Frontispiece: An Electrochemical Study of Key Catalytically Active Gold Complexes

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Abstract

Knowing the oxidative potentials of gold complexes is essential for a better understanding of their implications in various mechanisms, and also crucial for the rational design of new catalysts. In their Communication (e202509683), Véronique Michelet, Romain Melot, and co-workers determined these data using cyclic voltammetry and established key trends based on the nature of the ligands involved. As illustrated in this image, the electrochemical investigation of Au(I) complexes sheds light on how ligand structure significantly impacts gold oxidizability.

Abstract Image

Abstract Image

前言:关键催化活性金配合物的电化学研究
了解金配合物的氧化电位对于更好地理解其在各种机制中的意义至关重要,对于合理设计新的催化剂也至关重要。在他们的通讯(e202509683)中,v罗尼克·米舍莱、罗曼·梅洛及其同事使用循环伏安法确定了这些数据,并根据所涉及的配体的性质建立了关键趋势。如图所示,Au(I)配合物的电化学研究揭示了配体结构如何显著影响金的氧化性。
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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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