Carbon Capture Science & Technology最新文献

{"title":"Graphene-based metal-organic framework nanocomposites for CO2 reduction reactions","authors":"Kayode Adesina Adegoke,&nbsp;Potlaki Foster Tseki","doi":"10.1016/j.ccst.2025.100523","DOIUrl":"10.1016/j.ccst.2025.100523","url":null,"abstract":"<div><div>The CO₂ reduction reactions present a viable approach to addressing the challenges of energy scarcity and the pressing concerns of global warming. To enhance their kinetically sluggish processes, developing highly stable, cost-effective, selective, and energy-efficient catalysts is essential. Graphene-based metal-organic frameworks (MOFs) composite exhibits characteristics such as outstanding conductivity, structural tunability, and excellent surface chemistry and sustainability, positioning them as innovative competitors for both CO₂ conversion to fuels and chemicals. In this study, we present recent developments in graphene-based MOF catalysts for CO₂ reduction reactions (CO₂RR). Before discussing the evaluation of the approaches for graphene-based MOFs, rational, structural, and electronic synergies of graphene/MOF nanocomposites were addressed. Various synthetic techniques, a comprehensive review of characterization techniques, associated challenges, and the relation between graphene-based MOF structures and their conductivity are examined. A detailed breakthrough in both photocatalytic and electrocatalytic performance for CO₂RR is examined. The concluding remarks emphasized the knowledge gaps, related deficiencies, and strengths, with significant viewpoints and concepts for enhancing graphene-based MOFs for CO₂RR in accordance with pragmatic industry expectations. This study offers the scientific community a thorough insight into the present research emphasis and the significance of creating more efficient and environmentally sustainable graphene-based MOFs for clean energy conversion. This is essential for tackling the difficulties of reducing greenhouse gas emissions and alleviating the global energy deficit.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100523"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145320913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advanced soil carbonation strategies: insights into quantification, performance, and scalable carbon capture","authors":"Aaqib Ali ,&nbsp;Arshad Raza ,&nbsp;Mubashir Aziz ,&nbsp;Mohamed Mahmoud ,&nbsp;Umair Ali ,&nbsp;Ammar Mohammed Alshammari","doi":"10.1016/j.ccst.2025.100551","DOIUrl":"10.1016/j.ccst.2025.100551","url":null,"abstract":"<div><div>Accelerated soil carbonation (ASC) is a rapidly advancing carbon capture and storage technique which provides a dual benefit of permanent CO₂ sequestration and geotechnical soil stabilization. This paper presents a comprehensive review of soil carbonation processes, emphasizing the mechanisms, quantification methods, and engineering performance improvements achieved through MgO and CaO-based binders and industrial by-products. The carbonation process transforms reactive oxides into stable carbonate minerals, enhancing soil strength, stiffness, and durability while reducing moisture content and porosity. A systematic analysis of the impact of carbonation on physical, chemical, mechanical, and microstructural behavior is presented, together with quantification approaches such as thermogravimetric analysis, calcimetry, and gas-balance techniques. The techno-economic evaluation highlights that optimized magnesia-lime-slag systems can offset up to 70 % of embodied emissions, offering a cost-effective and scalable pathway for carbon-negative ground improvement. Despite these advances, the field faces challenges related to reaction uniformity, long-term durability, and standardization of quantification and field protocols. The study identifies key research directions to establish ASC as a reliable, sustainable, and verifiable carbon sequestration strategy in geotechnical engineering.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100551"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145680888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"District heating with negative emissions – direct air carbon capture and storage combined with small modular reactors","authors":"Heidi Kirppu,&nbsp;Miika Rämä,&nbsp;Esa Pursiheimo,&nbsp;Kati Koponen,&nbsp;Tomi J. Lindroos","doi":"10.1016/j.ccst.2025.100533","DOIUrl":"10.1016/j.ccst.2025.100533","url":null,"abstract":"<div><div>Achieving Paris Agreement targets for climate change mitigation requires an urgent shift away from fossil fuels. In addition, negative emissions by permanently removing carbon dioxide from the atmosphere are required. Both targets require substantial amounts of carbon neutral electricity and heat production. While electricity can be produced and transferred over long distances, the heat production needs to be local. This study investigates an energy system integrating both carbon neutral heat production and carbon dioxide removal from the atmosphere. The system is modelled using the Backbone energy system modelling framework. The carbon neutral heat production in the study is based on small modular nuclear reactors (SMRs), large-scale thermal energy storages (TES), heat pumps (HPs) and electric boilers (EBs), and the carbon removal is implemented by direct air capture (DAC) combined with permanent geological storage. The studied technologies are integrated into a specific large-scale district heating system located in Northern Europe. The impact of outdoor temperature for the efficiency of the DAC process is considered, and the system integration potential with the district heating system is evaluated. The results show that high 70–90 % utilisation rates for both SMR and DAC units can be reached but depending on the case year and corresponding profiles for demand, outdoor temperature, electricity and carbon prices, a large variation in utilisation rates is observed. The variable CO₂ capture costs were between 115–126 €/t CO₂ in the modelled scenarios, and with higher OPEX values at the range 152–163€/tCO₂, and the limit price for economic viability considering the investment was calculated to be in the range of 209–223 €/tCO_2, with lower, and 233–246 €/tCO₂ with higher adsorbent costs. When not accounting the biogenic CO₂ emissions, the carbon negativity can be reached in the system in all the scenarios where the CO₂ price is over 150€/t and the number of DAC modules is at least 400. When accounting the biogenic CO₂ emissions, the carbon negativity can be reached only in scenarios with DAC capacity at 900 modules and CO₂ price at 180–200€/t.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100533"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145412812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Machine learning-driven optimization of argon oxygen decarburization slag recycling for enhanced microalgal carbon sequestration","authors":"Wen-Long Xu ,&nbsp;Tian-Ji Liu ,&nbsp;Ya-Jun Wang ,&nbsp;Ya-Nan Zeng ,&nbsp;Liang-Yi Zhang ,&nbsp;Kai-Li Dong ,&nbsp;Yi-Tong Wang ,&nbsp;Jun-Guo Li","doi":"10.1016/j.ccst.2025.100502","DOIUrl":"10.1016/j.ccst.2025.100502","url":null,"abstract":"<div><div>The sustainable management of hazardous argon oxygen decarburization (AOD) slag demands urgent attention owing to its calcium-magnesium-silicon leaching risks in landfill scenarios. This study presents an innovative strategy for waste valorization by repurposing three modified AOD slag variants (raw, aged, and carbonated) as nutrient supplements for <em>Chlorella pyrenoidosa</em> cultivation. Moreover, process parameters in microalgae cultivation, such as algal characteristics and complex operational conditions, will affect its yield and productivity. Traditional methods struggle to enable comprehensive understanding and application. Thus, quantitative prediction was conducted using 96 sets of total CO₂ carbon sequestration data (80% for the training set and 20% for the test set). Combined with three machine learning models and the Shapley Additive explanation (SHAP) algorithm, the intrinsic mechanisms by which five leaching elements (Ca, Mg, Al, Si, and Cr) regulate the efficient carbon sequestration of microalgae were analyzed. Notably, the random forest model excelled well in predicting CO₂ storage and elemental leaching, with performance metrics exceeding 0.87. This approach integrating solid waste recycling, utilization and model development achieves three objectives: (1) establishing a circular economy pathway for metallurgical waste, (2) reducing microalgal cultivation costs through waste-derived nutrient substitution, and (3) providing a machine learning blueprint for hazardous waste valorization process optimization. The research results provide guidance for implementing a sustainable strategy of biocarbon capture while reducing industrial waste.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100502"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electroreduction of CO2 to C1 and C2 products on dual active sites","authors":"Naimat Ullah ,&nbsp;Munzir H. Suliman ,&nbsp;Sikandar Khan ,&nbsp;Zubair Ahmed Laghari ,&nbsp;Guillermo Diaz-Sainz ,&nbsp;Abdulmajeed Hendi ,&nbsp;Wan Zaireen Nisa Yahya ,&nbsp;Muhammad Usman","doi":"10.1016/j.ccst.2025.100532","DOIUrl":"10.1016/j.ccst.2025.100532","url":null,"abstract":"<div><div>Electrochemical CO₂ reduction (eCO₂RR) is a promising method for transforming CO₂ emissions into useful multicarbon products. This study involved the synthesis and evaluation of CuS/ZnS nanocomposites with varying compositions (CuS: ZnS = 1:1, 2:1, and 1:2) in both H-type and flow-cell electrolyzers. The catalyst with a 2:1 CuS/ZnS ratio (S2) exhibited excellent performance, with a Faradaic efficiency (FE) of 60 % for C₁ products and approximately 20 % for C₂ products (C₂H₄) at a current density of −280 mA·cm⁻² in the flow-cell configuration. The flow-cell arrangement significantly enhanced catalytic activity, suppressed hydrogen evolution, and increased selectivity for CH₄ and C₂H₄ at greater negative potentials. Augmented ethylene production was ascribed to Cu-rich active sites promoting efficient C–C coupling and increased CO₂ accessibility at gas diffusion electrodes (GDEs), corroborated by low charge-transfer resistance (∼1 Ω·cm²). This work emphasizes the pivotal importance of catalyst composition and reactor design, showcasing the 2:1 CuS/ZnS catalyst in a flow-cell format as a scalable and effective method for sustainable CO₂ conversion to multicarbon fuels. Density functional theory (DFT) calculations further validated the experimental results by revealing favorable adsorption energies and interactions between the CuS/ZnS catalyst and key intermediates in the CO₂ conversion process.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100532"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145358426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enabling e-fuels in Middle East and North Africa: Life cycle and techno-economic insights into CO2 capture and utilization","authors":"Loiy Al-Ghussain ,&nbsp;Bilal Rinchi ,&nbsp;Mohammad Alrbai ,&nbsp;Sameer Al-Dahidi ,&nbsp;Zifeng Lu","doi":"10.1016/j.ccst.2025.100538","DOIUrl":"10.1016/j.ccst.2025.100538","url":null,"abstract":"<div><div>This study evaluates the levelized cost and greenhouse gas (GHG) emission intensity of CO₂ capture and e-fuel production pathways across the Middle East and North Africa (MENA) region. Industrial point-source CO₂ capture shows favorable techno-economic performance, particularly from natural gas and oil processing facilities, with a regional weighted average cost of approximately 51 USD/tCO_2cap, making it a viable source of low-cost CO₂ for e-fuel production. Among MENA countries, Qatar, Oman, and the United Arab Emirates exhibit the lowest capture costs (38–44 USD/tCO_2cap), attributable to high emission volumes and low energy prices. The corresponding GHG emission intensity (EI) of point-source capture averages around 180 kgCO_2eq/tCO_2cap. Regarding e-fuel production, Fischer–Tropsch (FT) fuels are identified as the most expensive and carbon-intensive option, with average production costs exceeding 0.07 USD/MJ and EIs surpassing 30 gCO_2eq/MJ in most MENA countries. In contrast, ammonia synthesis offers the lowest emission intensity, ranging from 7.1 to 21.8 gCO_2eq/MJ depending on the energy source. Although none of the e-fuel pathways are currently cost-competitive with fossil fuels, industrial point-source CO₂ capture in the MENA region presents a promising near-term opportunity. Realizing this potential will require targeted policy measures, including the implementation of carbon pricing, the expansion of renewable energy capacity, and strategic infrastructure investments.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100538"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145516637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photothermal and electrothermal-driven thermochemical conversion of biomass: A critical review","authors":"Wenkai Xu,&nbsp;Qiang Hu,&nbsp;Yichen Dong,&nbsp;Jiawen Zeng,&nbsp;Yingquan Chen,&nbsp;Haiping Yang,&nbsp;Hanping Chen","doi":"10.1016/j.ccst.2025.100527","DOIUrl":"10.1016/j.ccst.2025.100527","url":null,"abstract":"<div><div>The integration of multiple renewable energy sources is crucial for achieving high-efficiency utilization of renewable energy, playing a vital role in the low-carbon energy transition. By integrating solar energy-derived photothermal and solar/wind-powered electrothermal processes with biomass conversion, this promising thermochemical approach can produce biochar, bio-oil, or syngas/hydrogen. This technology achieves zero or even negative carbon emissions as well as stores the renewable energies in the form of chemicals, thereby contributing to carbon neutrality. In this review, biomass thermochemical conversion driven by photothermal and electrothermal technologies are comprehensively reviewed. The reaction characteristics and current development status of biomass pyrolysis and gasification driven by photothermal, microwave, plasma, electromagnetic induction, and Joule heating are systematically compared and analyzed. Finally, the challenges and future development directions for photothermal- and electrothermal-driven biomass thermochemical conversion technologies are discussed, focusing on three key aspects: transformation mechanisms, process control and product valorization, and plant-scale implementation. This study provides insights into renewable energy-driven thermochemical biomass conversion, contributing to advances in energy storage and carbon neutrality efforts.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100527"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145320914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Energy-coupled CO2 capture–conversion via membrane–adsorption integration: Quantitative benchmarks and pilot-scale design","authors":"Hailing Ma ,&nbsp;Xin Zhang ,&nbsp;Yao Tong ,&nbsp;Yew Mun Hung ,&nbsp;Xin Wang","doi":"10.1016/j.ccst.2025.100537","DOIUrl":"10.1016/j.ccst.2025.100537","url":null,"abstract":"<div><div>This review advances a unified framework for engineering low-energy, high-efficiency CO₂ capture–conversion platforms by co-designing membranes, adsorbents, and multi-field catalytic modules. We benchmark key performance indicators across materials and flowsheets—specific energy (kWh·t⁻¹-CO₂), capacity–selectivity trade-offs, cyclic stability, and space–time yield—and quantify integration benefits under harmonized boundaries (functional units, explicit ±compression, common base year).At 90 % capture efficiency with 10–15 % CO₂ feed, 40–60 % relative humidity, and a pressure drop of 0.2–0.4 bar, the membrane–adsorption architecture reduces specific energy by 30–40 % compared with membrane-only or adsorption-only baselines. It maintains both high capacity and selectivity and is compatible with VPSA or TDS regeneration. Design rules are distilled for Graphene Oxide (GO)/Reduced Graphene Oxide (rGO)–Metal Organic Framework (MOF) sorbents and Mixed-Matrix Membranes (MMMs), together with operating-window guidance that addresses H₂O/O₂ tolerance and interface matching. Along the conversion pathway, photocatalytic, thermocatalytic, and electrocatalytic subsystems are organized into a multi-field scheme in which structural and electronic-state tuning directs product selectivity and energy efficiency. A scenario-based Techno-Economic Analysis (TEA)/Life Cycle Assessment (LCA) compares centralized industrial flue gas, distributed biogas upgrading, and Direct Air Capture (DAC), with sensitivities to electricity/H₂ prices and sorbent lifetime. The resulting KPI toolkit and process maps aim to accelerate pilot-to-scale translation of integrated CO₂-to-chemicals systems.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100537"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145462639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advances in concurrent CO2 sequestration and heavy metal mobilization during fly ash carbonation: A review","authors":"Qingqin Wang,&nbsp;Zichen Cao,&nbsp;Qingqing Li,&nbsp;Bing Song","doi":"10.1016/j.ccst.2025.100519","DOIUrl":"10.1016/j.ccst.2025.100519","url":null,"abstract":"<div><div>The escalating atmospheric CO₂ concentration and concomitant ecological crises underscore the urgent need for innovative carbon capture and utilization strategies. Fly ash (FA), a global industrial byproduct with annual production exceeding 1 billion tons, presents a promising opportunity for simultaneous CO₂ mineralization and heavy metal stabilization. This review systematically examines recent advancements in FA-mediated CO₂ sequestration coupled with heavy metal immobilization, addressing critical knowledge gaps in their synergistic mechanisms. We analyze the interplay between carbonation pathways and heavy metal fate, the effects of key reaction parameters on Ca²⁺ leaching efficiency and metal stabilization, and the impact of pre-treatment methods such as mechanical activation and acid/alkali modification. Furthermore, we review the application of theoretical calculations for atomic-scale mechanism analysis and process optimization via machine learning. Finally, we identify existing challenges—including kinetic limitations, pH-dependent metal mobilization, and economic viability—and propose future research directions for enhancing process efficiency and environmental safety. This review aims to facilitate the development of fly ash-based technologies for dual carbon sequestration and pollution control, contributing to sustainable industrial solid waste management.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100519"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of carbon capture in decarbonising EU industries: A review of projections for 2030 and 2050","authors":"Guillermo Martinez Castilla ,&nbsp;Marc Jaxa-Rozen","doi":"10.1016/j.ccst.2025.100528","DOIUrl":"10.1016/j.ccst.2025.100528","url":null,"abstract":"<div><div>Energy-intensive industries are expected to play a significant role in this deployment of carbon capture. However, the distribution of CO₂ capture deployment across industry sectors remains uncertain as it will depend on various factors, and sectoral projections available in the literature have a wide spread and are often not comparable. In response to the identified research gap, this work examines projections for CO₂ capture deployment within the EU industrial sectors, focusing on the cement, iron and steel, and chemical industries, for 2030 and 2050. We harmonize and discuss sectoral projections from seventeen scenarios, and in order to draw cross-sectoral conclusions, we compare them with 820 aggregated, EU-wide industry scenarios. The sectoral projections mapped project carbon capture to significantly reduce emissions in the cement sector by an average of 70 % by 2050. In the near term, projections for 2030 show the highest emission reductions in the chemical sector (10 %), followed by cement (7 %) and iron and steel (5 %). Sectoral projections align well with EU-wide scenarios, particularly with those complying with global 2 °C targets. Notably, many scenarios exceed the Net-Zero Industry Act target for 2030 and project capture levels beyond historical uptake trends of clean energy technologies. The findings highlight that while long-term projections consistently foresee large-scale deployment of CO₂ capture across EU industry, near-term expectations remain modest and risk falling short of the 2030 needs.</div></div>","PeriodicalId":9387,"journal":{"name":"Carbon Capture Science & Technology","volume":"17 ","pages":"Article 100528"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145262792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}