Applied Organometallic Chemistry最新文献

{"title":"Efficient Photocatalytic Degradation of Rhodamine B With Heterostructured CdS/Mn-MOF Composite","authors":"Huan Zhang,&nbsp;Wen-Qi Jin,&nbsp;Peng Li,&nbsp;Wei Gao,&nbsp;Xiu-Mei Zhang","doi":"10.1002/aoc.70141","DOIUrl":"https://doi.org/10.1002/aoc.70141","url":null,"abstract":"<div>\u0000 \u0000 <p>A highly efficient photocatalyst, the CdS/Mn-MOF composite, was synthesized by first preparing a new 2D Mn-MOF (Mn(L)·H₂O, H₂L = 5-(2-benzothiazolyl)isophthalic acid) precursor through the solvothermal method and subsequently growing CdS nanoparticles. X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), UV–vis spectroscopy, and other techniques were utilized to characterize the structural, morphological, textural, compositional, and optical properties of the composites. The prepared photocatalysts, designated as X-CdS/Mn-MOF (where <i>X</i> = 50, 25, and 10, represents the mass percentage of CdS), were tested for photocatalytic performance. Among them, the 50-CdS/Mn-MOF sample exhibits the optimized degradation efficiency of 99.1% for Rhodamine B (RhB, 20 mg/L) in 50 min under visible light irradiation, which is 7.3 times and 2.4 times higher than that of Mn-MOF and CdS, respectively. Various test results indicate that the improved photocatalytic activity of CdS/Mn-MOF composites can be attributed to the formation of heterojunctions. Specifically, the heterojunctions enhance the separation efficiency of photogenerated carriers and effectively suppress the recombination of electrons and holes, thereby improving the overall efficiency of the photocatalytic reaction. Moreover, the presence of heterojunctions optimizes the material's band structure, facilitating more efficient carrier transport, which further enhances photodegradation performance. Radical quenching experiments confirmed hydroxyl radicals (·OH⁻) and superoxide radical anions (·O₂⁻) played dominant roles in the photodegradation process. Additionally, the composite material also demonstrates good stability and reproducibility. The research further provides evidence that the efficiency of dye degradation can be significantly improved by the rational design of composite catalysts consisting of other semiconductors and MOFs.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural Diversity and Fluorescent Sensing for Antibiotics and Nitrobenzene of Cd-Based Sensors With Three Tricarboxylate Isomers","authors":"Xue Yang,&nbsp;Wanting Liu,&nbsp;Xiufang Hou,&nbsp;Zhixiang Wang,&nbsp;Yixia Ren","doi":"10.1002/aoc.70138","DOIUrl":"https://doi.org/10.1002/aoc.70138","url":null,"abstract":"<div>\u0000 \u0000 <p>Three novel Cd (II) coordination polymers (Cd-CPs) (<b>1–3)</b>, with the formula of [Cd(2-DBB)(1,4-bibz)(OH)]·H₂O(<b>1</b>), [Cd₃(3-DBB)(1,4-bibz)₂]·2H₂O(<b>2</b>), and [Cd(4-HDBB)(1,4-bibz)_0.5](<b>3</b>) based on three soft organic isomers: <i>n</i>-(3,5-dicarboxylato benzyloxy) benzoic acid (<i>n</i> = 2, 3, or 4-H₃DBB), and one linear N-donor ligand 1,4-bis(1-imidazoly) benzene (1,4-bibz) have been synthesized hydrothermally and characterized by X-ray single crystal diffraction, elemental analyses, thermogravimetric, UV, IR, and PXRD technologies. The significant structural differences are both coordination polymers <b>1</b> and <b>3</b> featuring 2D networks, but <b>2</b> with 3D framework due to the change of H₃DBB isomers. Despite structural differences, the series of Cd-CPs exhibits similar fluorescence sensing properties for nitrobenzene (NB) with low detection limits of 1.05 μM (<b>1</b>), 44.3 nM (<b>2</b>), and 59.1 nM (<b>3</b>), respectively. However, these Cd-CPs have been discovered to detect different antibiotics, respectively: <b>1</b> had a quenching effect on ornidazole (ONZ) but <b>2</b> and <b>3</b> on chloramphenicol (CHI). The results of the theoretical calculation verified the fluorescence detection mechanism by these Cd-CPs. Therefore, these Cd-CPs might be potential luminescent sensing materials for antibiotics and NB in the future.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"New Copper and Cobalt Complexes Based on a Fluorinated Pyrazole Derivative, Synthesis, Characterization and Antibacterial Activity","authors":"Mina A. Amin,&nbsp;Halide Diker,&nbsp;Onur Şahin,&nbsp;Canan Varlikli,&nbsp;Ahmed A. Soliman","doi":"10.1002/aoc.70140","DOIUrl":"https://doi.org/10.1002/aoc.70140","url":null,"abstract":"<div>\u0000 \u0000 <p>Two copper and cobalt complexes based on 3-(trifluoromethyl)-4-((3-(trifluoromethyl)phenyl)diazenyl)-1H-pyrazol-5-ol (Httdp) have been prepared and characterized using different physicochemical techniques. The crystal structure of the copper complex has been proven to be a square pyramidal, and the cobalt complex has an octahedral structure. DFT calculations of the complexes were performed, and the energy gaps between the HOMO–LUMO of the complexes (−3.38676 to −3.18138 eV) and the Cu (II) complex reflect a higher relative stability compared with Httdp and the Co (II) complex. The antibacterial activities of the two complexes were evaluated. The Co (II) complex demonstrated the highest antibacterial activity against various bacteria compared with Httdp and the Cu (II) complex. The mean inhibition zones exhibited by the Co (II) complex showed the highest activities toward the Gram-negative bacterial strains with mean inhibition zones of 30.3 ± 0.6 (<i>Staphylococcus aureus</i>) and 25.7 ± 0.6 (<i>Bacillus subtilis</i>) mm. Docking studies were carried out using <i>S. aureus</i> tyrosyl-tRNA synthetase (PDB ID: 1JIJ) to assess the antimicrobial activities, proving that the complexes were efficient for the protein.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Multifunctional Fe-Based Metal–Organic Framework With Ferroptosis for Synergistic Therapy","authors":"Lu Hong,&nbsp;Qiaoyu Chen,&nbsp;Lei Rao,&nbsp;Zhen Wang,&nbsp;Bing Wang,&nbsp;Qing He,&nbsp;Wenxin Lin","doi":"10.1002/aoc.70143","DOIUrl":"https://doi.org/10.1002/aoc.70143","url":null,"abstract":"<div>\u0000 \u0000 <p>Generally, single cancer treatment is insufficient to achieve ideal therapeutic effect. Multimodal therapy has the potential to overcome efficacy challenges and reveals great promise in enhancing therapeutic effect. Herein, a combination treatment system (DOX@Fe-PBC) based on chemotherapy, chemodynamic therapy (CDT), and ferroptosis was constructed by loading anticancer drug doxorubicin hydrochloride (DOX) into Fe-based metal–organic framework (Fe-PBC). In simulated tumor microenvironment, the system released anticancer drug DOX to be a DNA intercalator and topoisomerase II inhibitor to realize chemotherapy (CT) and iron ions were delivered to induce Fenton reaction, which boost the generation of •OH, resulting in the enhancement of the effect of chemodynamic therapy (CDT). Meantime, the system could consume glutathione (GSH) to reduce the expression of glutathione peroxidase 4 (GPX4); then, lipid peroxides (LPO) were accumulated to realize ferroptosis. DOX@Fe-PBC provided an effective strategy of chemotherapy, CDT, and ferroptosis to realize ideal cancer treatment.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Scalar Relativistic DFT Study on the Complexation Behavior and Selective Separation of Th(IV)/U(VI) With Four Amide Ligands Containing N-Heterocycles","authors":"Canran Wu,&nbsp;Wenjun Ouyang,&nbsp;Yun Wang,&nbsp;Xianghe Kong,&nbsp;Xilin Xiao,&nbsp;Changming Nie,&nbsp;Guowen Peng","doi":"10.1002/aoc.70131","DOIUrl":"https://doi.org/10.1002/aoc.70131","url":null,"abstract":"<div>\u0000 \u0000 <p>Achieving efficient separation of thorium and uranium is one of the main technical challenges for the nuclear fuel cycle of thorium-based molten salt reactors. In this work, the scalar relativistic density functional theory (DFT) calculations were adopted to deeply unravel the complexation behaviors and separation selectivity of Th⁴⁺/UO₂²⁺ with four amide ligands L_A, L_B, L_C, and L_D containing <i>N</i>-heterocycles. The analyses of dihedral angle, bond length, WBIs, IGMH, and ETS-NOCV indicated that the four ligands were more likely to coordinate with Th⁴⁺ in gas phase and that the interactions between metal ions and carbonyl oxygens in complexation were stronger than those between metal ions and pyridine nitrogen atoms. The QTAIM analysis showed that the metal-O/N bonds were typical coordination bonds, and the EDA revealed that the electrostatic and orbital interactions provided major contributions to attractive interaction. The thermodynamic study exhibited that L_C and L_D had stronger complexation ability than L_A and L_B and that the separation selectivity of the four ligands for Th⁴⁺/UO₂²⁺ was closely related to the solvent types. It was easier for the ligands to bind with Th⁴⁺ in solvents with hydroxyl (as water, 1-butanol,1-shexanol, 1-octanol). However, the ligands were preferential to bind with UO₂²⁺ in solvents without hydroxyl group (as nitrobenzene, acetone, cyclohexanone, cyclohexanone, and methyl benzoate). The selectivity coefficients of these ligands for Th⁴⁺/UO₂²⁺were generally over 98%. This work not only provides theoretical insights for Th (IV)/U(VI) separation based on PBIMO ligands but also offers an effective strategy for nuclear fuel cycle of thorium-based molten salt reactors.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic Degradation of 4-Chlorophenol and 3-Chlorobenzoic acid via Organic Ligand–Assisted Fe(II)/Persulfate Activation: Molecular Pathways and Environmental Impacts","authors":"Palanisamy Vasudhevan,&nbsp;Dong Yu,&nbsp;Ruoyu Zhang,&nbsp;Mysoon M. Al-Ansari,&nbsp;Velu Manikandan,&nbsp;Hui Ma,&nbsp;Saurav Dixit,&nbsp;Shengyan Pu","doi":"10.1002/aoc.70103","DOIUrl":"https://doi.org/10.1002/aoc.70103","url":null,"abstract":"<div>\u0000 \u0000 <p>Chlorinated aromatic chemicals are highly hazardous, transmissible, and bioaccumulative. Developing an economically feasible catalytic method to facilitate the effective removal of chlorinated aromatic pollutants is critical for contamination prevention. The current study extensively investigated the utilization of organic ligands such as citrate (CA) and ethylenediaminetetraacetic acid (EDTA) to increase Fe(II)-activated persulfate (PS) for 4-chlorophenol (4-CP) and 3-chlorobenzoic acid (3-CB) degradation in water. The decomposition and consumption ability of persulfate in PS alone and Fe(II)/PS systems for 4-CP and 3-CB was very low because of the rapid utilization as well as discontinuous availability of Fe(II), which indicates the decline of Fe(III) to Fe(II). But, when using the citrate/Fe(II)/PS and EDTA/Fe(II)/PS combinations, the degradation of 4-CP and 3-CB was 78.86%, 75.01% and 84.84%, 80.99% within 30 min, respectively. The significant enhancement is due to both ligand-to-metal transfer of charges process, and this increased the process of rate determination through carrying electrons into the citrate and EDTA ligands to Fe(III), generating Fe(II). In addition, the 4-CP and 3-CB degradation facilitated with citrate/Fe(II)/PS and EDTA/Fe(II)/PS systems was efficiently degraded at acidic pH (2.0–6.0) conditions. The pseudo-first-order kinetics model accurately predicted 4-CP and 3-CB degradation in the organic ligand/Fe(II)/PS systems. The degradation percentage of 4-CP and 3-CB increased with increasing PS and Fe(II) concentrations. Moreover, both sulfate and hydroxyl radicals formed by citrate/Fe(II)/PS and EDTA/Fe(II)/PS systems were identified as major reactive oxygen species for 4-CP and 3-CB decomposition. The present investigation recommends an alternate strategy to enhance the Fe(II)-activated persulfate mechanisms.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green Formulation, Chemical Characterization, and Neuroprotective Properties of Green Tea Green-Synthesized Copper Nanoparticles","authors":"Lufei Shao,&nbsp;Ping Yang,&nbsp;Xiaoxin He,&nbsp;Leilei Lin,&nbsp;Jinfang Liu,&nbsp;Aicui Liu,&nbsp;Di Xue,&nbsp;Xue Lin,&nbsp;Xiaolei Chen","doi":"10.1002/aoc.70137","DOIUrl":"https://doi.org/10.1002/aoc.70137","url":null,"abstract":"<div>\u0000 \u0000 <p>Cu NPs are utilized in medicine to improve the central nervous system's physiological function. In addition, green tea is a neuroprotective ingredient in several traditional medications. As a novel neuroprotective supplement, we chose to create Cu NPs in an aqueous medium with green tea leaf extract in the most recent work. Cu NPs were characterized using the standard characterization procedures, which include FE-SEM, EDX, XRD, and FTIR spectroscopy. The creation of Cu NPs is approved by the presence of signals in the EDX diagram for C Lα, O Lα, and Cu Lα. The size range of the produced Cu NPs was usually 10–30 nm. The nanoparticles showed crystalline shape and homogeneity. The hydrogen-bonded phenolic O-H group stretching vibrations are related to a wide peak seen at 3422 cm⁻¹. The trypan blue test was applied to determine PC12 cell viability in the biological portion of the current investigation. Rhodamine123 fluorescent dye was applied to examine the MMP, and the caspase activity colorimetric test kit was used to measure caspase-3 activity. Apoptosis and DNA fragmentation were demonstrated using terminal deoxynucleotidyl transferase dUTP nick end labeling (TUNEL) assay. The inflammatory cytokines concentrations were measured using the ELISA. Additionally, in the high concentration of nicotine-treated PC12, Cu NPs-treated cell cutlers dramatically (<i>p</i> ≤ 0.01) increased the MMP and cell survival while lowering the levels of DNA fragmentation. Our study's key conclusion showed that green tea-containing copper nanoparticles inhibited the cell death caused by nicotine in PC12 neuron-like cells. According to the clinical trial, Cu NPs may be used as a neuroprotective supplement to treat illnesses of the central nervous system.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143761914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tuning In Vitro Cytotoxicity in Diruthenium(I) bis-Cyclopentadienyl Complexes","authors":"Benedetta Bertoncini,&nbsp;Kseniya Glinkina,&nbsp;Stefano Zacchini,&nbsp;Paul J. Dyson,&nbsp;Lorenzo Biancalana,&nbsp;Fabio Marchetti","doi":"10.1002/aoc.70133","DOIUrl":"https://doi.org/10.1002/aoc.70133","url":null,"abstract":"<div>\u0000 \u0000 <p>A series of diruthenium(I) aminocarbyne complexes of general formula [Ru₂Cp₂(CO)(L)(μ-CO){μ-CNMe (Cy)}]⁺ (L = NH₃, [<b>2</b>]⁺; Py, [<b>3</b>]⁺, PPh₃, [<b>4</b>]⁺; DMSO, [<b>5</b>]⁺; thiourea, [<b>6</b>]⁺) and [Ru₂Cp₂(μ-H)(CO)₂{μ-CNMe (Cy)}], <b>7</b>, were prepared from the tricarbonyl precursor [Ru₂Cp₂(CO)₂(μ-CO){μ-CNMe (Cy)}]⁺. The reactivity of the diruthenium(I) vinyliminium complex [Ru₂Cp₂(CO)(μ-CO){μ-η¹:η³-C (Ph)CHCNMe (Cy)}]⁺, was also investigated, providing access to piano stool Ru (II) cyclopentadienyl complexes with a five-membered metallacyclic ligand containing sulfur. The new compounds were characterized by IR and multinuclear NMR spectroscopy and X-ray diffraction (in three cases). The solubility in water, lipophilicity, and the speciation of [<b>2</b>–<b>6</b>]CF₃SO₃ in water/DMSO and cell culture medium are regulated by different monodentate ligands. Subsequently, [<b>1</b>,<b>3</b>–<b>6</b>]⁺ were tested in vitro against human ovarian cancer cells (A2780 and A2780cis) and embryonic kidney cells (HEK293), demonstrating moderate to potent cytotoxicity.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143762244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrosilylation of Ketones With Manganese(I) Thiopyridine Catalysts","authors":"Antonia Reisenhofer,&nbsp;Ferdinand Belaj,&nbsp;Malek Y. S. Ibrahim,&nbsp;Nadia C. Mösch-Zanetti","doi":"10.1002/aoc.70129","DOIUrl":"https://doi.org/10.1002/aoc.70129","url":null,"abstract":"<p>Hydrosilylation of ketones using manganese complexes has emerged as an efficient and safer alternative to traditional reduction methods. Reported manganese(I) systems are typically monomeric Mn(I) carbonyl bromide catalysts, while dimeric systems have remained largely unexplored. Here, three manganese complexes of the dimeric type [{Mn(6-R-PyS)(CO)₃}₂] (R = H <b>1</b>, CH₃ <b>2</b>, CF₃ <b>3</b>) featuring thiopyridine ligands and Mn₂S₂ cores are found to be catalysts in the visible light-induced hydrosilylation of ketones at room temperature. Notably, optimal reactivity was achieved when the irradiation wavelength was set at 427 nm. Furthermore, a catalyst loading of 0.1 mol% was sufficient to achieve full conversion within 90 min over a wide scope of acetophenones and aliphatic ketones. However, the reactivity was drastically reduced when the sterically demanding, electron withdrawing CF₃ group was introduced to the ligand. An induction time of 10 min was observed that can be attributed to the formation of the active species, after which the reaction was found to proceed without irradiation. Further investigations into the mechanism revealed that upon irradiation of solutions of the complexes, CO is released forming an undefined paramagnetic species. In conclusion, for fast catalysis with the dinuclear Mn(I) complexes sterically unhindered ligands and activation with light are required. Furthermore, the catalytic reaction is amenable to continuous flow chemistry as exemplified by the hydrosilylation of acetophenone with 0.1 mol% of catalyst <b>1</b>. When carried out in a photoflow reactor, the reaction is completed after 14.2-min resistant time.</p>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.70129","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Zn (II) Complexes Synthesized With Salamo-Type Ligand as a Highly Efficient Sensor to Detect MnO4− in Aqueous Solution","authors":"Na Tuo,&nbsp;Le-Le Liu,&nbsp;Jia-Ying Ren,&nbsp;Yang Zhang,&nbsp;Li Wang","doi":"10.1002/aoc.70096","DOIUrl":"https://doi.org/10.1002/aoc.70096","url":null,"abstract":"<div>\u0000 \u0000 <p>Herein, Three Salamo-type Zn (II) complexes [Zn₂(L)(<i>μ</i>-OAc)]·CH₃OH (<b>1</b>), [Zn₄(L)₂]Cl₂ (<b>2</b>), [Zn₄(L)₂](NO₃)₂ (<b>3</b>) is synthesized as the fluorescence probe for ultrasensitive detection of MnO₄⁻ in aqueous solution. The structure analysis shows that complex <b>1</b> is a binuclear structure, while complexes <b>2</b> and <b>3</b> is a symmetric tetranuclear structure. Three complexes exhibited high stability of fluorescence intensity in aqueous solvent. The detection limit is 8.8, 12.8 and 13.8 μM. The anions involved in coordination in complex <b>1</b> undergo structural changes due to their different coordination modes compared with complexes <b>2</b> and <b>3</b>, resulting in better detection performance than the other two complexes. Zn (II) complexes have good selectivity and applicability for the determination of MnO₄⁻ in aqueous solutions. At the same time, the sensing effect in the real water samples was also detected. In addition, the fluorescence recognition mechanisms of three complexes for the detection of the above analytes were explored in detail.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}