外封面:具有18个交叉的拓扑手性[6]链烷的立体选择性自组装(新)。化学41/2025)

Zheng Cui, Li-Yan Hao, Yi-Fan Yuan, Xiao-Peng Xuan, Guo-Xin Jin
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引用次数: 0

摘要

封面图像描绘了一个[6]链烷拓扑结构,由6个互锁环和18个交叉点编织而成,通过协调驱动的自组装形成。对映体纯配体的手性转移只产生拓扑对映体。下面的镜面半透明结构代表了天体背景下的反方向拓扑结构,突出了整体的优雅和宏伟。详情请见Jin Guo-Xin, Zheng Cui等人的Research Article (e202515400)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Outside Front Cover: Stereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings (Angew. Chem. 41/2025)

Outside Front Cover: Stereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings (Angew. Chem. 41/2025)

The cover image depicts a [6]catenane topology woven from six interlocked rings with 18 crossings, formed via coordination-driven self-assembly. Chirality transfer from enantiopure ligands yields exclusively topological enantiomers. The mirrored, semi-transparent structure below represents the opposite-handed topology against a celestial backdrop, highlighting the elegance and grandeur of the assembly. Details are reported by Guo-Xin Jin, Zheng Cui, et al. in their Research Article (e202515400).

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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