Applications of Surface Science最新文献

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The Chadi total energy algorithm for determining surface geometries 确定表面几何形状的Chadi总能量算法
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90191-6
P.V. Smith
{"title":"The Chadi total energy algorithm for determining surface geometries","authors":"P.V. Smith","doi":"10.1016/0378-5963(85)90191-6","DOIUrl":"10.1016/0378-5963(85)90191-6","url":null,"abstract":"<div><p>The Chadi total energy minimization technique is probably the simplest, physically realistic approach for determining the surface geometries of solids and has proved highly successful in predicting the surface relaxation and reconstruction of a wide variety of covalent solids. One of the basic assumptions of this method has been that the tight-binding parameters, which describe the dependence of the electronic energy of the system upon the surface configuration of atoms, simply vary as the inverse square of the appropriate interatomic distance. More recent work, however, has shown that there are now strong grounds for doubting the validity of this 1/<em>d</em><sup>2</sup> approximation, and has suggested that a better representation of the spatial dependence of the LCAO model Hamiltonian parameters might be obtained from self-consistent bandstructure calculations performed at different lattice constants. The purpose of this paper is to assess the relative merit of these two alternative models by employing them in a direct determination of some of the lattice dynamical properties of silicon, and to discuss the implications of the results of these calculations for surface structure analyses within the Chadi formalism.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 596-603"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90191-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76366943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Hall mobility and field effect mobility studies on PbTe HWE thin films PbTe HWE薄膜的霍尔迁移率和场效应迁移率研究
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90206-5
P.R. Vaya , J. Majhi , B.S.V. Gopalam , C. Dattatreyan
{"title":"Hall mobility and field effect mobility studies on PbTe HWE thin films","authors":"P.R. Vaya ,&nbsp;J. Majhi ,&nbsp;B.S.V. Gopalam ,&nbsp;C. Dattatreyan","doi":"10.1016/0378-5963(85)90206-5","DOIUrl":"10.1016/0378-5963(85)90206-5","url":null,"abstract":"<div><p>Hall mobility (<em>μ</em><sub>H</sub>) and field effect mobility (<em>μ</em><sub>FE</sub>) studies were carried out on PbTe films of different thickness grown on KCl (100) substrates by the hot wall epitaxy (HWE) technique. The Hall mobility was obtained using the standard Van der Pauw technique. The diffused scattering mobility, <em>μ</em><sub>D</sub>, due to size effect was calculated and compared with <em>μ</em><sub>H</sub>. A large discrepancy between <em>μ</em><sub>H</sub> and <em>μ</em><sub>D</sub> was explained on the basis of a residual mobility contribution which was attributed to the scattering due to grain boundaries, dislocations, cleavage steps and other surface effects. For AC field effect studies an MIS structure with a thin mica spacer between the film surface and metal electrode was used. The field effect mobility, <em>μ</em><sub>FE</sub>, was obtained at different temperatures from 98 to 156 K in the frequency range of 40 to 200 kHz. The variation of <em>μ</em><sub>FE</sub> with frequency was found to be largely due to the relaxation of fast surface states having time constants from 1.84 to 0.96 μs in the above temperature range. The activation energy and capture cross-section of these surface states were calculated to be 0.02 eV and 10<sup>−19</sup> cm<sup>2</sup> respectively. Unlike the Hall mobility, the effective DC field effect mobility derived from the experimental results was found to be independent of film thickness.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 731-736"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90206-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80163324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Topics in ultraviolet inverse photoemission 紫外光逆发射的主题
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90066-2
V. Dose
{"title":"Topics in ultraviolet inverse photoemission","authors":"V. Dose","doi":"10.1016/0378-5963(85)90066-2","DOIUrl":"10.1016/0378-5963(85)90066-2","url":null,"abstract":"<div><p>Ultraviolet inverse photoemission is an exciting new technique for band mapping of empty electronic states in solids and at surfaces. It includes the energy region between the Fermi and the vacuum level inaccessible by ordinary photoemission. Applications discussed in this paper include band mapping in nickel, spin-resolved studies of iron, and chemisorption of NO and CO on palladium.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 338-348"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90066-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83062294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Detection of multiple species through isosbestic points in UV-photoemission spectra: Application to sulfide adsorption on copper 利用紫外光发射光谱等吸点检测多种物质:在铜上硫化物吸附中的应用
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90065-0
S.E. Anderson , G.L. Nyberg
{"title":"Detection of multiple species through isosbestic points in UV-photoemission spectra: Application to sulfide adsorption on copper","authors":"S.E. Anderson ,&nbsp;G.L. Nyberg","doi":"10.1016/0378-5963(85)90065-0","DOIUrl":"10.1016/0378-5963(85)90065-0","url":null,"abstract":"<div><p>When the spectra corresponding to successively greater adsorbate coverages are superimposed, there is often a singular point through which they all pass. This is recognized as an isosbestic point, which is shown should be present whenever there is only a single adsorbate overlying the substrate. The lack of such a point consequently indicates the existence of multiple adsorbate species. These criteria are applied to the adsorption of O<sub>2</sub>, H<sub>2</sub>S and benzenethiol on Cu(410). For H<sub>2</sub>S, two species are detected and assigned to surface and incorporated sulfur.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 325-337"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90065-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90725235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Field effect studies on MIS structures of n-type Pb0.8Sn0.2Te thin films n型Pb0.8Sn0.2Te薄膜MIS结构的场效应研究
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90211-9
A.L. Dawar , K.V. Ferdinand, C. Jagadish, anil Kumar , Partap Kumar, P.C. Mathur
{"title":"Field effect studies on MIS structures of n-type Pb0.8Sn0.2Te thin films","authors":"A.L. Dawar ,&nbsp;K.V. Ferdinand,&nbsp;C. Jagadish,&nbsp;anil Kumar ,&nbsp;Partap Kumar,&nbsp;P.C. Mathur","doi":"10.1016/0378-5963(85)90211-9","DOIUrl":"10.1016/0378-5963(85)90211-9","url":null,"abstract":"<div><p>DC conductivity and Hall coefficient studies were made on MIS structures of n-type Pb<sub>0.8</sub>Sn<sub>0.2</sub>Te thin films grown by a flash evaporation technique in the temperature range 77–400 K. The decrease in <em>R</em><sub>H</sub> with positive gate field and increase in <em>R</em><sub>H</sub> with negative gate field have been attributed to the accumulation and depletion of charge carriers due to bending of bands. Mobility-temperature data have been analyzed in terms of various scattering mechanisms.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 781-791"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90211-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72945511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent progress of amorphous silicon technology and its application to optoelectronic devices 非晶硅技术及其在光电器件中的应用进展
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90219-3
Yoshihiro Hamakawa
{"title":"Recent progress of amorphous silicon technology and its application to optoelectronic devices","authors":"Yoshihiro Hamakawa","doi":"10.1016/0378-5963(85)90219-3","DOIUrl":"10.1016/0378-5963(85)90219-3","url":null,"abstract":"<div><p>A review is given on recent progress in tetrahedrally-bonded amorphous semiconductors and their technological applications to optoelectronic devices. First, some significant advantages of these materials are pointed out, and tangible instances are demonstrated from current technological topics. The present state of the art in optoelectronic device development with this new kind of thin film is then reviewed, and the technical data are summarized and discussed.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 859-878"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90219-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87456603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Properties of ultrathin metallic films on Si(111) determined by high-resolution electron energy loss spectroscopy 用高分辨率电子能量损失谱法测定Si(111)上超薄金属薄膜的性质
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90073-X
J.E Demuth, B.N.J Persson
{"title":"Properties of ultrathin metallic films on Si(111) determined by high-resolution electron energy loss spectroscopy","authors":"J.E Demuth,&nbsp;B.N.J Persson","doi":"10.1016/0378-5963(85)90073-X","DOIUrl":"10.1016/0378-5963(85)90073-X","url":null,"abstract":"<div><p>UV photoemission, low energy electron diffraction and high-resolution electron energy loss spectroscopy (EELS) have been used in situ to study the nature of 1–25 Å of Au and Pd deposited on Si(111) at temperatures of 20 and 300 K. New information is obtained regarding the formation, nature and microstructure of these metallic layers. We describe and apply a theoretical analysis of EELS which allows the determination of DC transport properties in these ultrathin layers. All metallic layers exhibit significantly higher resistivities than expected in comparison to bulk metal silicides or metallic glass phases, and can be attributed to diffuse scattering of conduction electrons at the interface. The interaction and behavior of atomic hydrogen with these films as detected by EELS is also described and found to convey additional information about their microstructure.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 415-425"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90073-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87975457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure of silicon oxide films prepared by vacuum deposition 真空沉积制备氧化硅薄膜的结构
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90193-X
Yoshio Saito, Chihiro Kaito, Kenzo Nishio, Toshio Naiki
{"title":"Structure of silicon oxide films prepared by vacuum deposition","authors":"Yoshio Saito,&nbsp;Chihiro Kaito,&nbsp;Kenzo Nishio,&nbsp;Toshio Naiki","doi":"10.1016/0378-5963(85)90193-X","DOIUrl":"10.1016/0378-5963(85)90193-X","url":null,"abstract":"<div><p>The structure of thin silicon oxide films 5 nm in thickness, which were prepared by electron beam evaporation of SiO<sub>2</sub> glass onto a NaCl substrate, has been examined by high resolution electron microscopy and diffraction. Although the films which were prepared with substrate temperatures ranging from room up to 400°C gave rise to amorphous haloes, lattice fringes in areas 1–2 nm in extent were, however, seen in the micrographs. It is shown that the film is composed of α-quartz micro-crystallites. Crystals of α-cristobalite with sizes of several tens of nanometers appeared at a substrate temperature of 500°C. At a substrate temperature of 600°C, β-cristobalite crystals with sizes of several tens of nanometers appeared. The structural changes due to the substrate temperature were attributed to incorporation of sodium atoms from the substrate into the SiO<sub>2</sub> film.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 613-620"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90193-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86086298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
The electrical and optical properties of LiAlxB1−x thin films LiAlxB1−x薄膜的电学和光学性质
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90215-6
Hiroshi Kezuka, Makio Akimoto, Yotaro Taguchi, Kokuya Iwamura, Tomomo Masaki
{"title":"The electrical and optical properties of LiAlxB1−x thin films","authors":"Hiroshi Kezuka,&nbsp;Makio Akimoto,&nbsp;Yotaro Taguchi,&nbsp;Kokuya Iwamura,&nbsp;Tomomo Masaki","doi":"10.1016/0378-5963(85)90215-6","DOIUrl":"10.1016/0378-5963(85)90215-6","url":null,"abstract":"<div><p>The electrical and optical properties of LiAl<sub><em>x</em></sub>B<sub>1−<em>x</em></sub> thin films deposited at 350°C by the Sandwich-Type Evaporation Method are measured. These films are metallic with a resistivity of (1–4) × 10<sup>5</sup> ohm cm at room temperature. In addition, we have developed a unique method. named the Brewster Angle Method (BAM), for obtaining the optical constants of thin films for LiAl<sub><em>x</em></sub>B<sub>1−<em>x</em></sub>. In this method reflection coefficients are measured on the surface of thin films at any angle of incidence using a HeNe laser beam. The optical constants are calculated from the Brewster angle, <em>φ</em><sub>B</sub>, at the minimum value of reflection coefficient <span><math><mtext>|</mtext><mtext>R</mtext><msub><mi></mi><mn><mtext>B</mtext></mn></msub><mtext>|</mtext><msub><mi></mi><mn><mtext>min</mtext></mn></msub></math></span>. For a typical LiAl<sub><em>x</em></sub>B<sub>1−<em>x</em></sub> film the optical constants are <span><math><mtext>n</mtext><mtext> = 1.42 − </mtext><mtext>j</mtext><mtext>0.31</mtext></math></span> and the complex dielectric constants are <span><math><mtext>ϵ</mtext><mtext> = 1.94 − </mtext><mtext>j</mtext><mtext>0.87</mtext></math></span>.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 820-826"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90215-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79905161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
MEED study of some crystalline surfaces 某些晶体表面的MEED研究
Applications of Surface Science Pub Date : 1985-05-01 DOI: 10.1016/0378-5963(85)90036-4
G. Shimaoka
{"title":"MEED study of some crystalline surfaces","authors":"G. Shimaoka","doi":"10.1016/0378-5963(85)90036-4","DOIUrl":"10.1016/0378-5963(85)90036-4","url":null,"abstract":"<div><p>A new medium energy electron diffraction (MEED) system, which can observe both back scattering (BSMEED) and forward scattering (RMEED) patterns from the same surface of crystalline solids has been designed. Results obtained from MgO(001) and GaAs(001) indicate that MEED has the following favourable characteristics: (1) Unlike LEED, post-acceleration of the diffracted beam with a grid is not necessary for MEED. The diffraction pattern can be seen directly on a fluorescent screen. (2) Collimation and focusing of the incident beam are readily achieved and sharp diffraction spots are observed. (3) Unlike RHEED, a strictly flat surface is not necessary for MEED. Relatively rough, but clean surfaces can produce diffraction patterns. (4) From Kikuchi lines or bands it is possible to determine the precise orientation of the crystal surface. (5) By changing the energy of the incident beam it is possible to observe the surface layer both in two and three dimensions.</p></div>","PeriodicalId":100105,"journal":{"name":"Applications of Surface Science","volume":"22 ","pages":"Pages 55-62"},"PeriodicalIF":0.0,"publicationDate":"1985-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-5963(85)90036-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80181273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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