Analytical Sciences最新文献_第5页

Designing an optical sensor with exceptional sensitivity and specificity for the detection of ultra-trace amounts of boron 设计一种具有特殊灵敏度和特异性的光学传感器，用于检测超痕量硼。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-14 DOI: 10.1007/s44211-025-00737-5

Abdullah H. Alluhayb, Ahmed H. Alanazi, Alaa M. Younis, Refat El-Sayed, Khaled F. Debbabi, Alaa S. Amin

{"title":"Designing an optical sensor with exceptional sensitivity and specificity for the detection of ultra-trace amounts of boron","authors":"Abdullah H. Alluhayb, Ahmed H. Alanazi, Alaa M. Younis, Refat El-Sayed, Khaled F. Debbabi, Alaa S. Amin","doi":"10.1007/s44211-025-00737-5","DOIUrl":"10.1007/s44211-025-00737-5","url":null,"abstract":"<div><p>A specialized optical chemical sensor for boron detection was designed using a polymer inclusion membrane (PIM). This unique sensor relies on an encapsulation method to create its optical membrane. The components involved in this sensor include azomethine H (AMH) as the reactive agent, polyvinyl chloride as the foundational polymer, and dinonylnaphthalene sulphonic acid (DNNS) as the extraction agent within the PIM structure. Various parameters, such as membrane thickness, concentration of AMH and DNNS, plasticizer proportions, stirring dynamics, and the pH of the solution under study, significantly affected the sensor’s performance. Within a detection range spanning 4.0–116 ng mL<sup>−1</sup> of boron, the sensor demonstrated a strong linear relationship with detection and quantification thresholds of 1.25 and 3.94 ng mL<sup>−1</sup>, respectively. The peak absorption wavelength (<i>λ</i><sub>max</sub>) for this PIM-based sensor was identified at 424 nm. Moreover, the sensor displayed a reproducibility (RSD) of 1.65% and a repeatability RSD of 1.43%, coupled with a swift response time of approximately 3.0 min. The membrane selectivity was tested against boron in acidic environments. This proposed sensor effectively detected boron in diverse samples such as water, vegetation, soil, and ceramic samples, with findings corroborated by an AAS technique.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div><div><p>Schematic representation for the preparation, and complexation of the formed sensor and B‏‏–AMH–DNNS complex</p></div></div></figure></div></div>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":"41 4","pages":"473 - 486"},"PeriodicalIF":1.8,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143630058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solvent properties of ionic liquids on complex formation of Ni(II) ion with molecular liquids 离子液体与分子液体络合形成Ni（II）离子的溶剂性质。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-14 DOI: 10.1007/s44211-025-00741-9

Toshiyuki Takamuku

{"title":"Solvent properties of ionic liquids on complex formation of Ni(II) ion with molecular liquids","authors":"Toshiyuki Takamuku","doi":"10.1007/s44211-025-00741-9","DOIUrl":"10.1007/s44211-025-00741-9","url":null,"abstract":"<div><p>Room-temperature ionic liquids (ILs) attract much attention as green solvents because of their negligible volatility and non-flammability. In analytical chemistry, the application of ILs to chemical separation and solvent extraction has been investigated. However, there have been a smaller number of reports on the mechanisms of chemical equilibria in the solvents of ILs at a molecular level. In this review, the series of our investigations on the complex formation of Ni<sup>2+</sup> ion with molecular liquids (MLs) in imidazolium-based ILs, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([C<sub>2</sub>mim][TFSA]) and 1-methyl-3-octylimidazolium bis(trifluoromethylsulfonyl)amide ([C<sub>8</sub>mim][TFSA]) was summarized. The MLs involved methanol (MeOH), ethanol (EtOH), acetonitrile (AN), and dimethyl sulfoxide (DMSO). In [C<sub>2</sub>mim][TFSA], the Ni<sup>2+</sup>-ML complexes are stabler in the sequence of DMSO >> AN > EtOH ≈ MeOH complexes, which almost depends on the electron donicities of MLs. In contrast, in [C<sub>8</sub>mim][TFSA], the sequence changes to AN > DMSO > EtOH > MeOH complexes, despite of the lowest electron donicity of AN. Thus, only the electron donicities of MLs do not decide the stability of the complexes. The reasons for the stabilities of the Ni<sup>2+</sup>-ML complexes were interpreted in terms of the microscopic interactions between ML and the ILs’ cation observed by the infrared (IR) and <sup>1</sup>H and <sup>13</sup>C nuclear magnetic resonance (NMR) spectroscopic techniques. Furthermore, to clarify the effects of ML cluster formation on the complex formation mechanisms, the heterogeneous mixing between IL and ML were quantitatively evaluated by small-angle neutron scattering (SANS) at the mesoscopic scale.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":"41 5","pages":"609 - 622"},"PeriodicalIF":1.8,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143630062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Quantification techniques of soil organic carbon: an appraisal. 土壤有机碳定量技术评价

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-11 DOI: 10.1007/s44211-025-00746-4

Avinash Kanagaraj, Sathiya Bama Kaliappan, Thenmozhi Shanmugam, Bharani Alagirisamy, Kumaraperumal Ramalingam

{"title":"Quantification techniques of soil organic carbon: an appraisal.","authors":"Avinash Kanagaraj, Sathiya Bama Kaliappan, Thenmozhi Shanmugam, Bharani Alagirisamy, Kumaraperumal Ramalingam","doi":"10.1007/s44211-025-00746-4","DOIUrl":"https://doi.org/10.1007/s44211-025-00746-4","url":null,"abstract":"<p><p>This review provides an overview of the analytical methods utilized across laboratory, field, landscape, and regional scales for assessing soil organic carbon (SOC) in agricultural soils. The significance of soil depth in SOC estimation underscores the importance of selecting appropriate sampling designs, soil depths, analytical methods, and baseline selection methods for accurate soil carbon stock estimation. Traditional methods such as wet digestion and dry combustion (DC) remain prevalent in routine laboratory analysis, with DC considered the standard reference method, surpassing wet digestion in accuracy and reliability. Recent advancements in spectroscopic techniques enable SOC measurement both in laboratory settings and in situ, even at greater depths. Aerial spectroscopy, which employs multispectral and hyperspectral sensors, unmanned aerial vehicles (UAVs), or satellites, facilitates surface SOC measurement. While the current precision levels of these techniques may be limited, forthcoming hyperspectral sensors with enhanced signal‒to‒noise ratios are expected to significantly increase the prediction accuracy. Furthermore, at the global level, satellite remote sensing techniques have considerable potential for SOC estimation. Regardless of whether traditional or novel approaches are utilized, the selection of SOC determination depends on available resources and research requirements, each of which plays a distinct role in soil carbon and climate research. This paper provides an overview of various scale-dependent techniques for measuring SOC in agricultural soil, along with its potential limitations.</p>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143603099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multifunctional metal complex systems emerging from analytical chemistry for theranostic applications 多功能金属复合系统从分析化学中出现，用于治疗应用。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-11 DOI: 10.1007/s44211-025-00740-w

Nobuhiko Iki

{"title":"Multifunctional metal complex systems emerging from analytical chemistry for theranostic applications","authors":"Nobuhiko Iki","doi":"10.1007/s44211-025-00740-w","DOIUrl":"10.1007/s44211-025-00740-w","url":null,"abstract":"<div><p>Metal complexes have long played a pivotal role in analytical chemistry due to their ability to detect and separate ions through the synergistic interaction between metal centers and ligands. This functionality can be further enhanced by integrating metal complexes non-covalently with various media, such as materials or separation platforms. Over the past four decades, the author has explored metal complex systems, including thiacalixarene–lanthanide(III) complexes, diradical platinum(II) complexes, and MOF-74, which exhibit a broad spectrum of functionalities spanning analytical applications to theranostics. Examples discussed in this review include luminescent supramolecular sensors for soft-metal ions, upconverting complexes, near-infrared light-absorbing probes for pH and hydrophobic cavities, magnetic resonance imaging (MRI), photoacoustic imaging, photothermal therapy, and neutron capture therapy. The multifunctionality of these systems arises from their cooperative, synergistic, and supramolecular nature, underpinned by non-covalent interactions among their components. Analytical chemistry has been, and will continue to be, a cornerstone for the discovery and development of such multifunctional metal complex systems.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":"41 5","pages":"623 - 637"},"PeriodicalIF":1.8,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143603129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ratiometric electrochemical aptasensor based on functionalized graphene nanocomposites for detection of CA19-9. 基于功能化石墨烯纳米复合材料的比例电化学感应传感器检测CA19-9。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-06 DOI: 10.1007/s44211-025-00743-7

Feifei Lin, Xiaosha Li, Jian Zhang, Hailin Zhang, Zemiao Zhang, Lijie Hou, Bingjun Shen, Lihong Jin

{"title":"Ratiometric electrochemical aptasensor based on functionalized graphene nanocomposites for detection of CA19-9.","authors":"Feifei Lin, Xiaosha Li, Jian Zhang, Hailin Zhang, Zemiao Zhang, Lijie Hou, Bingjun Shen, Lihong Jin","doi":"10.1007/s44211-025-00743-7","DOIUrl":"https://doi.org/10.1007/s44211-025-00743-7","url":null,"abstract":"<p><p>A ratiometric electrochemical aptasensor was constructed based on rGO-cMWCNTs/AuNPs functionalized graphene nanocomposites for the detection of CA19-9 in serum samples. First, rGO-cMWCNTs/AuNPs nanocomposites were modified on the surface of glassy carbon electrodes. Second, the aptamer complementary chain labeled with anthraquinone-2-carboxylic acid (cDNA-AQ) was covalently linked by Au-S. Finally, the hybrid chain was formed with ferrocene (Fc)-labeled Apt-Fc by base pairing, and a sensing interface with specific target recognition and electrochemical signal amplification was constructed. In this study, the ratio of response signal to internal reference signal (I<sub>Fc</sub>/I<sub>AQ</sub>) was used as the target molecular response signal to achieve the quantitative detection of CA19-9. The ratiometric electrochemical biosensor based on aptamer molecular recognition has good selectivity, reproducibility and stability. Under the optimal reaction conditions, the logarithm of CA19-9 concentration had a good linear relationship with I<sub>Fc</sub>/I<sub>AQ</sub>, the linear range was 1.0-1.0 × 10<sup>6</sup> mU/mL, the detection limit was 0.65 mU/mL, and the recovery rate in CA19-9 serum was 94.12-97.83%. The results show that the sensor has potential practical application prospects, and provides a simple and feasible strategy for the rapid and accurate detection of other tumor markers.</p>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143565504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanobiodevices and quantum life science for future healthcare 未来医疗保健的纳米生物器件和量子生命科学。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-04 DOI: 10.1007/s44211-025-00742-8

Taisuke Shimada, Takao Yasui, Hiroshi Yukawa, Yoshinobu Baba

引用次数: 0

Stratified quantification of targets in skin by three-dimensional Raman spectroscopic imaging. 三维拉曼光谱成像对皮肤靶标的分层定量。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-01 DOI: 10.1007/s44211-025-00738-4

Yunchi Hu, Tong Ha, Yan Kang, Yiping Du

引用次数: 0

Quantitative analysis of related substances in acetaminophen tablets using pre-column derivatization coupled with HPLC-ICP-MS. 柱前衍生联用HPLC-ICP-MS定量分析对乙酰氨基酚片中有关物质。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-03-01 DOI: 10.1007/s44211-025-00739-3

Yalan Liu, Yaru Peng, Qiping Wu, Zeneng Cheng, Feifan Xie, Sanwang Li

{"title":"Quantitative analysis of related substances in acetaminophen tablets using pre-column derivatization coupled with HPLC-ICP-MS.","authors":"Yalan Liu, Yaru Peng, Qiping Wu, Zeneng Cheng, Feifan Xie, Sanwang Li","doi":"10.1007/s44211-025-00739-3","DOIUrl":"https://doi.org/10.1007/s44211-025-00739-3","url":null,"abstract":"<p><p>High-performance liquid chromatography coupled with inductively coupled plasma-mass spectrometry (HPLC-ICP-MS) is a promising structure-independent technique for accurate quantification of drug-related substances in pharmaceuticals. In this study, we aimed to develop a sensitive HPLC-ICP-MS method, combined with pre-column derivatization, to quantify related substances in acetaminophen tablets. Through this method, we enhanced the sensitivity and accuracy of detecting substances that do not directly respond to ICP-MS. The key advancements include the systematic optimization of derivatization conditions and the establishment of a calibration curve with correlation coefficients greater than 0.999. The method achieved impressive limits of quantification: 0.089 µM for o-acetaminophenol, 0.097 µM for p-nitrophenol, and 0.161 µM for p-aminophenol. It demonstrated suitable accuracy and precision for the following substances: o-acetaminophenol with accuracy between 95.7-104.4% and precision ≤ 4.9%, p-nitrophenol with accuracy between 97.6-101.8% and precision ≤ 2.7%, and p-aminophenol with accuracy between 95.6-102.5% and precision ≤ 3.2%. Comparative analysis with standard HPLC-UV method revealed less than 20% difference in quantification, underscoring the effectiveness of this combined technique. Our study demonstrated the feasibility of combining chemical derivatization with HPLC-ICP-MS as a robust tool for the accurate quantification of drug-related substances, particularly those lacking elements detectable by ICP-MS alone.</p>","PeriodicalId":7802,"journal":{"name":"Analytical Sciences","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143536609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The latest developments of near-infrared fluorescent probes from NIR-I to NIR-II for bioimaging. 生物成像用近红外荧光探针从nir - 1到NIR-II的最新进展。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-02-28 DOI: 10.1007/s44211-025-00735-7

Yuzuka Kuronuma, Ryuji Watanabe, Yuki Hiruta

引用次数: 0

Solid-phase-extraction device for extracting volatile organic compounds from gaseous samples 用于从气态样品中提取挥发性有机化合物的固相萃取装置。

IF 1.8 4区化学

Analytical Sciences Pub Date : 2025-02-26 DOI: 10.1007/s44211-025-00729-5

Ikuo Ueta, Koki Nakagami, Yoshihiro Saito

引用次数: 0