Applied Organometallic Chemistry最新文献

{"title":"Gold-Catalyzed Highly Regioselective Hydration of Alkynylsulfonamides for Atom-Economic Synthesis of N-Ketosulfonamides","authors":"Yuguang Wang,&nbsp;Menghao Ma,&nbsp;Yunlong Deng,&nbsp;Panpan Yao,&nbsp;Agui Xing,&nbsp;Wenjing Li,&nbsp;Yuan Chen,&nbsp;Ji'an Wu","doi":"10.1002/aoc.70003","DOIUrl":"https://doi.org/10.1002/aoc.70003","url":null,"abstract":"<div>\u0000 \u0000 <p>Gold(I)-catalyzed highly regioselective hydration of alkynylsulfonamides for synthesis of N-ketosulfonamides in 85%–96% yields. The reaction used water as a nucleophile, which had the advantages of mild reaction conditions, good functional group tolerance, high regioselectivity, high yield, and 100% atomic economy (without generating by-products or waste). This might endow this method with great potential in green synthesis of N-ketosulfonamides compounds.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pd/C as a Heterogeneous Catalyst for Ligand-Free Homocoupling Reaction of Halo Compounds in Water and Total Synthesis of Daclatasvir","authors":"Mouzma Mhate,&nbsp;Moumita Khanra,&nbsp;Nilotpal Saharia,&nbsp;P. Radhakrishnanand,&nbsp;V. Ravichandiran,&nbsp;Sharada Prasanna Swain","doi":"10.1002/aoc.8006","DOIUrl":"https://doi.org/10.1002/aoc.8006","url":null,"abstract":"<div>\u0000 \u0000 <p>The United Nations sustainable development goals 9 and 12 discuss about adoption of sustainable and green chemistry concept for manufacturing of pharmaceuticals and chemicals. Water is universally accepted as a green solvent for organic reactions, and solvent-free reactions are considered as green, sustainable methods for synthesis of heterocyclic compounds. Pd/C is a heterogeneous, recyclable catalyst and has been used for several cross-coupling reactions. A ligand-free Pd/C-catalyzed homocoupling reaction of haloarenes in water is reported. The reaction condition is mild (reaction temp. 40°C), and the desired products were isolated in moderate to good yield (56%–81%). Activation of phase transfer catalyst under microwave irradiation reduced the catalyst loading and reaction time (from 24 h to 30 min). The major advantages of this method over existing methods are (i) ligand-free homocoupling reaction, (ii) lower Pd/C catalyst loading, and (iii) use of water as a green and sustainable solvent. This reaction along with continuous-flow bromination, and amine deprotection reactions were successfully applied for synthesis of antiviral drug daclatasvir.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Sulfates on the Reaction Pathway Over CeO2-Based Catalyst for NH3-SCR","authors":"Zhongxian Song,&nbsp;Ruihua Guo,&nbsp;Mengru Zhang,&nbsp;Hongpan Liu,&nbsp;Yanli Mao,&nbsp;Zhenzhen Huang,&nbsp;Deming Gu,&nbsp;Haiyan Kang,&nbsp;Jinhui Zhang,&nbsp;Xuejun Zhang","doi":"10.1002/aoc.70005","DOIUrl":"https://doi.org/10.1002/aoc.70005","url":null,"abstract":"<div>\u0000 \u0000 <p>CeO₂-H₂SO₄ (C-S), CeO₂-TiO₂ (C-T), and CeO₂-TiO₂-H₂SO₃ (C-T-S) were used for the selective catalytic reduction of NO with NH₃ (NH₃-SCR). Nearly 100% NO_<i>x</i> conversion of C-T-S was achieved at 250°C–450°C. When the concentration of Ce₂(SO₄)₃ was excessively high, it causes tightly binding with Ce³⁺ ions in CeO₂, prevents some Ce³⁺ ions from effectively participating in redox reactions, and results in the inferior SCR activity. Consequently, C-T-S possessed the superior catalytic performance due to the optimal content of sulfates. Furthermore, the presence of NO₂ facilitated the rapid SCR reaction on C-T-S, thereby further enhancing the catalytic activity. Additionally, the formation of Ce₂(SO₄)₃ on C-T-S could increase the number of acid sites, particularly Brönsted acid sites, resulting in the improvement of SCR performance. C-S, C-T, and C-T-S mainly followed the Langmuir–Hinshelwood (L–H).</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Luminescent Lanthanide MOF for the Selective and Ultra-High Sensitivity Detection of Caffeic Acid","authors":"Yufen Li,&nbsp;Xiaomei Wang,&nbsp;Zhenqi Tan,&nbsp;Lanqing Liu,&nbsp;Qicheng Wang,&nbsp;Tao Yang,&nbsp;Xinhui Zhou,&nbsp;Zhigang Niu","doi":"10.1002/aoc.8002","DOIUrl":"https://doi.org/10.1002/aoc.8002","url":null,"abstract":"<div>\u0000 \u0000 <p>A novel metal–organic framework (MOF) [Eu₃L₄(CH₃COO) (H₂O)₇]·(CH₃CN)₅ (<b>1</b>) based on the ligand H₂L (3′,5′-di(1H-1,2,4-triazole-1-yl)-[1,1′-biphenyl]-3,5-dicarboxylic acid) has been synthesized by the hydrothermal method. A complete characterization of <b>1</b> was conducted, employing a range of techniques including crystallography, PXRD, SEM, FTIR spectroscopy, and TGA analysis. The fluorescence sensing behavior of <b>1</b> was examined in a solution of <i>N,N-</i>dimethylformamide (DMF). The results demonstrated that <b>1</b> exhibited a pronounced “turn-off” fluorescence phenomenon in the presence of caffeic acid (CA). Despite the interference of 11 potential substances, <b>1</b> was still capable of effectively recognizing CA. The luminescence intensity ratio of <b>1</b> showed a strong linear relationship with CA concentration in the range 0–5 μM. The K_sv value was 2.49 × 10⁵ M⁻¹. Additionally, the detection mechanism was studied using PXRD, SEM, UV–Vis, and fluorescence lifetime methods.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characterization of Cs2AgInCl6: Bridging Optical and Electrical Properties for Advanced Optoelectronic Applications","authors":"Achref Jebnouni,&nbsp;Abdullah A. Alatawi,&nbsp;Mohamed Bouzidi,&nbsp;Ahlam F. Alshammari,&nbsp;Amjad Salamah Aljaloud,&nbsp;Mona A. F. Alshammari,&nbsp;Maher Jebali,&nbsp;Mohamed Ben Bechir","doi":"10.1002/aoc.8000","DOIUrl":"https://doi.org/10.1002/aoc.8000","url":null,"abstract":"<div>\u0000 \u0000 <p>Lead-free double perovskites, such as Cs₂AgInCl₆, represent a promising class of materials for optoelectronic applications due to their favorable properties and environmental sustainability. This work focuses on the synthesis and comprehensive characterization of Cs₂AgInCl₆, employing a range of techniques including X-ray diffraction (XRD) for structural verification, thermogravimetric analysis (TGA) to assess thermal stability, and UV–visible absorption measurements to determine the optical bandgap energy of 3.32 eV. Additionally, we explore photoluminescence (PL) and decay measurements to elucidate the luminescent properties of the compound. Complex impedance measurements are performed under both blue and red light to investigate the electrical behavior, revealing two distinct conduction mechanisms: the overlapping large–polaron tunneling (OLPT) and nonoverlapping small–polaron tunneling (NSPT). We analyze the implications of our findings on the current–voltage (I–V) behavior and trap density, further supported by Raman spectroscopy under both illumination conditions. The combined insights from optical and electrical characterizations highlight the potential of Cs₂AgInCl₆ in optical applications, paving the way for its use in advanced optoelectronic devices.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143117281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Theoretical Insights and Anticancer Potential of 2,6-Bis((E)-(2-amino-4-nitrophenylimino)methyl)-4-methoxyphenol and Its Binuclear Cu(II) Complex","authors":"S. Praveen,&nbsp;G. Parinamachivayam,&nbsp;P. Jeyaraman,&nbsp;R. Prabakarakrishnan,&nbsp;A. Natarajan,&nbsp;K. Geetha,&nbsp;Arunachalam Chinnathambi,&nbsp;Sulaiman Ali Alharbi,&nbsp;Arivalagan Pugazhendhi,&nbsp;Sabariswaran Kandasamy","doi":"10.1002/aoc.7984","DOIUrl":"https://doi.org/10.1002/aoc.7984","url":null,"abstract":"<div>\u0000 \u0000 <p>This study explores the synthesis and applications of a new Schiff base, 2,6-bis((<i>E</i>)-(2-amino-4-nitrophenylimino)methyl)-4-methoxyphenol (HL), and its copper(II) complexes. The Schiff base was prepared by reacting 2-amino-4-nitroaniline with 2,6-diformyl-4-methoxyphenol and characterized using techniques like microanalysis, UV–Vis, IR spectroscopy, ¹H-NMR, and LC–MS, confirming its structure. Theoretical studies provided insights into its molecular geometry and electronic properties. Cyclic voltammetry of the copper complex revealed diffusion-controlled electrochemical behavior, involving a single-electron transfer. Both the Schiff base and its Cu(II) complexes exhibited promising anticorrosion and anticancer activities, highlighting their multifunctional potential in industrial and biomedical applications. This study emphasizes the importance of comprehensive characterization in developing innovative materials with practical uses.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143116713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring the Antiplasmodial and Antimicrobial Potential of Transition Metal(II) Complexes Bearing Hydrazone Ligands: Insights From Molecular Docking and ADMET Studies","authors":"Manju Rani,&nbsp;Jai Devi,&nbsp;Binesh Kumar,&nbsp;Rajesh Khurana","doi":"10.1002/aoc.7965","DOIUrl":"https://doi.org/10.1002/aoc.7965","url":null,"abstract":"<div>\u0000 \u0000 <p>In the search of antiplasmodium agents, the hydrazone ligands, that is, (2-hydroxy-5-nitrobenzylidene)benzo[b]thiophene-2-carbohydrazone <b>(H</b>_<b>2</b><b>L</b>^<b>1</b><b>)</b>/(3,5-dichloro-2-hydroxybenzylidene)benzo[b]thiophene-2-carbohydrazone <b>(H</b>_<b>2</b><b>L</b>^<b>2</b><b>)</b> and their Co(II), Ni(II), Cu(II), and Zn(II) metal complexes were synthesized. All the compounds were well characterized by wide range of spectral and physical techniques, that is, FT-IR, ¹H NMR, ¹³C NMR, ESR, mass spectrometry, UV-Vis, XRD, SEM-EDAX, molecular conductivity, and thermal studies (TG-DTA). The coordination by O-phenolic, O-enolic, and N-azomethine donor atoms and three aqua ligands to metal(II) ions was confirmed by various physicochemical techniques, affirming the octahedral geometry of the metal complexes. Biological evaluation of the synthesized compounds involved assessing by their antiplasmodium potency utilizing microassay and antimicrobial activities using serial dilution technique. The Cu(II) (<b>5</b>, <b>6</b>) and Zn(II) (<b>9</b>, <b>10</b>) metal complexes significantly inhibited the growth of parasitic ailments caused by <i>Plasmodium falciparum</i> 3D7 strain and also exhibited remarkable antimicrobial effectiveness against diseases caused by microbes comparable with the standard drugs (ciprofloxacin and fluconazole). Moreover, theoretical study including molecular docking was employed utilizing 3,5-dihydroxy-2-naphthoic acid (<b>PDB:1U5A</b>) <i>P. falciparum</i> protein receptor to validate the antiplasmodium effectiveness of the most potent H₂L¹ hydrazone ligand (<b>1</b>) and their complexes (<b>3</b>–<b>6</b>). This analysis indicated that the docked compounds could serve as a promising drug candidate for malaria. whereas the ADMET profiling authenticated the drug-like features of compounds <b>1</b> and <b>3</b>–<b>6</b>. Thus, this research provides fresh perspectives for in vivo study of the compounds with minor developments.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143116740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Structural Analysis, and Catalysis for Suzuki–Miyaura Coupling Reactions of Tetradentate N^C^C^N and Tetracarbene C^C^C^C Nickel–N-Heterocyclic Carbene Complexes","authors":"Chen Gao,&nbsp;Wen-Qi Luo,&nbsp;Xiao Xiao,&nbsp;Hai-Juan Shuai,&nbsp;Ling-Ying Chen,&nbsp;Chuan-Ming Jin","doi":"10.1002/aoc.7971","DOIUrl":"https://doi.org/10.1002/aoc.7971","url":null,"abstract":"<div>\u0000 \u0000 <p>Four novel Ni(II)–<i>N</i>-heterocyclic carbene (Ni–NHC) complexes were synthesized and characterized by NMR, ESI–MS, SEM, TEM, EDS mapping, XPS, and single-crystal X-ray diffraction (XRD) analysis. Ni–NHC complexes <b>7</b> and <b>8</b> are intramolecular tetradentate N^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}N-cyclometalated [1L + 1M] complex featuring coplanar of azole and quinoline rings, and Ni–NHC complex <b>11</b> is an interligand tetracarbene C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>-cyclometalated [2L + 1M] complex with two six-membered, conformation of boat-shaped, C_<i>NHC</i>^{^}C_<i>NHC</i>-cyclometalated structural units. Complex <b>9@Ni–NHC</b> is a softly fluffy black powder with the surface morphology of a tightly arranged honeycomb-like pore structure and may be an interligand tetracarbene C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>-cyclometalated [2L + 1M] structure containing a very small amount of Ni⁰ state. DFT calculations suggested enhanced stability for tetracarbene C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>^{^}C_<i>NHC</i>-cyclometalated complexes <b>9@Ni–NHC</b> and <b>11</b>. Cyclic voltammetry studies shown that complexes <b>7</b>, <b>8</b>, and <b>9@Ni–NHC</b> have similar redox properties of two pairs of redox peaks, and complex <b>11</b> displays only one reversible redox process with half-wave potentials at <i>E</i>_1/2 = −0.864 V. All complexes were found to be efficient catalysts for the Suzuki–Miyaura cross-coupling reaction, and complexes <b>7</b> and <b>8</b> display better catalytic activity than complexes <b>9@Ni–NHC</b> and <b>11</b> and exhibit catalytic activity comparable to Pd(OAc)₂ catalyst, which may be attributed to the intraligand chelating tetradentate coordination and the coplanar conjugate effect between the azole and quinoline rings.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143116739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluating Electronic Properties of Self-Assembled Inner Hollow (InAs)12n (n = 1–16) Nanomaterials With High Solar Light-to-Electricity Efficiencies Using First Principle Modeling","authors":"Run-Ning Zhao,&nbsp;Rui Chen,&nbsp;Ju-Guang Han","doi":"10.1002/aoc.7985","DOIUrl":"https://doi.org/10.1002/aoc.7985","url":null,"abstract":"<div>\u0000 \u0000 <p>Geometries and electronic properties associated with growth patterns, energy gaps, and relative stabilities of (InAs)_12n (<i>n</i> = 1–16) nanowires and nanosheets (nanoclusters) are systemically investigated at the GGA-PBE level. The relative stabilities of (InAs)_12n by means of the calculated fragmentation energies and cluster binding energies are determined and discussed. Particularly, the calculated energy gaps of (InAs)_12n nanowires (2.261<b>–</b>2.271 eV) and nanosheets (2.228<b>–</b>2.412 eV) are distinctly localized at the regions of visible light energy ranges, indicating that large-sized (InAs)_12n nanosheets or nanowires are relatively wide-band semiconductor nanomaterial; the calculated density of states reveals large-sized porous (InAs)_12n nanosheets and nanowires with a large surface area and narrow pore size distribution and slight thickness exhibit ultrahigh specific capacitance of trapping solar light energies and high light-to-electricity conversion efficiencies in solar energy absorption or conversion or photovoltaics. Consequently, (InAs)_12n-based nanomaterials are favorable for optoelectronic and energy miniaturized devices. Interestingly, the variable sizes depended energy gaps of (InAs)_12n nanosheets manifest quantum size effect. Especially, the gradually increased charge-transfers in large size (InAs)_12n nanowires and nanosheets with their sizes can significantly lead to the ionic bonding and metallic characteristic, which can stabilize themselves. Comparison with experiment results available is made.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polyaspartic Acid–Based Porous Carbon–Loaded Nickel Metal and Its Application to Hydrogen Adsorption","authors":"Mingqiu Lu,&nbsp;Huimin Zhu,&nbsp;Ling Liu,&nbsp;Meilin Jiang,&nbsp;Qiulan Shi,&nbsp;Jianbo Zhao","doi":"10.1002/aoc.8005","DOIUrl":"https://doi.org/10.1002/aoc.8005","url":null,"abstract":"<div>\u0000 \u0000 <p>Hydrogen energy plays an important role as a clean, renewable resource in replacing traditional fossil energy sources, and in this study, a polyaspartic acid (PASP) porous carbon loaded with metallic nickel was prepared for hydrogen storage. The PASP porous carbon loaded with nickel metal was successfully prepared by high-temperature pyrolysis and metal-solution impregnation using homemade PASP hydrogels as raw material. Compared to ordinary carbon materials, the addition of K⁺ as a porogenic agent to the material before carbon formation makes its pore structure rich and adjustable. In addition, nickel as an active site optimizes the overall electronic structure and surface properties of the material, which together increase the gas adsorption capacity. The materials of PASP, PASP porous carbon, and PASP porous carbon loaded with metallic nickel were also characterized by FTIR, SEM, BET, TEM, EDS, XRD, and XPS, and finally applied to hydrogen adsorption. The results show that C-PASP-50% has the best adsorption effect on hydrogen with different degrees of cross-linking, and the adsorption capacity can reach 126.49 cm³/g. The adsorption capacity increases significantly after loading metal nickel, and the adsorption capacity of C-PASP-Ni50% reaches 273.03 cm³/g.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}