前言:阴离子环芳烯中异常的抗卡沙辐射和TADF

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引用次数: 0

摘要

在环芳烯中掺入非苯环对其分子几何和光物理性质产生了深远的影响。在他们的研究文章(e202512344)中,郑舟和同事报告了一种还原裂解策略,将{FeCp}部分解离,产生两个阴离子环芳烯,这两个环芳烯表现出异常的抗卡沙发射和超长的热激活延迟荧光。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Frontispiece: Abnormal Anti-Kasha Emission and TADF in Anionic Cycloarylenes

Frontispiece: Abnormal Anti-Kasha Emission and TADF in Anionic Cycloarylenes

Incorporation of non-benzenoid rings into cycloarylenes profoundly affects their molecular geometry and photophysics. In their Research Article (e202512344), Zheng Zhou and co-workers report a reductive cleavage strategy that dissociates {FeCp} moieties to yield two anionic cycloarylenes, which exhibit abnormal anti-Kasha emission and ultra-long thermally activated delayed fluorescence.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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