002/cnl2.70007","url":null,"abstract":"<p>Iron-based selenides are considered as potential electrode materials in potassium-ion batteries (PIBs) owing to the merits of high capacity, intrinsic safety, and cost-effectiveness. However, sluggish electronic/ionic transport kinetics and large volume variations result in suboptimal electrochemical performance. Herein, we report a nickel-doped Fe₇Se₈ with double-shell N-doped carbon (Ni-Fe₇Se₈@DNC) as anode for robust potassium ion storage. Notably, the introduction of Ni induces the lattice distortion and leads to a rearrangement of charge, thereby creating numerous active sites and optimizing the band structure to enhance charge transport. Additionally, the elastic carbon shell can synergistically mitigate the volume expansion upon cycling and maintain the structural stability. Thus, the Ni-Fe₇Se₈@DNC presented excellent cycling stability of more than 1 year (464.8 mAh g⁻¹after 1000 cycles at 0.1 A g⁻¹, the best stability among all iron-based selenides) and satisfactory rate capability. The potassium-ion hybrid capacitors (PIHCs) have also demonstrated a remarkable energy density of 186.5 Wh kg⁻¹ at 0.2 A g⁻¹. Density functional theory calculations, in conjunction with a range of characterization methods, validate the rapid pseudocapacitive effect and lower ion diffusion energy barriers, resulting from Ni doping, improve reaction kinetics. This study paves the avenue for novel anode material designs for PIBs.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143707633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress on Fe-Based Cathode Materials for Sodium-Ion Batteries","authors":"Muhammad Hassan,&nbsp;Yanshuo Zhao,&nbsp;Qi Liu,&nbsp;Wenxiu He,&nbsp;Syed Ali Riza,&nbsp;Daobin Mu,&nbsp;Li Li,&nbsp;Renjie Chen,&nbsp;Feng Wu","doi":"10.1002/cnl2.70000","DOIUrl":"https://doi.org/10.1002/cnl2.70000","url":null,"abstract":"<p>Sodium-ion batteries (SIBs) have received significant interest as an alternative to lithium-ion batteries (LIBs) due to the abundant availability of sodium, low cost, and enhanced safety. Among the various cathode materials explored for SIBs, iron-based cathodes stand out as promising candidates for large-scale energy storage systems due to their affordability, environmentally friendly nature, and non-toxicity. This review provides a comprehensive overview of recent advancements in Fe-based cathode materials like layered oxides, polyanionic compounds, and Prussian blue analogs. We analyze their synthesis techniques, electrochemical properties, and structural features to assess their viability for SIB applications. The impact of different synthesis methods on the electrochemical performance of these materials is highlighted and their underlying mechanisms are examined. Additionally, strategies to enhance key performance such as energy density, cycle life, and conductivity are discussed. We also address the main technical challenges that limit the practical application of iron-based cathodes, including issues with cycle stability and charge/discharge performance. In conclusion, this review presents a comprehensive overview and a forward-looking perspective on the design of Fe-based cathode materials for next-generation SIBs.</p>","PeriodicalId":100214,"journal":{"name":"Carbon Neutralization","volume":"4 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cnl2.70000","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143554332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}