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Frontispiece: Non-Carbonized Pd Single-Atom Catalyst Supported on Lignin-Functionalized Phenolic Resin for Potent Catalytic Transfer Hydrogenation of Lignin-Derived Aldehydes 扉页：木质素功能化酚醛树脂负载的非碳化Pd单原子催化剂对木质素衍生醛的有效催化转移加氢
Angewandte Chemie Pub Date : 2025-05-30 DOI: 10.1002/ange.202582301
{"title":"Frontispiece: Non-Carbonized Pd Single-Atom Catalyst Supported on Lignin-Functionalized Phenolic Resin for Potent Catalytic Transfer Hydrogenation of Lignin-Derived Aldehydes","authors":"","doi":"10.1002/ange.202582301","DOIUrl":"https://doi.org/10.1002/ange.202582301","url":null,"abstract":"<p>A non-carbonization method for Pd SAC preparation using N-functionalized lignin-based phenolic resins as supports is presented by Chuanling Si and co-workers in their Research Article (e202503195). This approach enables the cross-linking of lignin, phenol and formaldehyde to form a unique network structure that provides abundant Pd-N coordination sites and facilitates the adsorption of ─CHO, making it possible to efficiently catalyze the conversion of various lignin-derived aldehydes.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202582301","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144179341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontispiece: Photoinduced Electron Transfer Across Phospholipid Bilayers in Anaerobic and Aerobic Atmospheres 前言：厌氧和好氧环境下磷脂双分子层的光诱导电子转移
Angewandte Chemie Pub Date : 2025-05-26 DOI: 10.1002/ange.202582201
{"title":"Frontispiece: Photoinduced Electron Transfer Across Phospholipid Bilayers in Anaerobic and Aerobic Atmospheres","authors":"","doi":"10.1002/ange.202582201","DOIUrl":"https://doi.org/10.1002/ange.202582201","url":null,"abstract":"<p>The biomimetic lipid bilayer of liposomes shown in the Frontispiece image symbolizes the synthetic membrane applied in the Research Article by Leticia González, Andrea Pannwitz et al. (e202423393) to compartmentalize reaction spaces for an oxidation and a reduction reaction. The membrane also assembles a light-active molecular wire for light-driven transmembrane electron transfer. This design is inspired by solar light energy conversion and transmembrane electron transfer in natural photosynthesis, symbolized by the leaf in the background. Image created with BioRender.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202582201","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontispiece: pH-Dependent Switching Between Nonlinear-Optical-Active Nitrate-Based Supramolecular Polymorphs 前言：非线性光学活性硝酸盐基超分子多晶之间的ph依赖开关
Angewandte Chemie Pub Date : 2025-05-19 DOI: 10.1002/ange.202582101
{"title":"Frontispiece: pH-Dependent Switching Between Nonlinear-Optical-Active Nitrate-Based Supramolecular Polymorphs","authors":"","doi":"10.1002/ange.202582101","DOIUrl":"https://doi.org/10.1002/ange.202582101","url":null,"abstract":"<p>The assembly of two π-conjugated planar primitives under different pH conditions unlocks the formation of three distinct nitrate-based supramolecular polymorphs, as reported by Chao Wu, Guangfeng Wei, and Chi Zhang et al. in their Research Article (e202503136). pH-Dependent secondary-bond interactions dictate the packing and transformation between these phases, yielding unique nonlinear optical properties. This study opens a new perspective in the precise engineering of high-performance nonlinear optical active supramolecular polymorphs.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 21","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202582101","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Outside Front Cover: Biomimetic Hierarchical Construction of Anti-Tumor Polyoxopalladates for Cancer Therapy (Angew. Chem. 23/2025) 外封面：用于癌症治疗的抗肿瘤多氧藻酸盐的仿生分层结构。化学23/2025)
Angewandte Chemie Pub Date : 2025-05-15 DOI: 10.1002/ange.202510019
Yue Zhao, Zheran Liu, Zijian Qin, Qinlong Wen, Jing Du, Xiang-Yu Ren, Chao-Qin Chen, Xingchen Peng, Ulrich Kortz, Peng Yang
{"title":"Outside Front Cover: Biomimetic Hierarchical Construction of Anti-Tumor Polyoxopalladates for Cancer Therapy (Angew. Chem. 23/2025)","authors":"Yue Zhao,&nbsp;Zheran Liu,&nbsp;Zijian Qin,&nbsp;Qinlong Wen,&nbsp;Jing Du,&nbsp;Xiang-Yu Ren,&nbsp;Chao-Qin Chen,&nbsp;Xingchen Peng,&nbsp;Ulrich Kortz,&nbsp;Peng Yang","doi":"10.1002/ange.202510019","DOIUrl":"https://doi.org/10.1002/ange.202510019","url":null,"abstract":"<p>Following the construction scheme of biomacromolecules, the hierarchical assembly of polyoxometalates via an overall management of covalent and non-covalent bindings is full of challenges and surprises. In their Research Article (e202505564), Peng Yang et al. achieved a highly ordered structural evolution of polyoxopalladates from monomer via dimer to supramolecular aggregates, along with an enhanced anti-tumor activity via DNA damage for cancer treatment.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510019","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144179317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inside Back Cover: First Encapsulation of Organometallic Single-Molecule Magnet into Single-Walled Carbon Nanotubes (Angew. Chem. 22/2025) 内页后盖：首次将有机金属单分子磁铁封装到单壁碳纳米管中。化学22/2025)
Angewandte Chemie Pub Date : 2025-05-13 DOI: 10.1002/ange.202510024
Haitao Zhang, Ryo Nakanishi, Takefumi Yoshida, Masahiko Nishijima, Koji Harano, Yoji Horii, Masahiro Yamashita
{"title":"Inside Back Cover: First Encapsulation of Organometallic Single-Molecule Magnet into Single-Walled Carbon Nanotubes (Angew. Chem. 22/2025)","authors":"Haitao Zhang,&nbsp;Ryo Nakanishi,&nbsp;Takefumi Yoshida,&nbsp;Masahiko Nishijima,&nbsp;Koji Harano,&nbsp;Yoji Horii,&nbsp;Masahiro Yamashita","doi":"10.1002/ange.202510024","DOIUrl":"https://doi.org/10.1002/ange.202510024","url":null,"abstract":"<p>Dysprosium cyclopentadienide is a single-molecule magnet. Like other organometallic compounds, it is highly sensitive to moisture and oxygen. Encapsulating it in single-walled carbon nanotubes protects it from decomposition by environmental water or oxygen and maintains its magnetic character, as reported by Haitao Zhang, Yoji Horii, Masahiro Yamashita et al. in their Research Article (e202503979).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510024","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Outside Back Cover: Photoredox Autocatalysis: Towards a Library of Generally Applicable Reductive Photocatalysts (Angew. Chem. 22/2025) 外封底：光氧化还原自催化：走向一个普遍适用的还原性光催化剂库（新）。化学22/2025)
Angewandte Chemie Pub Date : 2025-05-13 DOI: 10.1002/ange.202509841
Jaspreet Kaur, Mark John P. Mandigma, Nakul Abhay Bapat, Joshua P. Barham
{"title":"Outside Back Cover: Photoredox Autocatalysis: Towards a Library of Generally Applicable Reductive Photocatalysts (Angew. Chem. 22/2025)","authors":"Jaspreet Kaur,&nbsp;Mark John P. Mandigma,&nbsp;Nakul Abhay Bapat,&nbsp;Joshua P. Barham","doi":"10.1002/ange.202509841","DOIUrl":"https://doi.org/10.1002/ange.202509841","url":null,"abstract":"<p>Biarylsultams as self-synthesizing autophotocatalysts are represented as repeating tile patterns on mosaic lamps, with different coloured lamps representing different substituted biarylsultam derivatives. Reflecting the self-synthesizing library concept, the lamps are suspended within a library. On the spines of the books are imprinted the photocatalytic synthetic transformations exemplifying the reductive power of biarylsultam organophotocatalysts, as demonstrated by Joshua P. Barham et al. in their Research Article (e202423190).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202509841","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Outside Front Cover: Direct Observation of Cyclo-Pentazolate Anion Decomposition in a Tailored Molecular Trap (Angew. Chem. 22/2025) 外封面：直接观察环戊唑酸阴离子在定制分子阱中的分解（新）。化学22/2025)
Angewandte Chemie Pub Date : 2025-05-13 DOI: 10.1002/ange.202510027
Jinjin Zhang, Mingjie Tang, Siyuan Yang, Hongqing Li, Guangbin Cheng, Yongxing Tang, Ming Liu
{"title":"Outside Front Cover: Direct Observation of Cyclo-Pentazolate Anion Decomposition in a Tailored Molecular Trap (Angew. Chem. 22/2025)","authors":"Jinjin Zhang,&nbsp;Mingjie Tang,&nbsp;Siyuan Yang,&nbsp;Hongqing Li,&nbsp;Guangbin Cheng,&nbsp;Yongxing Tang,&nbsp;Ming Liu","doi":"10.1002/ange.202510027","DOIUrl":"https://doi.org/10.1002/ange.202510027","url":null,"abstract":"<p>A molecular cage was designed to trap cyclo-N<sub>5</sub>ˉ, a highly unstable anion, through collective weak interactions, as reported by Ming Liu et al. in their Research Article (e202501187). By intentionally avoiding strong interactions, the cage effectively preserved the aromaticity of cyclo-N<sub>5</sub>ˉ, while its decomposition was directly monitored via single-crystal X-ray diffraction.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510027","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inside Front Cover: Enzyme-Activated Orthogonal Proteolysis Chimeras for Tumor Microenvironment-Responsive Immunomodulation (Angew. Chem. 22/2025) 内封面：用于肿瘤微环境应答性免疫调节的酶激活正交蛋白水解嵌合体。化学22/2025)
Angewandte Chemie Pub Date : 2025-05-13 DOI: 10.1002/ange.202510013
Caixia Sun, Songhan Liu, Jun Wei Lau, Hanyu Yang, Yun Chen, Bengang Xing
{"title":"Inside Front Cover: Enzyme-Activated Orthogonal Proteolysis Chimeras for Tumor Microenvironment-Responsive Immunomodulation (Angew. Chem. 22/2025)","authors":"Caixia Sun,&nbsp;Songhan Liu,&nbsp;Jun Wei Lau,&nbsp;Hanyu Yang,&nbsp;Yun Chen,&nbsp;Bengang Xing","doi":"10.1002/ange.202510013","DOIUrl":"https://doi.org/10.1002/ange.202510013","url":null,"abstract":"<p>Novel tumor microenvironment-responsive enzyme-activated clickable PROTACs, termed as ENCTACs, are presented by Bengang Xing et al. in their Research Article (e202423057). Such ENCTACs enable selective formation of heterobifunctional degraders to disrupt BRD4 in tumor, effectively downregulating PD−L1 for immunotherapy. The cover illustration depicts fragments conjugation after enzyme reaction, realizing protein intervention and activating the antitumoral immune system.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510013","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “An Advanced 3D Crosslinked Conductive Binder for Silicon Anodes: Leveraging Glycerol Chemistry for Superior Lithium-Ion Battery Performance” 更正“用于硅阳极的先进3D交联导电粘合剂：利用甘油化学获得卓越的锂离子电池性能”
Angewandte Chemie Pub Date : 2025-05-08 DOI: 10.1002/ange.202505357
{"title":"Correction to “An Advanced 3D Crosslinked Conductive Binder for Silicon Anodes: Leveraging Glycerol Chemistry for Superior Lithium-Ion Battery Performance”","authors":"","doi":"10.1002/ange.202505357","DOIUrl":"https://doi.org/10.1002/ange.202505357","url":null,"abstract":"<p>Yu, Y., Yang, C., Zhu, J., Xue, B., Zhang, J., Jiang, M. An Advanced 3D Crosslinked Conductive Binder for Silicon Anodes: Leveraging Glycerol Chemistry for Superior Lithium-Ion Battery Performance. Angew. Chem. Int. Ed. 2024; p.e202418794.</p><p>In the above-mentioned article, the affiliation of the third author is partially incorrect. The correct affiliation is “Smart Devices, Brewer Science Inc., Springfield, MO 65806, USA.” Please remove the affiliation “Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USA.”</p><p>We apologize for this error.</p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 22","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202505357","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “Copper(I) Catalysed Diboron(4) Reduction of Nitrous Oxide” 对“铜(I)催化二硼(4)还原氧化亚氮”的更正
Angewandte Chemie Pub Date : 2025-05-08 DOI: 10.1002/ange.202506114
{"title":"Correction to “Copper(I) Catalysed Diboron(4) Reduction of Nitrous Oxide”","authors":"","doi":"10.1002/ange.202506114","DOIUrl":"https://doi.org/10.1002/ange.202506114","url":null,"abstract":"<p>T. M. Hood, R. S. C. Charman, D. J. Liptrot, A. B. Chaplin. <i>Angew. Chem. Int. Ed</i>. <b>2024</b>, <i>63</i>, e202411692 (https://doi.org/10.1002/anie.202411692)</p><p>The pressures of N<sub>2</sub>O used in this study were measured in gauge pressure and so should be expressed as 1 or 2 “bar gauge” rather than 1 or 2 “bar”. This does not affect the scientific interpretation of the findings as the deoxygenation reaction is zero order in N<sub>2</sub>O and the gas is not the limiting reagent. The estimated quantity of N<sub>2</sub>O quoted in Table 1 (footnote a) should correspondingly read “10 mmol” rather than “5 mmol”. Reactions performed under argon or using a 1:1 mixture of N<sub>2</sub>O/CO<sub>2</sub> were carried out using “1 atm” (absolute) pressure rather than “1 bar”. The Supporting Information has been corrected accordingly.</p><p>We apologize for this error.</p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202506114","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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