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Correction: Ligand-free 99mTc-polyurea dendrimer complexes: nanoradiotheranostics targeting ovarian cancer 更正：无配体 99mTc 聚脲树枝状聚合物复合物：针对卵巢癌的纳米放射治疗技术
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc90093j
Adriana Cruz, Rita F. Pires, Paula Raposinho, Célia Fernandes, António Paulo, Vasco D.B. Bonifácio
{"title":"Correction: Ligand-free 99mTc-polyurea dendrimer complexes: nanoradiotheranostics targeting ovarian cancer","authors":"Adriana Cruz, Rita F. Pires, Paula Raposinho, Célia Fernandes, António Paulo, Vasco D.B. Bonifácio","doi":"10.1039/d5cc90093j","DOIUrl":"https://doi.org/10.1039/d5cc90093j","url":null,"abstract":"Correction for ‘Ligand-free <small><sup>99m</sup></small>Tc-polyurea dendrimer complexes: nanoradiotheranostics targeting ovarian cancer’ by Adriana Cruz <em>et al.</em>, <em>Chem. Commun.</em>, 2024, <strong>60</strong>, 7874–7877, https://doi.org/10.1039/D4CC00892H.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"17 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxidative Addition of Diaryldichalcogenides to the Diferrocenylphosphenium Ion: Synthesis, Structure and Organocatalytic Activity 二氮基二硫族化合物与二茂铁基磷离子的氧化加成：合成、结构和有机催化活性
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01555c
Corina Stoian, Nils Schmidt, Thomas Kuzmera, Pim Puylaert, Enno Lork, Boris J. Nachtsheim, Emanuel Hupf, Jens Beckmann
{"title":"Oxidative Addition of Diaryldichalcogenides to the Diferrocenylphosphenium Ion: Synthesis, Structure and Organocatalytic Activity","authors":"Corina Stoian, Nils Schmidt, Thomas Kuzmera, Pim Puylaert, Enno Lork, Boris J. Nachtsheim, Emanuel Hupf, Jens Beckmann","doi":"10.1039/d5cc01555c","DOIUrl":"https://doi.org/10.1039/d5cc01555c","url":null,"abstract":"The reaction of the diferrocenylphosphenium ion, [Fc2P]+ (Fc = ferrocenyl) with PhEEPh (E = S, Se, Te), FcSeSeFc and dibenzo[1,2]diselenine (biphenSe2) gave rise to the formation of the bis(arylchalcogenido) diferrocenylphosphonium ions [Fc2P(SPh)2]+, [Fc2P(SePh)2]+, [Fc2P(TePh)2]+, [Fc2P(SeFc)2]+ and [Fc2P(Se2biphen)]+, which were utilised for the chalcogen bond (ChB)-mediated Michael addition of 1-methylindole and trans-β-crotonophenone.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"69 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A hydrophilic porphyrin-based COF to reduce CO2 and nitrite in situ for photoelectrochemical catalysis synthesis of urea 以亲水性卟啉为基础的COF，原位还原CO2和亚硝酸盐，用于光化学催化合成尿素
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc00846h
Zijian Zeng, Shaojun Shan, Ruizhi Peng, Zhihong Yan, Yi Liu
{"title":"A hydrophilic porphyrin-based COF to reduce CO2 and nitrite in situ for photoelectrochemical catalysis synthesis of urea","authors":"Zijian Zeng, Shaojun Shan, Ruizhi Peng, Zhihong Yan, Yi Liu","doi":"10.1039/d5cc00846h","DOIUrl":"https://doi.org/10.1039/d5cc00846h","url":null,"abstract":"Porphyrin-based photocatalysts exhibit superior photoelectronic properties, photothermal stability, and structural diversity. A hydrophilic covalent organic framework (COF_PP-DRS) was synthesized by linking aldolized tetrabromophenylporphyrin (PP) with dopamine(DA) and resveratrol(Res) copolymers via Schiff base reactions. It unfolded good CO2 reduction reaction (CO2RR) performance under photoelectrocatalytic (PEC) conditions, achieving a 25% higher catalytic efficiency than PP. This photocatalyst enabled urea (CO(NH2)2) synthesis from CO2 and NO2− while co-producing NH3, HCOOH, and CO. It exhibited broad pH tolerance (pH 4–10). Infrared data revealed that NO2− and CO2 adsorbed on the catalyst surface, formed *NO2 and *OCO intermediates, respectively. Sequential hydrogenation and dehydration steps yielded *NH and *CO, which coupled in situ to form CO(NH2)2. This work present a new COFs material for a green way to photoelectrocatalytic urea synthesis.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"33 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic optimization of MR-TADF materials via a rigid skeleton and charge delocalization for enhanced photoluminescence and electroluminescence performance 通过刚性骨架和电荷涣散协同优化 MR-TADF 材料，提高光致发光和电致发光性能
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01299f
Jun-Yi Wang, Hao-Ran Zheng, Xunwen Xiao, Xu-Feng Luo
{"title":"Synergistic optimization of MR-TADF materials via a rigid skeleton and charge delocalization for enhanced photoluminescence and electroluminescence performance","authors":"Jun-Yi Wang, Hao-Ran Zheng, Xunwen Xiao, Xu-Feng Luo","doi":"10.1039/d5cc01299f","DOIUrl":"https://doi.org/10.1039/d5cc01299f","url":null,"abstract":"Synergistic rigidification and charge delocalization enable ultra-narrowband MR-TADF emitters. CzYCzPhBN and OYCzPhBN exhibit PL FWHMs of 19 nm and 20 nm in toluene, with sensitized OLEDs achieving EQEs of 35.0% and 10.8% and EL FWHMs of 23 nm and 25 nm, respectively.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"102 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrastable germanium oxide induced self-crystallization of CsPbBr3@glass for white light-emitting devices and wide color gamut backlight displays 超稳定氧化锗诱导CsPbBr3@glass自结晶，用于白光发光器件和宽色域背光显示器
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01648g
Enrou Mei, Yanling Lin, Wenying Zhu, Xiaojuan Liang, Weidong Xiang
{"title":"Ultrastable germanium oxide induced self-crystallization of CsPbBr3@glass for white light-emitting devices and wide color gamut backlight displays","authors":"Enrou Mei, Yanling Lin, Wenying Zhu, Xiaojuan Liang, Weidong Xiang","doi":"10.1039/d5cc01648g","DOIUrl":"https://doi.org/10.1039/d5cc01648g","url":null,"abstract":"The GeO<small><sub>2</sub></small> additive has a ‘network breaking’ effect on the network structure of silicate glass, which promotes the <em>in situ</em> nucleation/growth of PNCs in the glass. This effect is beneficial for reducing surface defects, and the prepared CsPbBr<small><sub>3</sub></small>@glass has a PLQY of up to 90%.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoenzymatically-Induced Asymmetric Hydroarylation of Alkenes with (Hetero)aryl Halides 光酶诱导烯烃与（杂）芳基卤化物的不对称氢芳基化反应
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc00617a
Corey L Jones, Alandra Quinn, Xiaochun Alex Wang, Jason K. Smith, Jeffrey Casavant, Simon Berritt, Thomas Knauber, Carlos Martinez, Jovan Livada, Scott P. France, Paul Richardson, Roger Howard, Hatice Gizem Yayla
{"title":"Photoenzymatically-Induced Asymmetric Hydroarylation of Alkenes with (Hetero)aryl Halides","authors":"Corey L Jones, Alandra Quinn, Xiaochun Alex Wang, Jason K. Smith, Jeffrey Casavant, Simon Berritt, Thomas Knauber, Carlos Martinez, Jovan Livada, Scott P. France, Paul Richardson, Roger Howard, Hatice Gizem Yayla","doi":"10.1039/d5cc00617a","DOIUrl":"https://doi.org/10.1039/d5cc00617a","url":null,"abstract":"A set of stereocomplementary ene-reductase enzymes are described which, when induced by light and aided by an exogenous photocatalyst, catalyze the coupling of (hetero)aryl halides and alkenes in an asymmetric intermolecular hydroarylation process. Thus, carbon scaffolds containing C(<em>sp</em><small><sup>2</sup></small>)-C(<em>sp</em><small><sup>3</sup></small>) bonds are synthesized enzymatically from simple precursors in excellent enantiomeric excess. Furthermore, an intramolecular mode is presented with improved yield.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"1 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hematite Photoanode for Efficient Photoelectrochemical Water Splitting: Recent advances and outlook 赤铁矿光阳极高效光电化学水分解研究进展与展望
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01630d
Ke Liang, Jing Yang, Maoxuan Ye, Yuanming Zhang, Youn Jeong Jang, Hemin Zhang
{"title":"Hematite Photoanode for Efficient Photoelectrochemical Water Splitting: Recent advances and outlook","authors":"Ke Liang, Jing Yang, Maoxuan Ye, Yuanming Zhang, Youn Jeong Jang, Hemin Zhang","doi":"10.1039/d5cc01630d","DOIUrl":"https://doi.org/10.1039/d5cc01630d","url":null,"abstract":"Due to high abundance, non-toxicity, and moderate bandgap, Hematite (α-Fe<small><sub>2</sub></small>O<small><sub>3</sub></small>) photoanodes have always been a research hotspot in photoelectrochemical (PEC) water splitting. However, the performance is severely limited by low carrier mobility, short hole diffusion length, and slow oxygen evolution reaction kinetics. In this review, we discuss recent advancements of hematite photoanodes by promoting water oxidation reaction on the surface, enhancing charge separation and transport in the bulk, and paralleling multi-stacked photoelectrodes. The surface reaction kinetics of hematite photoanodes could be improved by surface hole storage layer, surface-loaded cocatalyst, and surface post-treatment. The charge separation and transport in the bulk could be enhanced by dual element doping and heterojunction/homojunction constructing. In particular, an innovative parallel multi-stacked hematite photoanodes has made a significant breakthrough of photocurrent density, achieving the approximate theoretical value of 10 mA cm<small><sup>‒2</sup></small> at 1.23 V<small><sub>RHE</sub></small> under 100 mW cm<small><sup>‒2</sup></small> solar irradiation. Besides, the typical methods of enhancing light absorption and accelerating charge transport are discussed, especially for element doping and hetero-/homojunction.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing Visible Light for Metal-Free Trifluoromethylation/Cyclization of Unactivated Alkenes 利用可见光进行非活化烯烃的无金属三氟甲基化/环化
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01822f
Zhiping Yin, Xiaowen Qin, Chenwei Liu, Weiheng Yuan, Heng Li, Shuhui Sun, Tiefeng Xu
{"title":"Harnessing Visible Light for Metal-Free Trifluoromethylation/Cyclization of Unactivated Alkenes","authors":"Zhiping Yin, Xiaowen Qin, Chenwei Liu, Weiheng Yuan, Heng Li, Shuhui Sun, Tiefeng Xu","doi":"10.1039/d5cc01822f","DOIUrl":"https://doi.org/10.1039/d5cc01822f","url":null,"abstract":"Visible light-driven radical trifluoromethylation/cyclization of unactivated alkenes offers a sustainable alternative to conventional methods for constructing chroman-4-one and related heterocyclic scaffolds. Herein, we report a metal-free photocatalytic system utilizing Rhodamine B as an organic photocatalyst and Togni II reagent as a trifluoromethyl source. This mild protocol enables efficient intramolecular tandem cyclization, affording diverse chroman-4-ones, dihydroquinolin-4-ones, and 1-indanones (24–69% yields) with broad functional group tolerance. The operational simplicity and avoidance of transition metals highlight the synthetic utility of this approach.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"305 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coordination-Assembly of a Redox-Active Pd6L3 Cage for Aerobic C(sp3)–H Bond Photooxidation of Aromatic Cyclic Ethers 芳香环醚需氧C(sp3) -H键光氧化活性Pd6L3笼的配位组装
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01997d
Yu-Hang Hu, Fan Yin, Shun-Xing Hong, Lipeng Zhou, Ke-Han Tang, Ying-Mei Zhong, Chen-Chen Li, Li-Xuan Cai, Qing-Fu Sun
{"title":"Coordination-Assembly of a Redox-Active Pd6L3 Cage for Aerobic C(sp3)–H Bond Photooxidation of Aromatic Cyclic Ethers","authors":"Yu-Hang Hu, Fan Yin, Shun-Xing Hong, Lipeng Zhou, Ke-Han Tang, Ying-Mei Zhong, Chen-Chen Li, Li-Xuan Cai, Qing-Fu Sun","doi":"10.1039/d5cc01997d","DOIUrl":"https://doi.org/10.1039/d5cc01997d","url":null,"abstract":"A redox-active Pd<small><sub>6</sub></small>L<small><sub>3</sub></small> cage with a large lantern-shaped cavity has been synthesized and characterised by NMR, ESI-TOF-MS and X-ray diffraction analysis, which shows exceptional catalytic activity in the selective aerobic C–H photooxidation of aromatic cyclic ethers under mild conditions.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"24 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acyl Migrations Sensitive to Supramolecular Encapsulation 对超分子封装敏感的酰基迁移
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-04-25 DOI: 10.1039/d5cc01417d
Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin
{"title":"Acyl Migrations Sensitive to Supramolecular Encapsulation","authors":"Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin","doi":"10.1039/d5cc01417d","DOIUrl":"https://doi.org/10.1039/d5cc01417d","url":null,"abstract":"Four isomeric resorcin[4]arene tetrabenzoates interconvert via reversible, base-catalysed acyl migrations. Extraction of solid Me4N+I− into a chloroform solution of the isomers gradually shifts the equilibria towards the C2V-symmetric component due to the formation of highly stable hydrogen-bonded molecular capsules.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"42 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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