{"title":"Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions.","authors":"Haokun Wang, Sijie Huang, Shik Chi Edman Tsang","doi":"10.1039/d4cc05471g","DOIUrl":"https://doi.org/10.1039/d4cc05471g","url":null,"abstract":"<p><p>The large-scale production and inadequate disposal of polyolefin (PO) plastics pose significant environmental challenges. Traditional recycling methods are energy-intensive and often ineffective, prompting a need for more sustainable approaches. In recent years, catalytic upcycling under mild conditions has emerged as a promising strategy to transform PO plastics into valuable products. Co-reactants such as hydrogen, short-chain alkanes or alkenes, oxygen, and CO<sub>2</sub> play a crucial role in driving these transformations, influencing reaction mechanisms and broadening the range of possible products. This review categorizes recent advancements in PO plastic upcycling based on the type of co-reactant employed and compares these with direct, co-reactant-free processes. Despite these advances, challenges remain in improving catalytic stability, product selectivity, and overcoming diffusion limitations in viscous plastic feedstocks. This review underscores the catalytic chemistry underpinning the development of efficient PO plastic upcycling processes with co-reactants, offering insights into future directions for sustainable plastic chemical management.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Supratim Chakraborty, Aleksander Gorski, Oksana Danylyuk, Katarzyna Niemirowicz-Laskowska, Halina Car, Michał Michalak
{"title":"NHC-Au-Xanthate Complexes","authors":"Supratim Chakraborty, Aleksander Gorski, Oksana Danylyuk, Katarzyna Niemirowicz-Laskowska, Halina Car, Michał Michalak","doi":"10.1039/d4cc05193a","DOIUrl":"https://doi.org/10.1039/d4cc05193a","url":null,"abstract":"We report the synthesis, isolation, and comprehensive characterization of N-heterocyclic carbene gold xanthate (NHC-Au- X, X - xanthate) complexes. These easily accessible complexes demonstrate significant versatility as photocatalysts, facilitating [2+2]-cycloadditions, and as π-catalysts in the intramolecular hydroxylation of allenes and hydrohydrazination of alkynes.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"138 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Selective Non-Enzymatic Synthesis of Ribose Simply from Formaldehyde, Metal Salts and Clays","authors":"Hao-Xing Xu, Ze-Run Zhao, Xiao Wang","doi":"10.1039/d4cc03981e","DOIUrl":"https://doi.org/10.1039/d4cc03981e","url":null,"abstract":"This study demonstrated that metal-doped-clay (MDC) can be a selective platform for ribose produced from formaldehyde under abiotic conditions. Ribose exhibits superior retention compared with other carbohydrates on naturally occurring minerals on the early Earth in the presence of divalent cations. This finding offers an insight into the necessity of ribose’s emergence as the backbone of extant RNA.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"41 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Concave Fe<sub>2</sub>O<sub>3</sub> nanocubes with high-index facets for ammonia production from electrocatalytic nitrate reduction.","authors":"Yuwei Zhang, Mingyang Xu, Jiaxin Zhou, Fen Yao, Hanfeng Liang","doi":"10.1039/d4cc05101g","DOIUrl":"https://doi.org/10.1039/d4cc05101g","url":null,"abstract":"<p><p>An iron oxide catalyst with high-index (13-44) and (12-38) facets achieves a high faradaic efficiency of 96.54% and a production rate of 1.13 mmol h<sup>-1</sup> cm<sup>-2</sup> towards electrocatalytic nitrate reduction to ammonia at 250 mA cm<sup>-2</sup>.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Garik G Martirosyan, Astghik A Hovhannisyan, Alexei V Iretskii, Peter C Ford
{"title":"Reduction of iron porphyrin nitrate to the iron nitrosyl by H<sub>2</sub>S/thiol. studies in sublimed layers.","authors":"Garik G Martirosyan, Astghik A Hovhannisyan, Alexei V Iretskii, Peter C Ford","doi":"10.1039/d4cc06229a","DOIUrl":"https://doi.org/10.1039/d4cc06229a","url":null,"abstract":"<p><p>Hemes play key roles in enzymatic production of the mammalian gasotransmitter NO by nitric oxide synthase as well as in conversion from inorganic nitrite. In the present study, we report a hitherto unknown pathway of nitrosyl formation <i>via</i> thiol reduction of a iron porphyrin nitrate complex in the solid state.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ferric nitrene-promoted anti-Markovnikov ring-opening of epoxides and nucleophilic functionalization of benzylic C-H bonds under photo-irradiation.","authors":"Ming Hou, Mengjie Jia, Rui Qi, Zhide Zhang, Linli He, Tianwen Bai, Chen Bao, Guanyinsheng Qiu","doi":"10.1039/d4cc04236k","DOIUrl":"https://doi.org/10.1039/d4cc04236k","url":null,"abstract":"<p><p>This paper describes a ferric nitrene/photoredox dual-catalyzed anti-Markovnikov ring-opening of epoxides under neutral conditions for providing α-substituted acetophenones. A DFT-based calculation supported the reaction regioselectivity. The catalytic system could also be applied to the formation of C-O and C-N bonds <i>via</i> nucleophilic functionalization of benzylic C-H bonds.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Viktoria Velichko, Davide Moi, Francesco Soddu, Roberto Scipione, Enrico Podda, Alberto Luridiana, Dario Cambie, Francesco Secci, Maria Chiara Cabua
{"title":"Two-step continuous flow-driven synthesis of 1,1-cyclopropane aminoketones.","authors":"Viktoria Velichko, Davide Moi, Francesco Soddu, Roberto Scipione, Enrico Podda, Alberto Luridiana, Dario Cambie, Francesco Secci, Maria Chiara Cabua","doi":"10.1039/d4cc04089a","DOIUrl":"https://doi.org/10.1039/d4cc04089a","url":null,"abstract":"<p><p>The continuous flow telescoped synthesis of 1,1-cyclopropane aminoketones was achieved by optimizing the photocyclization of 1,2-diketones to 2-hydroxycylobutanones (HCBs) and their reaction with aryl- and alkylamines, <i>via</i> tandem condensation C4-C3-ring contraction reaction. With the achieved operational conditions, we were able to obtain a library of cyclopropylamines with good chemical yields, high productivity, and short residence times.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Non-toxic core-shell nanowires for <i>in vitro</i> extracellular vesicle scavenging.","authors":"Piyawan Paisrisarn, Kunanon Chattrairat, Yuta Nakamura, Kazuki Nagashima, Takeshi Yanagida, Yoshinobu Baba, Takao Yasui","doi":"10.1039/d4cc03767g","DOIUrl":"https://doi.org/10.1039/d4cc03767g","url":null,"abstract":"<p><p>Extracellular vesicles (EVs) from cancer cells promote abnormal growth in normal cells, potentially leading to cancer proliferation. We developed a nanowire-based EV-elimination device that efficiently eliminated EVs without toxicity. This method restored normal growth in mammary gland cells cultured with breast adenocarcinoma-derived EVs containing medium treated with the device.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tobias Theiss, Stefan Buss, Iván Maisuls, Theresa Block, Jutta Kösters, Rainer Pöttgen, Cristian A Strassert
{"title":"Heterobimetallic contacts in statistical co-crystals of homoleptic coordination compounds with ligand-encoded H⋯F bonds: structure, photophysics and mechano-responsive properties.","authors":"Tobias Theiss, Stefan Buss, Iván Maisuls, Theresa Block, Jutta Kösters, Rainer Pöttgen, Cristian A Strassert","doi":"10.1039/d4cc03784g","DOIUrl":"https://doi.org/10.1039/d4cc03784g","url":null,"abstract":"<p><p>In this work, the structural and photophysical characterization of statistical co-crystals based on two homoleptic Pt(II) and Pd(II) complexes as well as their mechano-responsive properties are reported. Ligand-dominated H⋯F bonds, which reinforce metal-metal interactions in the crystalline state, support emission from <sup>3</sup>MMLCT states. All co-crystals show a distinct red-shift upon grinding, showcasing their inherent mechano-responsive characteristics stemming from (hetero-)bimetallic contacts.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Discrimination of nucleoside phosphates using principal component analysis of spectral changes in a single europium complex","authors":"Leila R Hill, Elizabeth J New, Stephen Faulkner","doi":"10.1039/d4cc05815a","DOIUrl":"https://doi.org/10.1039/d4cc05815a","url":null,"abstract":"Here we present the first use of principal component analysis of the full spectrum of a single europium complex to differentiate between structurally-similar analytes. We demonstrate that it can be used to distinguish between the nucleoside phosphate guests AMP, ADP, and ATP.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"97 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}