高Cu、Sn、Ni含量高强度低合金钢在板坯再加热条件下的结垢行为和表面质量

IF 2.1 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING
Georg Gaiser, Peter Presoly, Christian Bernhard, Sergiu Ilie
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引用次数: 0

摘要

如今,用电弧炉废钢生产是减少二氧化碳排放最常用的桥接技术。根据废料的质量,不可忽略的杂质元素,如铜、锡或镍被引入钢中。由于它们对氧的亲和力低于铁,在氧化过程中,它们通常在钢/水垢界面区和沿晶界富集,这可能导致质量问题。在固体钢加工过程中,氧化过程是不可避免的,因此,深入了解晶间氧化、液态金属渗入晶界等现象的发生,对不断提高产品质量至关重要。在本研究中,通过近工艺条件下的同步热分析进行了板坯再加热的氧化实验。为了清楚地说明不稳定元素在氧化过程中的作用,研究了含和不含不稳定元素的钢种。Cu和Sn未来含量的增加不影响外部氧化,但Cu和Sn的存在导致界面处液态Cu相的形成和晶界的渗透。镍的额外存在抵消了这种形成,但由于它对铁活性的巨大影响,它有利于形成粗糙的钢/鳞片界面。与Ni相比,Cu和Sn对铁的活性几乎没有影响。基于扩散模型的数值计算和著名的热化学软件FactSage的结果证实了这些影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Scaling Behavior and Surface Quality of High-Strength Low-Alloy Steels with Higher Levels on Cu, Sn, and Ni Under Slab Reheating Conditions

Nowadays the production of steel from scrap in electric arc furnaces is the most common bridging technology to reduce CO2 emissions. Depending on scrap quality, a non-negligible content of tramp elements such as Cu, Sn, or Ni is introduced into the steel. As their affinity to oxygen is lower than that of iron, they typically enrich at the steel/scale interface area and along grain boundaries during oxidation, which may result in quality problems. Oxidation processes are unavoidable in solid steel processing, and therefore, a deeper understanding of the occurring phenomena, such as intergranular oxidation and liquid metal infiltration of grain boundaries, is essential to continuously improve the product quality. In this study, oxidation experiments for slab reheating were performed by simultaneous thermal analysis under near-process conditions. For a clear statement on the role of tramp elements during oxidation, steel grades with and without tramp elements were investigated. The addition of the expected future contents of Cu and Sn does not affect external oxidation, but at the interface the presence of Cu and Sn leads to the formation of liquid Cu phases and infiltration of grain boundaries. The additional presence of Ni counteracts this formation, but due to its huge impact on iron activity it favors the formation of a rough steel/scale interface. In contrast with Ni, Cu and Sn hardly have any influence on iron activity. Numerical calculations based on a diffusion model and results of the well-known thermochemical software FactSage confirm these effects.

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来源期刊
Oxidation of Metals
Oxidation of Metals 工程技术-冶金工程
CiteScore
5.10
自引率
9.10%
发文量
47
审稿时长
2.2 months
期刊介绍: Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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