Applied Organometallic Chemistry最新文献

{"title":"Two Coordination Polymers Based on Rigid Benzimidazole Carboxylic Acid Ligands: Electrode Performance and Adsorption of Dyes","authors":"Bo-Yu Liu,&nbsp;Jian Zhao,&nbsp;Tao Zeng,&nbsp;Tian-Cai Yue,&nbsp;Lu-Lu Wang,&nbsp;Duo-Zhi Wang","doi":"10.1002/aoc.7982","DOIUrl":"https://doi.org/10.1002/aoc.7982","url":null,"abstract":"<div>\u0000 \u0000 <p>Two new cobalt-based coordination polymers (CPs) based on two different benzimidazole carboxylic acid ligands, namely, {[Co(<b>L</b>^<b>1</b>)(H₂O)₂]₂SiF₆·(H₂O)₂}_n (<b>1</b>) and {[Co(<b>L</b>^<b>2</b>)(H₂O)₂]₂SiF₆·(H₂O)₂}_n (<b>2</b>) (H<b>L</b>^<b>1</b> = 2-[1<i>H</i>-imidazol-5-yl]-1<i>H</i>-benzimidazole-6-carboxylic acid and H<b>L</b>^<b>2</b> = 2-[1<i>H</i>-imidazol-2-yl]-1<i>H</i>-benzimidazole-6-carboxylic acid), were synthesized via solvothermally method. Structural analysis revealed that <b>CP-1</b> featured a two-dimensional planar structure, while <b>CP-2</b> exhibited a one-dimensional chain structure. <b>CP-1</b> achieved a specific capacitance of 658.6 F g⁻¹ at a current density of 1 A g⁻¹ and retained good capacitance after charge–discharge cycling tests. In addition, both <b>CP-1</b> and <b>CP-2</b> showed good adsorption performance for the anionic dye Congo red (CR), and the maximum adsorption capacities were 1256 and 2985 mg g⁻¹, respectively.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrasonic-Assisted Adsorptive Uptake of Malachite Green Dye Onto Zn/Cu-Layered Double Oxide: Spectrophotometric and Smartphone-Based Detection","authors":"Bhamini Pandey,&nbsp;Poonam Singh,&nbsp;Ravinder Kumar","doi":"10.1002/aoc.7981","DOIUrl":"https://doi.org/10.1002/aoc.7981","url":null,"abstract":"<div>\u0000 \u0000 <p>In this work, efforts have been made to synthesize novel Zn/Cu-layered double oxide by performing calcination of Zn/Cu-layered double hydroxide, which was later used as an adsorbent for the uptake of toxic azo dye. Malachite green (MG) was used as a model cationic dye for assessing the practicability of dye wastewater treatment. From batch experiments study, it was evident that ultrasonication-assisted adsorption enables 90% of the MG to be removed from water within 30 min at neutral pH conditions. The ultrasound-assisted sorption process was driven by the acoustic cavitation process, which facilitated a homogeneous distribution of active adsorption sites on surface of the adsorbent resulting efficient removal of dye molecules. As predicted by the Langmuir isotherm model, the sorbent exhibited maximum adsorption capacity of 128.20 mg/g, and based on kinetic measurements, the pseudo-second-order adsorption model was found to be most accurate. The kinetic studies also revealed that intraparticle diffusion is the rate-limiting step of the adsorption process. The current study also demonstrates smartphone-assisted estimation of adsorbed MG dye in order to provide a simple, convenient, cost-effective, and instrument-free method to quantify dye concentration. A smartphone-based app called “ColorPicker” was used to calculate MG dye adsorption rate in real time based on RGB values and colorimetric responses. The percent removal obtained using smartphone app (87%) was in agreement with the data obtained using UV–vis spectroscopy (90%). As a result of its excellent properties, Zn/Cu-LDO appears to be a potential candidate for wastewater remediation.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two Novel Viologen/Polyoxometalate-Based Compounds for the Efficient Photocatalytic Reduction of Cr (VI) Under Visible Light Irradiation","authors":"Xiaoyuan Liu,&nbsp;Tao Liu,&nbsp;Jun Ying,&nbsp;Mengle Yang,&nbsp;Yanping Zhang,&nbsp;Aixiang Tian","doi":"10.1002/aoc.7929","DOIUrl":"https://doi.org/10.1002/aoc.7929","url":null,"abstract":"<div>\u0000 \u0000 <p>Designing efficient photocatalyst has attracted extensive attention for treating polluted wastewater containing Cr (VI). In this work, two viologen/polyoxometalate (POM)-based compounds were synthesized, [Ni (mimb)₂(H₂O)₄(β-Mo₈O₂₆)]·4H₂O (<b>1</b>) and [Zn (mimb)₂(H₂O)₄(β-Mo₈O₂₆)]·4H₂O (<b>2</b>) (mimb = 1-((3,5-dimethylisoxazol-4-yl)methyl)-[4,4′-bipyridin]-1-ium), through a hydrothermal method and investigated their ability of photocatalytic reduction of Cr (VI). The structures of compounds <b>1–2</b> were characterized by single-crystal X-ray diffraction, revealing that both possess a zero-dimensional (0D) structure and can form one-dimensional (1D) chain structures through hydrogen bondings. Photocatalytic experiments demonstrate that compound <b>1</b> has superior photocatalytic performance compared to compound <b>2</b>. Under optimal conditions (pH = 2, 15 mg catalysts, and 10 mg L⁻¹ Cr (VI) concentration), compound <b>1</b> can completely reduce Cr (VI) within 20 min, while compound <b>2</b> requires 30 min. Compounds <b>1–2</b> also show good stability after photocatalytic reaction, and maintain high photocatalytic activity after five reaction cycles. Additionally, the photocatalytic reaction mechanism of compounds <b>1–2</b> was studied, and the free radical scavenging experiments show that its main active species are e⁻, h⁺, and ˙O₂⁻. The nitroblue tetrazolium (NBT) experiments further confirm the crucial role of ˙O₂⁻ in the photocatalytic process. The good photocatalytic activity, stability, and recyclability of the viologen/POM-based compounds suggest their potential application in the treatment of wastewater containing Cr (VI).</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selective Novel Metal-Coordinated Biomedical Agents Encompassing Tetradentate Salen Ligand: Structural Elucidation, DFT Calculation, Cytotoxic, and Antioxidant Activities Supported by Molecular Docking Approach","authors":"Khalaf Al-Ghamdi,&nbsp;Mona M. A. Alharas,&nbsp;Samir A. Abdel-Latif,&nbsp;Dalal Alhashmialameer,&nbsp;Eida S. Al-Farraj,&nbsp;Manal A. Almalki,&nbsp;Rafat M. El-Khatib,&nbsp;Ahmed M. Abu-Dief","doi":"10.1002/aoc.7991","DOIUrl":"https://doi.org/10.1002/aoc.7991","url":null,"abstract":"<div>\u0000 \u0000 <p>Several physicochemical and analytical methods were employed to elucidate the structural analysis of some novel complexes derived from the {3,4-bis-[(3-ethoxy-2-hydroxy-benzylidene)-amino]-phenyl}-phenyl-methanone (ESAB ligand). Decomposition point determination, elemental analysis (CHN), spectroscopy (IR, NMR, and mass spectrometry), conductivity, magnetic susceptibility, UV–Vis spectrum study, and theoretical investigations were among these methods. With conductance values ranging from 7.5 to 15.12 Ω⁻¹ cm² mol⁻¹, molar conductance values showed that the Zn (II), Cu (II), and Ru (III) complexes are nonelectrolytes in fresh DMSO solutions, with the exception of the ESABRu complex, which is a monoelectrolyte. According to IR spectra, the ligand uses the (N &amp; O) donor sites from the (C=N &amp; C-O) groups in the ligand moiety to coordinate through the metal ions in a tetradentate form. A 1:1 (metal:ligand) molar ratio was proposed by Job's approach based on analytical data from solution complexation. According to the stability constant (<i>K</i>_<i>f</i>) values, the complexes' stability order was found to be ESABRu &gt; ESABCu &gt; ESABZn. The pH profile showed that the complexes under study are stable throughout a broad pH range, usually between pH = 4 and pH = 10. The complexes' geometric structures and ligand coordination capabilities were inferred with the use of magnetic and electronic spectrum studies. The DFT method uses quantum chemical simulations to evaluate the electronic structures of the ligand under investigation and its complexes. The unbound ligand's B3LYP level, B3LYP/6/311G* degree, and the complexes' B3LYP/6/311G**/LANL2DZ functional categories were employed in the computations of the density function concept (DFT). The findings revealed the consistency between the experimental and DFT computations. Natural bond orbital (NBO) analysis was used to investigate bond strength between molecules' charge exchange, hyperconjugative connections, and molecular equilibrium. By computing the hyperpolarizability (β) and molecular polarizability (α) parameters, the ensuing nonlinear optical properties were investigated, leading to a number of surprising optical properties for the produced compounds. The antipathogenic activity of the generated materials was experimentally verified against a subset of gram (+) and gram (−) bacteria as well as some fungi using the agar well diffusion method. Additionally, hepatic cellular carcinomas, cells from colon and breast cancer, were utilized to test the cytotoxic activity of the ESAB ligand and its metal chelates. Furthermore, the examined compounds' ability to suppress the DPPH radical was examined. Additionally, simulations of molecular docking were performed to ascertain how the produced compounds attached to the specific protein binding sites.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental and Theoretical Study of Delivering Metformin Anti-Lung Cancer Drug With Aluminum Nitride Nanoparticles","authors":"Juntao Hao","doi":"10.1002/aoc.8003","DOIUrl":"https://doi.org/10.1002/aoc.8003","url":null,"abstract":"<div>\u0000 \u0000 <p>Aluminum nitride (ALN) finds extensive application across various fields, and further advancement is undergoing to explore efficiency of this compound in drug delivery. The significance of this research lies in its contribution to nano-based drug delivery systems for anticancer treatments. This study focuses on the preparation of ALN nanoparticle using a simple and cost-effective route in an NH₃ atmosphere and in the presence of hydrated aluminum chloride. The characterization techniques such as FT-IR, TEM, SEM, UV, XRD, XPS, and EDS are used to analyze the synthesized nanoparticles. Then, metformin is incorporated into the fabricated nanostructure to achieve a drug loading of ~67%, demonstrating effectiveness of the selected nanocarrier for encapsulating this important drug. The specific impact of pH and time duration on the release profile of metformin highlights the versatility and potential applicability of ALN delivery system. Moreover, the gradual release of drug under physiological conditions (pH 7.4) as well as the accelerated release at the lower pH of 5.1 within 48 h proofed the responsiveness of the nanostructure to varying environmental conditions. Finally, a density functional theory (DFT) calculation was carried out to investigate adsorption of metformin. These computational analyses validated again the potential of ALN as an effective sensor for detecting metformin in biological systems. The unique characteristics of this study involve introducing a pH-responsive nanocarrier to release drug selectively in response to pH of the environment, using a nanoparticle with sufficient stability that improves solubility of poorly soluble metformin. This bioavailable drug delivery system can reduce off-target effects and toxicity associated with conventional drug therapies.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication of Fe3O4@Polypyrrole@Sulfamic Acid Composite for Efficient Adsorption of Four Cationic Dyes in Aqueous Solution","authors":"Yuhang Wang","doi":"10.1002/aoc.7977","DOIUrl":"https://doi.org/10.1002/aoc.7977","url":null,"abstract":"<div>\u0000 \u0000 <p>With the continuous development of industry, the issue of industrial wastewater emissions is increasing. Adsorption, as an effective means possessing the features of no pollution, high efficiency, and easy operation, has become one of the effective methods to treat industrial wastewater. Fe₃O₄@polypyrrole@sulfamic acid (Fe₃O₄@PPy@SA) composite is successfully prepare by hydrothermal method, in situ polymerization, and modification. Its adsorption behaviors of the composite on MG, MB, CV, and RhB are investigated by UV–Vis, and the impacts of temperature, dye concentration, and the contact time between the composite and the dyes on the adsorption efficiency are researched. The adsorption kinetics and adsorption isotherms exhibit that the adsorption of these four dyes is more in accordance with pseudo-second-order kinetic model and Langmuir adsorption isotherm model, the diffusion behaviors are affected through the combined effect of intraparticle diffusion and Boyd membrane diffusion, and the thermodynamic studies display that all these adsorption behaviors are spontaneous heat absorption behaviors. The prepared Fe₃O₄@PPy@SA is an efficient adsorbent in the field of applications.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green Ferrites: Eco-Friendly Synthesis to Applications in Environmental Remediation, Antimicrobial Activity, and Catalysis—A Comprehensive Review","authors":"Mir Waqas Alam,&nbsp;Neetu Dhanda,&nbsp;Hayfa Habes Almutairi,&nbsp;Noorah Saleh Al-Sowayan,&nbsp;Shehla Mushtaq,&nbsp;Sajid Ali Ansari","doi":"10.1002/aoc.7962","DOIUrl":"https://doi.org/10.1002/aoc.7962","url":null,"abstract":"<div>\u0000 \u0000 <p>Ferrite magnetic materials have emerged as capable materials in engineering, research, and medicine because of their exclusive and fascinating properties obtained from a variety of synthesis techniques. These ferrites are significant in commercial products, research, and biomedical applications. Green synthesis methods for ferrite nanocomposites and nanoparticles are becoming increasingly popular due to their usefulness in a range of industries, engineering, environmental, and medicinal remediation. Ferrite nanoparticles and nanocomposites (MFe₂O₄, where M = Ni, Cu, Mg, Co, Zn, and Mn) have recently gained popularity due to their many uses in biological, environmental, and chemical interactions. This review covers the most recent investigations over the last few years on green-synthesized ferrite nanoparticles, ferrites containing nanocomposites, and more elements, with a focus on microorganism-mediated and plant-based synthesis processes. The surface features of ferrite nanoparticles synthesized from green materials are discussed, as is their potential for sensors, energy, water treatment, antibacterial activity, biological, and heavy metal removal applications. This article presents an inclusive overview of green-synthesized ferrites, including the most recent research advances and findings. To fully realize the promise of nanoferrites in several fields, a thorough understanding of green manufacturing, properties, and applications is essential. Green-synthesized ferrites are chosen due to their potential for improved control over particle size and shape, lower cost, decreased toxicity, and environmental friendliness, all of which preserve magnetic properties that are better than those of conventionally synthesized ferrites, making them a more sustainable choice for a range of applications.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Ruthenium(II) Complex With a Two-Armed Benzimidazole Ligand as the G-Quadruplex Luminescent Probe","authors":"Liang Ma,&nbsp;Xue-Wen Liu,&nbsp;Geng-Jun He,&nbsp;Xia Hu,&nbsp;Yuan-Dao Chen,&nbsp;Song-Bai Zhang","doi":"10.1002/aoc.7996","DOIUrl":"https://doi.org/10.1002/aoc.7996","url":null,"abstract":"<div>\u0000 \u0000 <p>The selective detection of G-quadruplex DNA has the potential to reveal its biological function and provide important information for cancer diagnosis and treatment. Herein, a ruthenium(II) complex containing a two-armed benzimidazole ligand (bimbpy) (<b>RC1</b>) has been developed as a selective luminescence probe toward G4 DNA. <b>RC1</b> exhibited distinguishable luminescence response to G4 DNA, such as HTDNA, c-MYC, and 22AG. Especially, in the presence of HTDNA, the luminescence intensity of <b>RC1</b> increased to 6.1-fold. The limit of detection is 30 nM for HTDNA. However, it showed a small change in luminescence intensity against doubled-strand and single-strand DNA. The DNA binding experimental results indicated that <b>RC1</b> effectively stabilized G4 DNA through hydrogen bonds and π-π stacking. The selectivity of <b>RC1</b> to G4 DNA might be due to the increase in the rigidity of the two-armed benzimidazole ligand after binding to G4 DNA. Therefore, the design of ruthenium(II) complexes with a two-armed ligand will be an effective method to obtain Ru(II)-based G-quadruplex luminescent probes by adjusting the degree of rigidity of the two arms.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two Ferrocene-Modified Copper(I) Complexes for the Synergistic Enhancement of Chemodynamic Therapy","authors":"Rui Peng,&nbsp;Jing-Jing Zhong,&nbsp;Daohan Yang,&nbsp;Zhaoguo Hong,&nbsp;He-Dong Bian,&nbsp;Fu-Ping Huang","doi":"10.1002/aoc.7960","DOIUrl":"https://doi.org/10.1002/aoc.7960","url":null,"abstract":"<div>\u0000 \u0000 <p>In recent years, some Cu-based complexes and nanomaterials that can better adapt to tumour microenvironments and produce better chemodynamic therapeutic effects have been synthesised. Ferrocene and its derivatives have garnered increasing attention as a therapeutic option in chemodynamic therapy owing to their excellent catalytic activity. Herein, two ferrocene-modified Cu(I) complexes, <b>Fc-<span>AD</span>-Cu</b> and <b>Fc-IH-Cu</b>, were synthesised with atomically precise structures. Both exhibit good Fenton/Fenton-like activity, inducing the generation of reactive oxygen species in Hep-G2 cells and improving chemodynamic therapeutic efficiency.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anion Bridged One-Dimensional Copper-Based Metal Organic Frameworks as Peroxidase Mimics for Glucose Detection in Apple Fruits","authors":"Yuzhang Yang,&nbsp;Minji Li,&nbsp;Yunqian Gong,&nbsp;Xingliang Li,&nbsp;Jia Zhou,&nbsp;Qinping Wei,&nbsp;Junke Zhang","doi":"10.1002/aoc.7957","DOIUrl":"https://doi.org/10.1002/aoc.7957","url":null,"abstract":"<div>\u0000 \u0000 <p>Enzyme mimics attract wide attentions as detection sensors. However, the widespread application is limited by low efficiency and high cost. Herein, two novel enzyme mimics <b>1</b> and <b>2</b> were developed with peroxidase-like activities. The chain-like structure of <b>1</b> exhibited better stability, energy transformation efficiency, and catalytic property than <b>2</b>. Both of them could generate •OH radicals to oxide chromogenic agents, realizing the colorimetric detection of H₂O₂. Additionally, under the synergy of glucose oxidase, a cascade strategy for detection of glucose was constructed. This method exhibited excellent selectivity, anti-interference, and storage performance, as well as a wide linear range (1–60 μM) at pH = 7.4, with the low detection limits of 0.095 and 0.061 μM for <b>1</b> and <b>2</b>, respectively. Furthermore, the strategy was applied for detecting glucose in apple fruit samples. This work overcomes the shortcomings of current enzyme mimics and paves the way for bioanalysis and agricultural applications.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 2","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}