Rong-xin Zhang, Yi Liu, Dian-nan Huang, Li Zhang, Xing-guan Ma, Peng-fei Yu, Chuang Liu, Yong-yong Wang
{"title":"Influence of Influent Load on Nitrification/Denitrification with MBBR for Oil Shale Retorting Wastewater Treatment: Performance and Microbial Community Structure","authors":"Rong-xin Zhang, Yi Liu, Dian-nan Huang, Li Zhang, Xing-guan Ma, Peng-fei Yu, Chuang Liu, Yong-yong Wang","doi":"10.1007/s11270-024-07615-2","DOIUrl":"10.1007/s11270-024-07615-2","url":null,"abstract":"<div><p>Oil shale retorting wastewater is currently recognized as one of the most complex industrial wastewater due to its ultra-low chemical oxygen demand to total nitrogen (C/N) ratio, high organic load, and complex chemical composition. In this paper, the effect of influent load on the performance and microbial community changes of moving bed biofilm reactor(MBBR) in the treatment of highly polluted retorting wastewater was investigated. The MBBR was proposed and demonstrated to be efficient in treating the retorting wastewater, containing COD and NH<sub>4</sub><sup>+</sup>-N of 5000-10000mg/L and 3000-5000mg/L. The removal efficiency of COD and NH<sub>4</sub><sup>+</sup>-N increased steadily in 1-79d, and the effect was the best when the influent load was 0.0242–0.0312kg COD/kg MLSS·d and 0.0173–0.0208kg NH<sub>4</sub><sup>+</sup>-N/kg MLSS·d. The removal efficiency of COD was up to 83.46%, and the removal efficiency of NH<sub>4</sub><sup>+</sup>-N was 82.08%. The long-term operation showed that the biofilm could be rapidly formed after 40 days. Scanning electron microscope observation showed that cocci and short bacilli appeared in the pores of the fillers. With the increase of influent load, the total amount of extracellular polymeric substances increased significantly, in which the content of protein increased sharply in stage III, while the polysaccharide was in a state of continuous and stable growth. High-throughput sequencing analysis showed that the nitrifying functional genus Nitrosomonas was highly enriched in the MBBR system (0 → 17.55%) and played a key role in the high accumulation of NO<sub>3</sub><sup>−</sup>-N. The newly added denitrifying bacteria <i>Brevundimonas</i> (5.85%) and <i>Reyranella</i> (4.57%) enhanced the degradation of COD and maintained the nitrogen cycle in the system. The enrichment of <i>Acinetobacter</i>, <i>Rugosibacter</i>, and <i>unclassified_Syntrophobacteraceae</i> in the system played an important role in the degradation of complex organic compounds such as polycyclic aromatic hydrocarbons and aromatic compounds.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142694716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pankaj Kumar, Sadeq K. Alhag, Eman A. Al-Shahari, Maged S. Al-Fakeh, Sami Abou Fayssal, Rakesh Kumar Bachheti, Ivan Širić, Ebrahem M. Eid
{"title":"Impact of Irrigation with Contaminated River Water on Growth, Yield, and Heavy Metals Accumulation in Planted Armenian Cucumber (Cucumis melo var. flexuosus (L.) Naudin.)","authors":"Pankaj Kumar, Sadeq K. Alhag, Eman A. Al-Shahari, Maged S. Al-Fakeh, Sami Abou Fayssal, Rakesh Kumar Bachheti, Ivan Širić, Ebrahem M. Eid","doi":"10.1007/s11270-024-07642-z","DOIUrl":"10.1007/s11270-024-07642-z","url":null,"abstract":"<div><p>Cultivation of horticultural crops in riverbank soils which are enriched by deposition of nutrient-rich sediments is one of the most common practices in arid and semi-arid regions around the globe. However, contamination of river streams by urban, industrial, and agricultural runoffs resulted in the accumulation of excessive levels of certain nutrients and heavy metals in such crops. Keeping in view, the present study was conducted to understand the impact of Yamuna (non-contaminated) and Solani (urban sewage contaminated) Rivers streams on riverbank soils and planted Armenian cucumber [<i>Cucumis melo</i> var. <i>flexuosus</i> (L.) Naudin.] in a two-year (2022 and 2023) study. The results showed that <i>C. melo</i> cultivated in Solani River water irrigated soils had significantly (<i>p</i> < 0.05) higher growth, yield, and biochemical constitutes as compared to Yamuna River water irrigated soils. The bioaccumulation factor (BAF) studies showed that concentrations of eight heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) were higher in <i>C. melo</i> grown in Solani River soils. However, the levels of heavy metals were found below the safe limits as indicated by dietary intake of metal (DIM), health risk index (HRI < 1), and target hazard quotient (THQ < 1) indices. Overall, this study evidenced that river water impacted by urban sewage could result in elevated levels of heavy metals in river water, soil, and cultivated food crops, thus, signifying their regular biomonitoring in order to mitigate any associated health risk.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Guo, Xingwang Yang, Yanhua Xu, Jun Zhou, Wenquan Sun, Yongjun Sun
{"title":"Salt-Resistant Catalyst Fe-Bi@γ-Al2O3 for Catalytic Ozonation of High-Salt Simulated Wastewater","authors":"Lei Guo, Xingwang Yang, Yanhua Xu, Jun Zhou, Wenquan Sun, Yongjun Sun","doi":"10.1007/s11270-024-07652-x","DOIUrl":"10.1007/s11270-024-07652-x","url":null,"abstract":"<div><p>In order to study the effects of common ionic components in wastewater on the catalytic performance and salt resistance of the Fe-Bi@γ-Al<sub>2</sub>O<sub>3</sub> catalyst, hydroquinone was selected as the target organic pollutant. Five factors, namely cation species, anion species, total hardness, total alkalinity, and TDS were studied to investigate the effects of different ionic components on the degradation of hydroquinone by the Fe-Bi@γ-Al<sub>2</sub>O<sub>3</sub> catalyst. K<sup>+</sup> and Na<sup>+</sup> had basically no effect on the COD removal rate, and the COD removal rates were 81.43% and 83.81%, respectively, with no significant change from the COD removal rate from raw water (85.24%), Cu<sup>2+</sup> and Al<sup>3+</sup> had some inhibitory effect on the COD removal rate, and the COD removal rate was 68.57% and 70.00%, respectively. While, the presence of Fe<sup>3+</sup>, Cl<sup>−</sup>, Br<sup>−</sup> and SiO<sub>3</sub><sup>2−</sup> had a significant inhibitory effect on the COD removal rate, and the COD removal rate was 61.90%, 51.90%, 55.71% and 60.48%. The concentration of Ca<sup>2+</sup> was 50 mg/L and Mg<sup>2+</sup> was 200 mg/L, the COD removal rate was 57.62% and 60.48%, respectively due to water hardness. The alkalinity had an inhibitory effect on the treatment effect of simulated waste water, when the OH concentration was 1500 mg/L, the COD removal rate was 49.05%. The higher the TDS concentration, the more obvious was the inhibitory effect on the COD removal rate, and the COD removal rate was 41.43% when the TDS was 50,000 mg/L. The intermediates and possible degradation mechanisms after catalytic ozone oxidation of hydroquinone-simulated wastewater by Fe-Bi@γ-Al<sub>2</sub>O<sub>3</sub> were investigated by UV spectroscopy scanning, 3D fluorescence spectroscopy scanning, and GC–MS scanning.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142679711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Peng Jiang, Xin Wan, Mingxuan Che, Jingping Chen, Mingxue Liu
{"title":"Secondary Successional Forest Soil Bacterial Community Variation Correlates to Soil Type","authors":"Peng Jiang, Xin Wan, Mingxuan Che, Jingping Chen, Mingxue Liu","doi":"10.1007/s11270-024-07654-9","DOIUrl":"10.1007/s11270-024-07654-9","url":null,"abstract":"<div><p>This study investigated the factors affecting bacterial diversity in purplish and calcareous soils under the same vegetation type. The results showed that obvious differences in pH, water content, total phosphorus (TP), free iron oxide (Fe<sub>d</sub>) and amorphous iron oxide (Fe<sub>ox</sub>) existed between the two soils. The bacterial Shannon indexes of the two soils varied significantly, and Shannon index of purplish soil were higher than that of calcareous soils. The co-occurring network structures in two soil bacterial communities showed obvious variations, with higher edge counts, average degrees and clustering coefficients in calcareous soils than that in purple soils. The key species group identified in the two soils was Acidobacteria; belonging to the family Thermoanaerobaculaceae in purplish soil, and to the family Vicinamibacterales in calcareous soil. Also, the results of multivariate stepwise linear regression showed that Fe<sub>ox</sub> was a significant explanatory factor for changes in bacterial diversity (68.8%, P < 0.01) compared to other physical and chemical factors. Overall, our study indicated that soil parent material may be an important factor influencing soil bacterial communities.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Human Footprints on Sediment Quality in the Shadegan International Wetland, Northwest of the Persian Gulf","authors":"Kourosh Sabbagh, Hamed Haghnazar, Renato Somma, Karen H. Johannesson, Mojtaba Pourakbar, Ehsan Aghayani","doi":"10.1007/s11270-024-07609-0","DOIUrl":"10.1007/s11270-024-07609-0","url":null,"abstract":"<div><p>This study focuses on assessing the contamination of surficial sediments in the Shadegan International Wetland, southwest of the Persian Gulf, identifying heavy metal concentrations, evaluating pollution levels using multi-element indices, and determining pollution sources through statistical analyses. Sediment samples were collected from fifteen sites across the wetland and analyzed for the concentrations of six heavy metal(loid)s including Arsenic (As), Chromium (Cr), Copper (Cu), Nickel (Ni), Lead (Pb), and Zinc (Zn). The results revealed moderate to considerable contamination of sediments with heavy metals such as Cr, Ni, Pb, and Zn, with concentrations exceeding local background levels. Multivariate statistical techniques, including Correlation Matrix and Principal Component Analysis, identified common pollution sources, such as municipal wastewater, industrial effluents, and agricultural runoff. Pollution indices, including the Modified Pollution Index (MPI), the Aggregative Toxicity Index (ATI), the Ecological Contamination Index (ECI), the Contamination Severity Index (CSI), the Toxic Risk Index (TRI), and the Total Toxic Units (STU), were employed to assess pollution severity, revealing moderate to heavy pollution levels in certain areas, primarily attributed to anthropogenic activities. The Safe-Heart indicator, a novel visualization tool introduced in this study, provided a comprehensive overview of sediment pollution, highlighting areas of high contamination and underscoring the urgent need for remediation measures to safeguard the wetland ecosystem and aquatic organisms.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142679771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Source Apportionment of Hydrocarbons in Ghana's Coastal Sediments: Utilizing Hydrocarbons Ratios and Advanced Statistical Methods","authors":"Ebenezer Aquisman Asare, Dickson Abdul-Wahab, Anita Asamoah, Rafeah Wahi, Zainab Ngaini, Charles Kofi Klutse, Omolayo Ajoke Omorinoye","doi":"10.1007/s11270-024-07588-2","DOIUrl":"10.1007/s11270-024-07588-2","url":null,"abstract":"<div><p>This study presents a comprehensive analysis of hydrocarbon pollution in Ghana's coastal sediments, with a focus on aliphatic hydrocarbons and polycyclic aromatic hydrocarbons. The primary objectives were to identify the sources of hydrocarbon pollution, assess its extent, and understand its implications for environmental management and policy. A total of 15 samples were collected from 5 sampling spots. Soxhlet extraction technique was applied. Analysis was conducted by gas chromatography/flame ionization detector for aliphatic hydrocarbons and gas chromatography/mass spectrometry for polycyclic aromatic hydrocarbons. Isomeric ratios, such as the carbon preference index, low molecular weight to high molecular weight <i>n</i>-alkanes, etc., were used to infer the sources of <i>n</i>-alkanes. Polycyclic aromatic hydrocarbons diagnostic ratios, including Benzo[b + k]fluoranthene/Benzo[a]pyrene, Phenanthrene/Anthracene, etc., were used to predict PAHs sources into petrogenic and pyrogenic sources. The study also utilized statistical tools like principal component analysis-absolute principal component scores-multiple linear regression for a detailed source appointment. The type of aliphatic hydrocarbon detected in samples ranged from C<sub>10</sub>H<sub>22</sub> to C<sub>33</sub>H<sub>68</sub>. Concerning aliphatic hydrocarbon, C<sub>21</sub>H<sub>44</sub> has the highest average presence at 5.224 μg/kg of dry mass in sediment samples whereas, C<sub>10</sub>H<sub>22</sub> shows the lowest mean concentration of 1.953 µg/kg of dry mass. The mean concentrations of the polycyclic aromatic hydrocarbons detected in samples ranged from 0.544 µg/kg for Anthracene to 2.168 µg/kg for Acenaphthene. Primary findings revealed a mix of petrogenic and pyrogenic sources in the coastal sediments, evidenced by the varying aliphatic hydrocarbons and polycyclic aromatic hydrocarbons ratios. Notably, the presence of carcinogenic PAHs highlighted potential health risks. The APCS-MLR analysis identified specific sources influencing hydrocarbon pollution. These include crude oil, urban runoff, atmospheric deposition, etc. This research contributes to a better understanding of coastal sediment pollution, serving as a foundation for future environmental policies and sustainable coastal management strategies in Ghana.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142679557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ge Zhang, Huifen Yang, Xingjie Lin, Yu Miao, Chi Zhang, Fangze Li, Zhikun Pang, Xin Xin
{"title":"Preparation and Characterization of a Novel Ca-Fe-Si-S Composite for the Simultaneous Stabilization of Heavy Metals in Arsenic Slag","authors":"Ge Zhang, Huifen Yang, Xingjie Lin, Yu Miao, Chi Zhang, Fangze Li, Zhikun Pang, Xin Xin","doi":"10.1007/s11270-024-07616-1","DOIUrl":"10.1007/s11270-024-07616-1","url":null,"abstract":"<div><p>In this work, a novel Ca-Fe-Si-S composite was prepared from thermal desorption residue through FeSO<sub>4</sub> impregnation-pyrolysis. The characteristics and modification process of the composite were specified through a series of analytical methods. And stabilization experiments were conducted to investigate the performance of prepared materials. The optimal Ca–Fe–Si–S composite was obtained at impregnation ratio of 10%, pyrolysis temperature of 900℃ and pyrolysis time of 60 min. The modification process included the dissolution of calcium hydroxide, the formation of gypsum and ferrous silicate, the dehydration of gypsum, the reduction decomposition of calcium sulfate, the decomposition of calcium carbonate and the solid reaction at high temperature. The obtained optimal Ca–Fe–Si–S composite was a multifunctional material mainly composed of high contents of Ca, Fe, Si, S, which corresponding to FeS, CaS, Ca<sub>2</sub>SiO<sub>4</sub>, Ca<sub>3</sub>Al<sub>2</sub>(SiO<sub>4</sub>)<sub>3</sub>, Ca<sub>3</sub>Fe<sub>2</sub>(SiO<sub>4</sub>)<sub>3</sub>, Ca<sub>5</sub>(SiO<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>. The application of 5% optimal Ca–Fe–Si–S composite successfully lowed the leaching concentrations of As, Zn, Cu, Cd in arsenic slag to meet the discharging standard. Meanwhile, the non-specifically bound and specifically bound of As totally decreased by 3.72%, and the acid extractable species of Zn, Cu, Cd reduced by 11.20%, 29.37%, 2.76% respectively. The distribution of stable species for heavy metals significantly increased as united results of surface complexation, chemical precipitation and ion/anion exchange reactions between the prepared composite and heavy metals. The findings of this research provide an effective material for the simultaneous stabilization of multiple heavy metals.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142672757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vikas Kumar, Absar Alam, Jeetendra Kumar, Venkatesh Ramrao Thakur, Vijay Kumar, Saket K. Srivastava, Dharm Nath Jha, Basanta Kumar Das
{"title":"Water Quality Assessment, Possible Pollution Source Identification from Anthropogenically Stressed River Yamuna, India using Hydrochemical, Water Quality Indices and Multivariate Statistics Analysis","authors":"Vikas Kumar, Absar Alam, Jeetendra Kumar, Venkatesh Ramrao Thakur, Vijay Kumar, Saket K. Srivastava, Dharm Nath Jha, Basanta Kumar Das","doi":"10.1007/s11270-024-07649-6","DOIUrl":"10.1007/s11270-024-07649-6","url":null,"abstract":"<div><p>For effective and sustainable water management, assessing the water quality and identifying potential sources that threaten the river system are crucial steps. In the present study, spatiotemporal variation of 20 hydrochemical variables, water quality indices, and multivariate statistics were applied to evaluate the quality of Yamuna River water. In the middle and lower stretch, the levels of electric conductivity (EC), total dissolved solids (TDS), turbidity, dissolved organic matter (DOM), chemical oxygen demand (COD), and nutrients were higher than in the upper stretch. Based on the trophic state index, the upper, middle, and lower stretches were mesotrophic, moderate, and low eutrophic in nature, respectively. In the drinking water category, the water quality index (WQI) ranged from almost good (upper stretch) to inappropriate (middle and lower stretch). Nemerow pollution index (PI<sub>Nemerow</sub>) and the comprehensive pollution index (CPI) indicated that most sites were strongly and moderately polluted, respectively. Various point and nonpoint sources of pollution deteriorated the quality of Yamuna water. Spatial cluster analysis divided eleven stations into three groups based on water variables similarity. Discriminate analysis indicated that water temperature, flow, turbidity, pH, dissolved oxygen (DO), magnesium hardness (Mg-H) and COD were the most influencing variables seasonally, while water flow, pH, chloride (Clˉ), DO, Mg-H, and nitrate–N were for spatial variation in Yamuna water quality. Five potential sources were identified using principal component analysis (PCA); anthropogenic, natural, agricultural non-point sources, metrological, and seasonal factors. This study emphasizes the importance of using multivariate statistical techniques to identify variability patterns and develop management plans to improve river water quality by identifying the key variables responsible for maximum deterioration.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142672403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lu Wang, Ruichang Zhang, Shufa Zhu, Jing Li, Xinquan Zhou, Ning Zhang, Shuge Peng, Xuefeng Wei
{"title":"Enhanced Adsorption of Cadmium onto Microplastics Derived from Polyethylene Mulching Film by Weathering","authors":"Lu Wang, Ruichang Zhang, Shufa Zhu, Jing Li, Xinquan Zhou, Ning Zhang, Shuge Peng, Xuefeng Wei","doi":"10.1007/s11270-024-07650-z","DOIUrl":"10.1007/s11270-024-07650-z","url":null,"abstract":"<div><p>The interaction between microplastics (MPs) and heavy metals would significantly determine their environmental impacts. The aim of this study was to investigate the influences of weathering on the affinity of MPs derived from polyethylene mulching film towards Cd(II). Weathered (w-PEMP) and pristine MPs (p-PEMP) were prepared from mulching film sampled from a garlic planting field and the pristine one, respectively. MPs were characterized by spectrum, surface charge and hydrophobicity analysis to determine the variations in physicochemical properties during the weathering process. Batch adsorption and desorption experiments were conducted to compare the affinity of MPs towards Cd(II) before and after the weathering process. Results showed that the Pseudo-second-order dynamics model satisfactorily described the adsorption of Cd(II) onto w-PEMP, indicating the different binding sites on the surface and the main role of chemical adsorption in the interaction. According to Langmuir model, maximum adsorption capacity of w-PEMP was more than 4 times higher than that of p-PEMP, corresponding to the coarse microscopic surface and the exogenous elements and more oxygen containing groups introduced in weathering process. A higher K<sub>f</sub> value of w-PEMP in Freundlich model suggested that the weathered microplastics surfaces had a higher adsorption affinity for the Cd(II) than p-PEMP. The weathering process also significantly increased desorption capacity of the MPs for Cd(II), and mitigated the influence of pH on the adsorption of Cd(II) onto the MPs. The weathering process markedly altered the surface morphology and physicochemical properties of MPs, and significantly enhanced the adsorption and desorption capacity of Cd(II).</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142679525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Md.Saiful Islam, Abdullah Al Bakky, Abu Reza Md. Towfiqul Islam, Mir Mohammad Ali, Md. Towhidul Islam, Zulhilmi Ismail, Md. Tanvir bin Hossain, Sujat Ahmed, Khalid A. Ibrahim, Abubakr M. Idris
{"title":"The Novel Study On Arsenic Contamination, Health Risk, and Approaches to Its Mitigation From Water Resource of a Developing Country: A potential review","authors":"Md.Saiful Islam, Abdullah Al Bakky, Abu Reza Md. Towfiqul Islam, Mir Mohammad Ali, Md. Towhidul Islam, Zulhilmi Ismail, Md. Tanvir bin Hossain, Sujat Ahmed, Khalid A. Ibrahim, Abubakr M. Idris","doi":"10.1007/s11270-024-07619-y","DOIUrl":"10.1007/s11270-024-07619-y","url":null,"abstract":"<div><p>The pollution and contamination by arsenic (As) in the water resources is a worldwide concern due to its adverse toxic effects on the environment and public health. The current study aimed to investigate arsenic levels in the groundwater system with the possible health risk, and sustainable mitigation strategies. The data on arsenic in the water system were collected from the Web of Science and Scopus databases. The published data showed that arsenic concentration (0.0002–19.0 mg/kg) in the water system in Bangladesh was higher than the permissible standards and data from other countries, indicating severe contamination of water resources by arsenic. The study concluded that the water resource in Bangladesh is not safe for human consumption. The review has also identified the research gaps in various strategies for controlling the arsenic problem and their impact on the ecosystems. The present study suggested future research directions on sustainable intervention, impacts assessment of arsenic on humans, and formulating existence policy that helps to combat arsenic contamination.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142672404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}