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Regioselective terminal bromination of fluorinated oligophenylenes. 氟化低聚苯乙烯的区域选择性末端溴化。
IF 4.2 2区 化学
Chemical Communications Pub Date : 2025-10-02 DOI: 10.1039/d5cc05074j
Nour-Eddine El Alaoui, Konstantin Y Amsharov
{"title":"Regioselective terminal bromination of fluorinated oligophenylenes.","authors":"Nour-Eddine El Alaoui, Konstantin Y Amsharov","doi":"10.1039/d5cc05074j","DOIUrl":"https://doi.org/10.1039/d5cc05074j","url":null,"abstract":"<p><p>Herein, we demonstrate an unprecedentedly selective terminal bromination of fluorinated biphenylenes and oligophenylenes in the presence of excess metallic iron. The reaction can be carried out under ambient conditions at room temperature, yielding the target compounds with up to 98% yield. The high regioselectivity and scalability make this approach superior to existing methods.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145204998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chiral pool-engineered homochiral covalent organic frameworks for catalytic asymmetric synthesis of drug intermediate 催化不对称合成药物中间体的手性池工程同手性共价有机框架
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-02 DOI: 10.1039/d5cc04282h
Fei Li, Bing-Jian Yao, Jian Wang, Yi-Hao Leng, Wenbo Xu, Yu-Bin Dong
{"title":"Chiral pool-engineered homochiral covalent organic frameworks for catalytic asymmetric synthesis of drug intermediate","authors":"Fei Li, Bing-Jian Yao, Jian Wang, Yi-Hao Leng, Wenbo Xu, Yu-Bin Dong","doi":"10.1039/d5cc04282h","DOIUrl":"https://doi.org/10.1039/d5cc04282h","url":null,"abstract":"A chiral-pool strategy was employed to construct nanofiber-like cysteine-derived thiazoline COFs featuring a two-dimensional eclipsed (AA) stacking arrangement. The <strong>Cu(II)@(R)-THZTp</strong> achieved 95% yield and 93% <em>ee</em> in asymmetric Henry reactions. Integration with chitosan aerogel enabled gram-scale synthesis of <em>R</em>-salmeterol intermediate (92% yield, 93% <em>ee</em>) with excellent recyclability.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"22 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Effect of Nitrogen-doped CdIn₂S₄(Vs) and Andersontype Polyoxometalate on Enhanced Photocatalytic Hydrogen Production 氮掺杂cdin2 S₄（Vs）与anderson型多金属氧酸盐对增强光催化制氢的协同作用
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-02 DOI: 10.1039/d5cc04987c
Xiaoyu Dong, Xu Yang, Yulu Liu, Xue Zhao, Haixiu Yang, Yong Ding
{"title":"Synergistic Effect of Nitrogen-doped CdIn₂S₄(Vs) and Andersontype Polyoxometalate on Enhanced Photocatalytic Hydrogen Production","authors":"Xiaoyu Dong, Xu Yang, Yulu Liu, Xue Zhao, Haixiu Yang, Yong Ding","doi":"10.1039/d5cc04987c","DOIUrl":"https://doi.org/10.1039/d5cc04987c","url":null,"abstract":"The development of clean and sustainable energy technologies represents a critical focus in contemporary scientific research. In this study, we construct an efficient photocatalytic hydrogen evolution system using nitrogendoped, sulfur vacancy CdIn₂S₄ as the catalyst and (NH 4 ) 4 [NiMo 6 O 24 H 6 ]•5H 2 O (NiMo₆) as co-catalyst. Among all synthesized catalysts, the NiMo₆/10N-CdIn₂S₄(Vs) composite exhibits superior photocatalytic hydrogen evolution activity, achieving an exceptional production rate of 30.88 mmol•g⁻¹•h⁻¹, which is the highest activity among CdIn₂S₄-based systems. Ndoping and S-vacancies boost the light absorption and charge separation of CdIn₂S₄, while the polyoxometalate (POM) further enhances performance by facilitating electron transfer in the system, minimizing recombination of charge carriers and increasing stability of the photocatalytic system.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"5 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cobalt- and ionic liquid-functionalized covalent organic framework for cooperative catalytic CO2 cycloaddition. 协同催化CO2环加成的钴离子液体功能化共价有机骨架。
IF 4.2 2区 化学
Chemical Communications Pub Date : 2025-10-02 DOI: 10.1039/d5cc04684j
Fei Li, Jian Wang, Xiao-Kun Zhang, Bing-Jian Yao, Yu-Bin Dong
{"title":"Cobalt- and ionic liquid-functionalized covalent organic framework for cooperative catalytic CO<sub>2</sub> cycloaddition.","authors":"Fei Li, Jian Wang, Xiao-Kun Zhang, Bing-Jian Yao, Yu-Bin Dong","doi":"10.1039/d5cc04684j","DOIUrl":"https://doi.org/10.1039/d5cc04684j","url":null,"abstract":"<p><p>A nanofibrous crystalline cobalt(II)-anchored, imine-linked ionic covalent organic framework (Co-Py-COF) with a two-dimensional AA stacking structure was synthesized. This material exhibits outstanding catalytic activity for the cycloaddition of CO<sub>2</sub> under mild reaction conditions (1 atm, cocatalyst-free), attributed to the synergistic interaction between Co(II) ions and pyridinium groups.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145204948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrafast PFAS degradation using oxidant-containing microdroplets 利用含氧化剂的微滴超快降解PFAS
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc03862f
Yongqing Yang, Md Tanim-Al Hassan, Timothy Yaroshuk, Juana Perez Sanchez, Quentin A. Young, Richard N. Zare, Hao Chen
{"title":"Ultrafast PFAS degradation using oxidant-containing microdroplets","authors":"Yongqing Yang, Md Tanim-Al Hassan, Timothy Yaroshuk, Juana Perez Sanchez, Quentin A. Young, Richard N. Zare, Hao Chen","doi":"10.1039/d5cc03862f","DOIUrl":"https://doi.org/10.1039/d5cc03862f","url":null,"abstract":"Toxic per- and poly-fluoroalkyl substances (PFASs), known as “forever chemicals”, are toxic contaminants of huge environmental concerns. Existing methods for PFAS removal require a long time and high energy input to achieve high degradation efficiencies. This study reports a novel, ultrafast and effective method for degrading PFASs using the microdroplet technique. By forming microdroplets from PFAS solution spiked with oxidant such as sodium persulfate or Fenton’s reagent, a range of PFAS compounds including short-chain perfluorocarboxylic acids (PFCAs) such as PFPeA (C4F9COOH) were quickly degraded with degradation efficiency reaching 77-94%. The microdroplet reaction was completed in less than 1 ms under ambient conditions. In contrast, without oxidant, the microdroplet degradation efficiency was 10-17%. Also, incubating PFAS with the oxidant in bulk solution for 30 min resulted in &lt; 9% degradation efficiency. It appears that the PFAS degradation rate can be accelerated by over 2 million times in oxidant-containing microdroplets in comparison with the bulk solution. Based on the measured fluoride product concentrations, our result suggests that persulfate primarily facilitates PFAS degradation via the two-carbon degradation pathway, whereas Fenton’s reagent operates through the one-carbon degradation pathway. Overall, this study presents a new approach to PFAS degradation, offering valuable insights for developing effective PFAS removal strategies.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"18 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145195360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Electronic and Crystal Structure Regulation of Na2+2xFe2-x(SO4)3 via Zr Doping for High-Performance Sodium-Ion Batteries Zr掺杂对高性能钠离子电池中Na2+2xFe2-x(SO4)3的电子和晶体结构的协同调节
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc04836b
Xianbi Zhang, Shuang Xiang, Xiaobing Huang, Dan Sun, Yougen Tang, Hai-Yan Wang
{"title":"Synergistic Electronic and Crystal Structure Regulation of Na2+2xFe2-x(SO4)3 via Zr Doping for High-Performance Sodium-Ion Batteries","authors":"Xianbi Zhang, Shuang Xiang, Xiaobing Huang, Dan Sun, Yougen Tang, Hai-Yan Wang","doi":"10.1039/d5cc04836b","DOIUrl":"https://doi.org/10.1039/d5cc04836b","url":null,"abstract":"Na 2.5 Fe 1.71 Zr 0.02 (SO 4 ) 3 with a synergistically optimized electronic and crystal structure are designed for high-performance sodium ion batteries. The orbital interaction induced by Zr doping significantly improves its intrinsic conductivity. Additionally, the longer Na-O bonds after Zr doping accelerate Na + transfer kinetics. Ultimately, the Na 2.5 Fe 1.71 Zr 0.02 (SO 4 ) 3 exhibits a high specific capacity of 96.4 mAh g -1 at 0.1 C with 85% retention after 10000 cycles at 30 C.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"39 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145195356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in metal-catalyzed strategies for carbohydrate functionalization. 金属催化碳水化合物功能化策略研究进展。
IF 4.2 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc04316f
Ahmed El Rhaz, Lisa Bonin, Ameni Hadj Mohamed, Samir Messaoudi
{"title":"Advances in metal-catalyzed strategies for carbohydrate functionalization.","authors":"Ahmed El Rhaz, Lisa Bonin, Ameni Hadj Mohamed, Samir Messaoudi","doi":"10.1039/d5cc04316f","DOIUrl":"https://doi.org/10.1039/d5cc04316f","url":null,"abstract":"<p><p>Transition metal catalysis provides a versatile and powerful platform for the construction of structurally complex molecules. In recent years, its application has been successfully extended to the functionalization of carbohydrates, significantly expanding the toolbox of catalytic strategies available for sustainable synthesis. This review offers a comprehensive and up-to-date overview of recent advances in metal-catalyzed carbohydrate transformations, emphasizing key methodological innovations and their relevance to synthetic applications.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145197525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
β-Carboxyphospholes via carboxylative desilylation: luminophores with a versatile connectivity attached 通过羧化脱硅的β-羧磷孔：具有多功能连接的发光基团
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc04850h
Katharina Eichhorn, Clemens Bruhn, Rudolf Pietschnig
{"title":"β-Carboxyphospholes via carboxylative desilylation: luminophores with a versatile connectivity attached","authors":"Katharina Eichhorn, Clemens Bruhn, Rudolf Pietschnig","doi":"10.1039/d5cc04850h","DOIUrl":"https://doi.org/10.1039/d5cc04850h","url":null,"abstract":"The synthesis of a β-carboxyphospholes has been achieved via carboxylative desilylation of its β-TMS substituted analogue in CO<small><sub>2</sub></small> atmosphere. The scaffold allows facile functionalization of the title carboxylic acid including the respective acyl chloride, carboxamide, ester, anhydride compatible with bioconjugation while the integrity of the phosphole unit is maintained.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"109 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145195364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable Fabrication of δ-MnO₂/Graphene Oxide Composites from Waste Battery Graphite via In-Situ Electrochemical Exfoliation for Supercapacitors and Aqueous Zinc-Ion Batteries 超级电容器和水锌离子电池用废电池石墨原位电化学剥离制备δ- mno2 /氧化石墨烯复合材料
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc02065d
Kandavel Preethika Andal, Rangamannar Sanjay, Annamalai Senthil Kumar
{"title":"Sustainable Fabrication of δ-MnO₂/Graphene Oxide Composites from Waste Battery Graphite via In-Situ Electrochemical Exfoliation for Supercapacitors and Aqueous Zinc-Ion Batteries","authors":"Kandavel Preethika Andal, Rangamannar Sanjay, Annamalai Senthil Kumar","doi":"10.1039/d5cc02065d","DOIUrl":"https://doi.org/10.1039/d5cc02065d","url":null,"abstract":"In situ electrochemical exfoliation of recycled battery graphite in 1 M Mn²⁺ solution produced defective graphene oxide enriched with carbon-oxygen functional groups and uniformly deposited δ-MnO₂, demonstrating excellent performance in supercapacitors (1126 F g-1 by CV at v=1 mV s-1) and aqueous zinc-ion batteries (35 mA h g⁻¹ at 0.4 A g⁻¹)","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"21 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An activity-based probe library for identifying promiscuous amide hydrolases 用于鉴别混杂酰胺水解酶的活性探针文库
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-10-01 DOI: 10.1039/d5cc04162g
Chathuri Kombala, Jared Kroll, Lucas Webber, Stephen J Callister, Natalie C Sadler, Erin Bredeweg, Irlanda Medrano, Kristoffer R Brandvold, Sankarganesh Krishnamoorthy
{"title":"An activity-based probe library for identifying promiscuous amide hydrolases","authors":"Chathuri Kombala, Jared Kroll, Lucas Webber, Stephen J Callister, Natalie C Sadler, Erin Bredeweg, Irlanda Medrano, Kristoffer R Brandvold, Sankarganesh Krishnamoorthy","doi":"10.1039/d5cc04162g","DOIUrl":"https://doi.org/10.1039/d5cc04162g","url":null,"abstract":"A fluorogenic substrate library was developed to detect amide hydrolase activity in soil-derived chitin-degrading bacteria. Hit compounds were converted into pull-down probes for chemoproteomic enrichment, identifying previously unannotated proteins now linked to amide hydrolysis. This approach enables discovery of novel amide hydrolases with potential applications in environment, biomanufacturing, and medicine.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"31 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145195354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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