K. Priyadharsini Karthikeyan, A. G. Bharathi Dileepan, G. Murali, Natarajan Arumugam, Abdulrahman I. Almansour, Madhappan Santhamoorthy, S. Jeyaram
{"title":"利用假山茱萸叶提取物绿色合成纳米银:表征及其非线性光学应用","authors":"K. Priyadharsini Karthikeyan, A. G. Bharathi Dileepan, G. Murali, Natarajan Arumugam, Abdulrahman I. Almansour, Madhappan Santhamoorthy, S. Jeyaram","doi":"10.1002/aoc.70367","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>This study reports the synthesis of silver nanoparticles (AgNPs) using leaf extract of <i>Justicia adhatoda</i>. This green and eco-friendly method produces highly stable AgNPs, which are characterized using various techniques, including UV–visible absorbance, FT-IR, XRD, FESEM, and TEM. A strong surface plasmon resonance (SPR) is observed at a wavelength of 411 nm. The functional groups present in the AgNPs are identified using FT-IR, revealing a peak at 456 cm<sup>−1</sup> corresponding to Ag<sup>+</sup> bond vibration. The crystalline properties of AgNPs are examined via XRD, with an average crystal size measured at 23.33 nm. Moreover, FESEM and TEM studies revealed that the nanoparticles possess a spherical shape. The Z-scan technique is employed at a wavelength of 405 nm to investigate the third-order nonlinear optical (NLO) responses of AgNPs. The nonlinear refractive index (<i>n</i><sub>2</sub>) and nonlinear absorption coefficient (<i>β</i>) are attributed to self-defocusing and reverse saturable absorption (RSA) processes. A significant third-order NLO susceptibility is measured, estimated to be in the order of 10<sup>−7</sup> esu. Overall, the experimental results clearly indicate that the green synthesis of AgNPs using the leaf extract of <i>Justicia adhatoda</i> represents a promising material for NLO applications.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 9","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green Synthesis of Silver Nanoparticles Using Justicia adhatoda Leaf Extract: Characterization and Nonlinear Optical Applications\",\"authors\":\"K. Priyadharsini Karthikeyan, A. G. Bharathi Dileepan, G. Murali, Natarajan Arumugam, Abdulrahman I. Almansour, Madhappan Santhamoorthy, S. Jeyaram\",\"doi\":\"10.1002/aoc.70367\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>This study reports the synthesis of silver nanoparticles (AgNPs) using leaf extract of <i>Justicia adhatoda</i>. This green and eco-friendly method produces highly stable AgNPs, which are characterized using various techniques, including UV–visible absorbance, FT-IR, XRD, FESEM, and TEM. A strong surface plasmon resonance (SPR) is observed at a wavelength of 411 nm. The functional groups present in the AgNPs are identified using FT-IR, revealing a peak at 456 cm<sup>−1</sup> corresponding to Ag<sup>+</sup> bond vibration. The crystalline properties of AgNPs are examined via XRD, with an average crystal size measured at 23.33 nm. Moreover, FESEM and TEM studies revealed that the nanoparticles possess a spherical shape. The Z-scan technique is employed at a wavelength of 405 nm to investigate the third-order nonlinear optical (NLO) responses of AgNPs. The nonlinear refractive index (<i>n</i><sub>2</sub>) and nonlinear absorption coefficient (<i>β</i>) are attributed to self-defocusing and reverse saturable absorption (RSA) processes. A significant third-order NLO susceptibility is measured, estimated to be in the order of 10<sup>−7</sup> esu. Overall, the experimental results clearly indicate that the green synthesis of AgNPs using the leaf extract of <i>Justicia adhatoda</i> represents a promising material for NLO applications.</p>\\n </div>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"39 9\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70367\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70367","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Green Synthesis of Silver Nanoparticles Using Justicia adhatoda Leaf Extract: Characterization and Nonlinear Optical Applications
This study reports the synthesis of silver nanoparticles (AgNPs) using leaf extract of Justicia adhatoda. This green and eco-friendly method produces highly stable AgNPs, which are characterized using various techniques, including UV–visible absorbance, FT-IR, XRD, FESEM, and TEM. A strong surface plasmon resonance (SPR) is observed at a wavelength of 411 nm. The functional groups present in the AgNPs are identified using FT-IR, revealing a peak at 456 cm−1 corresponding to Ag+ bond vibration. The crystalline properties of AgNPs are examined via XRD, with an average crystal size measured at 23.33 nm. Moreover, FESEM and TEM studies revealed that the nanoparticles possess a spherical shape. The Z-scan technique is employed at a wavelength of 405 nm to investigate the third-order nonlinear optical (NLO) responses of AgNPs. The nonlinear refractive index (n2) and nonlinear absorption coefficient (β) are attributed to self-defocusing and reverse saturable absorption (RSA) processes. A significant third-order NLO susceptibility is measured, estimated to be in the order of 10−7 esu. Overall, the experimental results clearly indicate that the green synthesis of AgNPs using the leaf extract of Justicia adhatoda represents a promising material for NLO applications.
期刊介绍:
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.