发布求助
文献互助 智能选刊 最新文献

Chemical Communications最新文献

筛选
英文 中文
A dual-response fluorescent probe Rh-O-QL for simultaneous monitoring NAD(P)H and pH during mitochondrial autophagy 双响应荧光探针Rh-O-QL同时监测线粒体自噬过程中NAD(P)H和pH
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-18 DOI: 10.1039/d5cc00961h
Liandi Guan, Wanting Hu, Shiyu Zhang, Yongjian Ai, Qionglin Liang
{"title":"A dual-response fluorescent probe Rh-O-QL for simultaneous monitoring NAD(P)H and pH during mitochondrial autophagy","authors":"Liandi Guan, Wanting Hu, Shiyu Zhang, Yongjian Ai, Qionglin Liang","doi":"10.1039/d5cc00961h","DOIUrl":"https://doi.org/10.1039/d5cc00961h","url":null,"abstract":"Mitochondrial autophagy is closely related to abnormal NAD(P)H and pH. Here, we synthesized a dual-response fluorescent probe with high selectivity for NAD(P)H and sensitivity for physiological pH range, for simultaneous imaging analysis of mitochondrial NAD(P)H and pH, holding potential as a novel tool for understanding mitochondria-associated diseases.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"30 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143846989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Single-Atom Fe Anchored Graphdiyne for High-Efficiency Nitrate-to-Ammonia Conversion at Ambient Conditions 单原子铁锚定石墨炔在环境条件下用于硝酸盐到氨的高效转化
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-17 DOI: 10.1039/d5cc01394a
Jiayu Yan, Lu Qi, Zhiqiang Zheng, Zhaoyang Chen, Qi Wang, Yurui Xue
{"title":"Single-Atom Fe Anchored Graphdiyne for High-Efficiency Nitrate-to-Ammonia Conversion at Ambient Conditions","authors":"Jiayu Yan, Lu Qi, Zhiqiang Zheng, Zhaoyang Chen, Qi Wang, Yurui Xue","doi":"10.1039/d5cc01394a","DOIUrl":"https://doi.org/10.1039/d5cc01394a","url":null,"abstract":"The electrocatalytic conversion of wastewater nitrate (NO3-) to ammonia (NH3) under industrial-grade current densities at ambient conditions presents a sustainable alternative to the energy-intensive Haber-Bosch process, yet remains fundamentally challenging. Here, a highly efficient NO3- to NH3 electrocatalyst with single Fe atoms dispersing on graphdiyne (GDY) is constructed through an in-situ growth method. Experimental analysis demonstrates the formation of high-density atomic active sites on GDY, ensuring the high intrinsic activity of the electrocatalyst. Besides, the newly formed sp-C~Fe chemical bonds bridged GDY and Fe atoms provides a well-defined channel for selectively and efficiently transferring electrons from the active sites to the reactants/key intermediates, allowing for the selective NO3- activation and efficient protonation. This atomic-scale electronic modulation enables exceptional nitrate reduction performance, achieving record-high Faradaic efficiency (40.17%) and ammonia yield (106.65 μmol h⁻¹ cm⁻²) while maintaining operational stability.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"9 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143846911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Systematic exploration of alkali–anion pairs for descriptor identification in OH-mediated methane coupling 系统探索碱阴离子对在oh介导的甲烷偶联中的描述符识别
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc01090j
Shintaro Yoshida, William James Movick, Keisuke Obata, Kazuhiro Takanabe
{"title":"Systematic exploration of alkali–anion pairs for descriptor identification in OH-mediated methane coupling","authors":"Shintaro Yoshida, William James Movick, Keisuke Obata, Kazuhiro Takanabe","doi":"10.1039/d5cc01090j","DOIUrl":"https://doi.org/10.1039/d5cc01090j","url":null,"abstract":"The oxidative coupling of methane (OCM) was investigated using various alkali metal salts supported on SiO2. The addition of H₂O enhances both the methane conversion rate and selectivity across all alkali metal salts, which suggests there is an OH-radical-mediated pathway that is facilitated by the surface formation of alkali peroxide. To explain the observed experimental differences, we explored the interactive energetics of alkali–anion pairs with a particular focus on the stabilization of alkali peroxide intermediates by anion species. Anion polarizability is indicative of the alkali ion's degree of freedom and positively correlated with the catalytic performance due to formation capability of catalytic alkali peroxide species. This insight highlights the critical role of the reaction of surface alkali peroxide with H₂O as a key elementary step in OCM.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"24 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Halide-mediated Ag-Zn batteries in alkaline electrolytes 碱性电解质中卤化物介导的银锌电池
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc01489a
Jiajie Shen, Wenjiao Ma, Jianhui Jin, Huijian Wang, Xiao Liang
{"title":"Halide-mediated Ag-Zn batteries in alkaline electrolytes","authors":"Jiajie Shen, Wenjiao Ma, Jianhui Jin, Huijian Wang, Xiao Liang","doi":"10.1039/d5cc01489a","DOIUrl":"https://doi.org/10.1039/d5cc01489a","url":null,"abstract":"The incorporation of bromide ions (Br–) as electrolyte additives fundamentally alters the reaction mechanism of alkaline Ag-Zn batteries, effectively suppressing the shuttle effect and mitigating cathode dissolution. Furthermore, a self-supporting polymer-based silver cathode has been engineered to accommodate volume changes during cycling, thereby minimizing capacity degradation. As a result, the halide-mediated Ag-Zn battery demonstrates exceptional cycling stability over 330 cycles, delivering a high Coulombic efficiency exceeding 99.3% with excellent capacity retention. Notably, the system achieves a high areal capacity of 2.3 mAh cm–², highlighting its potential for practical applications in high-performance rechargeable batteries.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"23 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143831988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mixed-Linker Strategy in Covalent Organic Frameworks for Enhanced Sunlight-Driven Photocatalytic Oxidation Activity and Stability 共价有机框架中的混合连接剂策略增强阳光驱动光催化氧化活性和稳定性
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc01192b
Jikuan Qiu, Xinchun Xue, Kangna Zhang, Xiaoxin Tian, Wenrui Wan, Tingting Fan, Zhiyong Li, Huiyong Wang, Yuling Zhao
{"title":"Mixed-Linker Strategy in Covalent Organic Frameworks for Enhanced Sunlight-Driven Photocatalytic Oxidation Activity and Stability","authors":"Jikuan Qiu, Xinchun Xue, Kangna Zhang, Xiaoxin Tian, Wenrui Wan, Tingting Fan, Zhiyong Li, Huiyong Wang, Yuling Zhao","doi":"10.1039/d5cc01192b","DOIUrl":"https://doi.org/10.1039/d5cc01192b","url":null,"abstract":"We present a simple mixed-linker strategy to enhance the photocatalytic oxidation activity and stability of covalent organic frameworks semiconductors. The TpTfbPa-COF, featuring an unconventional reversed AA-stacking structure with both imine and ketoamine linkages, exhibits excellent structural stability and superior photocatalytic performance compared to the fully imine-linked TfbPa-COF and the fully ketoamine-linked TpPa-COF.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"27 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A highly active sulfur based pincer ruthenium catalyst for CO2 hydrogenation 一种用于CO2加氢的高活性硫基钳形钌催化剂
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc01194a
Alexander Mondragón-Díaz, Steven P. Kelley, Nilay Hazari, Wesley H. Bernskoetter
{"title":"A highly active sulfur based pincer ruthenium catalyst for CO2 hydrogenation","authors":"Alexander Mondragón-Díaz, Steven P. Kelley, Nilay Hazari, Wesley H. Bernskoetter","doi":"10.1039/d5cc01194a","DOIUrl":"https://doi.org/10.1039/d5cc01194a","url":null,"abstract":"The synthesis of a new air-stable SPS pincer ligand that supports a Ru catalyst for CO<small><sub>2</sub></small> hydrogenation to formate is described. This rare S-donor based pincer system gives higher activity compared to related PNP supported Ru catalysts and is less dependent on Lewis acidic Li co-catalysts for achieving high turnover numbers. The SPS ligated Ru catalyst is also active for <em>N</em>-formylation of amines with CO<small><sub>2</sub></small>.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"3 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chiral sensing combined with nuclease activity assay to track Cas9 dynamics in solution: ROA and CPL study 手性传感结合核酸酶活性测定跟踪溶液中Cas9的动态：ROA和CPL研究
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc00971e
Monika Halat, Magdalena Klimek-Chodacka, Agnieszka Domagała, Grzegorz Zając, Tomasz Oleszkiewicz, Josef Kapitán, Rafal Baranski
{"title":"Chiral sensing combined with nuclease activity assay to track Cas9 dynamics in solution: ROA and CPL study","authors":"Monika Halat, Magdalena Klimek-Chodacka, Agnieszka Domagała, Grzegorz Zając, Tomasz Oleszkiewicz, Josef Kapitán, Rafal Baranski","doi":"10.1039/d5cc00971e","DOIUrl":"https://doi.org/10.1039/d5cc00971e","url":null,"abstract":"Chiroptical studies of the SpyCas9 protein are extremely rare. Nondestructive methods are needed to characterize its active ribonucleoprotein form. Using Raman optical activity (ROA) and circularly polarized luminescence (CPL), we present a new approach to detect key biomolecules involved in CRISPR-Cas technology while preserving their original nucleolytic activity.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"67 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineering space dimensional and surface chemistry of MXene-based nanocomposite photocatalysts for sustainable environmental application 可持续环境应用mxene基纳米复合光催化剂的工程空间尺寸和表面化学
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc00587f
Yan Zhang, Chuanhui Dong, Zi Ye, Hou Yang, Sheng Ye
{"title":"Engineering space dimensional and surface chemistry of MXene-based nanocomposite photocatalysts for sustainable environmental application","authors":"Yan Zhang, Chuanhui Dong, Zi Ye, Hou Yang, Sheng Ye","doi":"10.1039/d5cc00587f","DOIUrl":"https://doi.org/10.1039/d5cc00587f","url":null,"abstract":"It is very urgent to solve environmental pollution problem. MXene-based composite photocatalysts show great promise, which utilize solar energy for purification. MXenes have excellent electrical conductivity, a large surface area due to their 2D structure, and surface functional groups beneficial for photocatalysis. In this review, various synthesis methods have been developed to prepare MXenes with different properties for specific applications, such as hydrofluoric acid etching, substitutes etching and molten fluoride etching. The influence of different groups on the performance of MXene have been determined. In photocatalytic reactions, modification strategies including heterojunction construction, doping, precious metal deposition and single atom anchor have been explored to enhance the photocatalytic performance of MXene-based composites. It is found that MXenes can act as support that limits photocatalyst size, enhance reactant adsorption, and functions as cocatalyst loaded onto semiconductors to improve charge separation. Our perspectives on the key challenges and future directions of developing high-performance MXene-based composite photocatalysts for environmental application are elaborated.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"121 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A dendrite-suppressed Li composite anode decorated by lithiophilic Li-Pb alloys for stable Li metal batteries 一种稳定锂金属电池用亲锂铅合金装饰的枝晶抑制锂复合阳极
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc01302j
Jing Bai, Ziwei Zhu, Xue Liu, Sheng Liu
{"title":"A dendrite-suppressed Li composite anode decorated by lithiophilic Li-Pb alloys for stable Li metal batteries","authors":"Jing Bai, Ziwei Zhu, Xue Liu, Sheng Liu","doi":"10.1039/d5cc01302j","DOIUrl":"https://doi.org/10.1039/d5cc01302j","url":null,"abstract":"A lithium-rich lithium-lead alloy-based composite electrode, featuring Li22Pb5 microparticles dispersed in lithium metal, is fabricated by mechanical rolling to suppress lithium dendrite growth. The lithiophilic Li-Pb alloys can guide a uniform lithium plating process, resulting in impressive cycling stability of both symmetric and full cells.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"121 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties 具有发散光催化性能的亚胺键共价有机笼的结构异构体
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-15 DOI: 10.1039/d5cc00380f
Jiajia Li, Yanping Yang, Shan Shiang Shiang Hii, Xinyuan Zhu, Youfu Wang
{"title":"Structural isomers of imine-linked covalent organic cages with divergent photocatalytic properties","authors":"Jiajia Li, Yanping Yang, Shan Shiang Shiang Hii, Xinyuan Zhu, Youfu Wang","doi":"10.1039/d5cc00380f","DOIUrl":"https://doi.org/10.1039/d5cc00380f","url":null,"abstract":"The impact of linkage orientation as minor structural changes on the overall properties of covalent organic cages (COCs) has been investigated for the first time. Isomeric imine-linked donor–acceptor COCs, featuring triphenylamine as the donor and anthracene as the acceptor, TNCA and TCNA, were synthesized and exhibited significant differences in their optoelectronic properties, which in turn affect their photocatalytic performance.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"15 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143832323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信