Oxidation of Metals最新文献_第3页

Design of Oxidation-Resistant Alloys Using Combinatorial Approaches with Chemically Graded Materials 利用化学级配材料的组合方法设计抗氧化合金

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-28 DOI: 10.1007/s11085-024-10284-5

Sabrina Ghanes, Mikael Perrut, Enrica Epifano, Matthieu Degeiter, Thomas Vaubois, Yohan Cosquer, Daniel Monceau

{"title":"Design of Oxidation-Resistant Alloys Using Combinatorial Approaches with Chemically Graded Materials","authors":"Sabrina Ghanes, Mikael Perrut, Enrica Epifano, Matthieu Degeiter, Thomas Vaubois, Yohan Cosquer, Daniel Monceau","doi":"10.1007/s11085-024-10284-5","DOIUrl":"10.1007/s11085-024-10284-5","url":null,"abstract":"<div><p>This work introduces a new high-throughput method to characterize the oxidation behavior of chemically graded Ni-based alloys in order to feed databases destined to numerical metallurgy approaches. A Ni–wCr–3Al (w ∈ [0, 30]) chemically graded material was obtained from two homogeneous samples by a diffusion couple method at 1300 °C for 100 h. The composition range was selected in order to observe the three types of oxidation behavior identified in the reference work of Giggins and Pettit (Giggins and Pettit in Journal of The Electrochemical Society 118:1782, 1971). The excellent agreement between simulated and experimental diffusion profiles validated the experimental method used to manufacture the chemically graded material (CGM). The CGM was then oxidized at 1200 °C in air. Surface and cross-section characterization was conducted by SEM/EDS and Raman spectroscopy to identify the oxides formed on the CGM. To accelerate the Raman characterization treatment, a method linking principal component analysis and K-means unsupervised clustering algorithm was developed. It allowed for the identification of the oxide type without peak indexation issues and is well suited for CGM. These results show that results similar to well-recognized reference experiments (Giggins and Pettit in Journal of The Electrochemical Society 118:1782, 1971) can be achieved using only one CGM.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"1249 - 1262"},"PeriodicalIF":2.1,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10284-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Editorial on the Influence of Additive Manufacturing on the High-Temperature Corrosion Behaviour of Alloys 关于增材制造对合金高温腐蚀行为的影响的社论

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-27 DOI: 10.1007/s11085-024-10293-4

Laurence Latu‑Romain, Jérôme Favergeon, Bruce Pint, Daniel Monceau, Clara Desgranges, Stéphane Mathieu, Fernando Pedraza

引用次数: 0

Effect of Electrodeposited Nickel Coatings on the High Temperature Degradation and Electrical Performance of Steel SOEC Interconnects 电沉积镍涂层对钢质 SOEC 互联器高温降解和电气性能的影响

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-27 DOI: 10.1007/s11085-024-10295-2

Louis Boccaccini, Fabien Rouillard, Fernando Pedraza

{"title":"Effect of Electrodeposited Nickel Coatings on the High Temperature Degradation and Electrical Performance of Steel SOEC Interconnects","authors":"Louis Boccaccini, Fabien Rouillard, Fernando Pedraza","doi":"10.1007/s11085-024-10295-2","DOIUrl":"10.1007/s11085-024-10295-2","url":null,"abstract":"<div><p>The performance of solid oxide electrolyzer cells (SOEC) can be improved through the development of coatings applied to the surface of ferritic steel interconnects in view of mitigating chromium evaporation and reducing the growth rate of low conductive oxides in oxidizing environments. This work investigated the oxidation and area specific resistance (ASR) of two electrodeposited nickel coatings on preoxidized and non-preoxidized AISI 441 ferritic stainless steel substrates. The nickel coating effectively restricted the outward diffusion of chromium after 100 h of exposure at 700 °C in air but led to nickel/iron interdiffusion between the substrate and coating forming an iron-nickel-rich spinel on the surface, with NiO underneath and Cr<sub>2</sub>O<sub>3</sub> at the coating-substrate interface and at the coating grain boundaries. The application of a LSM ((La<sub>0.80</sub>Sr<sub>0.20</sub>)<sub>0.95</sub>MnO<sub>3−x</sub>) coating on top of the Ni electrodeposited coatings resulted in the same type of oxides but the oxidation kinetics were slower. Interdiffusion continued with the exposure at 700 °C for 2400 h resulting in the growth of a thick iron-rich oxide layer on top of Cr<sub>2</sub>O<sub>3</sub>, steadily raising the interconnect ASR to 25 mΩ cm<sup>2</sup>. The addition of a preoxidation step before the electrodeposit of nickel helped to limit iron-nickel interdiffusion, leading to the formation of a thicker NiO layer on a Cr<sub>2</sub>O<sub>3</sub> layer between substrate and coating. While the ASR was higher than without preoxidation at the beginning of the test, it stabilized at about 33 mΩ cm<sup>2</sup> after 1750 h. Despite displaying a higher electrical resistance, the coatings effectively limited the outward chromium diffusion throughout exposure compared to the bare substrate.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1395 - 1408"},"PeriodicalIF":2.1,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxidation Behavior of a Novel Nickel-Based Alloy in Air and Steam at 1273 K for the Oxygen–Hydrogen Combustion Chamber 新型镍基合金在 1273 K 氧氢燃烧室空气和蒸汽中的氧化行为

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-27 DOI: 10.1007/s11085-024-10303-5

Abdul Latif, Mitsutoshi Ueda, Masao Takeyama

{"title":"Oxidation Behavior of a Novel Nickel-Based Alloy in Air and Steam at 1273 K for the Oxygen–Hydrogen Combustion Chamber","authors":"Abdul Latif, Mitsutoshi Ueda, Masao Takeyama","doi":"10.1007/s11085-024-10303-5","DOIUrl":"10.1007/s11085-024-10303-5","url":null,"abstract":"<div><p>As part of advancing oxygen–hydrogen combustion power generation technology, a study was carried out to evaluate the oxidation behavior of a novel developed Ni–Cr–W alloy as the structural material candidate. Tungsten is utilized in the alloy as a solid solution-strengthened element and as an α<sub>2</sub>-W precipitate former. The examination involved exposing the developed alloy and commercial alloys, Hastelloy X and Nimonic 263, to air and steam environments at 1273 K. The results show a different oxidation behavior of the developed alloy. Considering the air oxidation kinetics, the performance of the developed alloy was on par with that of Hastelloy X and superior to Nimonic 263. A single outer chromia scale was established with an intergranular oxide. Whereas steam exposure resulted in the formation of outer and inner chromia scales with a deeper intergranular oxide penetration. Thicker chromia formation with a lower mass gain indicates the evaporation of chromia under a steam atmosphere.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 1 supplement","pages":"203 - 224"},"PeriodicalIF":2.1,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10303-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Bond Coating Surface Morphology on the TBC System Lifetime 粘结涂层表面形态对 TBC 系统寿命的影响

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-25 DOI: 10.1007/s11085-024-10302-6

S. Hervier, M.-M. Desagulier, D. Monceau

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Editorial on the Advanced Characterization Techniques for Studying High-Temperature Corrosion 研究高温腐蚀的先进表征技术》社论

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-24 DOI: 10.1007/s11085-024-10294-3

Laurence Latu‑Romain, Jérôme Favergeon, Bruce Pint, Daniel Monceau, Clara Desgranges, Stéphane Mathieu, Fernando Pedraza

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Editorial on Fundamentals of High-Temperature Corrosion and Protection of Materials 材料的高温腐蚀与防护基础》社论

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-23 DOI: 10.1007/s11085-024-10290-7

Daniel Monceau, Jérôme Favergeon, Bruce Pint, Clara Desgranges, Laurence Latu‑Romain, Stéphane Mathieu, Fernando Pedraza

引用次数: 0

Exploring Fission–Fusion Synergies to Accelerate Compatibility Understanding 探索裂变-聚变协同作用，加快对兼容性的理解

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-22 DOI: 10.1007/s11085-024-10300-8

B. A. Pint, M. Romedenne, C. De Lamater-Brotherton, R. Pillai

{"title":"Exploring Fission–Fusion Synergies to Accelerate Compatibility Understanding","authors":"B. A. Pint, M. Romedenne, C. De Lamater-Brotherton, R. Pillai","doi":"10.1007/s11085-024-10300-8","DOIUrl":"10.1007/s11085-024-10300-8","url":null,"abstract":"<div><p>To address the significant commercial interest in fusion energy, it will be necessary to accelerate the compatibility research associated with liquid breeders including Li, eutectic Pb–Li and LiF-BeF<sub>2</sub> (FLiBe) molten salt. Particularly for FLiBe, compatibility understanding is limited especially for fusion relevant materials such as reduced activation ferritic-martensitic steels, SiC and V alloys. The historical knowledge associated with molten salt reactors (MSRs) and recent work to commercialize MSRs can benefit fusion research. Recent experimental and modeling work has improved understanding and this knowledge can be applied to fusion relevant materials. For liquid metals (LMs), the comparisons to Li and Pb–Li are less direct but nevertheless can help guide the pathway toward commercialization. For Pb–Li, Al-rich coatings have been shown to inhibit dissolution and potentially increase operating temperatures. For commercialization, the experience with sensors and on-line cleanup can help guide future developments. Thus, it is worth considering the potential for fission-related research with LMs and molten salts to help accelerate fusion research.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1331 - 1340"},"PeriodicalIF":2.1,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxidation of a Mo-Si-B-Ti Alloy 钼-硅-铋-钛合金的氧化作用

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-22 DOI: 10.1007/s11085-024-10298-z

Longfei Liu, Liam F. Wood, Phalgun Nelaturu, Tianrui Duan, Chuan Zhang, Fan Zhang, Dan J. Thoma, John H. Perepezko

{"title":"Oxidation of a Mo-Si-B-Ti Alloy","authors":"Longfei Liu, Liam F. Wood, Phalgun Nelaturu, Tianrui Duan, Chuan Zhang, Fan Zhang, Dan J. Thoma, John H. Perepezko","doi":"10.1007/s11085-024-10298-z","DOIUrl":"10.1007/s11085-024-10298-z","url":null,"abstract":"<div><p>The oxidation of a titanium (Ti)-modified Mo-Si-B alloy designed for aerospace applications was investigated. Test samples were produced using arc melting and laser powder bed fusion (LPBF) additive manufacturing methods. To address high-temperature oxidation, a three-step coating strategy was employed, comprising a Mo precoat, Si and B co-deposition, and a conditioning step for the formation of a self-healing coating. The study evaluates the oxidation resistance of both uncoated and coated Mo-Si-B-Ti alloys at temperatures ranging from 1100 to 1300 °C. Uncoated alloys exhibited catastrophic mass loss within 10 hours at temperatures between 800 and 1300 °C. In contrast, the coated samples demonstrated minimal mass loss at 1300 °C after 50 hours, with only minor mass gain observed under cyclic thermal loading after 300 cycles. Microstructural analysis revealed distinct differences between arc-melted and LPBF samples, with the latter displaying an ultrafine dendritic microstructure. The applied coating effectively prevented oxygen diffusion into the substrate, even at elevated temperatures, showcasing its protective capabilities. During cyclic tests, the coating exhibited a self-healing mechanism, with cracks filled with borosilica contributing to prolonged environmental resistance.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1383 - 1393"},"PeriodicalIF":2.1,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Co-Electrodeposition of Ni/Co–W and Cu/Co–W Alloys on Type 445 Stainless Steel for Application in SOFC Interconnects 在 445 型不锈钢上共电泳 Ni/Co-W 和 Cu/Co-W 合金以应用于 SOFC 互联器

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-21 DOI: 10.1007/s11085-024-10296-1

Thammaporn Thublaor, Youhei Tanaka, Una Tutagawa, Watcharapon Tengprasert, Panya Wiman, Thanasak Nilsonthi, Somrerk Chandra-Ambhorn, Isao Saeki

{"title":"Co-Electrodeposition of Ni/Co–W and Cu/Co–W Alloys on Type 445 Stainless Steel for Application in SOFC Interconnects","authors":"Thammaporn Thublaor, Youhei Tanaka, Una Tutagawa, Watcharapon Tengprasert, Panya Wiman, Thanasak Nilsonthi, Somrerk Chandra-Ambhorn, Isao Saeki","doi":"10.1007/s11085-024-10296-1","DOIUrl":"10.1007/s11085-024-10296-1","url":null,"abstract":"<div><p>The objective of this study was to investigate the oxidation resistance and area specific resistance at high temperature of Ni/Co–W and Cu/Co–W electroplated type 445 stainless steels using co-electrodeposition. Coated samples were exposed to oxidation at a high temperatures 800 °C in air containing 3 vol.% water vapour for 96 h. X-ray diffraction analysis revealed that the oxidation process resulted in the formation of CoWO<sub>4</sub> and Co<sub>3</sub>O<sub>4</sub> on the Ni/Co–W sample, and CoWO<sub>4</sub>, Co<sub>3</sub>O<sub>4</sub>, CuWO<sub>4</sub> and CoCr<sub>2</sub>O<sub>4</sub> on the Cu/Co–W sample. The Ni/Co–W coated sample effectively suppressed the outward diffusion of chromium. The Cu/Co–W coated sample exhibited a higher oxidation rate than the Ni/Co–W coated sample. The oxidation kinetics of the coated samples obeyed the parabolic rate law. The Cu/Co–W coated sample exhibited a lower area specific resistance compared to the Ni/Co–W coated sample.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1409 - 1419"},"PeriodicalIF":2.1,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142193061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0