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Hydrogen Bonded Organic Frameworks Pore Differentially Loading Triazole for photocatalytic uranium reduction
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-16 DOI: 10.1039/d4cc05924g
Qiong Wu, Ying-Ao Wang, Xun Wang, Qiao-Qiao Jiang, Ya-Jie Li, Ru-Ping Liang, Jian-Ding Qiu
{"title":"Hydrogen Bonded Organic Frameworks Pore Differentially Loading Triazole for photocatalytic uranium reduction","authors":"Qiong Wu, Ying-Ao Wang, Xun Wang, Qiao-Qiao Jiang, Ya-Jie Li, Ru-Ping Liang, Jian-Ding Qiu","doi":"10.1039/d4cc05924g","DOIUrl":"https://doi.org/10.1039/d4cc05924g","url":null,"abstract":"Using temperature modulation, two distinct hydrogen bond organic frameworks HOF-C and HOF-K with different pore sizes were synthesized from the same ligands, (tris(4-(4H-1,2,4-triazole-4-yl)phenyl amine). The pore size difference prevents TRZ from entering the HOF-K while allowing TRZ to selectively insert into the larger-pored HOF-C to form HOF-C-TRZ. The donor-acceptor (D-A) structure formed in HOF-C-TRZ enhances its photoelectric response and exhibits exceptional uranium reduction under visible light irradiation. This study provides an effective strategy for pore size regulation of HOFs and opens up new ideas for the development of advanced uranium photocatalysts.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"30 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regiodivergent Formal [4+2] Cycloaddition of Nitrosoarenes with Furanyl Cyclopropane derivatives as 4π Components
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-16 DOI: 10.1039/d4cc05662k
Darío Coto, Sergio Mata, Luis A. López, Ruben Vicente
{"title":"Regiodivergent Formal [4+2] Cycloaddition of Nitrosoarenes with Furanyl Cyclopropane derivatives as 4π Components","authors":"Darío Coto, Sergio Mata, Luis A. López, Ruben Vicente","doi":"10.1039/d4cc05662k","DOIUrl":"https://doi.org/10.1039/d4cc05662k","url":null,"abstract":"Cyclopropanes are commonly used as valuable 3-carbon building blocks. Herein, we disclose a different reactivity pattern of furanyl cyclopropanes, which serve as 4-carbon component in Lewis acid-promoted [4+2] cycloadditions with nitrosoarenes to afford 1,2-oxazine derivatives. Importanly, the regioselectivity of the cycloaddition reaction can be controlled by the appropriate choice of the Lewis acid.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"1 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A ferroelectric helical polymer 一种铁电螺旋聚合物
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-16 DOI: 10.1039/d4cc05250a
Supriya Bandyopadhyay, Shubhankar Barman, Swadesh Paul, Anuja Datta, Suhrit Ghosh
{"title":"A ferroelectric helical polymer","authors":"Supriya Bandyopadhyay, Shubhankar Barman, Swadesh Paul, Anuja Datta, Suhrit Ghosh","doi":"10.1039/d4cc05250a","DOIUrl":"https://doi.org/10.1039/d4cc05250a","url":null,"abstract":"This communication introduces helical polyacetylene (P1) with an appended acceptor (A)–donor (D)–acceptor (A) conjugated chromophore as a promising ferroelectric candidate. The helical conformation of P1 leads to a highly stable chiral assembly of the appended ADA chromophores. This results in prominent ferroelectricity as evident from the superior hysteresis loop at room temperature, exhibiting a saturation polarization (<em>P</em><small><sub>S</sub></small>) value ∼2 μC cm<small><sup>−2</sup></small> and remanent polarization (<em>P</em><small><sub>r</sub></small>) value ∼1.8 μC cm<small><sup>−2</sup></small> at a low coercive field (<em>E</em><small><sub>c</sub></small>) of 5.2 kV cm<small><sup>−1</sup></small>, rarely reported before for purely organic systems.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"21 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-Free [2+2]-Photocycloaddition of Unactivated Alkenes Enabled by Continuous Flow Processing
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-16 DOI: 10.1039/d4cc06000h
Diarmuid O'Hanlon, Sharon Davin, Brian Glennon, Marcus Baumann
{"title":"Metal-Free [2+2]-Photocycloaddition of Unactivated Alkenes Enabled by Continuous Flow Processing","authors":"Diarmuid O'Hanlon, Sharon Davin, Brian Glennon, Marcus Baumann","doi":"10.1039/d4cc06000h","DOIUrl":"https://doi.org/10.1039/d4cc06000h","url":null,"abstract":"We report a continuous flow approach generating bicyclic cyclobutanes from unactivated alkenes in a metal-free manner that is inspired by the Kochi-Salomon reaction. A filtered Hg-lamp in combination with a simple flow set-up and acetone as UV light-absorbing co-solvent are crucial for this method thus showcasing attractive features for further exploitations.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"22 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Charge-dependent hierarchical self-assembling of fluorinated gold clusters 氟化金簇的电荷依赖性分层自组装
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-16 DOI: 10.1039/d4cc04786a
Sun Duhong, Katsuaki Konishi, Yuki Saito, Hayato Kanai, Yasuhiro Ishida, Kuniharu Ijiro, Hideyuki Mitomo
{"title":"Charge-dependent hierarchical self-assembling of fluorinated gold clusters","authors":"Sun Duhong, Katsuaki Konishi, Yuki Saito, Hayato Kanai, Yasuhiro Ishida, Kuniharu Ijiro, Hideyuki Mitomo","doi":"10.1039/d4cc04786a","DOIUrl":"https://doi.org/10.1039/d4cc04786a","url":null,"abstract":"Au25(SR)18 nanoclusters decorated by semi-fluorinated thiolate ligands (SFL) self-assemble hierarchically depending on the charge state of the nanocluster component; the use of anionic cluster ([Au25]–) resulted in the generation of nanofibers, whereas the neutral counterpart ([Au25]0) gave micron-sized filaments as a result of the twisting of the nanofibers.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"22 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Continuous Flow Solvent-Free and Catalyst-Free Mechanochemical Production of Rhodamine-B Dyes and its Derivatives
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-14 DOI: 10.1039/d4cc04197f
Mukesh Purohit, Tabrez Rafique Shaikh, Amol Kulkarni
{"title":"Continuous Flow Solvent-Free and Catalyst-Free Mechanochemical Production of Rhodamine-B Dyes and its Derivatives","authors":"Mukesh Purohit, Tabrez Rafique Shaikh, Amol Kulkarni","doi":"10.1039/d4cc04197f","DOIUrl":"https://doi.org/10.1039/d4cc04197f","url":null,"abstract":"In this communication, we have described a simple and efficient, catalyst free and solvent-free protocol for continuous flow synthesis of Rhodamine-b dyes developed from the 3-diethyl amino phenol and phthalic anhydride. Nearly complete conversion was achieved within 12 minutes using a jacketed single screw reactor. This method is further used for the synthesis of six derivatives with 70 - 84% yield, when compared to 85% yield from a 1-hour long batch synthesis involving a catalyst.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"22 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142820718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen production from seawater electrolysis
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-14 DOI: 10.1039/d4cc05143b
Tian-Jiao Wang, Yuliang Yuan, Wenjuan Shi, Gai Li, Peng Rao, Jing Li, Zhenye Kang, Xinlong Tian
{"title":"Hydrogen production from seawater electrolysis","authors":"Tian-Jiao Wang, Yuliang Yuan, Wenjuan Shi, Gai Li, Peng Rao, Jing Li, Zhenye Kang, Xinlong Tian","doi":"10.1039/d4cc05143b","DOIUrl":"https://doi.org/10.1039/d4cc05143b","url":null,"abstract":"The world's energy landscape is undergoing a significant transformation, driven by the urgent need to address the climate issues and growing sustainable energy demand. Hydrogen can be produced from renewable sources and may play a crucial role in the zero-carbon economy, which is regarded as a promising alternative to fossil fuels. Currently, hydrogen production via water electrolysis still relies on high-purity water, while seawater electrolysis gets benefit from the abundance of seawater, which can be particularly beneficial for water-scarce countries, and deep-sea applications, such as floating platforms or islands. However, it faces several challenges, such as the impurities in seawater, the harsh marine environment, and unpredictable costs. Ongoing researches and development efforts are focused on addressing these challenges through innovative solutions, including the design of robust electrocatalysts, the development of smart integrated structures, and the exploration of innovative coupled systems. In this review, big progresses mentioned above aim to improve the efficiency of seawater electrolysis are briefly discussed, and the challenges and prospects are provided.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"5 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142820720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pyridine oxide-decorated covalent organic framework for catalysis allylation of aromatic aldehydes with allyl(trichloro)silane
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-13 DOI: 10.1039/d4cc04977b
Jian-Cheng Wang, Ru Pan, Wen-Ting Yang, Zhi Chen, Jia-Qi Du, Jing-Lan Kan, Yu-Bin Dong
{"title":"Pyridine oxide-decorated covalent organic framework for catalysis allylation of aromatic aldehydes with allyl(trichloro)silane","authors":"Jian-Cheng Wang, Ru Pan, Wen-Ting Yang, Zhi Chen, Jia-Qi Du, Jing-Lan Kan, Yu-Bin Dong","doi":"10.1039/d4cc04977b","DOIUrl":"https://doi.org/10.1039/d4cc04977b","url":null,"abstract":"A covalent organic framework Py-O-COF, which was directly synthesized from a monomer containing pyridine oxide with its partner via imine condensation, could significantly promote the allylation of aromatic aldehydes with allyl(trichloro)silane in a heterogeneous manner.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"200 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142815507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomimetic prebiotic synthesis of homochiral peptides via a potential 5′-aa-AMP precursor
IF 4.9 2区 化学
Chemical Communications Pub Date : 2024-12-13 DOI: 10.1039/d4cc05580b
Min Zhang, Shoujun Wang, Li Zhang, Xiaofan Guo, Dingwei Gan, Dongru Sun, Yufen Zhao, Jianxi Ying
{"title":"Biomimetic prebiotic synthesis of homochiral peptides via a potential 5′-aa-AMP precursor","authors":"Min Zhang, Shoujun Wang, Li Zhang, Xiaofan Guo, Dingwei Gan, Dongru Sun, Yufen Zhao, Jianxi Ying","doi":"10.1039/d4cc05580b","DOIUrl":"https://doi.org/10.1039/d4cc05580b","url":null,"abstract":"Inspired by biosynthetic peptides, we investigate the chiral recognition properties of adenylate amidate (<em>N</em>-aa-AMP, a potential analog of 5′-aa-AMP) in prebiotic peptide formation. Our findings demonstrate that <em>N</em>-<small>L</small>-aa-AMP preferentially binds to <small>L</small>-aa, facilitating the formation of homochiral peptides, while <em>N</em>-<small>D</small>-aa-AMP shows a preference for <small>D</small>-aa, thereby achieving homochirality in peptide synthesis. Collectively, these results enhance our understanding of the evolutionary origins of homochirality on prebiotic Earth.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"14 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142815610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stabilization of fast lithium-ionic conduction phase of nanaoconfined LiBH4 for lithium metal solid-state batteries. 稳定用于锂金属固态电池的纳碳锂电池的快速锂离子传导相。
IF 4.3 2区 化学
Chemical Communications Pub Date : 2024-12-13 DOI: 10.1039/d4cc05329j
Shunqin Zeng, Kaixiang Ren, Hongfei Ding, Shendong Xu, Hai-Wen Li, Yongtao Li
{"title":"Stabilization of fast lithium-ionic conduction phase of nanaoconfined LiBH<sub>4</sub> for lithium metal solid-state batteries.","authors":"Shunqin Zeng, Kaixiang Ren, Hongfei Ding, Shendong Xu, Hai-Wen Li, Yongtao Li","doi":"10.1039/d4cc05329j","DOIUrl":"https://doi.org/10.1039/d4cc05329j","url":null,"abstract":"<p><p>The nanoconfinement of LiBH<sub>4</sub> into mesoporous Al<sub>2</sub>O<sub>3</sub> as a fast lithium-ion conductor is presented, and its high-temperature phase is retained at near-room temperature. It exhibits an excellent electrochemical stability and Li<sup>+</sup> conductivity of 3.2 × 10<sup>-4</sup> S cm<sup>-1</sup> at 75 °C, which represents an increase of nearly three orders of magnitude compared to the pristine one.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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