Carbon Capture Science & Technology最新文献

{"title":"A self-consistent design method of the autothermal dual circulating fluidized bed reactor for in-situ gasification chemical looping combustion of coal","authors":"Xi Chen,&nbsp;Haibo Zhao","doi":"10.1016/j.ccst.2024.100292","DOIUrl":"10.1016/j.ccst.2024.100292","url":null,"abstract":"<div><div>This paper establishes a design method for the autothermal dual circulating fluidized bed reactor (DCFBR) of the coal-fueled <em>in-situ</em> gasification chemical looping combustion (<em>i</em>G-CLC) process. This method, grounded in a self-consistent phenomenological model, comprehensively elucidates the factors of mass and energy conservation, fuel and oxygen carrier (OC) reaction processes, and fluidization characteristics within the reactor. It is particularly suitable for the rapid screening of numerous potential designs, obtaining detailed design parameters, and studying their interrelationships. Utilizing this method, the regulation patterns of dual-bed interactive transport-reaction phenomena within a 5 MW_th <em>i</em>G-CLC DCFBR are studied. Firstly, the effects of key design parameters on the OC circulation rate and bed inventory are analyzed. Following this, the impacts of circulation rate on the interactive heat and mass transfer between two beds are examined, delineating a reasonable range for the control of autothermal CLC process (circulation rate of 50–90 kg/m²s, temperature difference of 30–90 °C, OC conversion of 0.2–0.35, and oxygen-fuel ratio of 3–6). Subsequently, this paper investigates the influences of main design parameters on the performance metrics, such as gas/solid fuel conversion, operational costs, and operational benefits. It is found that the carbon stripper significantly enhances the carbon capture efficiency of the device, provided that its separation efficiency is maintained above 70–95 %. Sensitivity analysis is employed to study the response patterns of performance metrics to changes in input parameters. Ultimately, based on these analyses, a design scheme for the 5 MW_th reactor is determined, with a detailed examination of the pressure balance state of the reactor under the design conditions, and the balanced material and energy flows at the reactor inlets and outlets.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100292"},"PeriodicalIF":0.0,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enabling simultaneous CO2 and water vapor removal by MOF-801/Pebax mixed matrix membranes: Molecular simulation and experimental study","authors":"Mahdi Ahmadi ,&nbsp;Saravanan Janakiram ,&nbsp;Sadiye Velioğlu ,&nbsp;Arne Lindbråthen ,&nbsp;Brian Arthur Grimes ,&nbsp;Magne Hillestad ,&nbsp;Liyuan Deng","doi":"10.1016/j.ccst.2024.100307","DOIUrl":"10.1016/j.ccst.2024.100307","url":null,"abstract":"<div><div>Dehydration and CO₂ removal are two important gas separation processes. An efficient membrane enabling simultaneous reduction of water vapor and CO₂ levels from humid gas streams, such as natural gas and power plant flue gas, may advance these processes. In this study, a water-harvesting metal-organic framework, MOF-801, was synthesized with an average particle size of 120 nm, which was then dispersed in a Pebax matrix to fabricate mixed matrix membranes (MMMs). The potential of the MOF-801 as a filler in MMMs was evaluated for water and CO₂ separation from CO₂/N₂ and CO₂/CH₄ mixed gas streams. Compared with the neat Pebax membrane, 70% enhancement in the water permeability was achieved for an MMM of 20 wt.% MOF loading at 10 bar with a humid feed composition of CO₂/CH₄. A considerable CO₂/N₂ separation factor (108) and CO₂ permeability (270 Barrer) were also obtained, exceeding the Robeson upper bound at both dry and humid states. A molecular simulation study was performed to reveal the adsorption sites in the MOF lattice and favorable interactions with gases. Interestingly, competition between gas components close to the Zr atom was observed, which is the favorable site for both CO₂ and water. Competitive adsorption was found to be the dominating transport mechanism for the selective transport of CO₂ and H₂O in MOF-801, revealing the role of MOF-801 in MMMs for CO₂ and water vapor separation under both humid and dry conditions.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100307"},"PeriodicalIF":0.0,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Prediction of CO2 adsorption of biochar under KOH activation via machine learning","authors":"Junjie Zhang ,&nbsp;Xiong Zhang ,&nbsp;Xiaoqiang Li ,&nbsp;Zhantao Song ,&nbsp;Jingai Shao ,&nbsp;Shihong Zhang ,&nbsp;Haiping Yang ,&nbsp;Hanping Chen","doi":"10.1016/j.ccst.2024.100309","DOIUrl":"10.1016/j.ccst.2024.100309","url":null,"abstract":"<div><div>To effectively increase the CO₂ adsorption capacity of biochar, the activation process is often an indispensable link. However, the introduction of an activation process poses challenges in clarifying the relationship between the characterization parameters of biochar, adsorption parameters, and CO₂ adsorption capacity. Herein, a comprehensive dataset encompassing the CO₂ adsorption data of KOH-activated biochar using a “two-sep method” was compiled. Subsequently, ridge regression, multi-layer perceptron, and random forest models were employed to predict its CO₂ adsorption performance. To comprehensively explore the effects of activation conditions, physicochemical properties and adsorption parameters on CO₂ adsorption capacities, partial dependence via Shapley additive explanation (SHAP) values analysis was conducted. The results demonstrate that the multilayer perceptron model exhibits the highest prediction accuracy with a test R² value of 0.961. Additionally, it was found that the CO₂ adsorption capacity of activated biochar is primarily determined by micropores and nitrogen-containing groups rather than total pore volume at low adsorption pressure (&lt; 0.3 bar). Moreover, it increases significantly with decreasing average pore size, increasing pore volume, and increasing nitrogen content at low adsorption temperatures (&lt; 20 °C). When the ratio of KOH to biochar is in the range of 1–2 and the activation temperature is ∼ 700 °C, activated biochar with high CO₂ adsorption performance can be obtained. This study may provide valuable insights for the application of activated biochar in CO₂ adsorption.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100309"},"PeriodicalIF":0.0,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient methane production from photocatalytic CO2 reduction by InCu0.05Co0.05Ox: The synergistic effect of Co and Cu","authors":"Shuhao Li ,&nbsp;Feng Wang ,&nbsp;Tianhan Shen ,&nbsp;Derrick Ng ,&nbsp;Yuning Huo ,&nbsp;Boxiong Shen ,&nbsp;Zongli Xie","doi":"10.1016/j.ccst.2024.100313","DOIUrl":"10.1016/j.ccst.2024.100313","url":null,"abstract":"<div><div>Photocatalytic reduction of CO₂ to methane (CH₄) is a promising strategy to address CO₂ emissions and energy scarcity. However, low efficiency limits its practical application. This study presents a bimetallic co-doping strategy using Cu and Co to enhance the photocatalytic performance of the In₂O₃ catalyst. The InCu_0.05Co_0.05O_x (InCuCo) catalyst demonstrated a CH₄ yield of 22.3 µmol·g⁻¹·h⁻¹, outperforming In₂O₃ (8.8 µmol·g⁻¹·h⁻¹), InCu (14.5 µmol·g^-1·h⁻¹), and InCo (18.0 µmol·g^-1·h⁻¹). This remarkable improvement highlights the synergistic effects of Cu and Co in the In₂O₃ catalyst. Characterizations and density functional theory (DFT) calculations revealed that Co doping narrows the bandgap of the catalyst, enhancing light utilization, while Cu adjusts the energy band positions and improves CO₂ adsorption. Consequently, the InCuCo catalyst significantly enhances the photocatalytic reduction of CO₂–CH₄, offering remarkable activity and stability. These results provide new insights into CO₂ photoreduction to CH₄, facilitating further practical applications.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100313"},"PeriodicalIF":0.0,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142326854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hypercrosslinked natural biopolymers with quasi-unimodal micropores for carbon capture","authors":"Liang Ding ,&nbsp;Yue Wu ,&nbsp;Guanchu Lu ,&nbsp;Yixuan Zhang ,&nbsp;Mariolino Carta ,&nbsp;Xianfeng Fan ,&nbsp;Cher Hon Lau","doi":"10.1016/j.ccst.2024.100305","DOIUrl":"10.1016/j.ccst.2024.100305","url":null,"abstract":"<div><p>Ultra-microporous solid sorbents with high CO₂ adsorption capacities and gas selectivity are preferred for carbon capture. Here we deliver such sorbents <em>via</em> a combination of narrow micropores, lack of mesopores and an abundance of CO₂-philic functional groups. This was achieved by crosslinking lignin waste obtained from a local paper factory, in Lewis's acid deep eutectic solvents (DESs) such as [ChCl][ZnCl₂]₂ and [ChCl][FeCl₃]₂, varying crosslinker types and optimizing experimental parameters. Hypercrosslinked polymers (HCPs) prepared in [ChCl][FeCl₃]₂ with 1,4-dichloroxylene crosslinkers comprised quasi-unimodal, ultra-narrow micropores. At 298 K, 1 bar, and using a gas mixture comprising 15 vol.% CO₂ and 85 vol.% N₂ (similar to post-combustion flue gas), the CO₂ adsorption capacity and CO₂/N₂ selectivity of this HCP reached 18.1 cm³ <em>g</em>⁻¹ and 835, respectively. Deployed in temperature swing adsorption and evaluated for vacuum pressure swing adsorption, the CO₂ recovery rates of this HCP were &gt;87 %, outperforming commercial solid sorbents such as zeolite 13X and PSAO2 HP Molsiv™. The optimization of sorbent microporosity with CO₂-philic functional groups could pave the route towards developing bio-derived solid sorbents for carbon capture.</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100305"},"PeriodicalIF":0.0,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001179/pdfft?md5=95da19847e8c68cb25c45e0e7608c18c&pid=1-s2.0-S2772656824001179-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142270463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Post-combustion CO2 capture retrofit from diesel-powered Arctic mines – Techno-economic and environmental assessment","authors":"M.O. Landry ,&nbsp;F. Larachi ,&nbsp;P. González","doi":"10.1016/j.ccst.2024.100299","DOIUrl":"10.1016/j.ccst.2024.100299","url":null,"abstract":"<div><p>This study evaluates the economic feasibility and environmental impacts of retrofitting a diesel-based powerhouse in the Canadian Arctic with a post-combustion carbon capture process at an active gold mining site isolated from cheaper or cleaner electrical grids. A techno-economic analysis was conducted to determine the total annualized cost (<em>TAC</em>) of implementing a monoethanolamine (MEA) chemical absorption process to mitigate carbon dioxide emissions. The calculated cost per tonne of CO₂ captured of $420 reflects the challenges of operating northern sites reliant on diesel fuel. Electricity generation costs, estimated at 0.44 $/kWh, are found to explain most of the variance in cost per tonne compared to other studies. A profitability model, comparing the additional annual expenditure to the current carbon tax exposure (<em>CTE</em>), suggests that carbon pricing alone is insufficient to incentivize investment in energy-intensive carbon capture technologies such as amine-based absorption processes. The sensitivity analysis, which evaluates profitability relative to variations in key variables, highlights the significant impact of the solvent regeneration heat demand. This major cost driver also contributes substantially to the carbon footprint of 0.55 tonnes emitted per tonne captured, as determined by a complementary life cycle assessment.</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100299"},"PeriodicalIF":0.0,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001118/pdfft?md5=520526a50ec1cb86981e4ccf886913a6&pid=1-s2.0-S2772656824001118-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142270462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Carbon sequestration behavior of magnesium oxychloride cement based on salt lakes magnesium residue and industrial solid waste","authors":"Yuanrui Li ,&nbsp;Baolan Li ,&nbsp;Weixin Zheng ,&nbsp;Jin Zhou ,&nbsp;Jing Wen ,&nbsp;Jinmei Dong ,&nbsp;Chenggong Chang ,&nbsp;Qiang Wang","doi":"10.1016/j.ccst.2024.100301","DOIUrl":"10.1016/j.ccst.2024.100301","url":null,"abstract":"<div><p>With the extensive utilization of lithium-ion battery in the electric vehicle and energy storage field, the consumption of lithium has been sharply increasing. Lithium resource occurrence area were facing increasing environmental pressure, particularly the magnesium residue (MR) produced in the lithium extraction process, and a sustainable exploitation pathway have not been established. In the framework of \"net-zero\", MRs were onverted to Salt lake magnesium oxide (SL-MgO) which was characterized by various elemental and surface analysis methods. Magnesium oxychloride cement (MOC) was prepared form SL-MgO and two industrial solid wastes [fly ash (FA) and phosphogypsum (PG)], and its carbon sequestration capacity was analyzed and evaluated. If all the MRs produced from the lithium extraction process were used to manufacture MOC materials for CO₂ sequestration. When the PG content was 20 %, the CO₂ sequestration capacity of the MOC was 0.29 kg/m², the compressive strength was 85.30 MPa, and the MOC neutralized 220.10 % of the CO₂ emissions from the lithium extraction process. In this procedure, evidence was found of the typical metastable carbonate products identifiable. Overall, utilizing MRs and industrial solid waste to manufacture new low-carbon MOCs may become the most direct and effective countermeasures to alleviate environmental pressure in these regions.</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100301"},"PeriodicalIF":0.0,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001131/pdfft?md5=7145c5a848f626375d22a4d324a97d9a&pid=1-s2.0-S2772656824001131-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142270468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"CO2 capture via subsurface mineralization geological settings and engineering perspectives towards long-term storage and decarbonization in the Middle East","authors":"Priyanka Kumari ,&nbsp;Rihab Yahmadi ,&nbsp;Fatima Mumtaz ,&nbsp;Lourdes F. Vega ,&nbsp;Andrea Ceriani ,&nbsp;Riccardo Tribuzio ,&nbsp;Ludovic F. Dumée ,&nbsp;Alessandro Decarlis","doi":"10.1016/j.ccst.2024.100293","DOIUrl":"10.1016/j.ccst.2024.100293","url":null,"abstract":"<div><p>Mineral carbonation or mineralization of CO₂ using rocks or waste industrial materials is emerging as a viable carbon capture and storage (CCS) technology, especially for smaller and medium-scale emitters where geological sequestration is not feasible. During mineralization processes, CO₂ chemically reacts with alkaline earth metals in waste materials or rocks to form stable and non-toxic carbonates <em>In situ</em> mineral carbonation holds promise due to ample resources and enhanced security. However, it is still in its early stages, with higher transport and storage costs compared to geological storage in sedimentary basins. <em>Ex situ</em> mineral carbonation has shown promise at pilot and demonstration scales, but its widespread application is hindered by high costs, ranging from US$50-US$300/ton of sequestered CO₂. This review delves into the current progress of proposed mineralization technologies and their potential in reducing the overall cost of CO₂ sequestration. The discussion critically analyzes various factors affecting carbonation reactions, such as temperature, pressure, leaching agents, solid-to-liquid ratio, and mineralogy for geological settings relevant to the Middle East and the net-zero strategy established within Gulf Cooperation Countries (GCC). Furthermore, the potential commercialization of mineral carbonation, emphasizing the importance of reducing energy consumption and production costs to make the process economically viable is highlighted, offering directions for circular economy and mineral carbonation as a substantial carbon mitigation tool in the Middle East region. Life Cycle Assessment and Techno-Economic Analysis) was also reviewed to provide a comprehensive understanding of both the environmental and economic implications of a CO₂ capture via subsurface mineralization</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100293"},"PeriodicalIF":0.0,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001052/pdfft?md5=8903ecec69272ce814add40e706429d8&pid=1-s2.0-S2772656824001052-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142243321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In-situ hydrogenation of dual function material for integrated CO2 capture and methanation with the presence of steam","authors":"Daocheng Liu,&nbsp;Liangyong Chen","doi":"10.1016/j.ccst.2024.100291","DOIUrl":"10.1016/j.ccst.2024.100291","url":null,"abstract":"<div><p>The impacts of steam on hydrogenation of dual function materials (DFM) for Integrated CO₂ Capture and <em>in-situ</em> methanation (ICCM) is a new area requiring detailed investigations prior to industrialization. This work investigated impacts from steams on hydrogenation of Ru-Na₂CO₃/γ-Al₂O₃ DFM for ICCM that containing Na₂O adsorbent, Ru sites, and γ-Al₂O₃ support. DFM performance was examined in cyclic reactions as introducing external steam during hydrogenation, and the behaviors of adsorbed CO₂ species during hydrogenation were characterized by <em>in-situ</em> DRIFTS and H₂-TPSR. CH₄ selectivity decreased sharply from 84.3 % to 1.2 % as increasing external steam concentrations to 20 vol.%, and the conversion of adsorbent component decreased from 298.5 μmol g^-1 to 167.1 μmol g^-1. <em>b</em>-CO₃^2- and <em>m</em>-CO₃^2- formed at Na₂CO₃/γ-Al₂O₃ interface were the carbonate species that could be hydrogenated into CH₄, some of which were desorbed into CO₂ due to moisture-driven desorption effects. With the presence of external steam in H₂ reactants, the conversion of carbonate species is a competing process between hydrogenation and moisture-driven desorption. In ICCM reaction with external steam present, <em>b</em>-CO₃^2- was preferred to be desorbed into CO₂; while for <em>m</em>-CO₃^2-, desorption into CO₂ by steam and hydrogenation into CH₄ proceeded in parallel. Strong moisture-driven desorption effects from steam product were demonstrated in a fixed-bed reactor, which also led to rapid decrease of localized selectivity of CH₄ along bed height.</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100291"},"PeriodicalIF":0.0,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001039/pdfft?md5=40bbc551bf4434d0f251bd58b0bc43ce&pid=1-s2.0-S2772656824001039-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142158388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancements in dual-phase carbonate membranes for carbon capture and syngas production","authors":"Liza Melia Terry ,&nbsp;Melvin Xin Jie Wee ,&nbsp;Claudia Li ,&nbsp;Guoqiang Song ,&nbsp;Jiuan Jing Chew ,&nbsp;Jian Song ,&nbsp;M. Hanif B.M. Halim ,&nbsp;Farahdila B. Kadirkhan ,&nbsp;Shaomin Liu ,&nbsp;Sibudjing Kawi ,&nbsp;Jaka Sunarso","doi":"10.1016/j.ccst.2024.100288","DOIUrl":"10.1016/j.ccst.2024.100288","url":null,"abstract":"<div><p>Globally, the rise in the environmental awareness on the reduction of greenhouse gas emissions has spurred the development of carbon capture and utilization (CCU) technologies, including membrane separation. Among the membrane separation technologies, dual-phase carbonate membrane is feasible for post-combustion carbon capture given its high thermal and chemical stabilities at high temperatures. The integration of carbon capture and dry reforming of methane (DRM) in a catalytic dual-phase carbonate membrane reactor to function as a single device for syngas production is an emerging area of research. This paper aims to provide a comprehensive review on the progress of the dual-phase carbonate membranes and membrane reactors in carbon capture and syngas production. The working mechanism and performance of three types of carbonate membranes in CO₂ separation from various aspects (i.e., material selection, membrane configuration, modifications on the materials, and operating conditions) are thoroughly examined. Additionally, an overview of the reactions involved (i.e., DRM, steam reforming of methane (SRM), and partial oxidation of methane (POM)) and catalyst design (i.e., nickel-based supported with metal oxides and zeolites) is provided. A detailed comparison of the performance of the catalytic dual-phase ceramic-carbonate membrane reactor using different types of catalysts for syngas production is presented. Finally, the review is concluded with a discussion of the challenges, recommendations, and future insights on the development of dual-phase carbonate membranes and membrane reactors.</p></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"13 ","pages":"Article 100288"},"PeriodicalIF":0.0,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772656824001003/pdfft?md5=a57f56b44633912d2a05ce77ebe60227&pid=1-s2.0-S2772656824001003-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142130148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}