Frontispiece: An Electrochemical Study of Key Catalytically Active Gold Complexes

Knowing the oxidative potentials of gold complexes is essential for a better understanding of their implications in various mechanisms, and also crucial for the rational design of new catalysts. In their Communication (e202509683), Véronique Michelet, Romain Melot, and co-workers determined these data using cyclic voltammetry and established key trends based on the nature of the ligands involved. As illustrated in this image, the electrochemical investigation of Au(I) complexes sheds light on how ligand structure significantly impacts gold oxidizability.