Connor S. Durfy, Joseph A. Zurakowski, Dr. Marcus W. Drover
{"title":"Frontispiz: CO2 Reduction at a Borane-Modified Iron Complex: A Secondary Coordination Sphere Strategy","authors":"Connor S. Durfy, Joseph A. Zurakowski, Dr. Marcus W. Drover","doi":"10.1002/ange.202580961","DOIUrl":"https://doi.org/10.1002/ange.202580961","url":null,"abstract":"<p>Bifunctional complex design can enable selective activation of the strong C=O bonds in CO2. Much like a fiddler crab, the {Fe-H/Cp*-BCy2} complex employed by Marcus W. Drover and co-workers in their Research Article (e202421599), features two distinct \"claws\". This study highlights that cooperativity between the iron hydride and pendant Lewis acidic borane is integral to facilitate the reduction of CO2 to a C1 product.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580961","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143475646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qi Jiang, Dr. Deming Xia, Xiaofan Li, Prof. Dr. Hong Zhang, Dr. Rujing Yin, Dr. Huaijun Xie, Prof. Dr. Hong-bin Xie, Prof. Dr. Jie Jiang, Prof. Dr. Jingwen Chen, Prof. Dr. Joseph S. Francisco
{"title":"Frontispiz: Rapid N2O Formation from N2 on Water Droplet Surfaces","authors":"Qi Jiang, Dr. Deming Xia, Xiaofan Li, Prof. Dr. Hong Zhang, Dr. Rujing Yin, Dr. Huaijun Xie, Prof. Dr. Hong-bin Xie, Prof. Dr. Jie Jiang, Prof. Dr. Jingwen Chen, Prof. Dr. Joseph S. Francisco","doi":"10.1002/ange.202580962","DOIUrl":"https://doi.org/10.1002/ange.202580962","url":null,"abstract":"<p>N2 has long been considered as a stable reservoir in the atmosphere. However, in their Communication (e202421002), Deming Xia, Jingwen Chen, Joseph S. Francisco et al. proposed a novel reduction-then-oxidation pathway, through which N2 can be rapidly converted to N2O by O2 and O3 on water droplet surfaces.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580962","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143475511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dr. Yue Zhou, Dr. Dong Chen, Dr. Wanmiao Gu, Dr. Wentao Fan, Dr. Runguo Wang, Dr. Liang Fang, Dr. Qing You, Dr. Shengli Zhuang, Guoqing Bian, Dr. Lingwen Liao, Ziyan Zhou, Dr. Nan Xia, Prof. Dr. Jun Yang, Prof. Dr. Zhikun Wu
{"title":"Frontispiz: Chemical Synthesis of ~1 nm Multilevel Capacitor-like Particles with Atomic Precision","authors":"Dr. Yue Zhou, Dr. Dong Chen, Dr. Wanmiao Gu, Dr. Wentao Fan, Dr. Runguo Wang, Dr. Liang Fang, Dr. Qing You, Dr. Shengli Zhuang, Guoqing Bian, Dr. Lingwen Liao, Ziyan Zhou, Dr. Nan Xia, Prof. Dr. Jun Yang, Prof. Dr. Zhikun Wu","doi":"10.1002/ange.202580862","DOIUrl":"https://doi.org/10.1002/ange.202580862","url":null,"abstract":"<p>An increasing need for the miniaturization of optoelectronic devices or machines has become evident as we are entering the post-Moore era. One bold conceit is that chemically synthesized nanoparticles (NP) can function as nanodevices or nanomachines. In their Research Article (e202420931), Zhikun Wu, Jun Yang, Nan Xia et al. demonstrate the feasibility by reporting a novel nanocluster with multileveled capacitor-like character, which is identified by a Cd(II) transport from the outershell to the innermost position after charged with NaBH4, as well as some other ways such as NPA charge distribution, voltammetry and electrocatalytic reduction of CO2 to CO. An intra-NP anti-galvanic reduction was found after the migrating of charge carrier.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580862","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuhang Wang, Di Zhang, Bin Sun, Xue Jia, Linda Zhang, Hefeng Cheng, Jun Fan, Hao Li
{"title":"Frontispiz: Divergent Activity Shifts of Tin-Based Catalysts for Electrochemical CO2 Reduction: pH-Dependent Behavior of Single-Atom Versus Polyatomic Structures","authors":"Yuhang Wang, Di Zhang, Bin Sun, Xue Jia, Linda Zhang, Hefeng Cheng, Jun Fan, Hao Li","doi":"10.1002/ange.202580861","DOIUrl":"https://doi.org/10.1002/ange.202580861","url":null,"abstract":"<p>In their Communication (e202418228), Hao Li and co-workers reveal an exciting contrast: the electric field response of the binding strength of *OCHO on Sn-N4-C and polyatomic Sn displays opposite behaviors. This response results in a fascinating, opposite pH-dependent volcano evolution for Sn-N4-C and polyatomic Sn. Most importantly, we propose that distinct strategies are necessary for designing catalysts using single-atom versus polyatomic metal catalysts.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580861","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Huilin Xie, Kaibin Zhong, Shihao Niu, Xiaoxu Li, Zexu Hu, Guang Xiao, Prof. Yifu Huang, Prof. Hongjie Zhang, Prof. Yuan Liu, Prof. Hefeng Zhang, Prof. Qiuquan Cai
{"title":"Rücktitelbild: Air-Mediated Biomimetic Synthesis of Polyhydroxyalkanoate with C4 Diol (Angew. Chem. 8/2025)","authors":"Huilin Xie, Kaibin Zhong, Shihao Niu, Xiaoxu Li, Zexu Hu, Guang Xiao, Prof. Yifu Huang, Prof. Hongjie Zhang, Prof. Yuan Liu, Prof. Hefeng Zhang, Prof. Qiuquan Cai","doi":"10.1002/ange.202502402","DOIUrl":"https://doi.org/10.1002/ange.202502402","url":null,"abstract":"<p>A strategy for the biomimetic synthesis of polyhydroxyalkanoates (PHA) using C4 diol and air, catalyzed by a synergistic catalyst, was presented by Qiuquan Cai and co-workers in their Research Article (e202417660). The resulting PHA can reversibly convert back to a small-molecule monomer in the form of a five-membered ring, demonstrating excellent ecological sustainability. This study highlights the potential for large-scale synthesis of high-value PHAs from diverse non-grain-based diols.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202502402","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Taito Hashimoto, Mario de la Hoz Tomás, Dr. Ryusei Oketani, Prof. Dr. Boiko Cohen, Miki Naruoka, Prof. Dr. Norimitsu Tohnai, Prof. Dr. Abderrazzak Douhal, Prof. Dr. Ichiro Hisaki
{"title":"Rücktitelbild: Single Crystalline, Non-Stoichiometric Hydrogen-Bonded Organic Frameworks Showing Versatile Fluorescence Depending on Composition Ratios and Distributions (Angew. Chem. 9/2025)","authors":"Taito Hashimoto, Mario de la Hoz Tomás, Dr. Ryusei Oketani, Prof. Dr. Boiko Cohen, Miki Naruoka, Prof. Dr. Norimitsu Tohnai, Prof. Dr. Abderrazzak Douhal, Prof. Dr. Ichiro Hisaki","doi":"10.1002/ange.202502492","DOIUrl":"https://doi.org/10.1002/ange.202502492","url":null,"abstract":"<p>Non-stoichiometric cocrystals of hydrogen-bonded organic framework were constructed from two tetracarboxylic acids, possessing naphthalene and benzothiadiazole cores. The single crystals showed versatile fluorescence, including not only homogeneous color such as purple, blue, green and white, but also heterogeneous bicolor such as blue-green and green-yellow depending on the component ratios and distributions. In their Research Article (e202419992), Ichiro Hisaki, Abderrazzak Douhal and co-workers revealed the relationship between crystal structures and fluorescent properties of single crystals.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202502492","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143475373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dr. Fei Gou, Qiuting Wang, Zihong Yang, Dr. Wenju Chang, Prof. Dr. Jie Shen, Prof. Dr. Huaqiang Zeng
{"title":"Frontispiz: Artificial Lithium Channels Built from Polymers with Intrinsic Microporosity","authors":"Dr. Fei Gou, Qiuting Wang, Zihong Yang, Dr. Wenju Chang, Prof. Dr. Jie Shen, Prof. Dr. Huaqiang Zeng","doi":"10.1002/ange.202580762","DOIUrl":"https://doi.org/10.1002/ange.202580762","url":null,"abstract":"<p>Polymers with intrinsic microporosity have been pioneered by Huaqiang Zeng et al. in their Research Article (e202418304) as a compelling platform for constructing artificial lithium ion channels. These Li<sup>+</sup> channels achieve exceptionally high Li<sup>+</sup> transport rates coupled with exceptional selectivity. Remarkably, their transport properties can be precisely tuned by adjusting the synthesis temperature, presenting a versatile strategy for optimizing performance.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580762","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143380198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yeonsu Kwak, Yu-Jin Lee, Seongeun Moon, Kimoon Lee, Safira Ramadhani, Eui-Rim On, Chang-il Ahn, Son-Jong Hwang, Hyuntae Sohn, Hyangsoo Jeong, Suk Woo Nam, Chang Won Yoon, Yongmin Kim
{"title":"Innenrücktitelbild: Scalable Atomic-Layer Tailoring of Abundant Oxide Supports Unlocks Superior Interfaces for Low-Metal-Loading Dehydrogenation (Angew. Chem. 9/2025)","authors":"Yeonsu Kwak, Yu-Jin Lee, Seongeun Moon, Kimoon Lee, Safira Ramadhani, Eui-Rim On, Chang-il Ahn, Son-Jong Hwang, Hyuntae Sohn, Hyangsoo Jeong, Suk Woo Nam, Chang Won Yoon, Yongmin Kim","doi":"10.1002/ange.202502040","DOIUrl":"https://doi.org/10.1002/ange.202502040","url":null,"abstract":"<p>A novel approach to H<sub>2</sub> extraction from liquid organic hydrocarbon carriers (LOHCs) using ultralow loading of Pt nanoparticles on a modified alumina structure with an ALD-titanium oxide shell is shown by Yongmin Kim et al. in their Research Article (e202417598). This unique catalyst design efficiently releases hydrogen from LOHCs, outperforming equivalent Pt and commercial catalysts. The ALD-TiO<sub>2</sub> shell enhances the catalytic activity while minimizing Pt usage.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202502040","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143475375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dr. Prisca Hamm, Dr. Marc D. Driessen, Dr. Niklas Hauptstein, Dr. Josef Kehrein, Rafael Worschech, Dr. Paria Pouyan, Prof. Dr. Rainer Haag, Prof. Dr. Ulrich S. Schubert, Prof. Dr. Thomas D. Müller, Prof. Dr. Dr. Lorenz Meinel, Prof. Dr. Tessa Lühmann
{"title":"Titelbild: Entschlüsselung der Polymer-Interaktionen in Biokonjugaten unterschiedlicher Architektur durch zeitaufgelöste limitierte Proteolyse mit massenspektrometrischer Analyse (Angew. Chem. 9/2025)","authors":"Dr. Prisca Hamm, Dr. Marc D. Driessen, Dr. Niklas Hauptstein, Dr. Josef Kehrein, Rafael Worschech, Dr. Paria Pouyan, Prof. Dr. Rainer Haag, Prof. Dr. Ulrich S. Schubert, Prof. Dr. Thomas D. Müller, Prof. Dr. Dr. Lorenz Meinel, Prof. Dr. Tessa Lühmann","doi":"10.1002/ange.202502486","DOIUrl":"https://doi.org/10.1002/ange.202502486","url":null,"abstract":"<p>Limited proteolysis mass spectrometry allows for in deep molecular characterization of complex bioconjugates. In their Communication (e202415354), Lorenz Meinel, Tessa Lühmann et al. present a protocol for time-resolved proteolysis, deciphering interaction sites within protein–protein complexes and protein–polymer bioconjugates by <sup>15</sup>N labeling. The cover image showcases the proteolysis of interferon-α2a and interferon-bioconjugates, resulting in peptide fragments that are analyzed using mass spectrometry.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202502486","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143475376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhenxing Wang, Muqing Si, Junyi Han, Ying Shen, Guangqiang Yin, Prof. Kaiyang Yin, Prof. Peng Xiao, Prof. Tao Chen
{"title":"Frontispiz: Hydrogen-Bonded Supramolecular Network Enabled Gentle Reprogramming of Liquid Crystal Elastomer toward Evolutionary Robot","authors":"Zhenxing Wang, Muqing Si, Junyi Han, Ying Shen, Guangqiang Yin, Prof. Kaiyang Yin, Prof. Peng Xiao, Prof. Tao Chen","doi":"10.1002/ange.202580761","DOIUrl":"https://doi.org/10.1002/ange.202580761","url":null,"abstract":"<p>The modular assembly of a hydrogen-bonded supramolecular liquid crystal elastomer (LCE) robot for multitasking is reported by Kaiyang Yin, Peng Xiao, Tao Chen et al. in their Research Article (e202416095). The behavior of the LCE actuator can be reconfigured and reprogramed on demand.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580761","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143380197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}