Water, Air, & Soil Pollution最新文献

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Viability of the Microalgae Thalassiosira Weissflogii and Prorocentrum Cordatum to Titanium Nanoparticles 微藻 Thalassiosira Weissflogii 和 Prorocentrum Cordatum 对纳米钛颗粒的活力
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-11 DOI: 10.1007/s11270-024-07561-z
Ekaterina Solomonova, Natalia Shoman, Arkady Akimov, Olga Rylkova
{"title":"Viability of the Microalgae Thalassiosira Weissflogii and Prorocentrum Cordatum to Titanium Nanoparticles","authors":"Ekaterina Solomonova,&nbsp;Natalia Shoman,&nbsp;Arkady Akimov,&nbsp;Olga Rylkova","doi":"10.1007/s11270-024-07561-z","DOIUrl":"10.1007/s11270-024-07561-z","url":null,"abstract":"<div><p>According to the results of the experimental study, it was found that the addition of titanium dioxide nanoparticles does not lead to changes in morphological, structural, functional and fluorescent indices of the diatom <i>Thalassiosira weissflogii</i> and the dinophyte <i>Prorocentrum cordatum</i> in the concentration range of 0.5–6.2 mg L<sup>−1</sup>. At the highest concentration of the pollutant (6.2 mg L<sup>−1</sup>), no decrease in the enzymatic activity (FDA fluorescence characterizes the level of metabolic activity of cells) of algae and no increase in the production of reactive oxygen (D2CFH-DA fluorescence, reflects ROS production in cells) species were observed after 72 h of cultivation. The efficiency of the cell photosynthetic apparatus (Fv/Fm) and relative electron transport rate (rETR) were maintained at a high relatively constant level for algae growing under high NPs TiO<sub>2</sub> concentration. Scanning electron and light microscopy micrographs also showed the absence of morphological changes in <i>T. weissflogii</i> and <i>P. cordatum</i> cells and no significant cell wall deformation when exposed to NPs TiO<sub>2</sub>. It is suggested that probably the absence of adsorption of titanium dioxide nanoparticles on the surface of <i>T. weissflogii</i> and <i>P. cordatum</i> cells is associated with the physicochemical properties of TiO<sub>2</sub> NPs, in particular, with their surface charge.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142411394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microbial Ecosystems as Guardians of Food Security and Water Resources in the Era of Climate Change 微生物生态系统是气候变化时代粮食安全和水资源的守护者
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-10 DOI: 10.1007/s11270-024-07533-3
Muhammad Danish Toor, Muneeb Ur Rehman, Javeria Abid, Dibyajyoti Nath, Izhar Ullah, Abdul Basit, Muhammad Mughees Ud Din, Heba I. Mohamed
{"title":"Microbial Ecosystems as Guardians of Food Security and Water Resources in the Era of Climate Change","authors":"Muhammad Danish Toor,&nbsp;Muneeb Ur Rehman,&nbsp;Javeria Abid,&nbsp;Dibyajyoti Nath,&nbsp;Izhar Ullah,&nbsp;Abdul Basit,&nbsp;Muhammad Mughees Ud Din,&nbsp;Heba I. Mohamed","doi":"10.1007/s11270-024-07533-3","DOIUrl":"10.1007/s11270-024-07533-3","url":null,"abstract":"<div><p>In the era of climate change, the correlation between climate, food security, and water resources is profoundly influenced by microbial ecosystems. This review explores the important role of these often-overlooked microorganisms in maintaining the delicate balance required for sustainable agriculture and clean water availability. Microbes, though minuscule, orchestrate vital processes shaping nutrient cycling, soil health, and ecosystem functionality in both terrestrial and aquatic domains. As climate shifts occur, these adaptable microbes adjust, affecting ecosystem dynamics. Climate-smart agriculture harnesses microbial partnerships for soil carbon sequestration and stress mitigation, safeguarding the food supply. Microbes support crop productivity and resilience while also managing pests and diseases in changing climates. Additionally, they contribute to water purification and quality stabilization through water treatment and biofilms, ensuring clean water resources. Microbial diversity acts as a buffer against climate-induced disruptions, underlining their role in sustaining ecosystem stability. Integrating microbial approaches into policies and practices becomes crucial for climate adaptation, paving the way for sustainable agriculture and water management. Novel microbial technologies hold promise in addressing climate-food-water challenges, while collaborative research remains essential for innovative solutions at this critical interface of science and policy. Moreover, microbial ecosystems emerge as essential to food security and water resources in the face of climate change, charting a path towards a resilient and sustainable future.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142411234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microalgae Cultivated in Cattle Wastewater as a Biofertilizer: Tests on the Production of Arugula (Eruca vesicaria) and the Benefits for Sustainable Agriculture 将牛废水中培养的微藻作为生物肥料:芝麻菜(Eruca vesicaria)生产试验及其对可持续农业的益处
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-10 DOI: 10.1007/s11270-024-07519-1
Laiza Santos Dagnaisser, David Vilas Boas de Campos, Érika Flávia Machado Pinheiro, Dione Galvão da Silva, Jéssica Chaves Cardoso, Conan Ayade Salvador, Elisa Helena da Rocha Ferreira, Henrique Vieira de Mendonça
{"title":"Microalgae Cultivated in Cattle Wastewater as a Biofertilizer: Tests on the Production of Arugula (Eruca vesicaria) and the Benefits for Sustainable Agriculture","authors":"Laiza Santos Dagnaisser,&nbsp;David Vilas Boas de Campos,&nbsp;Érika Flávia Machado Pinheiro,&nbsp;Dione Galvão da Silva,&nbsp;Jéssica Chaves Cardoso,&nbsp;Conan Ayade Salvador,&nbsp;Elisa Helena da Rocha Ferreira,&nbsp;Henrique Vieira de Mendonça","doi":"10.1007/s11270-024-07519-1","DOIUrl":"10.1007/s11270-024-07519-1","url":null,"abstract":"<div><p>Ensuring food security for the world's growing population while advancing sustainable agriculture and reducing conventional fertilizer use is a major challenge. The objective of this research was to comparatively evaluate the effect of microalgae biomass biofertilizer, derived from the production of <i>Arthrospira platensis</i> DHR 20 (Spirulina) in cattle wastewater under organic management (CW), on the development of arugula. It also examined the microbiological attributes of arugula leaves and the changes in soil chemical properties and structural composition of the soil post-experiment. The experiment consisted of three treatments: T1 – control, with urea application; T2 – CW; T3 – microalgae biofertilizer. The experimental design was completely randomized with seven replications and four plants per plot. The main conclusion of this research is that microalgae biomass biofertilizer presents nutritional potential for arugula, particularly as a source of N (187.5 mg L<sup>−1</sup>) and K (92.9 mg L<sup>−1</sup>), and can replace conventional urea fertilizer as a nitrogen source in the cultivation of arugula, with similar plant development quality according to the Dickson Quality Index. According to the SAR, the microalgae biomass biofertilizer and CW do not present soil sodicity restrictions and show a low to moderate level of restriction for soil use in terms of salinity. The average biofixation rate of 0.22 CO<sub>2</sub> L<sup>−1</sup> d<sup>−1</sup> obtained in the study suggests that <i>Spirulina</i> cultivation in CW is suitable for this greenhouse gas biofixation. Leaves from the three treatment groups yielded negative results for the presence of thermotolerant coliforms. Both microalgae biofertilizer and CW acted as soil conditioners, improving its structural quality when compared to soil fertilized with urea.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142411172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-tolerant microbial succession mediated by mining reclamation improves network stress resistance 采矿复垦介导的耐金属微生物演替提高了网络抗压能力
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07556-w
Yanfeng Zhu, Liping Wang, Jing Ma, Ziyi Hua, Fu Chen
{"title":"Metal-tolerant microbial succession mediated by mining reclamation improves network stress resistance","authors":"Yanfeng Zhu,&nbsp;Liping Wang,&nbsp;Jing Ma,&nbsp;Ziyi Hua,&nbsp;Fu Chen","doi":"10.1007/s11270-024-07556-w","DOIUrl":"10.1007/s11270-024-07556-w","url":null,"abstract":"<div><p>The development of heavy metal-resistant microbial species (STS) and their interactions in the reclaimed soil play a vital role in improving the stability of mining area ecosystems. However, the development of the STS in reclaimed soil (Re) and the interactions to resist heavy metal stress (HMs) for maintaining the stability of co‑occurrence networks is still unclear. Therefore, this study employed high-throughput sequencing and differential abundance testing to explore the mechanisms of STS changes and the formation of co‑occurrence network resistance to HMs in reclaimed soil succession. Our results revealed that (1) Re treatment significantly improved the physicochemical properties of the soil and reduced the levels of HMs. Compared with the control group (CK), the heavy metal content in Re treatment decreased as follows: Hg (50.76%) &gt; Cd (46.43%) &gt; Cu (43.91%) &gt; As (35.89%) &gt; Pb (33.49%) &gt; Cr (24.39%); (2) Compared with CK, the Shannon, ACE, and Observed species indices of bacteria in Re increased significantly by 11.70%, 549.33%, and 392.00% (<i>p</i> &lt; 0.05), respectively. Additionally, Re significantly altered the β-diversity of bacterial communities (<i>p</i> &lt; 0.01); (3) <i>Proteobacteria</i><i>, </i><i>Acidobacteria</i>, <i>Bacteroidetes</i>, and <i>Chloroflexi</i> were identified as the STS mediated by mining reclamation, and their changes exhibited a significant positive correlation with pH, SOM, and heavy metal content; (4) Compared with CK, the changes in STS increased the number of network modules in Re. The enrichment of <i>Chloroflexi</i> in the first four network modules in Re showed positive effects on Cu, Cd, and Pb stress, and taxa communities in module 3 may have a certain role in resisting As and Cr stress. Our results indicate the mechanisms of STS development and co‑occurrence network resistance in the long-term reclamation process of mining areas, thereby providing valuable insights for a deeper understanding of the role of microbes in ecological restoration of mining areas.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Validation and Spatial–Temporal Variability of Particulate Matter in Urban area Using WRF-Chem with Local and Global Emission Inventories 利用 WRF-Chem 和本地及全球排放清单验证城市地区颗粒物的时空变异性
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07540-4
Yagni Rami, Anurag Kandya, Abha Chhabra, Aman W. Khan, Prashant Kumar, Sneha Gautam
{"title":"Validation and Spatial–Temporal Variability of Particulate Matter in Urban area Using WRF-Chem with Local and Global Emission Inventories","authors":"Yagni Rami,&nbsp;Anurag Kandya,&nbsp;Abha Chhabra,&nbsp;Aman W. Khan,&nbsp;Prashant Kumar,&nbsp;Sneha Gautam","doi":"10.1007/s11270-024-07540-4","DOIUrl":"10.1007/s11270-024-07540-4","url":null,"abstract":"<div><p>This study examines the validation and spatial–temporal variability of simulated PM<sub>10</sub> and PM<sub>2.5</sub> concentrations over Ahmedabad city using the WRF-Chem model with EDGAR global emissions and locally developed PM emissions as inputs. The validation process involves comparing simulated PM<sub>10</sub>, PM<sub>2.5</sub>, and meteorological parameters with in-situ measurements from stations at Pirana and S P Stadium during 16th-17th May and 16th-17th December 2018. The analysis focuses on six-hourly averaged data, highlighting the significant role of Wind Speed, Wind Direction, and Planetary Boundary Layer Height (PBLH) in the dispersion of air pollutants. The results show that the model using locally developed PM emissions significantly reduces bias and provides better spatial distribution patterns compared to EDGAR emissions. For instance, in May, the average simulated PM<sub>10</sub> using EDGAR emissions was 85 µg/m<sup>3</sup>, while the locally developed emissions yielded an average of 183 µg/m<sup>3</sup>, closer to the observed in-situ average of 178 µg/m<sup>3</sup>. Similarly, in December, the simulated PM<sub>10</sub> using EDGAR emissions was 97 µg/m<sup>3</sup> compared to 232 µg/m<sup>3</sup> from local emissions, with an in-situ average of 147 µg/m<sup>3</sup>. The spatial analysis reveals that during May, 52% of the western areas experienced 'Good' air quality in the morning, decreasing to 40% by the evening. In contrast, December showed more severe pollution, with 45% of the North–North Western city experiencing 'Moderately Polluted' air quality by evening. The correlation coefficients (R<sup>2</sup>) for PM<sub>10</sub> validation at Pirana and S P Stadium were 0.73 and 0.93 respectively in May using EDGAR emissions, improving to 0.77 and 0.91 with local emissions. This study underscores the need for improved emission inventories and mitigation strategies to enhance air quality in Ahmedabad. The significant seasonal variations and the impact of meteorological parameters on pollutant dispersion highlight the importance of localized data and targeted interventions for effective air quality management.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure-Controlled Synthesis of Sodium Trititanate and Hexatitanate Nanorods and their Adsorption Properties for Ni2+and Pb2+ Ions from Aqueous Solutions 结构控制合成三钛酸钠和六钛酸钠纳米棒及其对水溶液中 Ni2+ 和 Pb2+ 离子的吸附性能
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07531-5
Chaochao Hao, Aili Wang, Hengbo Yin
{"title":"Structure-Controlled Synthesis of Sodium Trititanate and Hexatitanate Nanorods and their Adsorption Properties for Ni2+and Pb2+ Ions from Aqueous Solutions","authors":"Chaochao Hao,&nbsp;Aili Wang,&nbsp;Hengbo Yin","doi":"10.1007/s11270-024-07531-5","DOIUrl":"10.1007/s11270-024-07531-5","url":null,"abstract":"<div><p>Phase pure sodium trititanate (Na<sub>2</sub>Ti<sub>3</sub>O<sub>7</sub>) and hexatitanate (Na<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub>) nanorods were controllably synthesized using sodium carbonate and titanic acid as sodium and titanium precursors by calcination at 850 °C for 12 h. The adsorption properties of trititanate and hexatitanate nanorods for the removal of heavy metal ions, Ni<sup>2+</sup> and Pb<sup>2+</sup> from simulated wastewaters at pH of 3‒7 and 20‒65 °C were investigated. The adsorption of Ni<sup>2+</sup> and Pb<sup>2+</sup> ions on sodium trititanate and hexatitanate nanorods are through ion exchange and electrostatic adsorption. The adsorption of Ni<sup>2+</sup> and Pb<sup>2+</sup> ions could be well fitted by the pseudo-second order adsorption kinetics and Langmuir adsorption isotherm. Based on the Langmuir adsorption isotherm, the adsorption capacities of naked sodium trititanate nanorods for Ni<sup>2+</sup> and Pb<sup>2+</sup> from simulated wastewaters at 20 °C and pH 7 are 104.17 and 89.85 mg∙g<sup>‒1</sup> while the adsorption capacities of naked sodium hexatitanate nanorods are 95.69 and 76.69 mg∙g<sup>‒1</sup>, respectively. Sodium trititanate nanorods exhibit higher adsorption capacities for heavy metal ions from wastewaters than sodium hexatitanate nanorods because the former has richer Na<sup>+</sup> ions for ion exchange with heavy metal ions than the latter. The adsorption processes of Ni<sup>2+</sup> and Pb<sup>2+</sup> on sodium trititanate and hexatitanate nanorods are spontaneous. The phase pure sodium titanate nanorods may have practical application for the removal and enrichment of metal ions from wastewaters.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioremediation of Azo Yellow Dye Degradation – An Efficient and Sustainable Approach 降解偶氮黄染料的生物修复技术--一种高效、可持续的方法
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07544-0
Pavithra Marisamy, Aarthi Ponraj, Hemalatha Srinivasan, Faridha Begum Ibrahim
{"title":"Bioremediation of Azo Yellow Dye Degradation – An Efficient and Sustainable Approach","authors":"Pavithra Marisamy,&nbsp;Aarthi Ponraj,&nbsp;Hemalatha Srinivasan,&nbsp;Faridha Begum Ibrahim","doi":"10.1007/s11270-024-07544-0","DOIUrl":"10.1007/s11270-024-07544-0","url":null,"abstract":"<div><p>Ecosystems are impacted both directly and indirectly by the tanning industry's higher-than-average emission of harmful effluent. Plants, animals, and humans all suffer greatly from the contaminants in tannery wastewater. Therefore, the study focuses on separating novel organisms from chromium-containing wastewater by examining the screening results, which show that the novel organisms have degraded 96% of the synthetic azo-yellow dye. Novel bacterium that degrades and removes toxic organic and inorganic compounds, and synthetic azo yellow color. Several factors influencing the high percentage of degradation including temperature (36 °C), pH (7), inoculum concentration (10%), and duration (60<sup>th</sup> hours), are optimized for the breakdown of synthetic azo yellow dye. The degradation profile where C-N stretching nitrile and C = O stretching anhydride were absent, confirmed by instrumental analysis. Novel organisms can remove, synthetic azo-yellow dye, and toxic organic and inorganic substances. Consequently, process characterization, optimization, and modelling are done using advanced statistical design. Briefly covered were the foundations of RSM and how it is used in the biological treatment of wastewater. The different RSM-based prediction and optimization works are listed. The goal of the research is to completely degrade tannery effluent and zero sludge disposable, and this is oriented on practical applications at larger scale technologies and for irrigation purposes.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Degradation Of Tetracycline Antibiotic in Water by an Electro/Peroxydisulfate System Catalyzed with Fe2+ and Cu2+ Loaded on Activated Carbon 以活性炭上负载的 Fe2+ 和 Cu2+ 催化的电/过硫酸盐系统降解水中的四环素抗生素
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07513-7
Nana Wu, Guangze Wu, Yuying Pi, Qiang Liu, Fuchen Ban, Yulan Tang, Yifei Wei
{"title":"Degradation Of Tetracycline Antibiotic in Water by an Electro/Peroxydisulfate System Catalyzed with Fe2+ and Cu2+ Loaded on Activated Carbon","authors":"Nana Wu,&nbsp;Guangze Wu,&nbsp;Yuying Pi,&nbsp;Qiang Liu,&nbsp;Fuchen Ban,&nbsp;Yulan Tang,&nbsp;Yifei Wei","doi":"10.1007/s11270-024-07513-7","DOIUrl":"10.1007/s11270-024-07513-7","url":null,"abstract":"<div><p>Tetracycline antibiotics are a common type of antibiotics in life. In this research, Fe<sup>2+</sup> and Cu<sup>2+</sup> was used to modify granular activated carbon, and peroxydisulfate was activated under the synergistic action of electrochemistry (EC/Fe-Cu-GAC/PS). The effects of the initial concentration of tetracycline hydrochloride (TCH), initial pH, current density, and plate spacing on the degradation of TCH were investigated. Experimental results indicated that the removal efficiency of TCH was 87.27% by the EC/Fe-Cu-GAC/PS system. The removal rate of TCH decreased with the increase of initial concentration of TCH. The TCH removal rate is maintained at a high level when pH values range from 3 to 7. Increasing the amount of catalyst and persulfate in a certain range, as well as the magnitude of current density and plate spacing are helpful for TCH removal. When the initial TCH concentration is 20 mg/L, the initial pH value is 5.0, the amount of Fe-Cu-GAC is 2.0 g, the PS concentration is 2 mmol/L, the electrolyte concentration is 25 mmol/L, the current density is 15 mA/cm<sup>2</sup>, and the plate spacing is 9 cm, the TCH removal effect is the most effective. The free-radical experiment showed that sulfate radicals (SO<sub>4</sub><sup>•−</sup>) played a dominant role under acidic conditions. According to the data analysis, the kinetic model of the EC/Fe-Cu-GAC/PS system was consistent with the first-order reaction kinetics. According to the reaction dynamics, we get the rating of influencing factors that influence the effect of TCH removal. The EC/Fe-Cu-GAC/PS system can effectively degrade tetracycline antibiotics in water.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Mg-doped Ni0.33Zn0.33Co0.33Fe2O4 Nanoparticles on the Methylene Blue Adsorption Efficiency Under Various Operational Parameters 不同操作参数下掺镁 Ni0.33Zn0.33Co0.33Fe2O4 纳米粒子对亚甲蓝吸附效率的影响
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07529-z
Dema Dasuki, Amani Aridi, Marwa Elkady, Khulud Habanjar, Gehan M. El-Subruiti, Ramadan Awad
{"title":"Influence of Mg-doped Ni0.33Zn0.33Co0.33Fe2O4 Nanoparticles on the Methylene Blue Adsorption Efficiency Under Various Operational Parameters","authors":"Dema Dasuki,&nbsp;Amani Aridi,&nbsp;Marwa Elkady,&nbsp;Khulud Habanjar,&nbsp;Gehan M. El-Subruiti,&nbsp;Ramadan Awad","doi":"10.1007/s11270-024-07529-z","DOIUrl":"10.1007/s11270-024-07529-z","url":null,"abstract":"<div><p>Dye disposal in water has caused a serious environmental threat. Thus, ongoing research is driving efforts to explore solutions for this contaminant removal. Accordingly, the adsorption efficiency of ferrite nanoparticles has shown promising results for dye pollutant removal. Hence, in this study, Zn<sub>0.33</sub>Ni<sub>0.33</sub>Co<sub>0.33-x</sub>Mg<sub>x</sub>Fe<sub>2</sub>O<sub>4</sub> nanoparticles were synthesized by chemical co-precipitation technique and studied under various operational parameters for the removal of methylene blue dye. The structural characterization of nanoparticles, held by XRD, confirms the successful phase formation with a small percentage of the hematite phase (&lt; 8%). Additionally, the crystallite size decreased from 13.72 to 10.05 nm with Mg<sup>2+</sup> increase from 0.00 up to 0.20. Consequently, the morphological characterization confirms the dependence of Mg<sup>2+</sup> doping on the reduction of agglomeration between particles. The optical characterization was investigated by photoluminescence spectroscopy, highlighting an essential trend with the variation of excitation wavelength and Mg doping dependence. As the Mg content increases from 0.00 to 0.20, the surface area increases from 43.82 to 60.19 m<sup>2</sup>.g<sup>−1</sup> whereas the pore diameter decreases from 16.65 to 12.49 nm. Among the synthesized samples, Zn<sub>0.33</sub>Ni<sub>0.33</sub>Co<sub>0.33</sub>Fe<sub>2</sub>O<sub>4</sub> nanoparticles exhibited superior adsorption performance, achieving the highest adsorption capacity of 90.4 mg.g<sup>−1</sup>. In addition, the removal efficiency of methylene blue reached 95.8% for the Mg0.00 sample and 78.9% for the Mg0.20 sample, after a contact time of 30 min at pH 11. As the initial methylene blue concentration increased from 5 to 100 mg.L<sup>−1</sup>, the removal percentage in the presence of Mg0.00 decreased from 98.4 to 79.8%. The adsorption process followed second-order kinetics and was well-fitted with the Freundlich isotherm model.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comparative Study About Physical Properties of Copper Oxide and Zinc Oxide Nanoparticles on Fagus orientalis L. as Bioindicator 氧化铜和氧化锌纳米粒子作为生物指示剂在东方椑木上的物理性质比较研究
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2024-10-08 DOI: 10.1007/s11270-024-07551-1
Kaan Isinkaralar, Oznur Isinkaralar, Halil Barış Özel, Hakan Şevik
{"title":"A Comparative Study About Physical Properties of Copper Oxide and Zinc Oxide Nanoparticles on Fagus orientalis L. as Bioindicator","authors":"Kaan Isinkaralar,&nbsp;Oznur Isinkaralar,&nbsp;Halil Barış Özel,&nbsp;Hakan Şevik","doi":"10.1007/s11270-024-07551-1","DOIUrl":"10.1007/s11270-024-07551-1","url":null,"abstract":"<div><p>Nanoparticles (NPs) have recently begun to be used extensively in many areas of our lives. It is stated that the resulting NPs pollution will affect even the most remote ecosystems on the Earth. Therefore, determining the effects of NPs on diverse ecosystems is a research topic of interest. From this perspective, current researches on NPs affecting forest ecosystems and forest trees are very scarce. The aim of this investigation was to reveal the inhibitory and toxic properties of CuO and ZnO-NPs on oriental beech seed germination parameters and identify the toxic threshold values of CuO and ZnO-NPs. Therefore, the oriental beech (<i>Fagus orientalis</i> L.) seeds obtained from ten populations (P1 to P10) were treated with CuO and ZnO-NPs as single compounds at concentrations of 200, 400, 600, 800 and 1000 mg/L and germination rate (GR), germination percentage (GP), root collar diameter (RCD), plumula length (PL), radicle thickness (RT) and radicle diameter (RD) were determined for 35 days. The water containing CuO-ZnO NPs as a single compound at 1000 mg/L negatively affected all growth in general. The significant decrease in our study occurred at P9. The CuO-ZnO NPs were reduced in GP, RCD, PL, RT, and RD as 3.5–4.2%; 11.2–0.1%; 9.1–36.4%; 23.07–38.46%; and 39.29–17.86%, while GR enhanced as 21.46–20.09%. It was found that water with a low concentration of NP (200 mg/L) is suitable for irrigation of seeds grown in soil media and does not have a significant toxic effect on the growth and uptake of metal ions. The findings and limitations of the present research allow us to assess the feasibility of reusing NP-contaminated water in agriculture. Nevertheless, further research is needed to understand the toxic effects of NP mixtures on growth and absorption mechanisms.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 11","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142410778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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