通过羧化脱硅的β-羧磷孔：具有多功能连接的发光基团

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-01 DOI:10.1039/d5cc04850h

Katharina Eichhorn, Clemens Bruhn, Rudolf Pietschnig

引用次数: 0

摘要

通过在CO2气氛中对β-TMS取代类似物进行羧化脱硅，合成了β-羧磷孔。支架允许标题羧酸的容易功能化，包括与生物偶联相容的酰基氯、羧酰胺、酯、酸酐，同时保持磷酸单元的完整性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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β-Carboxyphospholes via carboxylative desilylation: luminophores with a versatile connectivity attached

The synthesis of a β-carboxyphospholes has been achieved via carboxylative desilylation of its β-TMS substituted analogue in CO₂ atmosphere. The scaffold allows facile functionalization of the title carboxylic acid including the respective acyl chloride, carboxamide, ester, anhydride compatible with bioconjugation while the integrity of the phosphole unit is maintained.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.