前言：阐明水相铁铬氧化还原液流电池中六氰铬氧化还原介质的配体交换动力学

Angewandte Chemie Pub Date : 2025-09-15 DOI:10.1002/ange.202583801

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引用次数: 0

摘要

在他们的研究文章（e202507119）中，Hyun-Wook Lee等人揭示了在[Cr(CN)6]4−/3−的配位破坏驱动下，六氰铬酸盐无溶质中氰化物和氢氧化物之间的配体交换是一个关键的稳定性因素。优化[OH−]/[CN−]比例稳定了氧化还原介质，使水相铁铬氧化还原液流电池的长期性能得以实现。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Frontispiece: Elucidating Ligand Exchange Dynamics of Hexacyanochromate-Based Redox Mediators in Aqueous Iron-Chromium Redox Flow Batteries

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Frontispiece: Elucidating Ligand Exchange Dynamics of Hexacyanochromate-Based Redox Mediators in Aqueous Iron-Chromium Redox Flow Batteries

In their Research Article (e202507119), Hyun-Wook Lee et al. reveal that ligand exchange between cyanide and hydroxide in a hexacyanochromate negolyte, driven by coordination disruption of [Cr(CN)₆]^4−/3−, is a key stability factor. Optimizing the [OH⁻]/[CN⁻] ratio stabilizes the redox mediator, enabling long-term performance in aqueous iron-chromium redox flow batteries.

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来源期刊

Angewandte Chemie 化学科学, 有机化学, 有机合成

自引率

0.00%

发文量

审稿时长

1 months